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By Ian Baker, Xavier Pierron

"Iron aluminides hold great promise for intermediate temperature applications (to ~ 600°C) because of their excellent oxidation and sulphidation resistance and good strength. However, they have poor low temperature ductility, a feature which is exacerbated by water-containing environments. This paper presents an overview of the effects of environment on the ductility of iron aluminides, including the effects of iron aluminum ratio; ternary alloying additions, particularly boron; strain rate; and temperature. The mechanisms involved in water-induced embrittlement are discussed.IntroductionOver the last few years, it has became increasingly evident that the ductility and fracture toughness of many intermetallic compounds, particularly aluminides, are reduced dramatically if they are mechanically tested in either air or in hydrogen-containing atmospheres (1-5). For FeAI and Fe3AI, it has been shown that water vapor, for example in air at room temperature, can form atomic hydrogen by reacting with the Al atoms (1, 2). As a result in iron aluminides, the environmental embrittlement process is quite similar to traditional hydrogen embrittlement. This can be easily demonstrated by either testing an iron aluminide in an environment free of the deleterious species or by testing at high strain rates, both of which result in greater ductility. The purpose of this paper is to review recent progress in understanding environmental embrittlement in FeAI and Fe3AI, and to consider possible environmental embrittlement mechanisms. Greater understanding of this phenomenon will lead ultimately to remedies to this problem which is a major reason for preventing the practical application of these materials. First, some background on the iron-rich aluminides."

Jan 1, 1996

By Darrell L. Beddard

The test program information provided for some immediate changes on the upcoming contracts and in contract administration for the I-880 Replacement Project. Plan sheet modifications included changes to the pile data tables showing the actual demand load required for structural stability. The normal class of pile with a minimum load carrying capacity was removed. This provided for substantial pile length reduction at several locations since the structural loading was much less than the predetermined pile class ultimate capacity. New specifications were developed and standard specifications were modified to accommodate the newer foundations, installation procedures and pile acceptance criteria. Current Caltrans specifications require that the Contractor provide bearing capacity at the specified tip elevation. This requirement was removed and pile acceptance was determined by the Engineer. Acceptance criteria was established by the State and was based on. set-up trend over time. Static loading tests were reduced especially in areas where testing was performed on the indicator program. Testing procedures were modified and set-up periods were established before piles could be tested. For the contract near the San Francisco Oakland Bay Bridge (Unit E) the FHWA 1000 tons (8.9 MN) test beam configuration was completely changed. This provided added safety and allowed more tolerance in the pile placement for the testing operations. Indicator piles were added as companion piles to the static loading test piles. These piles were used for restrike events which included collecting dynamic data for calibrating the wave equation analysis with static load test results. Indicator piles also provided quick access for restrike events, where as, the static loading test pile needed modification to perform the restrike operation. Penetration rates were recorded for these operations. Wave equation Analysis Program (WEAP) was used in developing the acceptance criteria. The standard Engineering News Record (ENR) formula in the current Caltrans' Standard Specifications was removed for the contracts. Contractors were required to submit, prior to driving piles, a driveability study for their contract. These studies required discussion of their operations, method of installation, effects of soil set-up, set periods, hammer settings, bearing graphs, inputs to the WEAP program and complete a "Pile and Driving Equipment Data" form. Dynamic monitoring was detailed in the specifications on how the monitoring process was to occur. Set periods were established and restrike events were called out with the frequency of these events.

Jan 1, 1996

By J. G. Groppo

A beneficiation process has been developed to provide selective separation of unburned carbon from high LOI fly ash. Previous reports of utilizing froth flotation to achieve selective separations required long residence times and high reagent costs. A proprietary reagent system has been developed to address both of these limitations. Based on the results obtained from laboratory and pilot-scale investigations, a flowsheet design has been developed to produce two distinct usable products from class F fly ash; low LOI ash and a high carbon product suitable for reburning or further upgrading. A process flowsheet and description are presented.

Jan 1, 1996

By Steven R. Pittman, Colin McCullough, Peter Galuska

"Traditionally Continuous Fiber Aluminum Matrix Composites have been fabricated using high strength fibers and high strength matrices, often commercial alloys, with the goal of producing high strength composites. However the specific role of the choice of matrix alloy on composite properties has not been well established. One way to control composite tensile strength is to use coatings to introduce a low strength interface between fiber and matrix which tends to reduce the importance of the matrix selection, but unfortunately renders the transverse strength unacceptably low. Thus using a system with strong bonding between fiber and matrix is desirable, such as an alumina fiber / aluminum alloy matrix system. In this case the transverse strength is a strong function of the matrix strength. However the longitudinal strength then depends largely on the characteristics of the matrix. The important role of the matrix is discussed using examples of alumina fibers in various aluminum alloy matrices. The key attributes are matrix constituent phases, alloy chemistry, alloy reactivity with the fiber, and matrix strength. From the understanding developed in these systems a set of design rules may be established for selecting an optimum matrix. IntroductionAluminum matrix composites (AMC's) reinforced with continuous fibers offer very attractive property gains over AI alloys, such as strength, stiffness, and fatigue resistance. These gains are magnified when specific mechanical properties are compared which make them attractive candidates for replacing steel, nickel, titanium and aluminum alloy parts in weight critical applications (1). Many systems have been tried in the past; B/AI, C/AI, SiC/AI, Si-Ti-C-O/AI and AI203/AI. Technically B/AI was a very good system but was expensive in regard to both fiber cost and fabrication and SiC/AI and C/AI systems are still plagued with reactivity problems. The Si-Ti-C-O/AI appears to be a good strength system but with lower stiffness. Until recently, the AI203/AI was a low strength system, in part due to a lack of a high strength fiber. Recently 3M introduced a high strength AI203 fiber - Nextel™ 610, which leads to high strength composites (1,2) and may also be both low cost and also compatible with less expensive casting approaches for fabrication."

Jan 1, 1996

By G. Babut

The restructuring of mining operations in Valea Jiului coal basin imposed by the transation to the market economy calls for an increased coal production. Under the circumstances, the role of drainage networks grows ever more important. The paper describes an original mathematical model and software developed on its basis, with enables the ventilation engineer to assess the configurations of different systems, as well as to test their reliability and prognose their future performance before conceiving another methane drainage system or changing the existing one. The paper also includes the underlying principles of an optimization program for methane drainage networks, which will enable the detection of the optimal methane drainage system, both from a technical and an economic point of view.

Jan 1, 1996

Exploration for SX-EW copper deposits and plant operation depend largely on the copper and gangue mineralogy inasmuch as? they govern the feasibility of leaching. Mineralogical parameters are pivotal in identifying if an ore is suitable to dump, heap, thin layer, vat or agitated leaching and/or if the ore requires curing, bioleaching or alternate lixiviants. Problems in metallurgical testing, production leaching and recovery forecasting are very often related to lack of mineralogical data. This presentation will illustrate the use of quantitative mineralogical analysis for exploration, acquisition assessment and optimization of copper leach operations.

Jan 1, 1996

By F. P. Hassani, A. Hara, M. Momayez

To be competitive on the international market, the Canadian mining industry must reduce its costs, increase its productivity and maintain a high standard of safety. There is a great need today for improved methods that would allow the detection of geological structures in advance of mining to reduce dilution and the monitoring of underground structures to increase safety. This will facilitate planning for optimum exploitation of the mine and to increase production at lower costs. This paper discusses two examples of more efficient mine planning using new technologies such as Ground Probing Radar (GPR). In Kidd Creek mine, GPR technology was used at the 2500and 2600 levels to (1) monitor the stability of the sill pillar; (2) locate the presence of disseminated sulphide pockets in the sill pillar for extracting the mineral content; (3) monitor the stope backs and wall structures to evaluate the effect of on-time filling sequences; and (4)assess rockfill quality in terms of the presence of voids and fractures within the rockfilled areas. In the New Brunswick coal mine in Minto, GPR was used along with core log data to map and construct a 3D block of a section of the bench showing the relative position of different layers overlying the coal seam.

Jan 1, 1996

By P. H. Qi

Activated carbon loaded with gold from different halide solutions has been characterized by thermal analysis techniques. The mechanism of gold uptake by carbon varies from predominately adsorption for gold iodide to predominately reduction for gold chloride. TGA and DT A measurements confirm the existence of adsorbed gold-halide species within the micropore structure of carbon. These results suggest that the ration of reduced; adsorbed gold increases for gold halides in the order Au-I > Au-Br > Au-Cl. In the case of Au-I, TA results for the loaded carbon were compared with pure compounds of 12, AuI and AuI3.

Jan 1, 1996

Jan 1, 1996

By Xinghui Meng

The leaching behavior of platinum powder in .iodide solutions under oxygen pressure in an autoclave was investigated. Ammonium salts were added to the leaching solution at neutral pH as a key lixiviant for platinum. The effect of temperature, partial pressure of oxygen, concentration of iodide and of arttmonium salts on the dissolution rate of platinum was examined. Under experimental conditions, the leaching behavior of platinum powder exhibited a complex reaction mechanism. A precipitate was found during the leaching process and was identified to be platinum ammine iodide, Pt(NH3hI4. The dissolution rate was controlled by a series of chemical reactions, the equilibrium concentration of the platinum ammine iodide being responsible for the ultimate limit to the recovery.

Jan 1, 1996

By Carlos Agreda

"It is widely accepted that the rock blasting results are a function of several stochastic variables given by: -The natural geological structure of the rock mass (joint spacings, discontinuities length orientation and characteristics, physical-mechanical properties, such as: ultimate strengths and elastic properties, etc.).-The detonation and explosion parameters of the explosive mixture (V.O.D., P2, T2, Q3, etc.).-The drilling and blasting pattern dimensions.-In this paper the most important stochastic variables regarding with the rock mass and the blast design dimensions before mentioned are identified, described and discussed.A non linear programming method to calculate the optimum burden Bo) is proposed and discussed.The great impact of the stochastic variable called burden (B) on the rock blasting results is emphasized. A comparison between burden theoretical calculations and some field blast results is also shown."

Jan 1, 1996

Microwave pretreatment can improve grindability by weakening brittle particulate material prior to size reduction. The differential thermal expansion experienced by multiphase materials during rapid heating can also promote damage in the grain-boundary region, which may ultimately translate into enhanced liberation. The effect of microwave pretreatment on the breakage characteristics of different ores has been studied using the Ultrafast Load Cell. The energy accumulated during impact (fracture energy) and the particle stiffness have been measured for untreated and microwaved ore samples. It has been observed that microwave pretreatment can weaken brittle multiphase particulate material, as observed by reductions in fracture energy and increase in damage.

Jan 1, 1996

Over the last 15 years the contract mining concept has developed into an integral part of the Australian mining industry. Today it is a $2 billion per annum industry with the potential to continue to grow at a rate of between ten and 20 per cent. Australian contract miners have also exported the concept overseas where growth prospects are unlimited. The industry today is at a cross-road where both contractors and mine owners must consider the current state of the contract mining industry and where it is heading. To look at the present and the future, it is necessary to look back at the history of contract mining and why it has developed. Current industry concerns can then be summarised and the areas that need to be considered to enable the industry to prosper, reviewed. The ultimate goal is to reach solutions with benefits to both the mining companies and the contractors.

Jan 1, 1996

By George A. Calboreanu

In order to overcome drilling and tapping of high hardness wear resistent material in slurry pumps, most of time mild steel inserts are mounted in the mold and after pouring they become an integrated part of the casting. This process is limiting the size and design possibilities of slurry pumps and efforts were made to drill and tap the hard iron itself. The paper will present practical results obtained in drilling and tapping Cr-Mo wear resistent material with hardness in excess of 700 HBN. The life time of the slurry pump parts used in hazardous waste fuel transportation with high slurry velocity and 15% solid loading some of it being quartz, increased 2.5 to 6 times.

Jan 1, 1996

By L. Henry Smith, David C. Arthur

"The Williams Mine is Canada’s largest gold producer, with annual production of 450 000ounces from 2 300 000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs.The mine ventilation system is modified to include a new vent raise and variable pitchvane-axial fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved.Heating costs associated with under-ground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, minewater and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors.System design, energy savings data and payback calculations are presented."

Jan 1, 1996

By J. K. Brimacombe

"Nearly all the easy things have been investigated in injection metallurgy. Water models have been used exhaustively to study mixing, gas distribution and flow in submerged jets. Mathematical models have been developed with their restrictive boundary conditions to quantify submerged gas jet behavior. While being valuable tools to our understanding of injection metallurgy, there is an obliqueness to their application. What we need now are measurements and modelling on the actual systems, hot and unfriendly, where gas meets liquid at temperatures above l000°C. This is where the challenge lies.AN APPRECIATONThere are those who follow the trail and there are those few who blaze new trails in search of novel concepts and processes. With his restless, inventive mind, Howard Womer is a trail blazer without doubt. Decades ago, he was a pioneer in the pursuit of continuous steelmaking with the WORCRA Process and, today, he is developing new processes for the treatment of waste. He is not only an inventor but has been a professor at the University of Melbourne and was the first Director of Research at BHP. He has influenced the lives of many people, including myself; with his achievements and humanity. Therefore it is most fitting that this symposium should be held in honour of Howard Womer, a luminary in the metallurgical world for over half a century.BACKGROUNDGas injection has been an integral part of pyrometallurgical processes since the early days of Bessemer, then of Pierce and Smith. Today, of course, one cannot imagine pyrometallurgical processes without submerged gas injection to effect reactions for metal extraction and refining, to provide mixing and to inject solids into molten metal, slag or matte. Spurred on by new developments like tonnage oxygen and argon production, the Savard-Lee concentric tuyere and porous plugs, new steelmaking processes have emerged; and now solids injection is changing copper extraction processes. The ingenuity of the extractive metallurgists who drove these developments is inspiring for they have applied gas injection to transform pyrometallurgical processes. Humankind has been the beneficiary.' Today these processes are safer, more efficient, cost effective, less energy intensive and more environmentally friendly."

Jan 1, 1996

By Keith A. Heasley

In the past, numerous displacement-discontinuity (DD) models of stratified rock masses have been proposed using a homogeneous isotropic elastic overburden. In this paper, it is postulated that a laminated overburden model might be more accurate for describing the displacements and stress in these stratified deposits. In order to investigate the utility of using a laminated overburden in a DD model, the fundamental mathematical basis of the laminated model is presented and graphically compared with the fundamental behavior of homogeneous isotropic elastic overburden and with field data. Specifically, the stresses and displacements surrounding an idealized longwall panel as determined from the laminated overburden model are presented and compared with results from the homogeneous isotropic overburden and with measured abutment stress data. Also, the remote displacements and surface subsidence as calculated by the laminated overburden model are compared with homogeneous isotropic calculations and with measured subsidence data. The results of this investigation show that the laminated overburden is more supple, apt to propagate displacements and stress further, and better able to fit observed data than the classic homogeneous isotropic overburden. Ultimately, it is suggested that the laminated model has the potential to increase the accuracy of displacement and stress calculations for a variety of mining situations.

Jan 1, 1996

By Gordon A. Irons

"Powder injection for melt refining is widely practiced in the steel industry, and is gaining acceptance in the non-ferrous industries. In these commercially-important systems, the thermodynamics and kinetics may be very complicated. More than one element may be removed by refining, and often the refining agents are not just one compound. In this paper, the thermodynamic and kinetic aspects of these processes are reviewed. A number of examples are given, such as the desulphurization of iron with a variety of reagent mixtures, and selenium removal from copper with several different reagent combinations.IntroductionI am very pleased and honored to present a paper at this Symposium recognizing the many contributions of Professor Howard Womer. Even at the time I was an undergraduate student, the WORCRA process was part of the curriculum. I remember at the time that I was fascinated by the concept, and due to it and the many other rapid developments in Process Metallurgy, I chose it as my field of study. I think the Symposium is testimony that Professor Womer has touched the lives of many others as well.My original assignment was an overview of the basic aspects of gas and solids injection. However, I reviewed most of this material at the Savard/Lee Symposium [1]. In the present paper, I will present some of the basic issues related to refining with powder injection, using work that we have recently completed in both ferrous and non-ferrous systems."

Jan 1, 1996

In this paper a numerical formulation is presented for determination of the axial load along a cable bolt for a prescribed distribution of rock mass displacement. Results using the program CABLE indicate that during excavation, the load distribution that develops along an untensioned fully grouted cable bolt depends on three main factors: (i) the properties of the cable itself, (ii) the shear force that develops due to bond at the cable-grout interface (i.e. bond stiffness), and (iii) the distribution of rock mass displacement along the cable bolt length. In general, the effect of low modulus rock and mining induced stress decreases in reducing bond strength as determined from short embedment length tests, is reflected in the development of axial loads significantly less than the ultimate tensile capacity even for long cable bolts. However, the load distribution is also dependent on the deformation distribution in the reinforced rock mass. Higher cable bolt loads will be developed for a rock mass that behaves as a discontinuum with deformation concentrated on a few fractures, than for one which behaves as a continuum, either due to a total lack of fractures or a very high fracture density. This result suggests that the stiffness of a fully grouted cable bolt is not simply a characteristic of the bolt and grout used, but also of the deformation behavior of the ground. In other words, the same combination of bolt and grout will be stiffer if the rock behaves as a discontinuum than if it behaves as a continuum. This paper also explains the laboratory test programme used to determine the constitutive behavior of the Garford bulb and Nutcase cables bolts. Details of the test setup as well as the obtained results are summarized and discussed.

Jan 1, 1996

By J. A. Luppens

Five years ago, Phillips Coal Company decided replacing mainframe/workstation programs with a new package of PC software was clearly the best solution for computer reserve modelling. The system chosen was actually three programs distinguished by their power, cost, flexibility and integration, and ease of learning and use. Phase I involves the use of the "StratiFact" program for borehole data management and seam correlation. This phase is probably the most neglected, yet critical aspect of reserve evaluation. Phase II employs the "PC/Cores" package for modelling and volumetrics. Phase m is "PC-Cut" which provides mine planning tools including an automated cut generator.

Jan 1, 1996