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By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

Jan 1, 1997

By M Muzammil, S. Mukerjee, S. Saran, M. Bharathi

"This paper presents the results of in-situ tests conducted on a set of under-reamed piles in a silty sand deposit. Three piles (i.e. vertical, vertical with one bulb and vertical with two bulbs) of diameter 0.2 m were cast upto a depth of 5 m. The pile cap had four foundation bolts cast into it so that a mechanical oscillatormotor assembly could be mounted centrally on it. The oscillator-motor assembly was used to generate purely sinusoidal dynamic forces, in either horizontal or vertical directions. For both horizontal and vertical vibration cases, it was observed that (i) the natural frequencies decreased with an increase in the excitation force level, (ii) for the same excitation level, the natural frequencies as well as the maximum amplitude of vibration are almost the same irrespective of the pile geometry i.e. number of bulbs in the pile, indicating that the full pile length is not being excited. For the vertical vibration case, the soil-pile stiffness at frequencies, before resonance, were observed to be higher than those at frequencies after resonance. In the horizontal vibration case, the stiffness of the soil-pile system was found to be decreasing with an increase in the excitation force level. The damping ratio was found to be increasing with an increase in the excitation force level.INTRODUCTIONUnder-reamed piles are piles, normally upto a depth of 6 m, with one or more bulbs along the pile stem. These have been used for structures like transmission towers, structures on expansive soils etc. for a very long time, however it is only in the last 30 years that dynamic response of a pile has been studied. Evaluation of dynamic soil-pile interaction is a very complex problem as the conditions and properties of soil are highly variable and unpredictable. Various models and approaches have been suggested by various investigators for evaluating the dynamic soil-pile interaction problem, but most of them are based on the assumptions that the behaviour of soil is linear and the soil surrounding the pile is strongly adhered to it. But in practice, it is not so. The soil surrounding the pile is always somewhat loosened and undergoes some deformation when a sinusoidal load is applied. This causes the soil-pile system to behave nonlinearly.In earlier studies by Novak, (1974), Novak and Aboul-Ella, (1978) etc. a linear elastic behaviour of soil was assumed. This approach was very useful in understanding the mechanism of soil-pile interaction to a large extent. Subsequently various models were suggested like the lumped mass models with nonlinear discrete springs, dashpots and friction elements Matlock et al. (1978), weak cylindrical zone around the pile model Novak and Sheta, (1980), ideal boundary zone model with non-reflective interface, Han and Sabin, (1995) etc. These approximate solutions give an idea about the mechanism of dynamic pile-soil interaction to a large extent. However, in reality both separation and slippage can occur due to the formation of a weak bond at the contact surface between the soil and the pile when a dynamic load is applied. In addition, the soil column adjacent to the pile experiences large deformations under dynamic loads and thus behaves nonlinearly.Some computer aided model studies on the dynamic response of under-reamed piles have been reported, however, very few insitu dynamic tests on under-reamed piles are reported. Dynamic tests on piles were carried out by Novak and Grigg (1976) on small scale single piles and pile groups in the field. Similar field tests on small scale piles were conducted to study the nonlinear behaviour of a single pile and a pile group under strong harmonic excitation by Han and Novak (1988), Han and Vaziri (1992), Burr et al. (1997), Manna and Baidya (2010) etc. The majority of these experimental studies were focussed on the response of the specific pile groups and compared with the results of a single pile. Hence there was a need to study the influence of pile g"

Jan 1, 2015

By Milton Camino Ramos

MARSA forma parte de los yacimientos vetiformes de la franja metalogenética aurífera del Batolito de Pataz, y políticamente se encuentra ubicado en la provincia de Pataz, La Libertad. En este sentido, el presente texto describe los resultados del programa de exploración 2010-2011, donde se dio el descubrimiento del primer cuerpo mineralizado del yacimiento, el cuerpo Esperanza, entre otras ocurrencias. Asimismo, se muestra que los cuerpos mineralizados de la franja metalogenética de Pataz, se formarian en estructuras de primer orden con evidencias de reactivacion, cuyo sistema estructural funciona como entrampamiento y en varias etapas de mineralizacion.

Sep 12, 2011

By Takuya Taguchi, Toshihiro Ogata, Atsuio Inoue, Shigeyuki Sasaki

Highly improved drilling machines and mucking machines have been used for the underground construction. To have rapid construction, the roles of blasting operation ha ve been growing more important. At the most tunneling of present, cartridged emulsion explosives have been used for a blasting in Japan. Under this circumstance, a blasting system of ANFO explosives using loading machine has been used recently for a tunnel blasting. However, ANFO has some problems, such as a useless explosives in wet boreholes, bad blasting fumes and the ammonia gas due to the decomposition of ammonium nitrate in contact with the sprayed concrete in tunnel.

Jan 1, 2005

By Marcus Vinícius Pereira Arruda

A moderna construção automotiva vem adotando uma série de estratégias para tornar os carros cada vez mais seguros e ecológicos. Dentre elas, o uso intensivo de aços de alta resistência tem proporcionado grandes avanços nos automóveis, principalmente aqueles ligados à segurança veicular. A escolha de um determinado aço é hoje definida, não só pela resistência mecânica, mas também pelos atributos do material ligados a sua aplicação. Assim, a composição química, as variáveis de processo, e, consequentemente, a microestrutura do aço, devem ser reflexo desses atributos. O presente trabalho apresenta o desenvolvimento de um aço multifásico da classe de resistência de 1180 MPa na Usiminas, assim como suas características mecânicas que influenciam a sua aplicação. São apresentados aspectos das simulações efetuadas em escala piloto, a consolidação das informações obtidas e o trabalho de engenharia de produto realizado para o desenvolvimento industrial.

Oct 30, 2017

The structure of the Bulli coal seam at Appin Colliery was detailed by the seismic reflection method. This unusual application of the seismic method was possible because there is a reflector near the seam as was revealed during exploration for petroleum in an area north-west of Appin. The reflector, which was at a depth of 1,500 ft, was shallow by normal reflection survey standards. Measurement of the seismic velocity at two ventilation shafts showed that the reflector was probably the Bulli coal seam. Accurate depth control was established from previous drilling results.INTRODUCTIONAppin Colliery, situated on the Southern Coalfield of N.S.W. (Fig. 1), is being developed to supply coking coal to the Port Kembla steelworks of Australian Iron and Steel Pty. Ltd. The colliery is mechanized and a detailed knowledge of structure, particularly faulting, is important in planning the workings.The Bulli seam, which is approximately 9 ft thick, and between 1,500 ft and 1,800 ft below the surface, is worked in the colliery. It is the uppermost member of the Permian Coal Measures and is overlain by Triassic rocks, which consist of thick sandstone beds containing beds of coloured shales, and which are subdivided into the Narrabeen Group, the Hawkesbury Sandstone, and the Wianamatta Group.In the early stages of development of the colliery, surface geological mapping and diamond drilling provided information on structure. Generalized results of the mapping are shown on Fig. 2. Drilling indicated that the physical and chemical properties of the Bulli seam are relatively constant, and that the seam is nearly horizontal, the average dipbeing about 1 in 25 to the west.

Jan 1, 1965

An optical computing system was used to determine spacings and frequencies in geological fabrics and engineering joint fabrics.Three-dimensional arrays of joints were plotted on an equal-area net. Directions in which true spacings are seen were determined from these plots. Photographs taken along these directions were used for optical computing.

Jan 1, 1970

By Richard L. Unger

The Bureau of Mines entered into a cooperative agreement with an eastern Kentucky coal mining company to comprehensively redesign the flow of equipment and supplies throughout its underground mines. Items were tracked from delivery to the warehouse and from surface storage areas to their final usage locations underground. Three underground mines were visited, and a great variety of tasks were videotaped for subsequent laboratory analysis. Of particular interest were tasks that required manual handling of the supplies or equipment components. Activities such as handling daily supplies (concrete blocks, rock dust, and cross- beams) and handling or lifting the continuous miner power cable were determined to be the most hazardous. Recommendations to the company included redesigned surface storage areas to facilitate the use of forklift vehicles to load the underground supply cars. Designs were also developed for different mechanical- assist devices to help in unloading the supply cars underground and to handle equipment maintenance tasks underground. Additionally, the videotapes of the underground manual handling tasks became the basis for simulating those activities in controlled laboratory conditions. This testing will contribute to developing guidelines for proper lifting techniques for low-seam coal mines.

Jan 1, 1986

By Sam X. Yao

The underwater concrete technology has historically evolved largely through a trial-and-error process of constructing marine works. Many outstanding examples exist of high quality concrete placed underwater. However, failures also occurred and led to excessive cost and/or schedule overruns. These failures were largely due to improper concrete mix design or improper placement. The problems may have occurred because proper underwater concrete construction techniques and experience have not been widely disseminated. This section focuses on technical issues of underwater concrete mix design, concrete production and placement, and quality control.

Jan 1, 2013

By Shaw-Shong Liew

This paper presents the processes of investigation, analysis, design, construction and monitoring of soil nail stabilisation work to facilitate a 14.5 m deep excavation at an uncontrolled fill ground. An extensive instrumentation programme had been implemented to monitor the performance of the stabilisation solution, to provide validation for the designed nail resistance and groundwater variation. From the monitoring results, it was proved that the soil nail stabilisation technique is effective for loose saturated fill provided that substantial care is taken during implementation. Construction difficulties, solutions to overcome the problems and lessons learned will be discussed in the paper.

Jan 1, 2006

In this address I look back over the past 40 years of mineral exploration in New Zealand û essentially the period since the Second World War (ie since 1945). It was the period of my personal involvement, and indeed of the personal involvement of a number of you. Luckily it was aperiod of great interest and activity. In the previous 50 years, virtually nothing had happened, and it is kindest to draw a veil over that period. In the very important earlier 40 years (1855 - 1895) the New Zealand gold rush occurred. That must have been a fascinating, rewarding period, which has been thoroughly documented by better historians than myself. I will simply comment firstly that its mineral explorers (gold-prospectors) were very successful indeed, and found most localities of the minerals they sought, in spite of using very different methods from ours of today. Secondly, they were preceeded by one of Maori exploration, which searched for a much restricted list of minerals, but succeeded in finding virtually every locality we know of today. The explorers of both of these early periods were obviously highly successful, but, in the time available, I must restrict myself to the period since 1945. I am currently editing the effective up-dating of Gordon WilliamsÆ 'Economic Geology of New Zealand' (1974). It covers the last 12 years or so. Many of you are contributing to that volume û both as authors and as referees û and I would like to take this opportunity of thanking you all. Although this new volume excludes the energy field, many of us have been involved in it, and I am therefore including energy minerals in this review, as Williams did in 1974.

Jan 1, 1987

By D. F. Smith

The thermodynamic data presented in the literature for zirconium compounds are incomplete. Among the compounds for which adequate data are Zacking are zirconium fluoride and sulfate. This paper reports experimental heat-content values determined by the Bureau of Mines for these two zirconium salts throughout the temperature range of 273° to 1,200° K. No crystalline transformations were found in the two compounds investigated, and neither of the compounds melted over the temperature range studied. MATERIALS TESTED The Oak Ridge National Laboratories, Oak Ridge, Tenn., supplied the two zirconium salts used in this investigation. The zirconium fluoride was high- purity reactor grade material. The zirconium sulfate contained between 0.01 and 0.10 percent hafnium and calcium, and other elements in concentrations below 0.01 percent, A spectrographic analysis of the two compounds is given in table 1. Before use the compounds were dried at 400° C. for several hours to removed adsorbed moisture.

Jan 1, 1962

By Earl T. Hayes

[This work represent a continuation of the efforts of the Metallurgical Division of the Bureau of Mines to ascertain and apply knowledge of miner physics to processes metallurgy.]

Jan 1, 1941

By Earl T. Hayes

[This work represents a continuation of the efforts of the Metallurgical Division of the Bureau of Mines to ascertain and apply knowledge of mineral physics to process metallurgy.]

Jan 1, 1941

By E. F. Johnson, V. O. Naumann, D. P. Bossler

A method is presented for calculating individual gas and oil or water and oil relative permeabilities from data obtained during a gas drive or a waterflood experiment performed on a linear porous body. The method has been tested and found both rapid and reliable for normal-sized core samples. INTRODUCTION Individual oil and gas or oil and water relative permeabilities are required for a number of reservoir engineering applications. Chief among these is the evaluation of oil displacement under conditions where gravitational effects are significant, such as a water drive or crestal gas injection in a steeply dipping oil reservoir. Numerous proposed methods of obtaining relative permeability data on reservoir core samples have been too tedious and time consuming for practical use, or have yielded questionable and sometimes inconsistent results. A method has been developed by which the individual relative permeability curves can be calculated from data collected during a displacement test. The method is based on sound theoretical considerations. Using this method, with a properly designed experimental procedure, relative permeability curves can be obtained using core samples of normal size (i.e., 2 to 3 in. in length and 1 to 2 in. in diameter) within a few days after receipt of the core. In a recent publication D. A. Efros1 describes an approach to the calculation of individual relative permeabilities that is based on the same theoretical considerations. We believe the approach described in the present paper is more adaptable to practical application than the method implied by Efros. In addition, comparisons with independently determined relative permeabilities are furnished to substantiate the reliability of the new method. DERIVATION Previously the theory of Buckley and Leverett as extended by Welge2 as been used to calculate the ratio of relative permeabilities. In the derivation which follows, this theory is further extended to permit calculation of the individual relative permeabilities. The theory assumes two conditions which must be achieved before the method is applicable. They are that the flow velocity be high enough to achieve what has been termed stabilized displacement,3 and that the flow velocity is constant at all cross sections of the linear porous body. In stabilized displacement the flowing pressure gradient is high compared with the capillary pressure difference between the flowing phases. The high pressure drop insures that the portion of the core in which capillary effects predominate will be compressed to a negligibly small fraction of the total pore space. The assumption of constant flow velocity at all

By Erik M. Westerberg

The Soilex Pile combines a slender shaft, for quick and easy installation, with an enlarged pile toe, for high capacity. The key component is the Expander Body, which is inflated by injecting cement grout when in position. The latest development in the Soilex Pile System results in a reduction of the total cost of Soilex Piles, in many cases values that are competitive with pre­cast concrete piles and displacement piles. Soilex Piles can now be installed on top of a bearing soil layer, instead of 3 to 4 m into that soil as previously required, further minimising the ground disturbance. Soilex Piles achieve high capacity in relatively loose soils, with ultimate loads typically between 1000 and 2000 kN in a sand with CPT qc = 5 to 10 MPa or SPT N= 10 to 20. It is possible to pre-load and proof-load all piles with dynamic testing up to 2000 kN or using built-in jacks, thereby verifying the capacity. The vibratory installation method, which is extremely quick and causes very little soil disturbance and noise, is exemplified by two case histories.

Jan 1, 2000

By G Veillette, B Parker, S Hart

This paper provides a history of the challenges that were experienced while treating both the clayey oxide gold ores and the supergene copper-gold ores at the Boddington Gold Mine during the period 1989 to 2001. However the bigger challenge was to find a process flow sheet that would allow the economic treatment of the large low-grade competent gold-copper resource that underlies the oxide and supergene gold resource. Metallurgical test work and engineering studies on this resource started in the mid 1990s and culminated in the approval in 2006 of the 35 Mtpa Boddington Expansion Project to treat this material. The process flow sheet provides the basis of an energy efficient comminution circuit that includes high pressure grinding rolls and a treatment circuit with gravity separation, flash and conventional flotation to produce a precious metal low-grade copper concentrate followed by cyanide leaching of the rougher-scavenger and cleaner tailings streams. The treatment circuit allows maximum removal of copper minerals prior to cyanide leaching and so provides an environmentally responsible tailings disposal circuit.

Jan 1, 2007

By Ira Sohn

This article revisits global projections made in 1981of eight metallic and fertilizer minerals for the year 2000. The objectives here are to quantify the differences between the projected and observed levels of consumption for the year 2000 for eight of the 26 nonfuel minerals covered in the earlier study. An attempt is then made to attribute these (often) large differences to the major determinants of minerals demand — income, technological, regulatory and other policy changes, and changes in the recycling rates of the metallic minerals. The eight minerals covered are aluminum, copper, iron, mercury, nickel, phosphate rock, potash and tin. This summary article presents the actual population, gross domestic product (GDP) and per capita GDP changes from 1970 to 2000, compared with the projected rates for these important determinants of mineral use, along with the observed growth rates of minerals consumption for the eight nonfuel minerals included in this study. When the projections are compared with the observed global consumption levels for the year 2000, the differences range from +43 percent for nickel to +229 percent for potash.

Jan 1, 2005

By Juliana Colacioppo

La voladura es un procedimiento que está diseñado para obtener pilas a través de una fragmentación adecuada para el carguío y transporte, aumentando así la productividad de las palas y camiones y asegurando la estabilidad de los taludes y condiciones del piso de los bancos en la mina. Asimismo, el diseño de la voladura debe optimizar las operaciones posteriores tales como chancado, zarandas, clasificación, molienda, flotación y lixiviación. En ese sentido, el presente texto describe la metodología de optimización de procesos de la miina Antamina hasta la oncentradora a través de la recolección de datos de campo, caracterización, modelación matemática y simulación de las operaciones, donde además se utilizan sistemas de rastreamento de minerales y de análisis continuo de imágenes.

Sep 9, 2007