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By T. Kerr, C. Mattich, J. Wilson

"In refractory gold concentrates, gold is occluded in sulphide minerals preventing efficient cyanide leaching. Hence, roasting is used to oxidize sulphur and organic carbon, the latter being necessary to minimize recovery loss through the preg-robbing effect. In 2009, Outotec commissioned the circulating fluidized bed roaster at Syama gold mine in Mali. Since 2013 Resolute and Outotec have been implementing improvements to the roaster performance with the capacity increasing from 8000 t/month in 2013 to above 13,000 t/month in 2016, while achieving a residual sulphide sulphur and organic carbon contents of below 0.1 wt.% and 0.4 wt.%, respectively. Thus a gold recovery in the CIL of above 90% is attained. In 2016, Outotec audited the Syama roaster. The analysis resulted in the Low Carbon Roaster (LCR) upgrade concept which (i) allows re-processing of calcine dust from the spray cooler and ESP after pelletization and (ii) allows the roasting of a further fine-organic carbon rich feed, i.e. de-slime circuit tailings. The LCR upgrade aims to reduce organic carbon to <0.2 wt.% and increase roaster-leaching gold recovery by >3%. Project development included extensive testwork. The LCR process is expected to become operational during FY 2019.INTRODUCTION Double refractory sulphide ores exhibit the characteristics of gold locked within pyrite grains, in the presence of preg-robbing natural (organic) carbon. Hence, to achieve high recovery during subsequent processing steps, i.e. cyanide leaching, oxidation of sulphide sulphur is required, producing a porous calcine by way of a roasting step. This allows for the gold contained within the pyrite grains to be accessible during cyanide leaching. Furthermore, it is necessary to oxidize the organic carbon. Oxidizing the organic carbon is essential as gold recovery loss occurs as a result of gold-cyanide complexes being adsorbed on organic carbon, this phenomenon is termed as preg-robbing (Miller et al., 2016). The gold absorbed on the organic carbon is lost, reporting to the tailings stream. Hence, the aforementioned oxidation of sulphide sulphur and organic carbon is the process goal. Nonetheless, the latter must occur at a controlled temperature which is concentrate/ ore specific, since the pores of the produced calcine should not sinter, as this makes the gold contained in the calcine less accessible during leaching, leading to gold recovery loss. The tight temperature control requirement is a decisive factor in the choice of a Circulating Fluidized Bed (CFB) as the roasting reactor, due to the excellent mixing characteristics of the CFB which results in temperature homogeneity of (+/-10°C). Roasting of double refractory ores, as described above, can be included in the flowsheet after comminution and grinding, a process termed as whole ore roasting, or by including a flotation circuit termed as concentrate roasting. Roasting the flotation concentrate results in less solid flow, increased sulphide sulphur grade and organic carbon content resulting in a higher heating value and higher gold content. A typical composition of the Syama ore and concentrate is given in Table 1. Ore average values presented correspond to the period 2015, while concentrate values are typical for the flotation performance throughout the period 2012–2015."

Jan 1, 2017

By S. Renslow, G. Wang, L. R. Moore, Y. Xiong, J. Gu

"Clays are known to contribute to a wide range of mineral processing challenges. These challenges can haunt a plant from the pit, through the beneficiation plant and even to the tailings pond and process water. Each step that the clay is present potentially experiences significant and costly impacts to the process efficiencies. The effect of clay minerals on the performance of phosphate flotation was investigated. The investigation led to an understanding of the movement of clay through the beneficiation plant, the impact on reagent usage, and the overall flotation performance. INTRODUCTION With the decline in mineral feed grades, mineral processing will continue to face challenges. One significant challenge would be obtaining high recoveries of industry specified quality mineral concentrates with lower quality raw minerals. Other challenges may be the handling of the excess tails and process water being produced to maintain a mill’s production volumes. For example, increased levels of clay have been, and will continue to be, a topic of concern for many mines. Some of these concerns include environmental regulations associated with water storage and discharge, as well as beneficiation. Gonglun Chen reported that clays produced in the phosphate industry are generally colloidal and fine (90% < 45 µm) (Chen, 2006). As such, these clays can take 20-30 years to settle, in the absence of polymeric assistance. The settling of these clays is essential as an accidental discharge can lead to substantial impacts to the wildlife and ecosystem. The Environmental Protection Agency (EPA) has referenced cases where the discharge of water can result in fines in the tens of millions of dollars, and at times causing the processing plants shut down, depending on the volume and quality of this discharged water (EPA, 1997). The turbidity discharge criteria will vary from state to state. Florida’s Department of Environmental Protection has listed a turbidity maximum of 29 NTUs, or 60 mg/L total suspended solids, above the natural background condition (Florida Department of Environmental Protection, 2016). A lot of the literature has been focused on the impact of high levels of clay (>10%) on mineral processing. Farrokhpay has reported the significant impact of clay minerals on froth stability in copper flotation (Farrokhpay, 2012). He reported that clays can form a hydrophobic slime coating on the surface of bubbles, which can yield an increase in froth stability. Clay concentrations as low as 5% can have significant impacts on the rheological properties or slurry viscosities. Increased slurry viscosities can lead to either elevated pumping/processing energies being required, decrease in flotation efficiencies due to a decrease in bubble mobility through the pulp, or decreased throughput to manage these viscosities (Tu, 2005; Farrokhpay, 2013; Burdukova, 2014)."

Jan 1, 2017

By Songlin Ye, Frank Su

"Recycling valuable metals from waste streams has become increasingly important to the mining and smelting industry in China due to resource depletion and environmental concerns. Predicated on multiple large scale metal recovery operations designed by BQE Water at active mines in the Jiangxi Province of China, this paper presents a case study demonstrating recovery of zinc and copper from the waste stream at a major gold smelter in the Shandong Province of China. One of the issues facing the smelter is the lack of a cost-effective and robust process to recover zinc from the acidic process waste stream. As such, significant amounts of zinc-containing wastewater are neutralized with lime, resulting in not only the loss of zinc metal but also the generation of large volumes of sludge. In the case study, a sulphide precipitation process is chosen to selectively recover zinc and copper from the wastewater, in the form of commercial grade metal concentrates that can be sold as regular concentrates at the going market price. In the current project phase, over 2,500 tonnes of zinc metal and 40 tonnes of copper metal can be recovered on an annual basis. This not only generates revenue to offset waste treatment costs, but also eliminates significant amounts of sludge that would otherwise require storing and further disposal if the metals are not recovered.Introduction / Background With resource depletion becoming a global concern and environmental regulations becoming increasingly strict, companies in the mining and smelting industry are actively seeking technologies to maximize resource recovery and provide concurrent minimization of waste residue production from operational activities. Mining and smelting companies have typically used lime neutralization as the primary method to reduce metal concentrations from mine waters prior to reuse or discharge to the environment. However, this process creates large volumes of metal laden sludge with long-term liabilities in the form of ongoing storage and management (Zinck et al 1997). Recovering metals of value from mine water not only reduces sludge volumes and the costs of associated liabilities, it produces a commercial grade metal concentrate that can be sold to generate revenues to offset treatment costs. ChemSulphide® is a sulphide precipitation process developed by BQE Water that has been successfully applied at mine sites in the Jiangxi Province of China to remove and recover copper from acid mine drainage. The success of these copper recovery water treatment plants demonstrates both the economic and environmental benefits of recovering residual metals from mine water and provides reference for the copper and zinc recovery project at a gold smelter in the Shandong Province that is the subject of this case study."

Jan 1, 2017

By W. V. Liu, D. Omane, H. Yu, Y. Pourrahimian

"A large-scale wildfire had broken out at Fort McMurray in Alberta, Canada during May 2016. Many oil sands mining activities were affected due to the wildfire and the associated ash emissions. In particular, ash emission generated from the fire outbreak is a huge problem during the post-fire cleanup. These emissions pose a severe health hazard to workers, environment, and global climate. The ashes emitted into the atmosphere are caused by either human activities or climate conditions. The objective of this research is to assess the effect of three different ash dust suppressants, namely water, #1 surfactants, and #2 polymers at various volumetric concentrations on ashes samples to prevent propagation of fine solid emissions into the atmosphere. It is found that both #1 surfactants solution and #2 polymers solution are effective in retaining fugitive ash dust generated from the ashes. Volumetric concentration efficiency of 0.05% of #1 surfactant and 5% of #2 polymers in 500 ml of water have been proven to provide ash dust retention efficiency greater than 99% after the spraying of these suppressants. It is also found that both #1 surfactants solution and #2 polymers solution maintain an ash dust retention efficiency higher than that of the use of only water. This confirms the merit of using chemical dust suppressants on fugitive ash dust for a longer period, which is proven by the 72-hour data from this experiment. This study gives a general view of how effective chemical suppressants on fugitive ash emissions work. INTRODUCTION On May 1st, 2016, a large-scale wildfire gutted Fort McMurray, Alberta, Canada. Many oil sands mining activities were affected due to the wildfire and the associated ash emission. Due to the wildfire, some of the biggest oil sands companies in Fort McMurray such as Royal Dutch Shell and Suncor Energy shut down their oil production, at 255,000 and 350,000 barrels per day respectively [1]. Syncrude Canada Ltd scaled down its normal production capacity level of 350,000 barrels per day [1]. This generated an estimated loss of about 1.1 million barrels of oil production per day, constituting a 30% reduction in the Canadian daily oil production, crippling the economy [2]. This loss in production by the companies translated into 0.33 % of the Alberta GDP in 2016 constituting a loss of $985 million and 0.06 % of the entire Canadian economy [3]. In 2017, it is estimated that the rebuilding and reclamation of the affected areas in Fort McMurray will add $ 1.3 billion in GDP to Alberta’s economy [3]. A population of over 90,000 people was evacuated from the location and its surroundings for health and safety reasons [4]. The fire destroyed about 2,400 structures and over 500,000 hectares of forest vegetation in Fort McMurray, leaving an estimated 232,000 tonne of post-fire ashes [5,6]."

Jan 1, 2017

By L. Bryson, J. H. W. M. Brits, K. Voogt

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."

Jan 1, 2017

By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

"The methods and technologies to be used for environmental monitoring of seabed mining activities are a key issue. Due to the large water depths, there are special challenges with respect to the monitoring equipment that is suitable. DNV GL has built up substantial experience of environmental monitoring from oil & gas projects in deep waters in the Norwegian Sea.Monitoring equipment and experiences from the oil & gas sector can to a large extent be applied to seabed mining.BackgroundThe International Seabed Authority is currently developing an environmental management strategy for the Area (ISA, 2017) as a part of the work on the regulations for exploitation for mineral resources in the Area.The draft environment strategy contains provisions related to monitoring and reporting of the activities. An Annex (Annex III) of the draft document describes the format and content of the environmental management and monitoring plan.The monitoring plan should contain, inter alia: ?Technology to be deployed.?Monitoring frequency of respective elements/components of the Marine Environment.?Monitoring procedures required to implement the Monitoring programme.?Details of the environmental monitoring stations across the Environmental Impact Area.?Monitoring specifics e.g. water quality; sedimentation rates; sound; plume extent; etc., as well as relevant Environmental Targets.?Monitoring of Mining Discharges.?Processes for Monitoring reviews and Environmental audits."

Jan 1, 2017

By Toru Yamasaki

"Bimodal lithostratigrafic assemblages are of significance in volcanogenic massive sulfide (VMS)-hosted lithology. The largest deposits are either bimodal-siliciclastic or maficsiliciclastic, and the presence of a significant siliciclastic component in the host stratigraphic succession favors large VMS deposits (e.g., Franklin et al., 2005; Barrie and Hannington, 1999). In the case of modern sub-seafloor VMS deposits in arc-related settings, the majority of deposits have been discovered in association with calderas or cauldrons (Halbach et al., 1993; Ishibashi and Urabe, 1995; Iizasa et al., 1999). These features are formed by the explosive eruption of silicic volcanoes, so that silicic host rocks and/or pumiceous volcanic clasts are generally observed around the ore deposits (e.g., Binns and Scott, 1993; Fiske et al., 2001). Caldera-like and graben-like morphological features therefore attract attention in geophysical surveys. However, silicic lithologies (dacite and rhyolite) normally contain only small amount of metallic elements (e.g., a few ppm to a few dozen ppm of Cu), whereas mafic rocks, such as basalts and basaltic andesites, contain significant amounts of metals (e.g., a few hundred ppm of Cu). Thus, the origin of metallic elements in VMS deposits associate with the silicic host rock remains unclear.The Iheya North Knoll is a volcanic complex in the middle of the Okinawa Trough. It is located in a young and actively spreading back-arc basin that extends for 1200 km behind the Ryukyu arc-trench system (Lee et al., 1980; Letouzey and Kimura, 1986). Several active hydrothermal fields have been recognized in the Iheya North Knoll. Mineralization at the Iheya North Knoll is characterized by relatively juvenile features consisting of VMS deposits with associated hydrothermal alterations to various degrees. Massive sphaleriterich sulfides at this site, recovered for the first time from beneath an active seafloor hydrothermal system, strongly resemble the black ore of the Kuroko deposits of the Miocene age in Japan (Takai et al., 2011). From February 11 to March 17, 2016, the SIP CK16-01 (Exp. 908) D/V Chikyu cruise was conducted at Iheya North Knoll and the rifting center of the Iheya Minor Ridge area, middle Okinawa Trough. The Iheya Minor Ridge area is also an active hydrothermal field, located ~30 km southeast of the Iheya North Knoll. In this area, basaltic rocks are widely distributed, and drilling has confirmed that the basaltic materials continue to ~120 m below the seafloor (Kumagai et al., in prep)."

Jan 1, 2017

By J. N. Van der Merwe

"Platinum is a highly valuable resource, its safe and economic extraction is paramount. The success of platinum mining by the bord and pillar method depends heavily on a comprehensive and dependable pillar design method. Pillars need to be large enough to safely support the load and small enough to avoid loss of resources. A critical evaluation of current pillar design systems used in narrow-reef platinum mining was undertaken using practical experience from a large feasibility-stage platinum exploration project, supplemented by observations from several platinum mines in Zimbabwe. An extensive literature survey was undertaken in order to determine the current status of design systems. Through this approach, the shortcomings of current pillar design systems are highlighted. Areas are proposed for further research to obtain a better understanding on how additional factors influence pillar system stability. The exploration work highlighted how rock mass classification methods can be utilized in determining the overall strength of pillars. Current pillar design systems for narrow-reef platinum mining consider width-to-heightratio (usually with different exponents for width and height) and the strength of the pillar material. However, there are many more important factors that are not considered and which have a bearing on pillar system stability. An in-depth study of these parameters with a view to establish effective narrow- reef platinum mining pillar design systems needs to be undertaken. IntroductionPillars have been used as a means of support since the early days of mining. Pillarsupported mining methods such as bord and pillar require a reliable design system for them to be successful. This paper presents an evaluation of the current hard-rock mining pillar design systems as applied to a practical large-scale narrow-reef platinum mining feasibility study. It is vital to have a dependable pillar design system for economic and sustainable mining. Using an extensive database collected from the project, the pillar strength formulae were tested and several discrepancies noted. This necessitates the establishment of more reliable pillar design systems. In narrow-reef platinum mining, large compressive stresses accompanied by geological and geotechnical factors contribute to pillar instability. A well-formulated pillar design system is required that accounts for such factors so as to minimize pillar failures."

Jan 1, 2017

By Tara Schenk-McFarland, Mark Bliss

Echo Dam, located near Coalville, Utah, is a facility that provides storage for irrigation and municipal use. Original construction of the dam was completed in 1931. Because of seismic concerns, the spillway crest structure and upper chute section, founded on old landslide and colluvial material, were recently replaced. Prior to replacement of these structures, jet grouting of a block of the loose and potentially liquefiable soils, directly beneath the spillway crest structure was selected as the preferred alternative to address the potential for settlement and cracking of the spillway crest structure. The replacement or alteration of the in-place soil reduces the likelihood of seismic-induced excess pore pressure development and subsequent settlements. Core drilling and sample recovery of the production jet grouted columns was completed to verify compliance with the specifications. It was recognized that due to the larger rock sizes within the deposits that full homogeneity of the jet grouted zone was unlikely to be achievable. However, the purpose of this jet grouted section was to strengthen enough of the soil so that widespread liquefaction does not occur. During the jet grouting production many instances of ground fracturing occurred. Fracturing was evident based on grout/air bubbles exiting the surface near some of the grout holes during jet grouting, air bubbles appearing in the spoil pits, and lifting of the ground surface in the vicinity of the monitor during the jet grouting process while the system was pressurized. In one instance, a section of the upstream spillway slab, which was left in place, was cracked due to pressurized grout escaping beneath the slab. The overall results of the jet grouting were satisfactory despite difficulties encountered. The cause of the fracturing is hypothesized and a recommendation is included to reduce the likelihood of this occurring on future jobs.

Jan 1, 2017

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By Jhony Mamani

El presente texto describe los casos de recuperación de recursos en rampas y taludes finales de un tajo abierto. El primer caso está referido a la recuperación de mineral en la rampa principal del tajo Chaquicocha, y el segundo, la recuperación de mineral en taludes de los tajos El Tapado y La Quinua.

Jan 1, 2017

By Clemens Kuhnert

"Nickelhütte Aue GmbH is specialized in the recycling of waste materials containing non-ferrous metals. We treat nickel, copper, cobalt, vanadium, molybdenum and precious metal containing materials like spent catalysts, ashes, dusts, grindings, liquids, slurries and sludge's as long as they contain one or a combination of the above mentioned metals. In our pyrometallurgical works we produce non-ferrous metal concentrates suitable for further treatment in our hydrometallurgical plant where we refine Ni-, Cu-, Co- and V-chemicals. Our production is based on synergy effects due to the combination of pyro- and hydro-metallurgy. As an example we can mention our heat recovery system and internal recycling of by-products. Furthermore, the use of alternative fuels instead of fossil fuels contributes to the economic and environ-mentally friendly treatment system.INTRODUCTION Nickelhütte Aue GmbH (NHA) can look back on nearly 400 years of tradition as a pyrometallurgical works and recycling company. The existence since its foundation in 1635 as a blue dye works shows responsible and successful action in the past. Therefore, we see highest customer service, minimization of interferences with nature by closing material cycles and maximized health and occupational safety protection by avoiding injuries and diseases, still as our future duties. These duties are evaluated and monitored by an integrated management system that meets the standards of DIN EN ISO 9001, 14001, 50001 and BS OHSAS 18001. We commit ourselves to the observance of all juridical and customized demands. The management and the department managers perceive their model function. We require responsible action from all employees. To protect the continuity of our enterprise, we will also perform in future continuous improvement of products and their quality, as well as steady progress in the areas of environment protection, health protection and industrial safety. Equally the effectiveness and propriety of the management system is checked and developed regularly. In order to obtain the objectives resulting from this policy, our company determines activities and measures by involving all employees."

Jan 1, 2017

By John P. Turner, Benjamin J. Turner

"This report describes a research project for evaluating the applicability of the widely accepted 80 percent criterion for elongation of ground anchors to anchors with unbonded lengths exceeding 100 feet. This issue is driven by several recent projects involving ground anchors for landslide stabilization in which a significant percentage of the anchors did not meet the criterion that requires measured elongation during proof load testing of at least 80 percent of the theoretical elastic elongation. The projects involved anchor unbonded lengths in the range of 85 to 220 feet, which is outside the range traditionally used in practice, although anchors of this length are being used more frequently for landslide stabilization. The principal objective of this research is to address whether the widely accepted criterion of 80 percent elongation is applicable for such applications, and whether other factors affect the ability of anchors to meet the criterion.Analytical methods for predicting transfer of load along the length of steel strand due to friction loss are used routinely in the prestressed concrete industry. These analytical expressions provide a rational framework for quantifying changes in load due to friction along the length of a ground anchor in terms of a ‘wobble coefficient’ (K) as defined in Aalami (2004). Values of the wobble coefficient for ground anchors can only be determined by back-calculating from load tests, i.e., fit the value of K to the appropriate analytical expression based on the known test load and measured percent elongation. The analytical basis is first developed and shown to provide a tool for evaluating results of anchor load tests to determine the magnitude of expected elongation as a function of unbonded length. Next, a database of anchor load tests is used to back-calculate values of K for anchors with unbonded lengths in the range typically used in geotechnical applications (< 100 feet). These values of K are then used to calculate expected friction loss for anchors with high unbonded lengths (100 to 250 feet) to evaluate whether the 80 percent criterion is reasonable."

Jan 1, 2017

By Zefang ChenLi, Laijun Ma, Lei Mao, Fang Lian

"In our work, the preparation technique of high pure manganese sulfate directly from low-grade rhodochrosite ore (MnCO3) was studied and improved intensively, including the effective leaching process and the short purifying process. Based on the same ion effect, the repeated leaching of rhodochrosite with sulfuric acid is proposed to improve the solubility of Mn2+ and inhibit the dissolution of the impurities Ca2+ and Mg2+. Moreover, the repeated leaching process could make full use of rhodochrosite and lower the dosage of sulfuric acidas raw material. With the aid of theoretical calculation, Ba(OH)2 was chose to adjust the pH value of manganese sulfate solution, and BaF2 to remove Ca2+ and Mg2+completely in the process of purifying. The results demonstrate that the extraction ratio and the recovery ratio of manganese reached 94.3% and 92.7%, respectively, which shows the prospect of industrial application. In manganese sulfate production, the heavy metal impurities have been decreased to less than 1ppm. Moreover, the content of calcium, magnesium and sodium has been decreased to less than 20ppm, which meets the standards of high pure reagent for energy and electronic materials. Our study enlightens an approach to the sustainable application of low-grade rhodochrosite.Introduction Low-grade manganese carbonate ores (=14%) becomes gradually the main resources for exploitation and applications in China according to national mineral resources survey (Tan et al 2004 and Singh et al 2017). Therefore, the electrolytic deposition technique of rhodochrosite faces great challenges including low electrolysis efficiency, high-resource input and high-pollution discharge (Fu et al 2010, Michelis et al 2009, Zhang et al 2013). Recently, more and more amount of manganese series with high or super high purity such as MnSO4, MnO2, Mn3O4 and MnO is demanded with the development of energy and electronic materials. Due to low-grade ores containing multiple elements such as iron, silicon, calcium and magnesium, conventional preparation of manganese sulphate with high purity from electrolytic product is characterized by long production-cycle and high-energy consumption (Subrat et al 2011, Mpho et al 2013). By contrast, hydrometallurgical method combined with thermal decomposition, hydrothermal synthesis and sol-gel processes has been widely studied because of its high efficiency, low consumption and low cost (Chen et al 2008). But the key problem in direct preparation of manganese series form low-grade rhodochrosite is to remove completely the multiple impurities such as iron, silicon, calcium and magnesium (Liu et al 2014). So it is urgent to develop a sustainable alternative approach with character of short process, high efficiency and environmental friendly."

Jan 1, 2017

By A. Pezzuto

"Pipes are used on mine sites in a variety of applications including transport of slurry, conveying clean and processing water, and in mine dewatering. Mine waters and slurries can cause pipe wear and failures via several mechanisms (or combinations thereof) such as abrasion, scaling, and corrosion. Polyethylene (PE) pipe materials have grown in popularity over the past several decades due to their chemical and mechanical properties (e.g., inertness, flexibility, relatively low density) and low cost. While PE is generally resistant to corrosion, it is subject to abrasion. To combat this, a novel, rubber-like liner is in development. In addition to comprehensive abrasion testing, however, the liner must be evaluated to see how it performs under other conditions. Here, a brief field study is described that tested PE pipes with the new liner against traditional PE pipes to specifically assess mineral scale buildup. The study was conducted in the Reiche Zeche study mine in Freiberg, Germany in six different locations with varying water qualities and flow conditions. INTRODUCTION Water and slurry conveyance are major operations on and around mine and mill sites, from mine dewatering, to tailings transport, to water treatment processes. Conveyance systems in such applications can include great lengths of pipe materials along with pumps and monitoring instruments, and thus represent significant capital investments. Due to the variability of the physical and chemical properties of water and slurries, pipe materials are subject to a wide range of conditions. These can cause pipe wear and eventually failure leading to serious economic, environmental and social, consequences. While pressure-induced pipe failures (e.g., ruptures or ""bursts”) can be immediate, most failure mechanisms involve gradual processes. Scaling and sedimentation can present major problems for pipe systems conveying highly mineralized waters. Sedimentation generally refers to the deposition of suspended solids, such as sand, clay, silt, or organic matter onto pipe surfaces. This phenomenon can occur due to a decrease in water velocity or particle collisions with the pipe wall. Scaling, on the other hand, commonly refers to the deposition of precipitated mineral salts (including oxides and hydroxides) onto pipe surfaces. Mine waters often have extremely high ion concentrations (i.e., high dissolved solids content) due to their interaction with enormous surface areas of minerals, which are exposed during mining and processing operations (Brown and Barley, 2002). As these waters are transported, slight changes in temperature, pressure or chemistry (e.g., pH or ORP) can cause instability with respect to ion solubility such that salt precipitation begins to occur. “Seed” crystals can rapidly grow and attach to pipes, either due to local surface phenomenon near the pipe wall (e.g., which can promote coagulation) or sedimentation of the precipitated solid. Whether due to suspended or precipitated solids, as the solids begin to stick to pipe walls, “aging” or hardening processes can commence; and the build-up of scale can become self-perpetuating as the scale itself provides an attractive “nucleus” for further attachment of particles or crystal growth (Muryanto et al., 2014). Over time, scale-buildup reduces the effective pipe diameter, which can ultimately result in decreased flow velocity, clogging and, in some instances, bursting (Dirany et al., 2016)."

Jan 1, 2017

By Robert Bachus, Jamey Rosen, Fabio Santillan, Georgette Hlepas

"A seepage barrier of length 4,800 feet and maximum depth 144 feet is being installed at Bolivar Dam in Ohio. This project is owned by the United States Army Corps of Engineers and contracted to Treviicos South. Many data types are being collected, synthesized and analyzed on a nearly real-time basis to monitor and track dam construction using several technologies including an enterprise relational database and web-based Geographical Information Systems. These data are being collected by both the owner and contractor and managed by the data subcontractor, Geosyntec Consultants. Each of the owner and contractor brings their own list of goals and desires to the data management program, and the subcontractor’s duty is to address these goals with minimal compromise by either party. The owner requires comprehensive, transparent and timely access to data in both “executive summary” and detailed formats. The contractor requires immediate analysis of disparate data to determine (for example) if a given excavation meets the specified tolerance and continuity requirements. This paper will describe the tools and methods used to store, analyze and visualize these data and discuss how each party’s needs were met in a collaborative system.INTRODUCTIONThe 4,800 foot long seepage barrier under construction at Bolivar Dam requires the collection, organization, and sharing of several types of data. These data include drawings and borehole logs that existed prior to construction; data collected during construction (seepage barrier panel composition and verticality data, slurry quality control and quality assurance data, grouting records, etc.); and instrumentation data collected and reviewed throughout and beyond construction. Each of these data streams require input and review from the Owner (United States Army Corps of Engineers (USACE), responsible for quality assurance and the ultimate consumer of the data), the Contractor (Treviicos South, responsible for the construction of the seepage barrier, its quality control and analysis of the data per the Contract Specifications), and the Data Management Subcontractor (Geosyntec Consultants, responsible for organizing and presenting the data to meet the needs of the Owner and Contractor). While all parties work with the same common goal, i.e.: producing a high quality product in an efficient manner making dam safety paramount during construction, and require immediate and comprehensive access to these data, the needs and desires of the parties differ. The challenge presented to the Data Management Subcontractor is to synthesize these data into a series of tools and reports that meet each of these needs."

Jan 1, 2017

By A. Navarra, F. Mucciardi, H. Marambio, R. Parra, F. Oyarzún

"Discrete event simulation (DES) is an appropriate framework for the plant-wide analysis of copper smelters. These smelters apply a common set of chemical reactions: copper-iron sulfides are blasted with oxygen-enriched air, sending the iron into a slag phase and the sulfur into the offgas. Moreover, conventional copper smelters exhibit similar operational dynamics: a smelting furnace operates continually, feeding into an alternating set of converters that produce batches of blister copper. The thermochemical and operational commonalities of copper smelters are integrated within the DES framework. This serves as a common basis to begin evaluating the system dynamics of individual smelters. For complex problems, the simulation framework should be developed in phases, incorporating feedback from different personnel who have complementary perspectives. Sample computations are provided in this paper based on the Hernán Videla Lira smelter, whose production is constrained by meteorological conditions. IntroductionWorld copper production is approximately 18.5 million t/y (Brininstool, 2015), worth $80 billion a year. Out of this total, 75 percent comes from the pyrometallurgical processing of sulfide minerals (Fig. 1), which occurs in copper smelters. The remaining 25 percent is from the hydrometallurgical treatment of oxides and complex ores (Rotuska and Chmielewski, 2008), which uses solvent extraction and electrowinning.The current paper describes the pyrometallurgical processing, recognizing that the underlying thermodynamics and kinetics are well known (Degterov and Pelton, 1999), with the notable exception of minor element transport, such as arsenic (As), antimony (Sb), bismuth (Bi), silver (Ag), gold (Au). The latter is an ongoing area of research, as smelters are faced with increasingly complex ores (Devia, Wilkomirsky and Parra, 2012; Swinbourne and Kho, 2012). This paper focuses on the system dynamics of copper smelter operations, which has received considerably less attention than the chemical thermodynamics and kinetics.Smelter engineers and managers may contribute to the sustainability of their plant by improving their understanding of operational system dynamics. Indeed, we have prompted smelter improvement projects (Navarra, 2016; Navarra et al., 2016; Navarra and Mendoza, 2013) simply by adapting methodologies that are commonly used in other sectors. These previous works incorporate principles from computer-integrated manufacturing (Groover, 2000) and theory of constraints (Dettmer, 2007), featuring the use of discrete event simulation (DES)."

Jan 1, 2017

By Yanchuan Li, Haifei Yao, Haiyan Wang

"Dust pollution is very serious in coal mining process, which is a great threat to the underground staff health and equipment and facilities safety. Coal seam water injection in mining process is an effective way to reduce coal mine dust concentration at the source. However, the effectiveness of water injection is limited in high-pressure and low-porosity coal seam. To improve the moisture content of coal seam, expand the wetting range and enhance the effect of dust reduction by water injection, the injectability and influencing factors of coal water injection are analyzed by numerical simulation method, and the sealing technology under high-pressure condition is studied. Then, according to the practical conditions of Tangkou coal mine, the parameters and process system of process system are designed, the effect of high-pressure water injection in coal seam was determined by testing water injection quantity, water increment and dust concentration. It is showed that the dust-removal rate of the high dust concentration operation such as falling coal and moving frame is 63.49% and 59.72%, the maximum dust-removal rate of multi-processes is 53%, which achieve a high level of application. The research results in this paper is of important theoretical and practical value to improve the water injection effect of high-pressure and low-porosity coal seam and improve the efficiency of dust removal in coal mining process.Introduction With the increasing of the depth and mechanization of coal mining, coal dust, the impact of ground pressure, ground temperature and other natural disasters continue to upgrade the harm degree (Wang 2011, Wu et al 2012), disaster incidents occur frequently, which seriouslythreaten the safe and efficient mining and the physical and mental health of underground staff. Coal seam water injection can effectively reduce the coal dust when coal crushing, prevent the impact of mine pressure, coal and gas outburst disasters, by increasing the thermal conductivity of coal, reduce coal temperature, and prevent spontaneous combustion of coal. In addition, coal seam water can soften the hard coal, so that speed up the recovery rate, improve coal production and efficiency (Wu et al 2008, Nie et al 2007). However, the coal seam in many mining area is with high-pressure and low-porosity feature, Coal joint cracks are not developed and relatively hard, water injection is difficult in these coal seams, then the desired disaster prevention effect cannot be achieved (Jin et al 2001, Zhao et al 2000). In this paper, the numerical simulation and field test methods are used to design the high-pressure and low-porosity coal seam water injection technology, so as to solve the difficult problem of coal dust control in high-pressure and low-porosity in deep well mining process."

Jan 1, 2017

By M. Epiney, A. Ghahreman, R. Kim1and

"In the presence of sulfidic refractory ores, increasing the dissolved oxygen (DO) concentration can positively affect the gold leaching rate. To identify the role of DO in gold cyanidation, electrochemical behavior was studied in the presence of 3 different ores. Sample 1 was a low sulfide pyrite ore, contained 5.14% pyrite, 0.19% galena and 3.09% S. Sample 2 was a pyriticore as well, contained more sulfide as 8.35% S, and 12.4% of pyrite. Sample 3 was a tailing of silicate gold ore, still containing75 g/tAu, 0.13% Pb and 0.18% S. Gold cyanidation kinetics were studied by cyclic voltammetry (CV) and chronoamperometry tests. With sample 1, the gold oxidation peak current density from CV curve was increased to 1.38mA/cm2under oxygen injection, while it was only 0.66 mA/cm2with air injection. From chronoamperometry test, the reaction rate was also faster under oxygen injection. Sample 2 showed similar behavior with sample 1, but the gold oxidation peaks higher than sample 1, i.e. 1.75 and 2.27 mA/cm2, under air and oxygen injection, respectively. However, it seemed that the gold oxidation was impeded by sulfide ions for a longer period. In the presence of sample 3, the gold oxidation peak was the highest among three ores –2.75mA/cm2under oxygen injection, because of its lowest sulfide content. However, from chronoamperometry test, it was also shown that the gold oxidation was impeded because of a significant amount of Pb in the ore sample.INTRODUCTIONIt is well known that gold is leached under oxidative condition (Marsden &House, 2006). Through the most representative and oldest gold leaching technique, cyanidation, more than 90% of gold can be selectively leached from an ore. According to Elsner’s equation, gold is leached in cyanide solution by forming cyanide complex [Au (CN)2–], and oxygen is consumed as an oxidant(Eq. 1)."

Jan 1, 2017

By Song Jiang, Xianzhi Tan, Minjie Lian

"The ground water heat pump system lades underground hot water which can be heated or cooled by heat exchanger in water source heat pump air conditioner. This system replaces the model of heating of air-conditioning by refrigerator and boiler. In this paper, the formation conditions of hot water energy in Shan Dong are analyzed in order to achieve the purpose of energy conservation and emissions reduction by taking full advantage of water resources such as water pouring and return water of beatification during the productive process of underground metal mine. In order to analyze the issue better, the paper points out some ways and methods for geothermal water often used in underground metal mine. This paper also presents the advantages of the technology of water source heat pump that is applied into underground metal mine. Here is a case study of comprehensive utilization of water source in a certain underground metal mine in Ji Ning. This mine, according to its own actual situation, designs heat pump heat exchange system which is used for indoor heating of buildings and bath for staff. It turns out that the system can save 23% water per year, cut down 3.303 million KW electric energy, and reduce 4160t emission of carbon dioxide. It is concluded that the technology of water source heat pump has broad application prospects in underground metal mine. Therefore, the results show that it is an ideal way to change the present structure of cooling and heating source in metal mine.Introduction In recent years, overuse of fossil fuels has posed a grave threat onto the environment, which makes renewable energy a more important status in energy structure. Development and utilization of renewable energy has become an important direction. Water source heat pump technology is to use solar energy stored in water as cold/heat source to convert energy. Currently, this technology has been widely used in some advanced countries. However, due to facers of implementation technology and component costs, there is still a gap in water source heat pump technology between China and these advanced countries. According to (Blum et al 2011) that after in-depth study, water source heat pump technology has developed rapidly in China recently, and the gap is gradually reduced. Groundwater source heat pump system as a kind of high efficiency, energy-saving and environmentally friendly technology in recent years, more and more get the people's attention. At the same time, its practical application has also been rapid development. Based on (Ni et al 2015) that According to the relevant departments of the prediction, the technology will become the 21st century the most efficient heating and cooling technology."

Jan 1, 2017