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By David L. Borusiewicz, M. Suri Surendra

"Abstract Helical piles have been used as anchors and for supporting lightly loaded structures as a method of underpinning, etc in the past. Recently, helical piles are being used to support new structures because of their simple installation process using relatively light and mobile equipment. This paper presents the results of evaluation and design performed for the temporary support of existing piers during a bridge rehabilitation project.INTRODUCTIONThe helical screw foundation was invented and patented by Alexander Mitchell in England in 1833. He installed screw piles to support lighthouses in the tidal basins of England. Many applications in the earlier years in the USA were in North Carolina and in Florida to support lighthouses (in coastal plain deposits). A lighthouse of similar foundation design is still in use at Key Biscayne, Florida.In the USA, the helical piles were reintroduced as foundation elements for electrical transmission towers. Helical piles were also used for anchoring guys of self supported towers and as tie-backs for excavation support systems. Typically, helical piles are being used for supporting lightly loaded buildings and for underpinning buildings undergoing distress as a means of remediation. The helical piles are not commonly used in the transportation industry.HELICAL PILESHelical pile is a segmented deep foundation system with helical bearing plates welded to a central steel shaft. Load is transferred from the shaft to the soil through these bearing plates. Central steel shafts are available in either a square shaft (Type SS) or a round shaft (Type RS). The Type SS series are available in 38 mm to 57 mm square sizes. The Type RS series are available in 73 mm to 114 mm diameter sizes. Type SS-RS combinations are also available for compression applications in soil conditions where dense/hard soils must be penetrated with softer/loose soils above the bearing strata.The leading segment consists of a shaft with one or more helical plates that are welded to the shaft. The plates vary in diameter from 203 mm to 355.5 mm and have a thickness of 9.5 mm or 13.7 mm. Typically the plate diameter increases from the bottom of the shaft upward. A helical bearing plate or helix is one pitch of a screw thread. All helices, regardless of their diameter, have a standard 76 mm pitch. Being a true helical shape, the helices do not auger into the soil but rather screw into it with minimal soil disturbance. Helical plates are generally spaced a distance of two to three times the diameter of the plate directly below in order for them to function independently as individual bearing elements. A typical detail of helical pile is shown on Figure 1."

Jan 1, 2014

By T. Kagogo, M. Neser, C. Knobbs, E. Gerryts

"Contrary to the way it is often portrayed, the average organization or company is far from being a cold, calculating machine. It is actually a highly emotive place where interaction with people is a fundamental part of its ability to perform satisfactorily.The company, through its employers, expects employees, including new graduates, to have the ability to cope adequately with this emotive environment. The graduate is frequently unable to meet this expectation because he/she has not been developed to do so. Technical knowledge is his only asset. This deficiency manifests itself in leadership shortcomings, both intrapersonal and interpersonal. Further analysis reveals a deficiency in three elements of leadership - self-awareness, oral communication, and an ability to work cooperatively in teams.To address these three elements of leadership, Sasol Coal, a subsidiary of the big petrochemical company in South Africa, sponsored a leadership programme at the University of Pretoria for their final-year bursary students in the faculty of Engineering. This programme, the Sasol Engineering and Leadership Academy (SELA), consisted of a number of interventions designed to address the three areas of self-awareness, oral communication, and cooperative behaviour in teams. These interventions varied from an intrapersonal nature to interpersonal aspects. Psychometric assessments were followed by experiential modules dealing with the three constructs.SELA was evaluated at the end of the year. The results showed a positive shift in the main constructs of self-awareness, communications, and cooperation. This was measured quantitatively and qualitatively. Conclusions were drawn and recommendations for improving the programme were proposed."

Jan 1, 2014

By Mario Terceros H, Bengt H. Fellenius

"ABSTRACTThe city of Santa Cruz, Bolivia, is historically dominated by houses and three to five storey buildings.The geology in and around the city is such that even very light buildings need to be supported onpiles. The recent increase of the Bolivian economy, notably that of Santa Cruz, has created a demandfor new residential as well as office and industrial buildings, which mostly consist of multi-storey orhigh-rise buildings with significantly larger foundation loads. Foundation piles have become largerand longer, and the load on individual piles is increased. The development has resulted in an increasein the demand for more sophisticated design and construction methods and stricter approach toverifying the quality of the construction processes and results.This paper describes to geology of the Santa Cruz region and how the geotechnical conditions areconsidered in the design and construction of piled foundations. The improvement of past constructionand design techniques, based mostly on bored piles constructed with bentonite slurry, is beingreplaced with new methods of constructing bored piles, e.g. the Full Displacement Pile (FDP) andincorporation of techniques such as enlarging the pile toe, e.g., with the Expander Body. This paperpresents the results of several full-scale tests and discusses the incorporation of the test results indesign and construction.1 GEOLOGY OF THE REGIONSanta Cruz de la Sierra is located in the eastern lowlands and sub-Andean zone of Bolivia, SouthAmerica. The area lies at an elevation of about +400 m and the geology is a Paleozoic (250 millionyears old) sedimentary basin. The soils of interest to civil engineering construction are quaternarywith the dominant minerals being calcite, silica and feldspar. The main agent is the Piray River and itstributaries. Their past meandering over the area has resulted in a sedimentation-erosionsedimentationprocess and a profile dominated by fine to medium sands with intermittent layers ofclay or clayey sand. With increasing distance from the river, the clay-containing layers are thicker.Fig.1.- View of Bolivia with location of Santa Cruz and map of Santa CruzThe upper about 15 to 18 m thick part of the profile consists of normally consolidated layers of clays,silts, sands, in various combination and thickness. Below, the soil is more homogeneous and consistsmostly of sand and gravel. The groundwater table lies typically at a depth of about 6 m in the highestpart of the city and at about 1 to 3 m depth in the lowest part of the city."

Jan 1, 2014

By George Piscsalko

"Quality control of drilled shafts and CFA piles is greatly dependent upon the practices of the site personnel. In many applications it is difficult or not possible to fully inspect the shaft prior to concreting, such as when the shaft is drilled under slurry. CFA piles are cast with no ability to inspect the shaft prior to concreting. There are numerous methods currently available to assess the integrity of drilled shafts and CFA piles. This paper will compare evaluations by three existing non-destructive test (NDT) methods with a new method of Thermal Integrity Profiling for assessing integrity in drilled shafts and CFA piles. This Thermal Integrity Profiling method determines the integrity over 100% of the shaft cross section, both inside and outside the reinforcing cage, by measuring the hydration temperature of the concrete along the length of the shaft. These temperature measurements are made typically only 12 to 48 hours after concrete placement, thus accelerating the construction process. Thermal Integrity Profiling will be described in detail and the Thermal Integrity Profile (TIP) results from several shafts with purpose built defects will be discussed along with several case histories from drilled shafts and CFA piles where Thermal Integrity Profiling was used. The case histories will compare TIP with various other NDT tests utilized on these particular piles including comparisons with Low Strain Integrity Testing and Cross Hole Sonic Logging. Test results for the various methods will be discussed and the excavation of the upper portion of one drilled shaft will be shown and discussed. IntroductionDrilled shafts can be a desirable foundation element in many applications due to the large axial and lateral capacities which are attainable for very large drilled shafts. Drilled shafts can be cast in a dry hole which allows for inspection of the hole prior to casting, but the casting process is very difficult to nearly impossible to inspect with any accuracy. Drilled shafts are frequently cast under slurry as a means to stabilize the surrounding soils during the construction process. When casting a drilled shaft under slurry, it is very difficult to accurately inspect the hole prior to casting and it is equally difficult to inspect the shaft during the casting process. CFA piles are another popular choice for their relative ease and speed of installation. The trend has been larger CFA piles carrying greater loads, which makes quality control critical for these piles. Many of the above mentioned processes are blind to inspection and therefore the chances increase for having defects present in the completed elements."

Jan 1, 2014

Incomplete liberation of mineral particles is one of the key factors limiting the performance of industrial flotation circuits. This work aims to quantify the relationship between different breakage modes and how these affect mineral liberation properties. A copper porphyry (bornite) ore sample was subjected to breakage using a piston-die compression unit and an impact mill. The particles produced as a result of each mode of breakage were then characterised using Mineral Liberation Analysis (MLA) to quantify the mineralogical and liberation properties of the progeny particles. The impact mill was found to produce bornite that was finer grained relative to the host particles. In con-trast, bornite discharged from the piston-die unit closely followed the size distribution of the host particles and was retained to a greater extent in the larger/intermediate size fractions. The results provide insight into what breakage methods are optimal for the purposes of downstream separation.

Jan 1, 2014

Of the many organic impurities present in Bayer liquor, sodium oxalate is known to have one of the most detrimental effects on the Bayer process. Because of its limited solubility, it will co-precipitate with gibbsite during the precipitation stage which results in many operational challenges for the refinery. Despite the importance of this phenomenon, the interaction mechanism between gibbsite and sodium oxalate is not well understood. In this study, the growth of sodium oxalate on three main morphologies (random agglomerates, prims and hexagons) of water-washed and caustic-washed gibbsite was observed under synthetic Bayer conditions using in situ optical microscopy. After a short induction period, oxalate started to nucleate on gibbsite crystals, and grew with a needle-shaped morphology which eventually developed into oxalate bundles. In addition, the results indicated that caustic washing was able to partly decompose gibbsite crystals and thus make the gibbsite surface rougher, which provides more potential sites for oxalate nucleation and growth. The growth rate of oxalate crystals on the basal (001) face of water-washed gibbsite was 1.33 µm/min determined by the time-lapse imaging of in situ optical microscope.

Jan 1, 2014

By Jon R. Maki

"EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer’s pellet silica requirements. In addition, the mine plan was moving towards a lower grade ore and funding was not available for plant improvements to compensate for the change in ore or improving quality. Small changes to optimize various processing equipment resulted in significant improvements in both quality and productivity; for example, productivity on one mill line increased by 10% while producing lower silica concentrate. This paper will provide the methodology that allowed EVTAC to improve quality and productivity through process optimization with little capital investment.INTRODUCTION EVTAC, an iron ore mine in Minnesota, had trouble meeting the customer pellet silica requirements. In addition, the short-term mine plan was changing to a lower ore grade. Because of limited funds, EVTAC did not have the capital for investing in the plant to compensate for the ore change or to make improvements to lower product silica levels. Small changes to optimize process equipment resulted in significant improvements in quality and productivity; for example, one mill line feed rates increased by 10% while also producing a higher quality concentrate. These changes were sufficient enough to allow the mine to lower the target ore grade beyond their initial goal. At one time, a $3M flotation facility was considered as a way to meet quality with the new ore grade. However, the process changes were able to accomplish the same silica reduction with roughly a $50,000 investment in VFDs for sump controls. This paper will discuss some of the modifications that allowed EVTAC to meet the quality and production objectives with little capital investment. It also discusses the methodology used to make these process improvements."

Jan 1, 2014

By O. D. Khmelnitskaya

The research on selecting of an efficient technology of pyrite cinders complex treatment, sulfuric acid production wastes, have been made. The grades in the initial product were 2.04 g Au/t, 35.0 g Ag /t, 0.38%Cu, 1.1% Zn. Laboratory tests on cyanide technology, thiourea and sulphite leaching were carried out. Magnetic and flotation beneficiation and biohydrometallurgical technology were tested. After considering the results of the tests, the most economically efficient technology of pyrite cinders complex treatment with cyanide leaching of precious metals was determined. The technology involves water washing of soluble copper and zinc compounds, lime treatment and cyanide leaching of gold and silver, detoxification and utilization of mineral wastes. The precious metals are recovered from solutions by cementation onto zinc. Copper is recovered from rinse waters by SW/EW and then zinc is precipitated as hydroxide. All the solutions and organic agent are used in recirculation and therefore the technology is practically waste-free. Mineral wastes can be used as iron-containing materials for cement industry. The technology has been tested in pilot-plant scale under continuous operation with complete re-circulation of cyanide solutions. In this process recovery of 54% Au, 45% Ag, 30% Cu and 50% Zn has been achieved.

Jan 1, 2014

By W. M. Zeng

A mixed culture of moderately thermophilic microorganisms was enriched from Acid Mine Drainage (AMD) samples collected from several chalcopyrite mines in China,which can leach copper from chalcopyrite effectively. Its tolerance to chalcopyrite was brought up to 80 g/L after being adapted to gradually increased concentrations of chalcopyrite. The effects of several leaching variables on copper recovery in Stirred Tank Reactor had been investigated. The ore contained chalcopyrite (62.2%) and galena (25.6%) as the main sulfide minerals. The results of the tests show that it is possible, operating at 8% of pulp density to attain copper extraction of 75% in 44 days. The leaching rate of chalcopyrite tends to increase with the dissolution of total iron. Microscopic counts of microorganisms in the solution tend to be higher at low pH range. Furthermore, the analyses of leached residues indicate that the passivation of this chalcopyrite is mainly due to the formation of a mass of jarosite and anglesite (about 48.3% and 21.7% in residue respectively), other than elemental sulphur layer. The bacterial community composition was analyzed by using amplified ribosomal DNA restriction analysis (ARDRA). Two moderately thermophilic bacteria species were identified as Leptospi-rillum ferriphilum and Acidithiobacillus caldus, with different proportion in the bio-pulp, 67% and 33%, respectively.

Jan 1, 2014

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By Sudarshan Martins, Peter Radziszewski

"Tumbling mills are machine, operating in non-equilibrium, capable of applying forces on the ore contained within, causing the ore to break down. The action of the mill on the ore is very inefficient, producing a large quantity of heat. The inefficiencies of the mill drive the desire for improvement, spawning research and development activities. Given the non-equilibrium nature of the mill, the theory of Large Deviations is proposed as the framework that captures the state of the mill. The theory of Large Deviations allows for the determination of the rate function and the scaled cumulant generating function (SCGF), for systems in either equilibrium or non-equilibrium. Powerful connections can been made between familiar concepts of statistical physics and the concepts introduced by the theory of Large Deviations: entropy can be associated with the rate function; the scaled cumulant generating function with the free energy. It is shown that observables, compatible with Large Deviation theory, can be identified for the tumbling mill. Here, the time series of the energy associated with an element of the charge is such an observable. Furthermore, using some experimental data, it is shown that the time series of the energy can define a rate function, thereby describing the system within the Large Deviation framework. Finally, a discussion of the results is given, particularly how this theory can be further developed for tumbling mills."

Jan 1, 2014

By F. M. Doyle, G. Sidhu, A. J. Dussault, A. Raygani

There is a growing demand for rare earth metals for use in high strength permanent magnets, most notably Nd2Fe14B. Rare earth metals are extremely reactive, with reduction potentials around -2.5V SHE, and are conventionally produced by molten salt electrolysis. The current work was done to investigate an earlier report of electrodeposition of a neodymium ferroalloy from aqueous solution, to determine whether this approach could be an environmentally and economically competitive commercial approach for producing feedstock for permanent magnets. Such a process would be analogous thermodynamically to the Castner- Kellner process, in which aqueous sodium chloride brine is electrolyzed in cells with mercury cathodes. Metallic sodium forms an alloy (amalgam) at the cathode, thereby lowering the activity of the metallic sodium significantly below unity and making the reduction potential of sodium significantly less negative than the standard reduction potential. Here we report the effects of Nd/Fe ratio in the electrolyte, current density, temperature and two different complexing agents, glycine and cysteine, on the composition and morphology of the electrodeposits, along with current efficiency. The energy needed to produce neodymium as Nd:Fe alloys by aqueous electrodeposition was compared with values estimated for production by molten salt electrolysis and the thermodynamic energy requirement.

Jan 1, 2014

By W. Ferreira

Steel is produced in a basic oxygen furnace from hot metal obtained from a blast furnace. A sintered iron ore with good hightemperature properties (strength and permeability) should be used as feed to the blast furnace. The quality of this sintered ore depends on the reactivity of the iron ore used as feed to the sinter plant during the lime assimilation step in the sintering process. The penetration test is the standard method for evaluating the reactivity of iron ore with lime. It is, however, difficult to determine the exact depth of penetration from the standard test. A new test method is proposed that allows automatic evaluation of iron ores in terms of lime assimilation with increasing temperature. A comparison of the coefficients of variation for the new and standard methods for each ore type demonstrates that the results of the new test are more reproducible and more precise than those of the standard method. The test is also less time-consuming and easier to implement.

Jan 1, 2014

The estimation of the spatial variation of the b-value of the Gutenberg- Richter relationship is important for both the general interpretation of the mechanism of rock mass response and seismic hazard assessment. The interpretation of b-value as a parameter of rock mass response is discussed in this paper. The methods applied to evaluate the spatial variation of b-value and the algorithm for obtaining the magnitude of completeness and b-value for subsets of data are presented with some verification analyses. The algorithms presented enable the automation of a spatial evaluation of b-value.

Jan 1, 2014

By Yuri Yemelianov, Stanislav Balikov, Alexander Epiforov, Andrey Boldyrev, Andrey Bogorodsky

"Test work was carried out using copper gold-bearing flotation concentrate with 6.85%Cu, 14.30%Fe, 20.70%S and 2.34%As. Gold and silver grade in the concentrate is 54.6 g/t and 92 g/t, respectively. Gold and copper are valuable components in the concentrate. Gold is partially associated with pyrite and fahlores. Copper in the concentrate can be found as tennantite (Cu12As4S13). The 71% of gold from the flotation concentrate is recoverable by cyanidation with simultaneous cyanide consumption in the amount of 96 kg/t. The major reason of refractoriness is that gold is fine encapsulated into sulfides and the presence of cyanicide-copper. The concentrate ground as much as 95% minus 10 µm was treated using low-temperature POX at the temperature of 100±5°C, L:S ratio of 5:1 and the process time of 1-5 hours. Residual sulfide sulfur in the cake is 2.28% which is 89% sulfide oxidation. The highest copper recovery to POX solution is 91%. It was found that gold recovery to cyanide solution is 85-94% during alkaline pre-treatment of POX cakes followed by cyanidation. In this case, cyanide and lime consumption is 75-90 kg/t and 120 kg/t, respectively. In order to recover precious metals from POX cakes leaching using sodium sulfite was carried out. Test work was conducted at varied reagent concentration, L:S ratio and leaching time. Gold and silver recovery achieved was 85-95% and 59-63%, respectively."

Jan 1, 2014

By Cz. Mora, A. Pawelczyk, D. Hreniak, P. Nowak, A. Dyonizy, S. Strek, W. Strek, K. Grabas, A. Ostrowski

Globalization and a growing demand for limited raw material resources have forced changes in the approach to the supply chain. This is particularly true in the case of rare earths, which are regarded as one of the most important development indicators of modern technologies. To ensure a secure supply of commodities, the European economies have been prompted to investigate REE recovery from sources which until recently, for technical or economic reasons, were considered not sufficiently attractive. An interesting example is apatite phosphogypsum waste dumps. The REE content in these waste dumps averages around 0.5-1 %. One of the most important phosphogypsum locations in Poland is the Lower Silesia region where a phosphoric acid Chemical Plant "Wizów" operated for several dozen years. In this work, rare earths are leached from the phosphogypsum crystalline structure by a chemical treatment and can then be separated into individual chemical compounds. The technology used in these recovery tests, matches up to a coherent European raw materials policy supporting effective management of resources and promoting waste materials recycling.

Jan 1, 2014

By J. Jacob

Diamondiferous linear beaches in Mining Area No. 1 have been the mainstay of Namdeb?s diamond production for more than 80 years. Most of the onshore beaches have been mined out, but in recent years mining has been extended offshore into the surf zone through a process of beach accretion. A total of 61.6 million carats has been produced from the gravel beaches since their discovery in 1928, and Mining Area No. 1 is considered to have great remaining potential from areas currently submerged under water. To date, the surf zone has remained largely unexplored due to the consistently strong winds, currents, and large waves which make access to this area extremely difficult. This paper describes the processes used in developing a practical methodology for exploration of the surf zone in a domain extending approximately 22 km long in a northwest?southeast direction and 0.3 km wide in a perpendicular direction adjacent to the current Mining Area No 1. The vigorous surf zone poses multiple technical challenges in terms of obtaining geological and diamond information. In order to access the area for sampling, a jack-up walking probe drill platform (PDP) with a 5-inch diameter reverse-circulation drill has been developed to carry out exploration drilling in the dynamic surf zone. The hydraulically driven platform has eight legs, each of which is 18 m long. Four of the legs are in fixed positions on the fore and aft sides of the platform. The other four moveable legs are fitted to sliding frames attached to the port and starboard sides of the platform. The sets of fixed and moveable legs can be raised and lowered by hydraulically powered jacking stations. By alternately lifting and lowering the sets of fixed and moveable legs in conjunction with the frames moving back and forth horizontally, a walking action is performed by the PDP. The platform can walk at a speed of 10?15 m/h, depending on weather and footwall conditions. Optimization of sampling for diamondiferous gravel occurrence in Mining Area No.1 was undertaken through creation of a virtual orebody on which different sample configurations were tested. The input data for the construction of a virtual orebody comprises a set of drilling data, collected from recently accreted areas directly adjacent to the 22 km × 0.3 km target domain. The input drilling data covers only 34% of the domain, and for the purpose of this study, a single realization is deemed to be sufficient. The texture obtained from using only the drilling data to construct a simulation did not make geological sense; hence it was necessary to make use of analog data in order to improve the simulation. The first analog data used consists of the gully patterns found in the metasedimentary Precambrian bedrock footwall. Gullies are, in general, gravel filled and it is fair to assume that gully patterns form a subset of the total gravel occurrence. Total gravel occurrence includes marine terraces (governed by sealevel stands) above bedrock peaks, together with gravel within gullies below bedrock peaks. The second analog ?data? introduced is through the use of ?expert interpretation?. The indicator drilling data is interpreted by expert opinion and the 2-dimensional result is hand-sketched, digitized, and then pixelated. The pixelated data set is then used as input for variogram calculation. This study cannot provide a single definite optimization result as the nature of the data does not permit this. The use of different validation approaches (conditioning data, where available; expert interpretation; and gully pattern data), however, can give a very good indication of how to balance sampling effort with de-risking aspects related to geological continuity. Work undertaken by sampling the simulation will give an assessment of the relative probabilities of determining gravel occurrence in the study area. This study showed that a 50 m × 400 m cross-configuration will be a good initial sample spacing for highlighting areas where gravel may be absent, and further infill drilling may be required. The relative efficiency of a 50 m × 400 m cross off-set sampling configuration has been demonstrated using a trumpet curve versus sampling effort when using kriging as the estimation method. Keywords sampling configuration, marine diamonds, orebody simulation.

Jan 1, 2014

By A. Schönecker, P. Y. Pichon, B. Kraaijveld, Y. Meteleva-Fischer

"Ribbon-growth-on-substrate is a casting method, which offers a possibility to control heat flow, nucleation and subsequent crystal growth at the liquid-substrate interface. This technology allows for low-cost and high throughput shaping of silicon sheets with controlled crystal grain size and orientation for use in solar cells. In this work, sheets of silicon- metal silicide composite materials were produced and their microstructure was studied. It was shown that depending on the relevant phase diagram and casting conditions, a micro/nano-sized eutectic structure of the casted sheet can be formed. Such composite materials possess properties promising for various applications in energy generation, storage and conservation. The advantages, potential and challenges of the ribbon-growth-on-substrate technique for production of composite sheet materials as well as novel areas of application for such materials are discussed.IntroductionThe Ribbon Growth on Substrates (RGS) process is well known in the solar industry as a process to produce multicrystalline silicon wafers. An industrial size pilot production line for continuous casting of silicon wafer was developed by RGS Development B.V. in the Netherlands (Figure 1). A comprehensive review of this technology and properties of the produced silicon wafers were reported by Schönecker et al [1]. The principle of the RGS process is explained in Figure 2. The relatively cold substrate extracts the crystallization heat from the liquid silicon in the casting frame. This results in the growth of a silicon ribbon (Vc) in contact with the substrate. When the substrate (Vp) is transported from the casting zone into the cooling section, the crystal growth stops, the wafer can be removed and the substrate can be re-used. Last few years large work was done on the industrialization and market development of RGS wafers for the solar industry. Part of this work was discussed by Schönecker et al [2]. Although there is still a good perspective on the middle and long term solar market for the RGS wafers, the current market situation was found to be unfavorable for new entrants."

Jan 1, 2014

By Helfried Nafe

"For about a century thermodynamically absurd facts have been propagated in conjunction with the iron-carbon phase diagram. These facts concern fundamental relationships of chemical thermodynamics. Attention is turned here to the discussion of only one of the relevant aspects of the subject, i.e. the definition of the thermodynamic activity of the solute and its implications for the iron-carbon solution.IntroductionThe view on the iron-carbon solution is characterized by the assumption that the solute may appear in two different forms, i.e. graphite and cementite. Accordingly, two carbon solubilities are differentiated, on the one hand for graphite and, on the other hand, for cementite. As a consequence, two versions of the phase diagram exist simultaneously, the application of which depends on the prevailing conditions, (i) the so-called stable phase diagram with graphite as solute and (ii) the metastable one that is based on the cementite-in-iron solution. These diagrams are joined together in the double phase diagram that originates from Heyn [l ], with the first ideas mainly going back to Stansfield [2] and Charpy [3].Thermodynamically, the most inadequate implication of the Fe-C double phase diagram is that the carbon activity may take values larger than unity. With the standard state of the activity being that of the pure substance, i.e. the Raoultian one, such a value implies the nonsensical existence ofa state purer than pure. The explanation of this physical state, ifthere is any, vaguely refers to supersaturation and, in the wider sense, to the physico-chemical phenomenon of metastability. Other aspects of chemical thermodynamics are likewise involved. Therefore, the comprehensive investigation into the present subject requires more topics to be considered than only one separate issue. Not only should the criticism of the present view be in the focus but also the discussion of new ideas capable of reconciling the experimental facts, known about the F e-C system, with the fundaments of chemical thermodynamics. All this, however, cannot be provided here because of the limited space available. As a consequence, in what follows only a part of the whole problem is under scrutiny, i.e. the definition of the thermodynamic activity and its role for the interpretation ofrelevant experimental facts."

Jan 1, 2014

By L. S. Zhou

Germany-made AFX-100 multi-grade fluidized classifier, with exquisite built-in structure and unique novel design, materializes not only advanced and efficient classification, but also precise particle distribution and safe operation, in addition to lower energy consumption and operational cost. It, simultaneously in place of screw grader, water cyclone, and fine mesh sieve, is equipped with multi-function, and indicates superior advantage in comparison with other else grading facilities. As the third-generation equipment, which is efficient and modern, it, in China and therefore all over the world, will find wide application in processing both fine and ultra-fine iron ore resources. Industrial test, carried out in Benxi Steel?s Waitoushan Iron Mine, shows efficient classification, i.e., ?74µm particle contents in coarse, medium and fine products come to 6.09%,11.82% and 82.73%, respectively, while qualitative and quantitative efficiencies end up by 74.38% and 87.66%, respectively. Its separation efficiencies amount to 2.2 times as many as spiral classifiers, 1.8 times as hydrocyclones, and 1.3 times as vibration high-frequency fine screens. Another industrial test, which was practiced in Anshan Steel?s Donganshan Sinter Plant, indicates that classification qualitative efficiency comes to 65.06%, equal to 1.51 times as many as hydrocyclones; yield, 55.79%; -71µm particle contents in medium and coarse products, 42.02%; -71µm content in fine product, 95.42%; and concentration, 12.33%. Estimated separation indexes are as follows: Yield for concentrate at 31.22%, up 0.22% than that from general processing line; concentrate grade at 66.42%, up 1.13%; recovery ratio comes to 65.84%, up 1.28%, which, based on pilot study, results in 20 million yuan of economic return for Donganshan Floatation Plant.

Jan 1, 2014