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By Z. Y. Lan

Bioleaching of marmatite with various mixed cultures of microorganisms was investigated. The experiments were carried out in shaking flasks with iron-free nutrient and the pulp density of 10% wt/vol at the temperature of 30?. The results show that zinc is preferentially leached before iron. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans is 62% in 18 days. The leaching rate of zinc with the mixed culture of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans is nearly the same as that with the mixed culture of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans (45% versus 50%). SEM and EDX analysis of the leaching residues indicate that a solid product layer composed of iron sulfide, elemental sulfur and jarosite accumulates in the mineral surface and becomes a barrier to the dissolution of marmatite. The bioleaching of marmatite follows the shrinking core product layer model. When the product layer increases and becomes insoluble, the leaching rate is controlled by the diffusion through the product layer and slows down. When the product layer decreases or becomes a porous layer, the leaching rate is controlled by chemical reaction and enhanced dramatically.

Jan 1, 2014

By Y. Tang

The paper studied the extraction characteristics of the fly ash from a location in Guizhou province. Under ordinary pressure, the fly ash is extracted by an acid and alkali, and then studied for its reaction characteristics with different extraction agentia, temperature, consistence and time. The results of acid extraction show that there are good reaction characteristics for Fe2O3 with HCl and the extraction rate decreases with the increasing of extraction time. There are good selective characteristics between Al2O3 and H2SO4 and they weaken with the increasing of temperature and the expanding of time. The best extraction results are shown with CaO and MgO because of their chemical characteristics and the over-saturation degree of the extraction processing. In addition, It?s found that it cannot leach all the substances from fly ash even with the higher consistence (10mol/L) of extraction agent, the longer extraction time (2h) and the higher temperature (100?) .It shows that the extraction rate of Fe2O3 is 82.81% and that of Al2O3 is 29.01%. The results of alkali extraction show that the extraction rate increases with the consistence of extraction agent and temperature, and the extraction rate of SiO2 by NaOH increases rapidly with the time expanding while that of Al2O3 falls gradually.

Jan 1, 2014

"Chairman: Professor B. W. MacKenzieRapporteur: Professor D. A. PretoriusPapers:Optimum spacing for soil sample traverses by W. A. HodgsonEvaluation of geochemical data by C. J. LenzResearch in oil exploration decision-making by J. W. Harbaugh and A. Prelat A drill hole data bank by M. R. AndertonOre reserve estimation and depletion planning for a beach diamond deposit by M. M. OosterveldIn opening the session, the Chairman indicated that the papers and discussions would revolve about quantitative methods of analysis and optimization of various aspects of exploration planning. The five papers would cover a wide range of topics within a general theme of exploration analysis, and it would be appropriate, therefore, to present the. papers as representing a sequential information-gathering process, namely, (i)geochemical and geophysical types of surveying for the location and identification of anomalous zones, (ii) tren¬ching and drilling of the anomalous zones found, and (iii) further refinement of the data for ore reserve calculations and production planning.The first paper, which was presented by Dr W. A. Hodgson, dealt with the optimum spacing between soil sample traverses conducted during geochemical prospecting. The theme of the paper was that the critical sampling interval should be based on the concept of element continuity, and that this interval could be determined by means of a correlogram. Ensuing discussion concerned the probability of the method, designed for areas where dispersion was high, working in localities where dispersion was either low or virtually non-existent. In the latter eases, specific orientation surveys for varying topographic, climatic and geological conditions would possibly be more useful than the preparation of correlograms. A further suggestion was made that cost versus risk should be taken into consideration when deciding upon the spacing between traverses. A balance could be struck by mathematical optimization. If the exploration budget was fixed, then the variance of risk could be minimized.The second paper was a short contribution by Mr C. J. Lenz. Computer-based plotting and evaluation of geochemical prospecting results were carried out because the low cost of analysis in Rhodesia permitted very large volumes of data to be accumulated in mass-coverage operations. Anomalous areas were demarcated within different environments by selecting probability or population boundary values from frequency distributions. In the short discussion which took place it was debated whether the method should be used only in the early high-risk stages of geochemical exploration and whether the introduction of geological bias could influence the actual results of an exploration program."

Jan 1, 2014

By Mario A. Terceros H., K. Rainer Massarsch

"ABSTRACTThe Expander Body (EB) technology has been used successfully to increase the pile toe capacity of bored piles in loose to medium dense soil. An important advantage of the EB system is the ability to monitor the EB expansion process, which provides important information regarding soil strength and soil stiffness. This information, obtained for each installed pile, can be used to determine the actual shape and pile toe area. The expansion pressure can be used to design the pile base capacity.The Expander Body system has been recently improved by incorporating the possibility of post-grouting of the soil below the expanded pile toe. This improvement measure provides additional strength and stiffness to the pile toe and reduces pile settlement.The shaft bearing capacity of bored piles can be increased by using a soil displacement auger, which avoids soil decompression and increases lateral soil stress. This paper describes the principle of the EB system. During the past 20 years, a large number of EB piles have been installed in Bolivia and elsewhere, providing a sound database. Results from field loading tests are presented. A comprehensive study of test piles with and without EB base has been carried out which demonstrates the improvement effects that can be achieved by the EB pile system and the combination with the displacement auger pile method. A design concept for the EB pile system with the full displacement auger pile is presented. A high degree of quality control can be achieved by monitoring the entire pile installation process, including the displacement pile and the Expander Body.1. IntroductionIn many regions of South America, soil deposits consist often of predominantly loose to medium dense sands and silts, often with high groundwater table. In the Santa Cruz area in central Bolivia, such soils are frequently quaternary sediments, deposited by the river Piray. The city of Santa Cruz is located at the right bank of the river.The most common deep foundation method during the last 30 years has been cast in situ piles, augered and concreted under support of bentonite slurry. The design of such piles has been based on SPT results. However, SPT is often performed without quality control and the reliability of geotechnical data is therefore often poor. Traditional methods of pile installation with simple well drilling equipment of insufficient capacity are frequently used. Such methods lack basic requirements of quality control. Such piles have usually low toe resistance and work mainly by shaft resistance . Although the construction process and materials are cheap, the final product has variable and limited capacity. However, the most serious deficiency is that actually achieved pile capacity and pile settlement can be erratic and difficult to predict, leading to uncertainties with regard to actual foundation performance."

Jan 1, 2014

By Upali Siriwardane, Tushar V. Kudale, Naidu V. Seetala

"Cellulose acetate (CA) membranes with 25% triethyl citrate (TEC) as plasticizer were prepared with varying thickness for CO2 gas separation from water-gas-shift (WGS) reaction products. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO2 permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO2. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Annihilation Lifetime Spectroscopy (PALS) was used to estimate the nano-porosity (pore size and concentration) changes of CA/TEC films. PALS results show a decrease in pore size with increasing CA-TEC concentration in acetone, while the pore concentration increases. The PALS results are correlated with the CO2/CO permeability variations as the CA-TEC concentration change.IntroductionHydrogen is one of the main energy sources available for the future advancement of clean fuel technologies especially for fuel cells. Generation of hydrogen and CO2 from Water Gas Shift (WGS) reaction mixtures of CO and H2O is of interest to many researchers since it allows a large scale production of hydrogen [1, 2]. Once hydrogen is produced using the WGS reaction, the output products contain mixture of CO, CO2, H2, and water vapor. Metallic membranes have been used as hydrogen separation membranes [3-6]. As H2 is separated from the mixture using the metal membranes, we need to separate CO2, and find ways of sequestration of CO2 to avoid environmental problems by greenhouse gasses. Polymeric Membranes have been used for CO2 separation [7]. Plasticizer can control the micro-structural properties such as pore size and concentration of polymer membranes [8], which influence the size/molecular weight dependent diffusion rates of the gas molecules. We have used cellulose acetate with triethyl citrate as plasticizer to separate CO2 from the WGS reaction products. Positron annihilation lifetime spectroscopy (PALS) is very sensitive and able to identify different kinds of defects and their agglomerates such as vacancies, vacancy loops, and voids [9, 10]. PALS has been successful in determining the free volume in polymers that influence the properties of the polymers [11, 12]. Microscopic properties of the free volume obtained from PALS have been correlated to macroscopic properties [13, 14]. We used PALS to study the nanoporosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO2/CO permeability as the CA-TEC concentration in the membranes change."

Jan 1, 2014

By P. Ross, O. Rielo, P. Katsabanis

Selection of delay times to optimize fragmentation has been a controversial topic among researchers and blasting practitioners. The paper reviews all available experimental information, ranging from small and medium scale tests in geologic materials to small scale tests at the laboratory and synthetic materials, simulating rock. Tests have been re-analyzed and discussed in terms of the information they present and the limitation of the testing environment in representing actual conditions. New results obtained from blasting experiments in specimens made of a grout have provided a clear picture of the effect of delay on fragmentation. The grout used has a strength of 60 MPa (8700 psi), density of 2.5 g/cm3 and P-wave velocity of 4000 m/s (13100 ft/s). Each block was placed in a yoke to eliminate unwanted reflections and the desired delay was obtained using the appropriate length of detonating cord between holes or sub-millisecond electronic detonators. Delays ranged from 0.1 ms/m (0.03 ms/ft) of burden to 16 ms/m (4.9 ms/ft) of burden. Fragmentation was obtained using screen analysis of the collected fragments. Delay time has been shown to be a significant parameter affecting fragmentation and back break. Generally larger fragments and less back break was observed at short values, while fragmentation somewhat deteriorated at significant delay times, compared to what was observed at intermediate delay times. The work is now extended to include the effect of energy partition on fragmentation as well as the effect of initiation point and coupling ratio.

Jan 1, 2014

By A. B. Cecala

Enclosed cabs have been used for many years to isolate workers on mobile equipment in the mining industry for health and safety reasons. These enclosed cabs create a microenvironment for workers where they can be either more protected or more vulnerable to contaminants. Over the past decade, the U.S. National Institute for Occupational Safety and Health (NIOSH) has performed substantial research efforts to improve the air quality inside enclosed cabs of underground and surface mobile mining equipment. In these efforts, NIOSH has partnered with mining companies, original equipment manufacturers (OEMs) and manufacturers of filtration and pressurization systems in a synergistic effort to reduce respirable dust and improve the air quality inside these enclosed cabs. Various field studies over this time have shown an array of results ranging from very minor to very significant reductions (protection factor: 3-89) in respirable dust levels inside these enclosed cabs. In addition to and concurrent with the field work, NIOSH also performed a comprehensive laboratory study to evaluate all the factors involved in cab filtration and pressurization systems and identified those factors that were most significant for an effective system. From this comprehensive research effort, the key components for an effective filtration and pressurization system have been identified in an effort to provide the best air quality to equipment operators inside of enclosed cabs of mobile mining equipment, thus minimizing respirable dust exposure.

Jan 1, 2014

By James Ransford Dankwah

High sulphur carbonaceous materials like petroleum coke and rubber tyre are unsuitable as reductants in ironmaking because part of the sulphur is transferred to the reduced metal. Globally, while large amounts of petroleum coke are produced annually from the industrial processing of crude oil, billions of end-of-life rubber tyres are held in landfills and stockpiles. This work therefore investigates the potential feasibility of utilising these high sulphur carbonaceous materials as reductants in ironmaking without transferring the sulphur into the reduced metal. Composite pellets of iron oxide containing end-of-life rubber tyre (RT), petroleum coke and blends of RT/petroleum coke and petroleum coke/high density polyethylene (HDPE) were heated under argon atmosphere in a horizontal tube furnace. Reduced pellets were analysed after 10 minutes of reduction for their sulphur content. The results showed that sulphur-free metallic iron can be successfully synthesized using RT and petroleum coke as reductants. The level of desulphurisation depends on the nature of blending of the carbonaceous materials.

Jan 1, 2014

By A. Newman, A. Brickey

Although some of the prevalence of openpit production scheduling software can be explained by the predominance of openpit mining throughout the world, other factors have led to a lag in corresponding underground software. We explain mathematically why underground production scheduling is more difficult than its openpit counterpart and provide directions for research in the underground scheduling arena.

Jan 1, 2014

By J. Edberg

"This article details the use of an alternative testing method to the 2004 "Post-Tensioning Institute (PTI) Recommendations for Prestressed Rock and Soil Anchors" manual’s recommendations for temporary and permanent rock anchors for applications in shafts and tunnels. This method was developed and used for the Black River Tunnel (BRT) project in Lorain, OH as a means to reduce testing time of rock bolts during shaft construction while maintaining a similar level of quality control and assurance. The following sections will detail the project background, subsurface characteristics, shaft construction, the 2004 PTI testing method and associated difficulties, the alternative testing method and conclusions reached.Project backgroundThe city of Lorain is located in north central Ohio on the south shore of Lake Erie, approximately 40 km (25 miles) west of Cleveland and 119 km (74 miles) east of Toledo. The city chose to build a large-diameter storage tunnel and pump station to meet its requirements to reduce sanitary sewer overflows to the nearby Black River. NTH Consultants Ltd. (NTH) was retained by the city’s prime consultant, Malcolm Pirnie Inc. (now the water division of Arcadis), to perform a geotechnical investigation, develop design and construction bid documents for the tunnel and shaft liner systems and ultimately provide oversight assistance during the construction phase of the project.The BRT is an approximately 1,700-m (5,560-ft) long, 7-m (23-ft) diameter rock tunnel to be lined with a 5.8-m (19-ft) inside diameter secondary concrete lining (Fig. 1). The tunnel is designed to accept flow at a new drop shaft (Shaft 3) located on the west side of the Black River, across from the city of Lorain Black River waste water treatment plant (BRWWTP). The tunnel will be dewatered at the south end by a large diameter pump station (Shaft 1) located in the existing Lorain Port Authority Public Boat Launch. Flow from the new pump station will be discharged into an existing shallow interceptor sewer and directed back to the BRWWTP."

Jan 1, 2014

By E. A. Brocchi

This work is dedicated to the chemical treatment of a typical EAF dust by chlorine content agents. The residue contains 48% Fe2O3 and 28% ZnO mainly in the franklinite structural form. The others less compounds are: 4.00% CaO, 2.60% MnO, 2.20% MgO, 1.08% PbO, 0.36% Cr2O3, 0.21% B2O3, 0.03% CdO and 0.01% NiO. The experiments purpose is selectively to remove zinc from the residue leaving the iron behind. Thermodynamics studies have indicated some roasting possibilities. The experimental results have shown that both HCl leaching and carbochlorination will remove iron and zinc without any selectivity. However, either the chlorine or the calcium chloride roasting seems to form, preferentially, the zinc chloride. So, it will be presented how the EAF Dust can be treated by the using of chlorine roastings process such as carbochlorination in order to separate the zinc and iron present in the frankilinite, main EAF dust content.

Jan 1, 2014

By Gerald S. Cole

It used to be that a science/engineering presentation on "light weight" at a metallurgy conference, would relate to the materials science, processing, component fabrication and applications of aluminum, magnesium and titanium. Within the automotive industry, light weight now includes how to "lighten up", how to lightweight, or how to mass reduce vehicle components and systems. Increasingly stringent global emissions-reduction requirements require increasing vehicle fuel efficiency; mass reduction is an enabler to achieve this. While light metals certainly are the basis, a host of other materials can be used to optimize mass reduction while meeting vehicle performance, safety and cost requirements. New grades of ultrahigh strength steels and even nanosteels can be thinned down and save over 1/3 the mass vs conventional mild steels. A compacted graphite cast iron engine can be made lighter than an aluminum one. Aluminum components in vehicles were only castings; now aluminum stampings, forgings and extrusions are becoming more visible components of mass reduction. Lower mass high temperature polymers, and carbon fiber polymer composites now replace aluminum and steel. These materials often require specialized processing and manufacturing techniques to produce a component, including superplastically formed twin roll cast sheet aluminum and magnesium, and hot stamped/in-mold quenched steels. The assembly of hybrid structures requires unique joining/bonding, and corrosion-inhibiting techniques that might include sophisticated structural adhesives. This thinking "light" presentation, will conclude with a discussion of U.S. and Canadian government engineering and research support for mass reduction, including the proposed $148 M American Lightweight Materials Manufacturing Innovation Institute.

Jan 1, 2014

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014

By Derek Egan

"Abstract Construction clients want their foundation solutions to be right first time, every time; but it is often the geotechnical contractor who carries the most risk in achieving this. Robust validation to ensure that the installed geotechnical product is appropriate for the encountered ground conditions, will perform as required and be correctly measured for payment and record purposes is very important to minimise the contractor’s and the client’s risk. This paper outlines the development and operation of a robust real-time installation monitoring system which controls and validates the installation of driven cast in-situ (DCIS) piling. Using state of the art information technology the system allows the design engineer to interrogate the data acquired from the piling rig via his computer as the piles are completed. The use of the validation process, where data acquired during the driving of DCIS piles can be processed to estimate the finished pile performance, will be explained with reference to a new case study on large diameter DCIS piles. Examples of the routine use of the system will be presented to illustrate how automated monitoring of installation parameters can be used to raise the standard of reliability, efficiency and sustainability on piling projects. The conclusions to the paper will cover the key features and operational challenges characterising real-time monitoring of the execution of geotechnical works as developed from a number of years of experience of using a rig based data acquisition instrumentation system.INTRODUCTIONDriven Cast In-Situ (DCIS) piles have a long and successful history of use worldwide. The process, where a temporary steel drive tube, sealed at the bottom with a sacrificial base plate, is driven into the ground and filled with concrete before the tube is withdrawn, is well known (BS EN 12699, 2001 and Egan, 2013). Examples of large structures supported on DCIS piles installed by Keller UK include the Millennium Dome (now the O2 Arena) and the 2012 Olympic stadium in London.In recent times advances in piling rig instrumentation and telecommunications have enabled a new level of sophistication in the recording of installation parameters and the validation of pile performance. It is now possible to embed these features into the DCIS design and installation process which has improved the quality and efficiency of DCIS piling.This paper summarises the development and operation of a real time data acquisition and processing system for DCIS piling, but which is equally applicable to other forms of driven piling (for example concrete precast piling)."

Jan 1, 2014

By R. J. Hundermark, L. R. Nelson

The critical importance of tap-hole design and management to furnace performance and longevity is explored through examining some of the specific matte, metal and slag tapping requirements of non-ferrous copper blister and matte converting and smelting, ferroalloys smelting and ironmaking systems. Process conditions and productivity requirements and their influence on tapping are reviewed for these different pyrometallurgical systems. Some critical aspects of the evolution of tap-hole design to meet the diverging process and tapping duties are examined. Differences and similarities in tapping practices and tap-hole management are reviewed. Finally core aspects of tap-hole equipment and maintenance are identified that are considered important to securing improved tap-hole performance and life, so pivotal to superior furnace smelting performance.

Jan 1, 2014

By Partha Patra

Numerous proteins of varying properties are available in extracellular bacterial proteins (EBP) isolated from Paenibacillus polymyxa. EBP was fractionated through ammonium sulfate precipitation in a controlled fashion and characterized through SDS-PAGE technique. Different groups of proteins, (Group A~D) exhibited varying degrees of surface affinity to minerals such as quartz, pyrite, chalcopyrite, galena and sphalerite. Interaction with mineral specific bioproteins rendered pyrite and chalcopyrite hydrophilic while surface of quartz, galena and sphalerite turned more hydro-phobic. Specific groups of proteins could thus be used for selective separation of galena, sphalerite and quartz from pyrite and chalcopyrite (as a mixed sulfide) through microbially-induced flotation or selective flocculation.

Jan 1, 2014

By Jacqueline Satur, Yoshiaki Kon, Buenaventurada Calabia, Xiao Sheng Yang, Arvo Naumanen, Kenzo Sanematsu, Sayaka Morita, Tetsuichi Takagi

Granite ores are composed of silicate minerals and a variety of valuable REE (rare earth elements)-bearing minerals, however the processing technique to recover these valuable minerals is not yet developed. In this study, the recovery of REE-bearing minerals by dry magnetic separation and wet high intensity magnetic separation (WHIMS)-settling from surface sample and from drill core sample, respectively, of a granitic REE-Zr-Nb ore deposit was investigated. The two samples have different mineralogy however in both samples, light REE are commonly contained in REE carbonate minerals while Y and heavy REE are commonly contained in zirconium silicate minerals and pyrochlore. The liberation size of the REE-bearing minerals in the two samples ranges from 10-250 ?m. Previous flotation testwork conducted on the drill core sample reported high recoveries of La2O3 (88%) and Ce2O3 (88%) but low recoveries of Y2O3 (42%), ZrO2 (17%), and Nb2O5 (29%). The objective of this study was to obtain higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling. Both processes implemented the application of a low magnetic intensity to initially separate the ferromagnetic minerals then a high magnetic intensity to recover the REE-bearing minerals. The results showed higher recoveries of Y2O3, ZrO2, and Nb2O5 by dry magnetic separation and WHIMS-settling indicating the potential of magnetic separation and gravity separation in recovering the heavy REE-bearing minerals. WHIMS-settling is more recommendable than dry magnetic separation because of its applicability in treating a wider range of particle size. In the WHIMS-settling, the light REE, Y, and Zr minerals were recovered mainly by applying four stages at high magnetic intensity of 21,500 gauss while the weakly magnetic pyrochlore was recovered mainly by decantation of the nonmagnetic slurry after a short settling time of 0.25 to 0.50 h. (MAX.300 words)

Jan 1, 2014

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

By O. Kökkilic

This study covers the tests to develop separation process for production of clay and colemanite rich concentrates, and aims to serve the clay and colemanite concentrates extracted from the tailing dams to the industrial applications. For this purpose, samples from the tailing dams in Kestelek Boron Plant (Turkey) with an average B2O3 content of 8%~11 % were subjected to the investigations. The separation process of hydrocyclone--to make clear the way to obtain either clean clay or cole-manite--was initially discussed. Therefore, following the gentle scrubbing (to keep the bimodal size distribution between clay and colemanite) of the tailings to disperse the slurry, two alternative multistage hydrocyclone processes; allowing to recycling the overflows or underflows to concentrate clay and colemanite were respectively tested. As a result of the preliminary tests, the multistage hydrocyclone separation in direction to the clean colemanite concentrates (recycling the underflows) gave the better separation efficiencies. So, all the parameters such as apex and vortex finder diameters and feeding pressures were examined with the multistage hydrocyclone process allowing the recycling the underflows. The detailed multistage hydrocyclone separation process of the tailing dam wastes yielded with colemanite concentrates (approx. 12 % of the feed, w/w) with B2O3 content of 35.0 % and the clay concentrates (approx. 42 % of the feed, w/w) with B2O3 content of 2.1 %. Colemanite concentrates were found good enough either to re-feed in to the separation process or to keep upgrading for final product ready to use in Industry whereas the attempts on production of light bricks from clay concentrates has failed. But it is worth to point out that these clay concentrates can be used for agricultural purposes just in the form as it is.

Jan 1, 2014

By R. Pelton, Z. Dai, S. Yang

ABSTRACT Hydrophobic polystyrene nanoparticles were evaluated as potential flotation collectors for pentlandite. The flotation of hydrophilic glass beads demonstrated the nanoparticles’ ability to induce flotation. Deposition of nanoparticles on glass surfaces increased the contact angle and enhanced adhesion of the beads to air bubbles. High flotation recoveries were achieved when 5–10% of the bead surfaces were covered with nanoparticles. Surface functionalization—the addition of vinylimidazole to polystyrene nanoparticle surfaces—caused the nanoparticles to selectively deposit onto pentlandite surfaces in the presence of Mg-Si slimes. Ongoing work includes attempts to identify specific applications where nanoparticle collectors might be cost effective. _ KEYWORDS Flotation, Nanoparticle collector, Coverage

Jan 1, 2014