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By G Nicholas, S Coward, J Vann, R Wolff, S Jackson, S Moayer, A Bye

"A new approach to mineral project evaluation is described called Scenario-Based Project Evaluation (SBPE). SBPE incorporates well established æscenario planningÆ and æscenario thinkingÆ approaches, which are used extensively in other industries,?most notably the?petroleum industry. While most scenario planning is qualitative and non-probabilistic, the approach described here includes both quantitative and qualitative aspects. SBPE is complementary to optimisation approaches and allows mining firms to build and operate projects that are more robust in the face of adverse changes as well as proactively respond and exploit the upside offered by a realistic assessment of variability. The approach has potential to improve project performance and decrease operational risk. It also has important applications for currently operating mines.Conventional evaluation of metalliferous mineral deposits uses estimates of metal grades and deleterious attributes in singular æorebody modelsÆ, usually 3D block models, which fail to capture two critical aspects that underpin the realised value of mining projects: the inherent uncertainty of the estimated attributes the spatial variability of attributes, at the scale of mining selection, which impact on downstream processing steps and fundamentally drive realised value. While singular models are appropriate for estimating block averages, conditional simulation (CS) models of the relevant attributes are needed to represent uncertainty and capture spatial variability. Any attributes that can be either built into CS models and/or modelled in the envisaged mining/processing steps, can be evaluated fully through to highly ægranularÆ (ie detailed and un-smoothed) cash flows. A complete view of SBPE relies on selected strategies being tested against plausible æscenariosÆ of factors external to the project and thus outside management control. æExternalitiesÆ captured in such scenarios include market prices, costs and taxes. Via SBPE, project managers may demonstrate that there is material value in preserving or purchasing options that provide future flexibility to respond to the changing externalities or changes in orebody performance. Such flexibility generally comes at a cost but is very difficult to value. It is argued that full value chain evaluation using SBPE can help to value these options for a mining company. A case study for a gold mine is presented.CITATION:Vann, J, Jackson, S, Bye, A, Coward, S, Moayer, S, Nicholas, G and Wolff, R, 2012. Scenario thinking - A powerful tool for strategic planning and evaluation of mining projects and operations, in Proceedings Project Evaluation 2012, pp 5-14 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 24, 2012

By R Redden

"The Didipio Gold-Copper project in the Philippines has been a well-defined reasonably high gold grade porphyry for almost two decades. OceanaGold are now bringing the project into production in late 2012 and have recently reoptimised the project with the goal of combining the inherent high grades with higher through-put than previously proposed that will see strong initial metal production. The project was discovered and well defined by 1995, but has seen some obstacles to development, namely sovereign risk, capital cost and project funding. The project strengths over this time that have kept the flames alive are: strong grades large orebody with low stripping ratios a simple beneficiation process and a clean high-grade concentrate strong support from the Philippines government.The initial study in 1998 used Gold and Copper price assumptions of $325/oz and $0.95 lb respectively. Today reserves are based on $950 and $2.85. So, being a porphyry with a large reducing grade halo, the deposit now lends itself to extraction on a much larger scale than before, without any significant capital expenditure as a larger open pit now dominates the project.Didipio is a game changer for OceanaGold, so it has been important to learn from history and to capitalise on a strong initial metal production profile. The project sits in a reasonably remote mountainous area of Luzon which sees annual typhoons and numerous short duration high intensity rainfall events and two rivers flowing through the project area, so it has not been without some innovative technical solutions.CITATION:Redden, R, 2012. Didipio - Learning the lessons, adapting and getting ready for production, in Proceedings Project Evaluation 2012, pp 67-76 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 24, 2012

By Jennifer J. Swenson

El presente texto describe los problemas de deforestación, precios e importaciones de mercurio en la minera artesanal aurífera de Madre de Dios. En ese sentido, a medida que la interconexión de la economia mundial avanza, es más difícil que países en desarrollo aprovechen las fuerzas lucrativas de la demanda global para lograr una sostenibilidad social y ambiental. En consecuencia, los países en desarrollo contienen un peso ambiental desigual en relación con los países desarrollados qie importan materias primas. Como ejemplo de ello, el precio del oro aumentó, así como la minería aurífera informal y no industrial en los países en los países en desarrollo y el mal manejo del mercurio en el uso del oro, repercutió en el medio ambiente y los mismos mineros, al igual que el problema de la deforestación. Por ello, se plantea un programa para enfrentar dchos problemas en la región de Madre de Dios y reducir el aumento de la minería informal.

May 1, 2012

By Dave J. Porter

Si bien, los proyectos son el camino para que una organización minera cumpla con su estrategia, la gran mayoría de su historial de cumplimientos son un fracaso puesto que el impacto del proyecto no es tan rico en sus etapas y las organizaciones mineras no pueden cumplir con su visión y estrategía. En ese sentido, el presente texto señala la importancia de una adecuada gestión de proyectos para que la organización minera cumpla con su estrategia. Así, la madurez de la gestión de proyectos es un indicador de éxito continuo y requiere de visión, compromiso en las etapas iniciales, ya que sus ganancias son difíciles de cuantificar.

Apr 1, 2012

By I M. Platten, S C. Dominy

The Clogau St DavidÆs gold mine has a recorded production of around 81 000 oz Au and it is the largest mine in the Dolgellau gold-belt and BritainÆs most prolific historical producer. The original mine was first worked for copper, however; in 1854, gold was found in waste material from the St DavidÆs section. In recent times the mine has operated intermittently between 1983 - 2007. The principal black shale-hosted gold-bearing reef (Main Reef) can be traced for about 3 km, striking approximately NE-SW and dipping steeply between 60¦ - 90¦ SE. The reef system pinches and swells, changes strike and splits into a number of smaller branches. Reef width is variable, ranging from over 6 m to a few cm and in places reducing to small irregular blobs. The reef is internally complex and composed of swarms of narrow (1 - 300 mm) subparallel veins separated by country rock sheets. The gold-bearing veins within the reef package are discontinuous; though generally possess bonanza grades running 10s - 100s oz/t Au. It has historically been shown that some gold-rich vein segments can grade up to 300 oz/t Au. The predictability of the gold-rich segments is poor, but has been shown to be related to presence of the Clogau (black shale) Formation, and/or the mechanical interactions of the reef with greenstone sills, reef branching and splitting and/or cross-fractures to form ore shoots. The mine is currently being re-evaluated as a potential small-scale selective operation.CITATION:Dominy, S C and Platten, I M, 2012. Geology, mineralisation and potential of the Clogau St DavidÆs mine, Dolgellau gold-belt, Gwynedd, Wales, in Proceedings Narrow Vein Mining 2012 , pp 101-120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By P. Zhang

This paper gives a review of promising technologies for phosphate processing, and covers flotation, analysis and process control, as well as tailings treatment and utilization. Air bubbles of less than a µm in size, combined with relatively large bubbles, have been demonstrated, both in the lab and on a pilot scale, to improve flotation dramatically, by reducing reagent use while improving product grade. Innovative use of polymers has allowed rapid dewatering of fine tailings with a final product that does not segregate. The first online laser-induced breakdown spectroscopy (LIBS) analyzer was created, allowing rapid analysis of wet samples using the laser technology. Many large commercial projects are successfully pursuing the utilization of phosphogypsum.

Feb 1, 2012

By T. J. McKeon

Gravity separators such as spirals are commonly used in multistage cleaning and scavenging circuits to improve the quality and recovery of concentrates produced in the industrial minerals industry. Unfortunately, field surveys suggest that many industrial operations are poorly configured in terms of equipment layout. This shortcoming can often be attributed to a failure by engineers to make use of fundamental process engineering tools for circuit design. One of the most important of these is linear circuit analysis. This powerful tool makes it possible to mathematically compare the relative efficiency of circuit configurations in advance of experimental testing. This article provides a basic review of the linear circuit analysis concept and discusses some of the key insights it provides for the layout of multistage circuits. An industrial case study is provided to show the tremendous impact that this process engineering tool can have on the design of multistage spiral circuits in a heavy mineral wet plant.

Feb 1, 2012

By Drew Martin

In March 2010 the Boral Linwood Quarry, Adelaide South Australia, implemented the blasting contractors Monte Carlo Blast Vibration Model as part of their blast design process. The Linwood Quarry was developing an area where blasting activities were marginally complying with the statutory vibration limits. Compliance to the statutory limits was only being achieved through the use of small blasts (less than 15 000 T (14 763 ton)) at a high cost to the quarry.

Jan 1, 2012

By Timothy Fogarty, Gregory Poole, Roger Reeder, David Switz

This project involved the construction of a new pump station and intake structure at an existing water treatment facility. Although the project involved a significant amount of rock removal, the specifications said no blasting.

Jan 1, 2012

The optimal design of production phases and ultimate pit limit for an open pit mining operation may be generated using conventional or stochastic approaches. Unlike the conventional approach, the stochastic framework accounts for expected variability and uncertainty in metal content by considering a set of equally probable realizations (models) of the orebody. This paper evaluates the performance of a new stochastic network flow approach for the development of optimal phase design and ultimate pit limit using a gold deposit as the case study. The stochastic and conventional frameworks as considered here utilize the maximum flow and Lerchs-Grossman (LG) algorithms, respectively. The LG algorithm is restricted to considering an estimated (average-type) orebody model, while the stochastic maximum flow algorithm is developed to simultaneously use a set of simulated orebody realizations as an input. The case study demonstrates that, when compared to the conventional LG algorithm as used in the industry, the stochastic approach generates a 30 per cent increase in discounted cash flow, a 21 per cent larger ultimate pit limit, and about 7 per cent more metal, while it maintains a consistency in phase size.

Jan 1, 2012

By W. G. Pariseau

This contribution describes rock mechanics features of the Davis Cavern at the former Homestake Mine in Lead, South Dakota, U.S.A. The mine is located in the northern Black Hills of South Dakota. In 2003 and again in 2008, the mine site was recommended for development as a national Deep Underground Science and Engineering Laboratory (DUSEL) in cooperation with the Sanford Underground Science and Engineering Laboratory under the South Dakota Science and Technology Authority (SDSTA). The original Davis Cavern was excavated about 9.1x16.8x9.7 m high (30x55x32 ft high) in 1965 (Mitchell 2009) at a depth of 1,478 m (4850 ft). The purpose of the cavern was to house apparatus for detecting solar neutrinos. The experiment ultimately proved successful and earned R. Davis a share of the 2002 Nobel Prize in physics. Recently, a new experiment (LUX=Large Underground Xenon detector for dark matter particles and WIMP's=weakly interacting massive particles) was proposed for the Davis Cavern that required an increase in height of 2.4 m (8 ft). For many years, the Homestake gold mine was the deepest operating mine in North America. Development extended to the 8000 Level (2,438 m). The mine closed in 2003. Pumps were shut off and the water level rose to the 4350 Level, about 150 m (500 ft) above the Davis Cavern. Some six years later after selection for DUSEL proposal development by the National Science Foundation (NSF), access to the 4850 Level and the Davis Cavern was regained. Pumping has lowered the water level to well below the cavern floor. Figure 1 shows the layout and location of the Davis Cavern (Cavity). Detector tank, supporting steel, and so forth were subsequently removed. The cavern was re-supported and new access was developed. By August, 2010, 13,000 ft3 had been removed during enlargement and renovation of the Davis Cavern. Figure 2 shows the detector tank under construction in 1965.

Jan 1, 2012

By G. J. Joy

Although rates of pneumoconiosis in coal miners have declined substantially in the United States since the passage of the Federal Coal Mine Health and Safety Act of 1969, new cases continue to occur, including cases of rapidly progressive disease. In contrast, Australia's underground coal mining industry has reported few new cases of pneumoconiosis for more than 20 years. Mortality from coal workers' pneumoconiosis in official health statistics and the prevalence of pneumoconiosis among miners screened in X-ray surveillance programs are also lower in Australia. The U.S. National Institute for Occupational Safety and Health (NIOSH) was requested by both industry and labor stakeholders to examine this issue, with the ultimate aim of reducing the rate of pneumoconiosis among U.S. coal miners. A number of factors, including coal dust exposure, silica exposure and coal rank were examined as potential contributors to the above noted differences. Comparison of coal rank data from each country did not illuminate the issue. Air sample data from the coal mining industries in both countries show that coal dust levels in Australian mines are somewhat higher than those reported in similar U.S. mines; however, quartz exposure for Australian miners is lower than for many U.S. miners. If quartz is contributing to the greater number of cases of pneumoconiosis in the United States, more effective dust control measures, as well as an independent exposure standard for respirable quartz in coal mining, should be implemented to reduce this potentially disabling condition.

Jan 1, 2012

By P. Condori

Palabora Mining Copper (PMC) has two autogenous mills that have been in operation since 1976. The mills were originally designed to treat 30 000 t/d of open cast copper ore in a closed circuit with cyclones. As the ore body went deeper the open cast method of mining was changed to block caving, a consequence of this was the dolerite content (hardest barren material) increased significantly, increasing the production rate of pebbles and thus reducing the milling capacity. In order to cope with the increased ore hardness and to increase mill capacity, a second ball milling stage and pebble crushing were incorporated to the circuit. The above actions created new challenges to the circuit operation and bottlenecks in different areas of the milling circuit. This paper reports the holistic work performed on the Palabora autogenous milling circuit including the implementation of a mill constraint control scheme, the implementation of a pebble removal system from the circuit and a new circuit configuration. The achieved plant stability and increment of ore throughput are also reported in this paper.

Jan 1, 2012

By M. J. King, D. A. Van den berg, R. Fukuzawa

"Mercury bearing ore bodies are often treated for the production of copper, lead, zinc, gold, and silver. The mercury deports either to tailings or is collected during various stages of the extraction process. This paper reviews the relationship between various mercury collection processes and the subsequent management of the mercury by-product or waste. It focuses on mercury removal sequestration including cementation, sulphide precipitation, bulk neutralization, and carbon adsorption. Long term mercury management strategies including third-party stabilization, stabilized mercury co-disposal, secure storage, and mercury recycle are also evaluated. INTRODUCTIONMercury is produced in North America as a by-product of non-ferrous metals processing and from recycling of products such as dental amalgam, fluorescent lamps, and thermometers. Its toxicity is recognized to have significant negative impacts on the environment and human health. As a result, many countries are adopting regulations limiting mercury use and its uncontrolled release.The European Union banned mercury exports in 2011 and the United States will do so in 2013. The export bans aim to prevent mercury use in developing countries for activities such as artisanal small scale gold mining. However, by-product mercury production from the non-ferrous metals industries continues.These factors contribute to an oversupply of mercury and the need to find suitable treatment methods for the long term management and storage of mercury and mercury bearing materials."

Jan 1, 2012

By A. M. A. Mohamed, F. H. Samuel, S. Alkahtani

"This article was undertaken to investigate the effect of nickel and zirconium additions on the strength of 354 aluminum cast alloy. The cast alloys were given a solutionizing treatment followed by artificial aging at 190 ºC for 2 hr. High temperature tensile tests were conducted at various temperatures from 25ºC to 300ºC. Optical microscopy and scanning electron microscopy were used to study the microstructure of the samples. The results revealed that the intermetallics phases of (Al,Si)3(Zr,Ti), Al3CuNi and Al9NiFe are the main feature in the microstructures of alloys with Zr and Ni additions. The results also indicated that the tensile strength of alloy decreases with an increase in temperature. The combined addition of 0.2 wt% Zr and 0.2 wt% Ni leads to a 30% increase in the tensile properties at 300ºC compared to the base alloy.INTRODUCTIONThe task of improving the mechanical properties in an aluminum alloy at high temperatures should include the knowledge of several factors which are related principally to a decrease in the strength of the metal with increasing temperatures. This behavior is linked to the change or deterioration in the principal metallurgical parameters of the specific cast aluminum alloy during its performance at higher temperatures. Most of applications of Al-Si casting alloys are generally used at temperatures of no more than 230°C (Lee & Chen, 2002). This recommendation is made in view of the fact that, for certain applications such as those required by the automotive industry, these alloys must operate over a wide range of temperatures and stress conditions where temperatures are liable to rise even higher than 230ºC (Robson & Pragnell, 2003).Aluminum-silicon-copper-magnesium alloys such as the 354 alloys show a greater response to heat treatment as a result of the presence of both Mg and Cu. These alloy types display excellent strength and hardness VALUES (although at some sacrifice of ductility and corrosion resistance. These alloys are used for a wide range of applications, such as engine cooling fans, crankcases, high speed rotating parts, structural aerospace components, air compressor pistons, fuel pumps, compressor cases, timing gears, rocker arms, machine parts, and so forth (Cáceres, Svensson, & Taylor, 2003; Rurrxia, Rong-de, Yu-hua, Cherrxi, Xiao-feng, Heng-rong, & H. Zhuang-qi, 2004)."

Jan 1, 2012

In Canada and other countries, legislation dealing with accurate factual disclosure for mining projects is being expanded to include more metallurgical design information. Grinding characteristics, metallurgical recovery of contained metal and environmental hazards associated with tailings disposal will be part of the Canadian package. This paper will examine only that portion of the plant design standard practice that relates to grinding ? in SAG mills and ball mills that grind ore from as received crushed material to final ground product that is fed to downstream plant recovery processes. Since grinding plants represent a significant portion of the overall concentrator cost, accountability in grinding design should no longer be left to chance, opinion, or hidden proprietary information. This is the 21st century. It is reasonable to expect that a factual basis will be needed so that a Qualified Person (QP) reviewing the grinding mill design can understand it. That will also involve how many and what quality of samples are taken to define the characteristics of the deposit, the accuracy of the tests used to measure ore hardness and the method by which the dimensions and power of the mills are determined. If these criteria are not met, the QP may have no choice but to call attention to the lack of convincing information regarding the grinding mill design for the project. At the same time clients are expected to demand getting the correct design information at a cheaper price, results in a more timely way, and accurate design to the point where the risk of tonnage shortfalls are reduced or eliminated. Tables will be presented to show how this can be done to current standards using existing technologies. At the same time it is acknowledged that current standards are ill-defined and that to achieve consensus among those involved in SAG mill design work, it may require that a consortium funded project be set up to establish what tests and methods for grinding design are suitable to meet the new standards for metallurgical disclosure. By running parallel design methods on several major projects over a period of 5 years, the process of how to design grinding circuits will be better understood because the projects will start at the design stage, include procurement of the mills and will end with a benchmark test on the plant. Selecting the samples and the best schedule for doing test work on core samples submitted and mill design, will be discussed in this paper. The issue of completing the grinding design in time for early procurement decisions is on the critical path for most major projects. Discussions between mining engineers, geologists and process engineers are needed early in the development cycle, at the scoping study level (SS), preliminary engineering assessment (PEA), prefeasibility study (PFS), and at the feasibility study stage (FS), to ensure that proper planning for design sample selection is done. Using adequate sampling and testing methods in a timely way allows early procurement of the grinding mills and minimizes project risk.

Jan 1, 2012

By T. Xu

"The CTL-500 centrifugal extraction machine, which was independently developed by Baotou Shibo Rare Earth Extraction & Equipment Co., Ltd., is presented in this article. The machine is based on centrifugal extraction principle and has been used in P507-HCl-RECl3 extraction system. Automatic control has been utilized in the system. In this paper, a comparison is made between centrifugal extraction and conventional mixer-settler extraction and satisfactory results are shown. INTRODUCTIONCentrifugal extraction is a fast and efficient liquid-liquid extraction method. The process includes solute transfer and separation of the two liquid phases. In the CTL-500 machine, the organic and aqueous phases individually enter a lower mixing chamber in certain proportions and are mixed and dispersed and solute thereby transferred from one phase to the other. The mixed phases pass into a rotating drum and the two liquid phases are separated under centrifugal force. As it flows upward, the aqueous phase, which has a higher specific gravity, flows away from the rotating drum centre towards the drum wall and the organic phase flows towards the drum center. The two liquid phases enter into collection chambers through independent weir plates and are discharged from the machine.The centrifugal extraction machine has been widely used in liquid-liquid separation, either without solid or with small quantities of solids (Chen, Zhang, Zhuo, Chen & Li, 2008; Duan, Jing, Zhu & Chen, 2007; Duan, Zhou & Zhou, 2006). Examples of the use of the centrifugal contactor include the separation of water from crude oil, treatment of heavy oil and diesel to eliminate water and salt; the extraction of penicillin, garlic oil, malathion, and interferon; the hydrometallurgy recovery of nickel, copper and uranium; extraction of edible oil, spice, refined oil and food color; treatment and recycle of print and dyeing wastes; treatment of hydroxybenzene-contaminated sewage by multistage extraction and separation of water from oil in ship sewage."

Jan 1, 2012

By Mehdi Asadi, Heinz Palkowski

"In recent years, the increased demand for advanced high-strength steels (AHSS) mainly had been driven by the need of the automotive industry to reduce weight and to improve safety. Beside good ductility and high strength, those steels have a high bake hardening (BH) effect, giving additional contribution to the strength of structural parts, subjected to the paint baking process. In this paper we concentrate results gained for hot rolled dual phase (DP) steels.For the simulation of changing process conditions within the final hot rolling the specimens were hot deformed using different schedules of temperatures and reductions, selected according to the non-recrystallization temperature (TnRX). It was possible to refine the DP steel structure by control-ling the deformation temperature and the amount of strain below TnRX during the thermo-mechanical controlled processing (TMCP). This structure refinement resulted in an improvement of the strength and BH behaviour. A wide spectrum of mechanical properties could be obtained depending on the different hot deformation schedules. The best strength and BH levels were recorded for the deformation below TnRX at the highest amount of strain.IntroductionDP steels are characterized by a good formability, high strength and a good compromise between strength and ductility [1]. Moreover, the DP steels exhibit a continuous yielding behaviour, low yield point and a high strain-hardening coefficient [2]. Furthermore, the DP steels often show a large potential for bake hardening (BH). BH refers to the increase in yield strength as a result of the paint baking treatment of the shaped auto-body parts. The primary mechanism that causes the additional strengthening is the immobilization of dislocations by the segregation of interstitial atoms, known as classical static strain aging [3]. The increase of strength thus achieved allows a further reduction of sheet thickness and improves the crash safety and the dent resistance. The BH of special steel qualities is technically used in DP, where e.g. the increase in strength is realized in the final heat treatment [4]. Previous own investigations [5-6] stated that the BH effect of DP is much stronger than that one for conventional BH steels."

Jan 1, 2012

By Keith A. Heasley

The LaModel program has been used successfully in the United States for many years to design pillars to ensure global stability of pillar recovery operations. However, the recent Crandall Canyon Mine collapse showed that further research was required to improve the design of pillar recovery under deep cover. Toward this end, a new calibration procedure was implemented in LaModel. This calibration procedure prescribes techniques for calibrating the critical LaModel input parameters based on empirical abutment loading and pillar strength, as utilized in the time-tested ALPS and ARMPS programs. The calibration procedure is intended to help guide a novice modeler in choosing calibrated input parameters that produce a standard model that fits within the verification database. However, the rigid parameter specification incorporated in the calibration procedure also removes most of the flexibility in LaModel for specific calibration to the unique conditions at a given mine site. In this paper, a number of the LaModel input parameters are varied outside the bounds of the suggested calibration and the effects on the model results are analyzed. Ultimately, it is shown how the LaModel user might vary certain input parameters to adjust the model to site-specific conditions, while still maintaining the general accuracy and philosophy of the recommended calibration.

Jan 1, 2012

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012