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By Kiyotaka Ohno, Nobushige Yasuoka, Yosuke Hioki

"The diameter of improved columns adopted by the original DJM Method had been 1000 mm, however, in order to comply with the social need for construction cost reduction, the Expanded Dry Jet Mixing (EX-DJM) Method with maximum column diameter expanded to 1300 mm was developed between 1998 and 2001 and has been widely applied since then. From the first application of EX-DJM in January 2002 for a first construction project, the total volume of improved soil has reached 325,000 m3 in 17 projects up to September 2014. Because of the advantages of the EX-DJM such as reduction of construction costs and periods leading to reduction in the number of improved columns, adoption of this method is expected to increase in the future. This paper describes the advantages of the EX-DJM, its construction results and case examples including those applied to restoration projects after the Great East Japan Earthquake, 2011.1. BACKGROUND OF DEVELOPMENTThe Dry Jet Mixing (DJM) Method is a soil stabilization method in which a powdery or granular binder is pneumatically fed into and mixed with soft soil to induce chemical reactions that stabilize and strengthen the soil. It was developed by government - private collaboration in Japan between 1977 and 1979. Up to March 2014, the total volume of soil improved by DJM method reached 33,500,000 m3. The initial diameter of improved columns of the original DJM Method was 1000 mm. In order to comply with the social need for construction cost reduction, the Expanded Dry Jet Mixing (EX-DJM) Method with maximum column diameter 1300 mm was developed between 1998 and 2001.2. ADVANTAGES OF EX-DJMThe construction equipment for the EX-DJM consists of two major parts, which are DJM machine and binder plant are shown in Fig. 1.The construction machine is of double mixing-shaft type with its column diameter expanded to 1200mm or 1300mm. In association with the increase in the column diameter, the binder feeder has also increased its discharge rate by approximately 1.69 times. Same as the increase rate of the area of original diameter 1000mm to diameter 1300mm are shown in Fig. 4."

Jan 1, 2015

One of the seminal pioneering papers in reserve evaluation was published by Danie Krige in 1951. In that paper he introduced the concept of regression techniques in providing better estimates for stope grades and correcting for what later became known as the ‘conditional bias’. In South Africa, the development of this approach led to the phenomenon being dubbed the ‘regression effect’, and regression techniques ultimately formed the basis of simple kriging in Krige’s later papers. In the late 1950s and early 1960s, Georges Matheron (1965) formulated the general theory of ‘regionalized variables’ and included copious discussion on what he termed the ‘volume-variance’ effect. Matheron defined mathematically the reason for, and quantification of, the difference in variability between estimated values and the actual unknown values. In 1983, this author published a paper that combined these two philosophies so that the ‘regression effect’ could be quantified before actual mining block values were available. In 1996 and in some earlier presentations, Krige revisited the regression effect in terms of the conditional bias and suggested two measures that might enable a practitioner of geostatistics to assess the ‘efficiency’ of the kriging estimator in any particular case. In this article, we revisit the trail from ‘regression effect’ to ‘kriging efficiency’ in conceptual terms and endeavour to explain exactly what is measured by these parameters and how to use (or abuse) them in practical cases.

Jan 1, 2015

By A. Flora, E. Bilotta, F. Foria, V. Nappa

"All the typical applications of deep mixing rely on the good mechanical properties of the improved columns to strengthen or stiffen the ground for a number of geotechnical applications.This paper focuses on a completely different kind of deep mixing, carried out in order to obtain columns much softer than the surrounding soil. This kind of deep mixing, named Soft Deep Mixing (SDM), is introduced as an original means to tackle seismic risk, and can be convenient when the existing structure to be protected has a historic relevance that cannot be altered with structural modifications. The idea is that properly assembled layers made of partially overlapped SDM columns, with dynamic impedance much smaller than that of the surrounding soil, will filter and reflect most of the seismic energy.The paper presents the results of some 2D parametric numerical analyses aimed to investigate the seismic performance of this innovative approach. Simplified dynamic inputs (Ricker wavelets, having only one largely predominant frequency) were adopted to better understand the effect of signal frequency. The analyses show that the effectiveness of the soft grouted isolating barrier depends on soil and SDM geometrical, physical and mechanical properties, as well as on the frequency content of the seismic input.INTRODUCTIONPassive structural systems installed at the foundation level of existing buildings are a common solution to protect them against earthquakes. However, installation procedures are expensive and not always feasible, as for instance in the case of valuable buildings. As an alternative, ground improvement techniques can be used to modify ground properties, in order to mitigate the intensity of shaking at ground level. The propagation of shear waves in the ground can be modified by introducing a layer of artificially modified material, having a dynamic impedance (defined as n =p VS, where p is the material density and VS the velocity of shear waves) very different from that of the natural soil. Both very high or very low values of the dynamic impedance of the grouted soil (nt) can be effective in reducing the overall transmitted energy, with the difference that – for a given reduction of the transmitted energy - stiff grouted layers tend to filter the low frequency components of the amplitude spectrum without modifying in a significant way the high frequency components, while soft grouted layers have the opposite effect. Then, ideally the choice of the best grouting technique should be made considering the effects of the different frequency components on the building to be protected. These effects are detrimental for the structure when they are close to its natural frequency: high frequency components result into large structural loads on massive squat structures (high natural frequency), and low frequency components may be critical for tall and flexible structures (low natural frequency). Therefore, the typical procedure of stiffening the uppermost soil layers regardless of the kind of building to be protected is not necessarily beneficial, and for the case of squat structures soft grouting should be preferred. However, this procedure has not been taken into account yet in the engineering practice, and may pose static problems at ground level (i.e. excessive static settlements)."

Jan 1, 2015

By F. Hassani, E. Aflaki, M. Nokken, M. Kermani

"This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill consists of tailings, different binders such as Portland cement, fly ash and blast furnace slag and an alkali activator such as sodium silicate. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. The influence of sodium silicate concentration, pulp density and mixing time on the mechanical properties of samples were evaluated using the uniaxial strength test. Mercury intrusion porosimetery (MIP) was used to analyse the microstructure of CHF and Gelfill samples.This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Mixing time strongly influences the mechanical properties of Gelfill samples but did not have any effect on CHF samples. (iv) The MIP analyses indicate that the pore size distribution and total porosity of Gelfill and CHF were different, and this did contribute to higher strength development of the Gelfill samples. INTRODUCTIONThe increased depths of mines in the Canadian Shield and the high stress associated with these depths favour a new method of mine backfill that can both meet strength requirements and help mine productivity. The mine backfill mainly consists of tailings, water and binder materials, the latter being most expensive. Gelfill is a new mine backfill material whose binder usually consists of alkali activators such as sodium silicate and other cementitious materials such as blast furnace slag and normal Portland cement. Although sodium silicate has been used in concrete manufacture, the use of this material in mine backfill is relatively new (Doucet, 2007, Razavi, 2007). Until very recently there have been only a few isolated publications, mostly out of McGill University, regarding mine Gelfill (Razavi, 2007 and Kermani et al., 2009 and 2010). These papers have investigated some of the basic mechanical properties and mechanical behaviour of Gelfill. However, the physical performance of Gelfill in various conditions has yet to be understood. Therefore, the main objective of this study was to investigate the influence of mixing time and sodium silicate concentration on the mechanical performance of Gelfill and CHF through a series of experiments. Moreover, the microstructure of the Gelfill and CHF samples was studied."

Jan 1, 2015

By Saeed Zhandi, Behdeen Oraee

"Rock bursts remain an important problem in longwall coal mining. These bursts are due to a sudden and severe failure of rocks from a high stress concentration in deep underground excavations that occur with the instantaneous release of strain energy stored in the rocks. They can potentially cause irrecoverable damage to equipment and personnel, thus accurate rock burst prediction and control is expected to be carried out by the mine design engineer. As a result, this can constitute major challenges for said engineer. In this paper, forensic engineering has been used to evaluate the possibility and extent of rock bursts in deep coal mining. For this purpose, established mining engineering principles, including factors influencing the severity of rock bursts, have been incorporated in the forensic engineering technique. The analyses took place in five steps:• Assessment of regional and local conditions prior to the event• Assessment of conditions after the event• Hypothesize plausible ways in which pre-event conditions can become post-event ones• Search for evidence that either denies or supports various hypotheses• Apply engineering knowledge to relate the various facts and evidence into a cohesive scenario of how the event may have occurred.The paper concludes by demonstrating a method for predicting rock bursts and preventing their reoccurrence. The methodology used in this paper, together with the results obtained, can serve as useful tools for the coal mine design engineer in the primary evaluation of rock burst potential in underground coal mines.INTRODUCTIONA rock burst is defined as the sudden and great failure of rocks due to a high stress concentration in deep underground mines. This phenomenon occurs with the instantaneous release of strain energy that is stored in the rocks, and can cause irrecoverable damages to both equipment and personnel (see Figure 1). Rock bursts pose a hazard owing to their lake of predictability; in fact, research into understanding rock burst mechanics and implementing techniques for their monitoring and prediction has been taking place for over 50 years."

Jan 1, 2015

By Rafic Moubarac

FRP (Fiberglass Reinforced Polyester) equipment has been used in different and several applications during metals processing and extraction, and the hydrometallurgical process. Case histories of such equipment will be shown of major projects worldwide.

Jan 1, 2015

By Baisheng Nie, Longlong Yang, Tao Yang, Wenjie Jia

"Gas adsorption in coal is an exothermic and physical process. Temperature might change during the dynamical process. In order to get the temperature variation of gas adsorption process, the experiment system which can test the temperature variation and analyze the thermal effect was established. Gas adsorption experiments under different conditions were done by using the test system. The results show that temperature increases during the adsorption process. It is an exothermic reaction process. Also, the temperature variation and the variation gradient increase with the increasing of equilibrium pressure. The temperature variation value is smaller if the experiment temperature is higher. The paper will provide basic experimental data for explaining gas adsorption mechanism better.INTRODUCTIONChina is the largest coal producer in the world while it also has the most serious coal mine disasters. According to the statistics, there are nearly a thousand coal mines in China including more than 110 the key state-owned mines risking to happen coal and gas outburst. Hundreds of coal and gas outburst occur each year which often causes serious casualties and economic losses (State Administration of Work Safety, 2007). With the continuing exploitation of the coal resources, the depth of the Chinese coal mines increases about 100 meters every year which causes the situation of gas accident becoming more and more serious (Xie et al., 2006).At present, the real mechanism of gas adsorption, desorption and the diffusion process in coal and the influence factor of it are not so clear. And because of the limit of prediction method and the technological level caused gas accident prevention theory and technology not so valid."

Jan 1, 2015

By R. Chen, K. Xia

In deep mining activities, blasting induced compressive stress wave would be reflected as tensile wave at a free surface around the openings, which would facilitate the tensile failure of the deep rock since it is much weaker in tension than in compression. It is thus critical to understand the dynamic tensile failure of rocks subjected to static tension for deep rock engineering applications. A modified split Hopkinson pressure bar (SHPB) system is adopted to load Brazilian disc (BD) samples statically, and then exert dynamic load to the sample through stress wave generated by impact. The pulse shaper technique is used to generate a slowly rising stress wave and thus to facilitate the stress equilibrium of samples during each test. Five groups of Laurentian granite (with tensile strength of 12.8 MPa) BD samples under the pretension stress of 0 MPa, 2 MPa, 4 MPa, 8 MPa, and 10 MPa are tested under different loading rates. The result shows that the dynamic tensile strength of the rock decreases with the increase of pre-tension stress, which is easy to understand because pre-tension stress weakens the rock sample. It is also observed that under the same pre-tension stress, the dynamic tensile strength increases with the loading rate, revealing the so-called rate dependency that is common for engineering materials. Furthermore, it is found that the loading rate sensitivity of the rock increases with the increase of pre-tension stress. A qualitative explanation for this phenomenon is that more microcracks are generated and activated under higher pretension stress, resulting in a more viscous material. Based on the results, an empirical equation is proposed to fit the data and explain the dynamic tensile behaviour of rock under pre-tension stress. A physical model is used to simulate the dependency of the dynamic tensile strength of rock on the pre-tension stress and the loading rate, which is shown to be in good agreement with the experimental results.

Jan 1, 2015

By S. M. Rupprecht

"SynopsisThis paper is intended to document recent personal thoughts, opinions, and debate around the South African Code for the Reporting of Exploration Results, Mineral Resources and Mineral Reserves (the SAMREC Code) (2009) and its current usage by Competent Persons. Admittedly, some debates are as old as the SAMREC Code itself and have been ‘parked’ as no consensus could be reached by members of the SAMREC Working Group.Some of the more critical issues currently under examination are the definition of Competent Person and the potential registration of Competent Persons, the current re-write of the Code, and the introduction of reporting of Exploration Results, Mineral Resources, and Mineral Reserves on an ‘If not – why not’ basis, noncompliance with the Code and discipline, the role of the Johannesburg Stock Exchange Readers Panel, and the valuation of mineral assets based on scoping studies.IntroductionThis paper is intended as a personal memoir of recent thoughts and debate around the South African Code for the Reporting of Exploration Results, Mineral Resources and Mineral Reserves (the SAMREC Code) (2009) (‘the Code’). Admittedly, some debates, such as reporting of Mineral Reserves inclusive or exclusive of the Mineral Resource, are as old as the SAMREC Code itself and have been ‘parked’ as no consensus could be reached by members of the South African Mineral Resource Committee (SAMREC) Working Group. The author, who has been involved with the SAMREC Working Group since 2007, offers observations in his personal capacity as a professional mining engineer with the intent of getting practitioners to contemplate the influence of the Code on the mineral industry. Current practices in the compilation and reporting of Exploration Results, Mineral Resources, and Mineral Reserves are often deficient in adhering to the Code and a conscious effort must be made by the mining sector to improve the standard of public reporting, in particular Competent Person Reports (CPRs) and Public Reports issued by listed mineral exploration and mining companies."

Jan 1, 2015

By T. J. Lutz, J. L. Carr, J. A. Yonkey, C. C. Jobes

"Since 1984, the date of the first recorded fatality involving a remote controlled continuous mining machine, 38 miners in the United States have been killed when they were struck by a continuous mining machine. Proximity detection is a valuable tool for preventing fatalities, and the use of these systems is expected to significantly improve safety. Proximity detection provides a means to prevent accidents like these. Researchers at the National Institute for Occupational Safety and Health (NIOSH) conducted a series of underground tests to evaluate the accuracy and repeatability of proximity detection systems under a number of conditions such as varying the orientation and height of the personal wearable device (PWD), moving the PWD close to the trailing cable, and activating the machine’s mining mode. At the 2014 SME Annual Meeting, results from tests on first-generation proximity detection systems were presented. This paper will provide results from the similar tests performed with second-generation systems. The results show that performance has improved. For example, the negative impact of PWD orientation and the trailing cable has been reduced. However, some inconsistencies remain. Notably, performance changes dramatically when mining mode is activated. INTRODUCTION Since 1984 there have been 38 fatalities involving striking and pinning of the operator and other workers by the continuous mining machine (CMM) [1]. In August 2011, the Mine Safety and Health Administration (MSHA) published a proposed regulation that would require proximity detection systems on all continuous mining machines except full-face machines [2]. Proximity detection systems are designed to stop machine motion to protect miners from striking/pinning hazards. Several MSHA-approved proximity detection systems are commercially available. MSHA estimates that of the 38 fatal striking and pinning accidents that have occurred since 1984 involving CMMs, the use of proximity detection could have been a preventative factor in at least 28 cases [1]. Furthermore, MSHA estimates that proximity detection could prevent 20% of all deaths throughout the industry [3]. NIOSH researchers have been involved in the development and testing of proximity detection technology since creating the HASARD system [4] and have recently conducted research intended to develop more advanced proximity detection technology for CMMs [5,6,7,8]. In addition, NIOSH has also conducted research investigating how the signals of a proximity detection system propagate [9,10] and have developed a novel method for determining the location of a personal wearable device (PWD) relative to the magnetic field generators [11,12]."

Jan 1, 2015

By P. Nos, L. Kolbeinsen, M. W. Kennedy, A. Filzwieser, R. T. Jones, A. MacRae

Modern furnace designs often incorporate extensive use of cooled elements to achieve long campaign lives at high operating intensities. However, contact between water and high temperature fluids can result in powerful Boiling Liquid Expanding Vapour Explosions (BLEVEs). Therefore cooling such elements with water carries inherent risks when used under slag and particularly below molten metal or matte. Alternative cooling media exist that can reduce or eliminate the risk of BLEVEs. These media are analysed and discussed in the context of deeply cooled furnace elements. Important factors in selecting alternative coolants are explored including: critical heat flux, thermal limits, toxicity, flammability, unit cost, etc. Key cooling system design criteria are reviewed in the context of both traditional and alternative coolants. Results of Computational Fluid Dynamics are presented for an example tap-block cooler design using a number of selected coolants. Research needs to advance the safe use of alternative coolants are presented.

Jan 1, 2015

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

"Gravity concentration remains the main separation method for fine iron ore and is used extensively for treating various minerals. Gravity concentration methods separate minerals of different specific gravity by their relative movement in response to gravity and one or more other forces, the latter often being the resistance to motion offered by a viscous fluid, such as water or air (Wills, 2006).Spirals concentrators are one of the gravity concentration equipment used for beneficiation of minerals. Spirals are typically used for processing of fine minerals (-1mm) size fraction. The main operating variables for a spiral concentrator are the feed rate, the solids concentration, the wash water addition and the position of the cutters or splitters used to separate the tailings, middling and concentrate streams (Sadeghi, Bazin & Renaud, 2014).The aim of this study is to investigate the effect of feed rate, solids concentration and wash water on grade and recovery on iron ore material. The Multotec SC20HC/7 WW spiral was used for the experimental test work. The spiral was tested at varying solids concentration and feed rate. The wash water rate was also varied to establish the best washing rate. The splitter positions were kept constant. Optimization of these variables is expected to provide optimum conditions for a good compromise between grade and recovery.INTRODUCTIONSpiral concentrators are simple low energy consuming devices that separate minerals mainly on the basis of density. Spirals are widely used in mineral processing as a method for preconcentration and have proven to be metallurgically efficient and cost effective.Spirals have a wide application, they are used in iron ore processing, coal, gold, chromites, mineral sands, glass sands, and in soil cleaning.Separation on a spiral is achieved through a combination of forces that act on particles as they move down the trough of the spiral. The main forces known to act on the particle on a spiral are the gravitational forces, centrifugal force, hydrodynamic drag, and lift and friction forces (Kapur & Meloy, 1998). Apart from the forces acting on a spiral, the properties of the slurry flowing on a spiral including, solids concentration, feed rate and wash water also plays an important role in the separation on the spiral.The relationship between separation efficiency and feed rate was shown to be linear, with a decrease in efficiency at higher flow rates. Previous work on flow profile by Holland - Batt (1990) indicated that any increase in the feed rate to a spiral results in a greater part of the additional flow volume reporting to the outside of the trough. The flow on the outside of the trough becomes energized and consequence to that the heavy particles find it hard to settle and escape this region to the inner region. This effect has a high impact on recovery of heavy minerals, since any increase in volumetric flow on the spiral is not made available for recovery in the inner region of the spiral."

Jan 1, 2015

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present study the effect of using different grinding media, viz, ceramic balls, forged steel balls, 15% Cr steel balls, stainless steel and mixture of stainless steel and 15% Cr steel balls (50:50) on the flotation performance of a Platinum Group Mineral (PGM) UG2 ore was investigated. Test work was conducted using a laboratory scale horizontal tumbling mill and a batch flotation cell. Power draw to achieve a specific P80 was determined for each media type. Changes in flotation behaviour were evaluated in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. pH, Eh and DO levels were also measured. Grinding products of five different media produced similar solids and water recovery, which is indicative of the froth characteristics, but the grades and recoveries of PGE and chromite were different. The product obtained when using ceramic media showed the best flotation performance, producing the highest PGE recovery and the lowest Cr2O3 recovery. The products obtained when using stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery. The paper proposes possible reasons to explain these observations which may have significant importance for the operation of a PGM concentrator.

Jan 1, 2015

By Shoichi Tsukuni, Akihiko Uchida, Kazuo Konishi

"In order to investigate the effect of grid-form deep mixing walls as a countermeasure for liquefaction damage to roads and private houses in Urayasu, Japan, three dynamic centrifuge model tests were conducted. Urayasu is located in the Tokyo Bay area, and private houses in the city incurred severe damage due to liquefaction during the 2011 Tohoku earthquake. In grid-form deep mixing walls design, the distance between grid-form walls is critical to prevent liquefaction. This study clarifies the relationship between the settlement of private houses and the distance between grid-form walls under the conditions that exist in Urayasu.INTRODUCTIONMany private houses in Urayasu, Japan suffered severe damages due to liquefaction during the 2011 Tohoku earthquake (Photograph 1). Fig. 1 shows the location of Urayasu and the maximum acceleration of the observed seismic waves in the Tokyo Bay area. At Urayasu, the duration of the seismic waves (hereafter called the Urayasu Wave) was about 2 min. The maximum acceleration was 1.57 m/s2 (Fig. 2), which is relatively small. The damages occurred in the land reclamation areas that consist of loose sand with an SPT-N value less than 10.To prevent liquefaction in future, it is necessary to adopt suitable countermeasures in the areas where many private houses suffered severe damages. Grid-form deep mixing walls are one such countermeasure. Fig. 3 and Photograph 2 show grid-form deep mixing walls. Walls are constructed using the deep cement mixing method. Fig. 4 shows a plane view of planned grid-form deep mixing walls for roads and existing private houses in Urayasu."

Jan 1, 2015

By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Nucleation and growth of copper on 316L stainless steel from synthetic acidified copper sulfate was studied in the absence and presence of chloride ions and/or organic additives (HydroStar® 4208, DXG®-F7, Cyquest® N-900) using a potentiostatic technique. The current-time data obtained at 0.16V vs. SHE was analyzed using nucleation and growth models. Scanning electron microscope (SEM) images of deposits produced at 300 A m-2 show that the addition of 20 mg/L chloride ions increased the size and reduced the number of copper nuclei. Potentiostatic current-time data from the electrolyte without organic additives indicate progressive nucleation with two-dimensional (2-D) growth under diffusion control. SEM images obtained confirmed progressive nucleation with 2-D growth. 20 mg/L Cl- and 2.5 mg/L organic additives did not change the nucleation and growth mechanism, however the additives increased the number and reduced the size of copper nuclei leading to more uniform coverage of the stainless steel substrate.INTRODUCTION Electrowinning of copper is an important process in the manufacture of high purity copper metal. It is approximated that 20% of the world’s refined copper is produced from acidified copper sulfate solutions by electrowinning (Schlesinger, Sole, and Davenport, 2011). In many plants, copper is electrodeposited on AISI 316L stainless steel substrates for a period of 6-7 days, after which the copper is stripped from the blanks. Even though the deposition time for a commercial copper electrowinning circuit is around one week, it is critically important to control the nucleation, growth, and nature of the initial deposit (Sun and O'Keefe, 1992). Deposit morphology and structure are influenced by the real current density at the electrode surface. The real current density across the cathode surface is made uniform by proper design of the electrowinning cell and electrodes and careful operational practice. Even with good design and control, some current maldistribution occurs. The outcome of severe current maldistribution is poor deposits that affect product quality and/or increase energy consumption. To combat current maldistribution and create a larger operating window in terms of current density, temperature, and copper concentration, small amounts of organic smoothing agents (traditionally guar products) are added to copper electrowinning electrolytes. Moreover, these additives inhibit the growth of copper dendrites, which leads to improved deposit quality by producing bright, smooth, and dense cathodes."

Jan 1, 2015

By E. Pizarro, A. Videla, G. Compan

One of the main problems related to mining investment decisions is the use of accurate prediction models. Metallurgical recovery is a major source of variability, and in this regard, the Chuquicamata processing plant recovery was modelled as a function of geomining-metallurgical data and ore characteristics obtained from a historical database. In particular, the dataset gathered contains information related to feed grades, ore hardness, particle size, mineralogy, pH, and flotation reagents. A systemic approach was applied to fit a multivariate regression model representing the copper recovery in the plant. The systemic approach consists of an initial projection of the characteristic grinding product size (P80), based upon energy consumption at the particle size reduction step, followed by a flotation recovery model. The model allows for an improvement in the investment decision process by predicting performance and risk. The final geometallurgical model uses eight operational variables and is a significant improvement over conventional prediction models. A validation was performed using a recent data-set, and this showed a high correlation coefficient with a low mean absolute error, which reveals that the geometallurgical model is able to predict, with acceptable accuracy, the actual copper recovery in the plant.

Jan 1, 2015

By K. N. Han, H. C. Cho, R. Kim

"As an extension of the work on the effect of OH- on various cations in hydrometallurgical systems, the effect of Cl-, Br-, I- and CN- on cations such as Ag+, Cd2+, Hg2+, Cu+, Cu2+, Co2+, Zn2+, Pb2+ and Sn2+ has been examined in detail. The Newton-Raphson technique has been used to determine the amounts of various metal species as a function of the concentration of anions. Some practical implications of various metal complexes in metal separation and removal from solutions have been examined and discussed.IntroductionUnderstanding the role of anions in hydrometallurgical processes often determines the success of an operation. The successful choice of concentration and type of anions not only leads to an effective extraction and removal of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2009; Al-Tarazi et al., 2004), but also to assisting effective separation of various metals, whether it is a solvent extraction, ion exchange operation or even a simple precipitation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974).This paper continues the discussion of the role of anions in hydrometallurgical systems beyond the role of OH-, which was the topic of a previous paper (Kim et al., 2014). Table 1 lists various anions that are frequently used in conjunction with metal ions to be selectively separated or precipitated. As seen in the table, many anions are used frequently in hydrometallurgical practices. Some of the more frequently used anions include OH-, SO4 2- and CO3 2-. The halogen elements, Cl-, Br- and I- , as well as CN-, are also used in hydrometallurgical applications, especially in relation to noble metal recoveries (Meng and Han, 1994; Zhang et al., 1996; Sun et al., 1996; Starovoytov et al., 2007)."

Jan 1, 2015

By Xiaoqiong Wang, Daobing Wang, Fanbao Meng, Jianbo Wang, Hongkui Ge

"Shale gas has become an important unconventional oil and gas resources. Its effective development relies on comprehensive and accurate understanding of shale gas reservoirs. Rock mechanical properties is one of the important components of reservoir evaluation. Two adjacent black shale samples, which are cored from the depth of 1145 meters in Chongqing, southwest China, are subjected to acoustic emission(AE) test under uniaxial stress and compared with coarse grained granite. The results of synchronous AE, stress-strain and ultrasonic velocity experiments show that shale has weak anisotropy. Compared with granite sample, two shale samples are similar, but their strength, velocity and brittleness are quite different, indicating that shale has strong microscopic heterogeneity. TOC, XRD, SEM microstructure analysis show that total organic content, mineral composition and natural fractures are the main impacting factors for mechanical heterogeneity. INTRODUCTIONShale gas is a typical low-grade marginal resource, which is characterized by ultra-low matrix permeability and small single well control volume. In order to enable commerical development, complex hydraulic-fracture networks must be created in the shale to allow gas to escape from the micro/nano-pores and natural fractures where it is trapped in the rock (C. Clark et al.,2013; Ge et al., 2013). The development of shale gas requires accurate evaluation methodologies to evaluate shale reservoir properties and predict production. (Jarvie et al., 2007). Rock mechanical properties are an important part of the reservoir evaluation. It is significant for efficient drilling, completion and hydraulic fracturing to understand mechanical behavior of shale gas play (John, 2011; Wei, 2013).Rock mechanical properties mainly include heterogeneity, anisotropy, brittleness and acoustic emission activity (Lockner et al., 1992; Jerome et al., 2009; He et al., 2010; Liang et al., 2012). Shale mechanical properties are evaluated from laboratory tests following a complex workflow that covers tasks from sampling to testing (Md. Aminul Islam et al., 2013). It is common to include various experimental methods such as stress-strain curves, ultrasonic velocity and acoustic emission when evaluating the mechanical properties (Rao et al., 2006). Because of the presence of organic-rich matter, mineral composition orientation and natural fractures, shale tends to have strong anisotropy and heterogeneity (Deng et al., 2004; Wang et al., 2013; Hathon et al., 2013)."

Jan 1, 2015

By Michal Topolnicki

"Discussed is the use of wet Deep Soil Mixing, generally executed with single mixing tools 0.8 to 1.6m in diameter, employed in the foundation of viaduct supports. The applications involve economical patterns of ground improvement, covering in average about 40% of the foundation area or less, which contribute to the competitiveness of DSM solutions when compared to traditional piling. The focus is on selected aspects of the geotechnical design, applicable for geo-composite systems in which the interaction between the stabilised and the native soil should also be considered. Evaluation of settlement can be carried out with simplified methods, accounting for punching effects, or with more advanced FE models in case foundation tilt or differential settlements become important. Potential bending of DSM columns should be considered when evaluating column stresses, especially when dealing with deep deposits of soft soil and/or foundations loaded with overturning moments and/or high horizontal forces. Statistical evaluation of UCS data using lognormal distribution is recommended, and a new classification system for DSM application is proposed. Field investigations and monitoring data from completed projects are also presented.INTRODUCTIONThe first applications of wet Deep Soil Mixing in foundation of road viaducts constructed across and along the newly built A2-highway in Poland took place in 2002. Following detailed analyses, it was concluded that 39 viaducts, originally designed to rest upon large diameter piles in order to reduce excessive settlement of individual supports, could also be founded directly on the ground improved with DSM columns, fulfilling all relevant requirements of serviceability and ultimate limit states (SLS and ULS, respectively). It was also noticed that shorter construction times and lower costs of ground improvement with DSM contributed to substantial economical savings as compared to classical piling. Since then, more than 250 road and railway viaducts have been successfully founded on DSM treated ground in Poland, and wet soil mixing is now seen as a reliable and widely accepted technology for this purpose. These applications, together with a parallel use of wet DSM for foundation of buildings, industrial halls and wind turbines, have drawn international attention to the state of practice of wet DSM in Poland for foundation of engineering objects. What follows is an attempt to summarise experience gained during planning and execution of DSM works for foundation of the majority of road and railway viaducts constructed in the last 13 years, with emphasis on selected design aspects and evaluation of collected data and observed performance.The design process of DSM treatment is iterative, as described e.g. in Annex B of EN 14679, and typically involves two main steps, i.e., the selection of the design strength of cemented soil, called soil-mix design, and the adoption of suitable column pattern, referred to as geotechnical design. Soil-mix design was initially based on purposely arranged simple laboratory tests, involving mixing of soil specimen with different cement types and dosages and subsequent strength testing. However, with a growing number of completed projects the accumulated field strength data of different stabilised soils have been more and more frequently used, reducing the need for preceding laboratory testing of soil-mix to special projects only. Information on cement factors utilised in Poland and the range of recommended compressive strengths for different stabilised soils, as well as on mixing tools and characteristics of the wet method applied, can be found in Topolnicki (2008). Consequently, soil-mix design is not further discussed herein. Selected aspects of the geotechnical design are the main focus."

Jan 1, 2015