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By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By S K. Michelic, N Preisser

For certain applications, steels have to feature a very distinct and well-defined level of cleanness in terms of the number and composition of non-metallic inclusions. Therefore, one crucial aspect of steelmaking is removing and controlling said non-metallic inclusions during the process. Particle removal during ladle refining comprises three stages, namely: 1. Flotation 2. Transport through the steel/slag interface 3. Dissolution of the particle in the slag. Only if all three stages are completed the particle can be considered as fully removed from the steel melt which, in turn, leads to the slag being one of the most influential parameters for inclusion removal and control. Depending on the composition of the particles and the slag, the dissolution can be controlled by different mechanisms. This study focuses on the diffusion-controlled dissolution of solid oxidic particles in slags. For this, a model of particle dissolution has been developed. For modelling diffusion, either the differential equation following Fick’s second law can be solved, or an analytical solution to this equation valid for stationary interfaces can be used. Both approaches allow for calculations of concentration profiles of the dissolving species in surrounding slag. From this, the mass flux can be derived, which finally leads to calculating the boundary layer velocity due to considerations of mass balance. In this work, both methods as well as results of dissolution experiments using High Temperature Confocal Scanning Laser Microscopy are compared. This research aims to provide a framework for diffusion-based dissolution modelling in further expanding the understanding of particle dissolution in secondary metallurgy.

Aug 21, 2024

By P Vaikkattil, K Li, J Bullock

Unlocking maximum value is essential when designing a stope and the associated drill and blast packets. This is becoming increasingly important at Olympic Dam as the operation continues to expand south into the new mining areas away from existing infrastructure, increasing operating costs and required capital investment; into areas with less competent ground conditions, requiring smaller stopes and increased interactions. The introduction of Orica’s WebGenTM system is one way in which Olympic Dam can continue to unlock value into the future by decoupling traditional drill and blast limitations. The Lime 390 stope was the first stope at Olympic Dam to trial the new technology on the last blast packet. This paper reviews the drill and blast design of the Lime 390 stope, including the technical and operational challenges associated with the stope and the trial of the Orica’s WebGenTM system for the firing of the last blast packet.

Mar 15, 2021

By B McFadyen, Y Potvin, K Woodward

The Australian Centre for Geomechanics (ACG) held two workshops in 2019—one in Australia and one in Canada—to discuss processes and methods currently used in the mining industry for stope design and reconciliation. In practice, this work strives to optimise stope performance and aims to maximise ore recovery (minimise underbreak), while minimising dilution (overbreak). One of the key findings from the workshops was that current stope design practices, almost exclusively, rely on some versions of the empirical Stability Graph methods developed in 1980s. Although robust and useful at the feasibility study stage, there are a number of inherent shortcomings with this approach. The Stability Graph’s limitations first lie in that it cannot assess underbreak, which is a very important measure of performance. Furthermore, the method doesn’t consider a number of factors which often have a critical influence on stope stability, for example, drilling and blasting or the presence of faults. Given the current industry standard practice, there is a great opportunity to reinvent the stope design process to optimise performance. A finding of the workshops was that every mine quantifies stope performance in terms of volume reconciliation with a focus on dilution and ore losses, and reconciling metal tonnes recovered from the mill. Many mines further investigate stope performance by looking at individual stope faces and the causes for the deviations between the planned stope shape and the measured cavity. Recent research at the ACG has shown that investigating overbreak and underbreak at a higher resolution is a powerful way to identify the root causes of overbreak and underbreak. Finer scale assessment is achieved using an octree analyses, which effectively divides the relevant stope volume into cubes on the scale of a metre and produces many tens of thousands of data points. The octree data structure and subsequent analysis underpins a data-driven stope design methodology. The ACG is currently developing a design approach based on multivariate modelling methods that can account for the many variables that influence stope performance and forecast stope overbreak and underbreak results. Back-analysing stopes based on octree reconciliation results provides a rich database for training the model. Once the model can achieve reliable forecasting of overbreak and underbreak, an interactive drill-and-blast design will allow for the assessment of different firing strategies to optimise stope performance.

Mar 15, 2021

By O A. Aladejebi, S Mitra, T Singh, D J. Pinson, S, S J. Chew, T Honey

Currently, many commercial sinter plants are exploring the potential addition of high-grade iron ore concentrates to improve the sinter grade. A better understanding of the ore blend, granule behaviour and green bed properties is critical to making this change and maintaining productivity in the sinter plant. This study compared the performance of a laboratory scale granulation drum to a commercial scale unit. The blend used was an Asia-Pacific style sinter blend containing iron ore concentrates. The operating conditions of the two granulation drums (laboratory and commercial scale) were fixed at the same Froude Number (0.00337), space factor (15 per cent) and residence time (4.5 mins). The granules were characterised by measuring their mean size, size distribution and green bed voidage. It was found that the laboratory scale granules were representative of commercial sinter plant granules at similar moisture content. When the moisture was fixed at ~6.9 per cent, granulation time had no significant effect. A further fundamental investigation was undertaken to measure the water holding capacity and intra-particle porosity of the individual ores used in this study. The kinetics of water absorption were measured which showed that water absorbs quickly into the ore particles within the first 60 seconds, slowing down until final saturation was attained after six hours. A linear relationship between the water holding capacity and intra-particle porosity was noted for different ore particle sizes. The results of this study provide a baseline understanding of the current commercial sinter blend and encourage exploring the specific effect of increasing the proportion of ultrafine concentrates in sintering in a future study.

Sep 18, 2023

By D W. Evans

Research into the dynamic properties of ground support elements continues to grow at a global level, given the increasing importance of this field of application within underground hard rock mining. Measuring the mechanical response of such elements under the rapid onset of simulated rock burst loads forms the basis for this experimental work, typically utilising gravitational drop testing methods. This field of research is fundamentally driven by an increasing need for dynamic performance data, given the constant evolution of rock bolting product designs, materials selection, combination testing and specific application needs based on ground types and loading scenarios. A smaller number of globally recognised dynamic test facilities have predominantly lead research within this arena, typically in association with academic institutes, larger industry groups and government research institutes. However, due to the increasing requirement for dynamic performance data, additional facilities have now emerged in order to satisfy the overall demand for test work. These newer facilities are more typically associated with suppliers to the underground hard rock industry, with experimental designs looking to replicate, at least in part, the work of the primary facilities. For standardisation, repeatability and calibration purposes, the cross validation of test data between primary and secondary facilities becomes an obvious and important consideration across this field of research. This paper outlines the development of a new dynamic drop test facility for testing rock bolts, including the structural design and associated high speed data capture system. Based on the utilisation of identical bolt types, material grades, anchoring systems and decoupled ‘free-lengths’, comparative data has been generated to provide cross validation of the new test facility against data generated by a globally recognised primary facility. The cross validation of data provides increasing confidence in the repeatability and accuracy of the new facility as activity continues towards the provision of further experimental test work.

Nov 29, 2022

By N Madani, S Abulkhair, N Morales

Conventional geostatistical algorithms cannot reproduce bivariate complexities such as inequality constraint, nonlinearity and heteroscedasticity. Poor reproduction of these features may decrease the accuracy and reliability of mine planning results. For example, it is not unusual to have an inequality constraint between primary and disturbing elements in a metalliferous deposit. Implementation of traditional methodologies for such complex data sets can lead to the incorrect reproduction of a bivariate relationship, which will affect the validity of NPV results. In this paper, an iron data set containing iron and silica grades with an inequality constraint between variables is introduced as a case study. This study proposes an algorithm based on a hierarchical sequential Gaussian cosimulation integrated with inverse transform sampling. The proposed methodology considers the linear inequation between two variables in the hierarchical cosimulation process to reproduce an inequality constraint. As a comparison, conventional sequential Gaussian cosimulation is also applied to the same data set to demonstrate the difference in bivariate relationships from both models. Unlike the proposed algorithm, the conventional cosimulation cannot reproduce an inequality constraint and slightly overestimates silica grades. The modelled realisations are then used to assess the uncertainty of a plan and generate a stochastic strategy that adapts the destination of the blocks depending on the scenario. Two-stage stochastic long-term production scheduling takes extraction decisions using average information (ie e-type model) and ore/waste destinations based on geostatistical realisations. As a result, the proposed strategy is closer to the upper bound, highest possible NPV for each realisation, than to the lower bound, deterministic strategy that does not manage the risk of sending extracted material to wrong destinations. Furthermore, Comparing production schedules resulting from proposed and conventional geostatistical methodologies shows the importance of inequality constraint reproduction and more accurate long-term mine planning.

Nov 8, 2021

By G Zhang, I Glacken

Multiple indicator kriging (MIK) has been used in the minerals industry for some decades. As one of the non-linear estimation methodologies, MIK has advantages related to resolving multiple or mixed populations, high variability data and strongly skewed distributions. Applying the MIK methodology requires a lot more effort when compared to other non-linear methodologies, for example localised uniform conditioning. This is due not only to the variogram modelling for multiple indicators, but the validation is also very important because the panel model is fundamental for follow-up work, including the generation of recoverable resources at the local or SMU scale. Apart from this, only a few reported case studies of MIK have documented post-processing of the estimated modelled distribution, representing the probability distribution at point scale at un-sampled locations. The MIK post processing should include the change of support from the point scale to the panel scale, and then the extraction of quantile values from the panel conditional cumulative distribution function (CCDF) for localisation of grades into the SMUs within each panel, based on a ranking estimate marking the SMUs from high to low. In this paper, we present a case study on a gold deposit with the MIK method with full-post processing implemented for recoverable resources. The MIK point estimate was carried out with an indirect lognormal change of support from point to panel scale, and localisation was done with a custom script. The localised uniform conditioning (LUC) method was also applied for comparison purposes. The comparison shows that MIK has advantages compared to LUC when comes to capturing the high-grades, especially when mixed or varying anisotropy is present within the mineralisation.

May 24, 2023

By J Rutter, D Francois-Bongarcon, M Federov, N Odiar, M Scott

There are two fundamental methods for metalliferous sensing of primary crushed ore available for deployment at operations. These methods can be classed as surface measurement techniques (including XRF, LIBS, NIR, SWIR) or penetrative/semi-penetrative measurement techniques (including PGNAA, PFTNA, GAA, MR). While the individual sensing technologies exploit different physical phenomena to measure metal content, penetrative sensor measurements of grade are often regarded to be superior to surface measurement techniques due to the much larger sampling volume penetrative techniques provide. Surface sensing techniques often utilise simpler, established technologies that have considerable benefits in the speed of analysis, capital costs, ease of deployment, social license to operate and operational safety. This paper investigates whether surface sensing techniques achieve adequate sampling representativity of primary crushed rock mass to provide economic benefit over penetrative sensing technologies for bulk ore sorting applications. The paper details the methodology used to assess whether surface XRF measurements change throughout various stages of comminution, and increased surface exposure, from primary crushed ore (top size of -175mm) to finely crushed product for assay (top size -2mm). The methodology was applied to 2 ore mineralisation styles, across variable metals and grades, to identify any associated opportunities and limitations to surface sensing techniques. The results assist in developing a method to determine if surface sensing and measuring via XRF is an adequate representation of the rock mass for bulk ore sorting applications and identify any associated limitations in particle size distribution, mineralisation or natural deportment strength to guide suitable application of surface sensing techniques.

Nov 10, 2020

By C Jacobsen, N Harries

Assessing and managing instability hazards is an essential activity when working with unstable natural slopes and excavated open pit mining slopes. Slope monitoring has become the standard technique for the management of geotechnical risks associated with mine slope instability hazards. In recent decades, a proliferation of new monitoring techniques such as terrestrial radar, satellite InSAR and LIDAR have become standard operational tools, complementing conventional survey-based monitoring solutions. A reliable monitoring system should identify and record incipient anomalous slope movement. Although the most obvious purpose of a monitoring system is safety related, slope deformation and performance monitoring also enhance the understanding of slope behaviour and assists in improving system design and implementation. For a monitoring system to be considered an effective early warning tool, it needs to operate in real-time and should be linked to the mine’s emergency communication systems. Terrestrial radar systems have been developed that can provide near real-time measurements, at a high level of precision and covering broad areas in all weather conditions. This has had a positive impact on the management of geotechnical risks in operational conditions. The technology adoption of RADAR in mine monitoring has significantly progressed in the last 20 years from technology enthusiasts, to visionaries, to pragmatists to conservative users. However, the increasing adoption of RADAR cannot reduce or remove other monitoring techniques that often have important benefits; even if these technologies cannot be used as a real-time operational tool. An increasing awareness on the importance of combining data from different monitoring techniques to develop a holistic picture of all possible geotechnical hazards is a current industry trend. This is proving to be an excellent foundation for managing hazards associated with slope instability in open pit mines, and is only expected to improve with time with the adoption of new technologies based on big data and Artificial Intelligence (AI).

Nov 29, 2022

By Brown H. R, Wright E. A

The authors identify the workable coal seams, their distribution in relation to quality and economic occurrence and relate their analytical characteristics to industrial use. The development of established collieries is also discussed with regard to increased production demand.The authors also indicate the potential of the coal resources of the Southern District and postulate their ultimate development.INTRODUCTIONThe Southern Coalfield yields 30 per cent of the total production of bituminous coal in New South Wales. The economic potential of the coalfield was examined last by Harper (1915). Since that time additional knowledge has been gained by prospectors, mining companies and public authorities. Expansion in the steel industry and the building of power stations on the coalfields together with improvements in fuel technology, mining methops and road transport have resulted in production of coal from seams mice thoughtto have no economic value.DESCRIPTION OF THE COALFIELDFor the purpose of this paper the term Southern Coalfield includes also the South-Western Coalfield which together comprise the following Coal Districts:IllawarraDouglas ParkWollondilly-NattaiMoss Vale-Berrima (Hanlon, 1953).Geographically the coalfield is contained by the Illawarra Range in the east, the Shoalhaven River to the south, the Wollondilly River to the west, and in the north by a line...

Jan 1, 1958

By Milner A, Brockway D, Hodges S

The combustion of brown coals in Latrobe Valley power stations produces approximately 500 000 tonnes of solid wastes each year. This material, which includes precipitator ash, char and furnace ash, is hydraulically sluiced to large ashing ponds and the supernatant solution is ultimately discharged to the sea. There are significant operational and capital costs associated with the current ashing system. The ash produced from the Latrobe Valley coals is unique and has a wide variety of potential applications including soil conditioning, concrete and cement extenders, fillers in non-metallic materials, components of building products. In addition, with the application of appropriate technology, it is possible to extract char, sodium sulphate, calcium carbonate and magnesium metal (as the chloride) in substantial quantities from the ash. Research has been carried out to explore the prospects of these various options for ash utilisation. The research has focused on detailed characterisation of the ash material and the potential extraction efficiency for various species under various conditions. From this work a conceptual process has been developed and subsequent studies have been directed towards understanding variables and optimising operating regimes for product extraction. Currently, the work is concentrating on the separation of char, the development of high-grade carbon products and the extraction of sodium sulphate.

Jan 1, 1992

By S L. Martin, M Wimberger

The binary indicator coding of assay and lithological data according to a single criterion or multiple criteria is a powerful technique for representing mineralised shapes through the modelling of probabilities. This can be as simple as using a single indicator to model the probability of occurrence of a condition, usually a grade threshold or a lithology, but it can also be used with a number of categories. Case studies are presented to show the power of this approach, where the geological controls on mineralisation or on the distribution of a rocktype or alteration, often coupled with mineralisation, are unclear. The categorical approach is often used as a de facto grade filter in disseminated or stockwork mineralisation. The ultimate expression of the indicator formalism is in multiple indicator kriging (MIK), where a conditional distribution of probabilities is generated for each estimation panel. This has applications in recoverable resource estimation, as the input for continuous or categorical simulation, where the distribution of sample grades is multimodal, or when there are superimposed mineralisation events with different orientations. However, in some cases, MIK is being used as an excuse for ignoring a quality geological interpretation. Examples from the public domain show the abuse of the categorical and MIK approaches to modelling probabilities, together with a plea for greater consideration of the geology.

Mar 22, 2022

By M Scoble

This paper is based upon the experiences of collaborating academics in two mining schools and their personal view of attempts to integrate the principles of sustainable development into mining education and research. In this quest, the concept of sustainable mining practices is proposed, not only relating to environmental, social and economic performance but also stressing mine safety and efficiency. These practices need to support strategies that enable flexibility and resilience within mine operations to counter recessionary cycles. Also, these counter-cyclical strategies are now imperative for sustaining mining education and research itself. There is a critical interdependence between these two different perspectives on æsustainabilityÆ. The paper concludes by demonstrating models of strategies that promote inter-disciplinarity, collaboration and networking for sustaining mining schools.

Jan 1, 2009

By A Simmons, R Longey, D Brett

The South Deposit Tailings Storage Facility (SDTSF), located at Grange Resources Pty Ltd’s (Grange) Savage River mine in north west Tasmania, has recently begun construction. The facility will provide storage for approximately 37 million cubic metres of tailings, equating to approximately 20 years’ tailings storage.The SDTSF embankment will be constructed entirely out of waste rock won from mining operations, and will feature a flow-through drain constructed from alkaline, non-acid forming (NAF) waste rock. This provides Grange with an economical storage solution for waste management (both tailings and waste rock) and maximises available space on site. The outflows discharged through the alkaline rock ‘flow-through’ will provide a long-term source of alkalinity to Main Creek, subsequently feeding into Savage River. This will provide environmental benefits to the downstream ecology that has long been degraded due to the effects of legacy acid and metalliferous drainage (AMD), caused by historical mining operations.CITATION:Longey, R, Brett, D and Simmons, A, 2015. Integrated mine waste management – South Deposit Tailings Storage Facility, Savage River mine, Tasmania, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 343–352 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

In the UK during the 1990s the energy companies had developed a policy of æDash for GasÆ, building large natural gas power stations to produce more than 30 per cent of the UKÆs electricity demand. The price of imported thermal coal was dropping and the electricity generators were putting pressure on the UK coal producers to produce coal at a reduced cost. Imported coal from Columbia, South Africa, America and Australasia had increased their market share in thermal coal sales to over 50 per cent of a 55 Mtpa market. The pressure on the UK coal industry to reduce costs and improve productivity levels from an ever decreasing resource was high. Companies were benchmarking their operations on the imported coal producers and had to realign their organisations, productivity levels and costs to world best practice, not just technically, but in world class organisational management techniques.

Jan 1, 2005

By D W. Airey

Frictional rock bolts are widely used because of their low cost. However, they have a thin wall section that makes them prone to corrosion, and they cannot be relied on to provide long-term ground support. It is difficult to assess the capacity after the bolts have been installed as they can only be pulled out if this has been allowed for during insertion. The questions of how long can the rock bolts function effectively and the effectiveness of various surface coatings, which can have significant cost implications are, investigated in this study.A series of accelerated corrosion tests have been performed on frictional rock bolts. The rock bolts, typically 900 mm long, have been inserted into concrete cylinders produced using a styrofoam insert to create the hole for the bolt insertion. Strata rock bolts with four surface coatings have been tested: uncoated black steel, galvanised, enduro (plastic coated) and coated with a proprietary aluminium/zinc alloy. Tests have been performed on two diameters of bolts. Following insertion of the bolts, the concrete cylinders were placed in a large drum filled with saltwater and current was applied to accelerate the corrosion process. The rock bolts were then extracted at various times after the commencement of corrosion. Comparison of the insertion and extraction resistances shows that corrosion initially increases the bolt resistance and that substantial section loss is required for the bolt resistance to drop significantly.CITATION:Airey, D W, 2014. Laboratory corrosion tests of frictional rock bolts, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 257–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

Historically the insurance industryÆs involvement in any project has been relatively late in the process. Often it was a case of the last item to be ticked off the checklist has been to ensure that the insurance is in place. However, in more recent times insurers have imposed more restrictions on the cover they are prepared to provide, which has in some cases necessitated a change in the contracting structure to accommodate the insurance policy(ies). In addition, changing contractual practices have changed the allocation of risk between the various parties involved. This calls for a more proactive approach to the design and implementation of an insurance program for both the construction and operational phases of any resource project. This paper explores how a risk managed approach to the design and implementation of an insurance program for a resource project can align itself with current management approaches to project development. From the authorsÆ experience, this approach is best adopted early on in the project (often in conjunction with the bankable feasibility study) and follows AZ/NZS4360 to objectively examine and compare a wide range of risk exposures of the project in a time-effective manner across the following areas: personnel; environment; general management; compliance û legislation, systems, protocols; asset management; change management; financial impacts to the organisation; products/services; service delivery; and technology. Having identified and then analysed the risk exposures according to common consequence and likelihood ratings the next step is to develop a risk map of all considered exposures. The true value of this approach lies in the development and implementation of a risk treatment plan for identified exposures where the exposure is unacceptable. The plans will lead to the optimal solution to the appropriate risk prevention, risk mitigation and risk transfer options available. This paper also examines other benefits to the project that may arise from adopting a risk managed approach in addition to the ability to design an insurance program which recognises the exposures and the ability of the organisation (and other project parties) to retain risk.

Jan 1, 2007

By B Firth, G OÆBrien, B Jenkins

In coal flotation, particles of different components of the coal such as maceral groups and mineral matter and their associations have different hydrophobicities and therefore different flotation responses. By using a new coal grain analysis method for characterising individual grains, more detailed flotation performance analysis and modelling approaches have been developed. The method involves the use of microscopic imaging techniques to obtain estimates of size, compositional and density information on individual grains of fine coal. The density and composition partitioning of coal processed through different flotation systems provides an avenue to pinpoint the actual cause of poor process performance so that corrective action may be initiated. The information on grain size, density and composition is being used as input data to develop more detailed flotation process models to provide better predictions of process performance for both mechanical and column flotation devices. A number of approaches may be taken to flotation modelling such as the probability approach and the kinetic model approach or a combination of the two. In the work reported here, a simple probability approach has been taken, which will be further refined in due course. The use of grain data to map the responses of different types of coal grains through various fine coal cleaning processes provided a more advanced diagnostic capability for fine coal cleaning circuits. This enabled flotation performance curves analogous to partition curves for density separators to be produced for flotation devices.

Jan 1, 2005

By M A. Wells

The various mechanisms by which phosphorus (P) occurs and is distributed within banded iron formations (BIF)-derived iron ore are examined. In unenriched, precursor BIF P occurs predominantly as discrete grains of primary apatite. In high-grade ores hosted mainly by the Brockman Iron Formation, P occurs in three main forms:1. as secondary apatite;2. other submicron, P-rich phases (eg Rare earth containing minerals (REE), vivianite, strengite,wavellite) present in pore networks; and3. as P occurring with iron oxides, in particular, goethite.However, the presence of secondary P-bearing phases does not contribute signifi cantly to the total P level in iron ore, and it is P associated mainly with goethite, which represents the most common occurrence of P in these ores.No direct evidence for the replacement of Fe by P within the structure of synthetic goethite has been demonstrated. Therefore, it is most likely that in iron ores P associates with goethite in occluded form as adsorbed PO4 3- species or as discrete P-bearing minerals, such as strengite, wavellite or vivianite, in ultra-fine, micro-pores or within intra-domain regions of multi-domainic goethite. Such occluded P is not easily extracted with commonly used lixiviants, such as weakly alkaline leachates. Recent development of a low temperature-alkalie/water leach extraction method has been successful in reducing not only the P content, but also amounts of Si and Al inthe initial ore. Refi nement of such a method to commercial application will have enormous benefit in realising the economic potential of large tonnages of high-P (ie >0.07 wt per cent P) bearing iron ore.

Jul 11, 2011