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By N. S. Dalal, X. Shi

"Electron spin resonance measurements provide evidence for the formation of long-lived Cr(V) intermediates in the reduction of Cr(Vl) by glutathione redtuctase in the presence of NADPH and for the hydroxyl radical formation during the glutathione reductase catalyzed reduction of Cr(Vl). Hydrogen peroxide suppresses Cr(V) and enhances the formation of hydroxyl radicals. Thus Cr(V) intermediates catalyze generation of hydroxyl radicals from hydrogen peroxide through a Fenton-like reaction. Thus the mechanism of Cr(VI) toxicity might involve the interaction between macromolecules and the hydroxyl radicals.C(Vl) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals (1-3). In contrast, most Cr(III) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic (1,4). Cr(VI) and Cr(III) oxidation states are different in their metabolic pathways: Cr(VI) , ions are rapidly transported across cellular membrane (1,4,5), while Cr[III) moieties do not easily penetrate cells and are not oxidized by cellular constituents (!). Since it is known that the reduction of Cr(VI) ion is required for its reaction with DNA (1), the molecular mechanisms for the intracellular Cr(Vl) reduction has been the focus of current studies but the details are still not understood.Earlier studies on the mechanism of Cr(Vl) reduction include those on the reduction of Cr(VIJ by glutathione (GSH) .0,6-8), ascorbic acid (9), glucose (10), lactose (IO), galacturonic acid (11), microsome (12), and mitochondrial electron transport chain complexes (13). These studies have shown that the Cr(VI) reduction involves the formation of Cr(V)-containing species which are often considered to be the toxic form of chromium. Thus far, however, no information is· available on the subsequent fate of those biologically formed Cr(V) species, in particular employing well defined biochemical systems. In this context, we report here our investigations of the reduction of Cr(VI) by glutathione reductase (GSSG-R). This enzyme was selected because it is ubiquitously present in cellular systems and it has been postulated to be involved in the Cr(VI) reduction (14-17) but the underlying mechanism has not been clarified. We find that the reduction proces·s involves not only Cr(V) but also ·OH radicals. We further investigate the reactivity of Cr(V) and find that it catalyzes generation of OH radical from H2O 2 through a Fenton-like reaction. The role of ·OH in Cr(VI) carcinogenicity is suggested from this study."

Jan 1, 1989

By Bob Katsiouleris

Having passed through the worst of times for industrial minerals demand, there are signs that the best of times lie ahead. If the downturn was the result of unsustainable economic policy, the path forward has everything to do with sustain-ably meeting the demands of more people enjoying higher standards of living than ever before. Minerals producers must be poised to understand and meet their requirements well into the next decade. Successfully marketing industrial minerals - the building blocks of a growing and increasingly urban world population - will depend on producers? ability to respond nimbly to a rapidly changing and regionally evolving macroeconomic environment. A renewed focus on energy conservation, sustainable agriculture and building practices and consumer demand for products with a smaller environmental footprint will drive product and market segmentation strategies. These trends will not only shape the way industrial minerals producers do business, but also the type of skills and people they will require to run those businesses.

Jan 1, 2011

By Laura A. Sanders

Mineral scale formation is prevalent in numerous mining operations. Such scale formation can occur in the direct-contact heat exchangers ahead of an autoclave. In these heat exchangers, the incoming slurry comes into contact with steam in a stage-wise fashion, which is re-circulated from the downstream flash vessels to heat the slurry in stages ahead of the autoclave. Calcium sulfate scaling causes severe problems in mining operations where increased temperatures are involved due to rising temperatures promoting calcium sulfate scaling through a decreasing solubility. In a number of these operations, the scale formation can occur in the presence of mineral solids, where fine-grained charged particles are at concentrations in excess of 35%. Scale prevention is not difficult in standard aqueous systems; however, the presence of solids leads to significant deficiencies in the prevention of scale due to the adsorption of the polymer onto the charge solids instead of the polymer interaction with the scale. Therefore, a technical solution to prevent mineral scale build up occurring in presence of pulp slurry in mining operations is needed. Several novel antiscalant technologies were developed and evaluated which provided a substantial improvement in the scale prevention in such systems.

May 1, 2013

By Xiaodong Jia, Williams. Richard A.

This paper describes the recent developments, arising from research at Leeds, in the computer modelling of packing of complex shaped particles and prediction of physical properties of the structures represented by the packing. The computer model DigiPac, is capable of packing particles of any shapes and sizes in a container of arbitrary geometry. The ability to predict packing structure of real particle shapes and to compute directly some structure-dependent physical properties (such as liquid permeability, mechanical strength/ stability, compaction and sintering, dissolution and leaching, etc.) is obviously highly desirable and has significant potential in industrial applications. Examples are presented relating to the packing of granular materials.

Jan 1, 2003

By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By Siavash Zamiran, Abdolreza Osouli

"One of the most concerns of room and pillar mining system is subsidence of the ground surface due to coal mining particularly in room and pillar mines. Subsidence of ground surface is a result of floor, pillar, or roof failure of the mine. At the same, due to many difficulties associated with surface disposal facilities of coal refuse, some mining companies are trying to use underground space as a disposal storage place. In this study, stability and subsidence analyses of an underground coal mine located in the Illinois Basin are conducted. This room and pillar mine was abandoned and later on was used as a storage place to accommodate the coal fine refuse with slurry backfilling method. The geological stratigrophy and geomechanical properties of the mine floor and roof were collected. Floor and pillar stability analyses were conducted for areas with various extraction ratios. The stability of the mine was evaluated both prior and after slurry backfilling. The floor and pillar stability analyses results of the mine due to moisture exposure after slurry backfilling are discussed. The subsidence potential due to mine failure is also evaluated.INTRODUCTIONA typical lithology of coal seams in the Illinois Basin consists of weak underclay stratum. The immediate weak underclay causes frequent floor instability problems in Illinois underground coal mines. There are two different stages in assessing floor stability of the mines where slurry backfilling is planned. The first stage is during the mining operation when weak underclay layer squeezes under pillar stress and results in punching or bearing capacity failure. The second stage is after slurry backfilling. During this stage, the slurry material soaks non-durable floor layers and causes strength reduction in floor material. Pillar stability conditions should also be taken into account during both the operational period and after the slurry backfilling."

Jan 1, 2015

By D M. Frantois-Bongarton

"A few situations are first reviewed where practical shortcuts lead to acceptable solutions where none seemed to be possible. These include: The solving of many complex sampling optimisation problems with the simple approach of the worst case policy (WCP). A simple approach to single-stage sampling problems will be mentioned at continuation. In the plants, minimising the impact of border effects in incorrect samplers, so that the resulting samples are approximately correct and acceptable in practice because the bias risk attached to them is controlled. Examples are given, as well as practical tools and a general methodology.Finally, some sources of undue conservatism are reviewed with general recommendations aiming at eliminating them.CITATION:Frantois-Bongarton, D M, 2012. Practical considerations and shortcuts in sampling, in Proceedings Sampling 2012, pp 171-174 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 21, 2012

By Bjorge, Guy N.

MINING method improve through the gradual process of evolution and in 1340 there were no marked outstanding innovations. On the other hand refinements of detail and betterment: in equipment design continued to progress. Among the most important changes have been the increased application of trucks and highway equipment, including tractors and bull- dozers, to open-pit mining as exemplified by Phelps Dodge's Morenci operations; the Mesabi iron range; and the Tri-State district. Mass or bulk handling contributed its part underground with slurhers and conveyors at Consolidated Coppermines and slushers at Climax; and in open-pit mining. conveyors found increased use on the Mesabi range.

Jan 1, 1941

By A. Elsayed

Lightweight metals such as magnesium show potential in replacing aluminum alloy castings for engine cradles, cylinder heads and transmission cases. Unfortunately, magnesium alloys are susceptible to entrapping oxides and other impurities during casting that hinder strength and ductility. The current study examined various filter sizes and configurations with the aim of improving the mechanical properties of permanent mould cast AZ91E. The unfiltered casting had a yield strength, tensile strength and ductility of 93.3 MPa, 153.3 MPa and 2.2 % respectively and increased to 96.5 MPa, 167.0 MPa and 3.1 % with the use of a fine mesh filter within the well of the mould. The increased strength and ductility was likely due to the filtered castings containing fewer inclusions on their fracture surfaces as compared to the unfiltered castings.

Jan 1, 2011

By S. P. Nagaeva, O. U. Poperechnikova, A. V. Kuptcova

"In case of free gold presence in ore, there is always problem of a choice between the gravity-flotation and gravity separation flowsheets. Study of morphology of gold being extracted by different methods allows to find the most efficient solution. One of the latest methods of gold concentration for wide range of grain size (-0.8+0 mm) is a flash flotation. The paper presents comparative testing results of flash and centrifugal separation.The goal of the studies was to determine process and flotation parameters of flash flotation. In case valued minerals are soft if compared to host rock, such minerals tend to concentrate into circulating load of grinding circuit. Thus, valued minerals can be overground, and in turn, will result in low extraction in flotation circuit. Integration of flash flotation operation into process flowsheet has been evaluated. Flash flotation operation can be successfully used not only for gold but also copper, lead, nickel and silver minerals.With low-sulphide ores being a case study under laboratory conditions, various flotation (impeller rotational speed, air flowrate) and process (pulp density, collector consumption, frother consumption, time of flotation) parameters were studied in view of its impact on gold flash flotation. Experiments were carried out under laboratory conditions using special pneumatic mechanical flotation machines.INTRODUCTIONGravity separation is used for extraction of coarse gold before cyanidation and before flotation of polymetallic ores to increase gold total recovery into gravity copper and lead concentrates.Benefit of the flash flotation is efficient recovery of coarse gold carrier particles (sulphides) thus preventing its regrinding and, as a result, low recovery. Furthermore, combination of flash and conventional flotation results in final tailings that do not require further cyanidation.Combined gravity-flotation flowsheets are designed for concentration of ores containing gold within thewide range of grain sizes (see Table 1)."

Jan 1, 2018

By David Van Aken, Arpana S. Murthy, Simon Lekakh, Von L. Richards

"Three heats of 17-4PH stainless steel: with zero, three percent, and seven percent cobalt addition were melted in a 45kg (1 00lb) induction furnace under argon; and cast into no-bake molds and preheated investment shell molds. Specimens were sealed into quartz tubes under vacuum, and homogenized at 1200°C from 2h to 72h. Computational thermodynamics and optical microscopy were used to predict and characterize the microstructures. The lath martensite packet size and the amount of 8-ferrite were observed to be inversely related. A compromise between decrease in segregation and increase in lath martensite packet size was chosen for the optimum homogenization treatment. The specimens were austenitized, quenched, and characterized for retained austenite using x-ray diffraction. Age hardening kinetics were studied at 454°C (850°F), 468°C (875°F), and 482°C (900°F); and, the activation energies for precipitation of copper were calculated. Tensile properties and Charpy V-notch impact energies were measured in the peak aged condition. Fracture surfaces were observed using scanning electron microscopy and Energy Dispersive Spectroscopy. The addition of cobalt was found to be beneficial for the improvement of strength as well as notch toughness.IntroductionSegregation in the as-cast condition is one of the drawbacks of metal casting. This paper presents a study on the homogenization treatment of 17-4 PH cast stainless steel and the effect of cobalt addition on tensile properties and Charpy V-notch toughness. Lattice dilatation studies show that additions of up to 6% Co to iron has a negligible effect on the lattice parameter, whereas both the modulus of elasticity and shear modulus increase with increasing cobalt additions5• An ordering reaction has been reported in cobalt-containing, maraging steels and contributes to the hardening during ageing1-4• Although, cobalt addition in maraging steels has been extensively researched, and has been reported to be beneficial; it has not been explored much in other age-hardening stainless steel systems. In a previous study, the addition of 3% Co in cast 17-4 PH martensitic age-hardenable steel was found to improve the strength and elongation while maintaining the charpy V-notch toughness6."

Jan 1, 2011

By AIME AIME

PETROLEUM technology was the sole subject of discussion at the meeting of the Petroleum Division at the Baker Hotel, Dallas, Texas, Oct. 6-7, except for the brief talks by President Becket and Secretary Parsons at the dinner on Friday evening. Even on this occasion, following the scheduled official features, it was in order to talk "shop." W. E. Wrather and E. A. Stephenson, respectively Chairman and Secretary of the Division, had planned for a meeting of this nature and by preference, apparently, the 122 who registered fell in with the scheme wholeheartedly. Not because the competent local committee had not provided for it, but by choice, the members just did not sign up for entertainment or field trips, but did attend largely the three technical sessions and engage in earnest discussion of the approximately dozen excellent papers. In this connection, and without question, the high lights of the meeting were the papers by Morris Muskat and R. D. Wyckoff, and Prof. W. K. Lewis. The former, entitled, "A Theoretical Analysis of Waterflooding Networks," had been entirely demathematized by the authors for presentation at this and the Los Angeles meetings; the author of the latter, which was on the "Physical-chemical Relationships of Hydrocarbon Gas-liquid Mixtures at High Pres¬sures," had airplaned to Dallas in the company of Dr. H. D. Wilde from Chicago in order to present his paper at the final session on Saturday morning.

Jan 1, 1933

By ARCHIBALD DOUGLAS

BY this time almost everyone knows, in a general way, the corporate income distribution policies of the 1936 Revenue Act, and many of the practical problems arising there under. This article is not intended to be a technical discussion of that act by title, subtitle, section, or supplement, nor an analysis of inter- dependent sections of the various acts over many years woven on the fiscal loom f our Congressional machine. Such a discussion would require the spinning of a web of words too long for patience. Yet ,a general statement of the underlying plan of the 1936 Act, so far as it affects dividend policies, is perhaps useful.

Jan 1, 1937

By Robert M. Weidenhammer

For years before the war, Coal had the reputation of being a sick industry. Currently it is operating at peak production and succeeding pretty well in keeping out of the red. But, says Mr. Weidenhammer, it will have a relapse as soon as the war ends unless (1) working capital can be built up; (2) it gets the support of the people and Congress; and (3) a truly long-range national fuel policy is formulated.

Jan 1, 1943

By Marcus Nadler

WAGES in the United States, in spite of the wage freeze, have increased materially. Overtime payments have become standard practice in almost all industries. Now efforts are being made to place wages on an annual basis, and if this is adopted, it will result in an increase in the cost of production. Organized labor today is more powerful than ever before; union membership is large and steadily increasing, and in many instances membership in the union is a prerequisite to employment. The treasuries of many unions are strong as a result of the large membership and full employment. The unions, therefore, today are in a much better position than ever before to carry on long strikes. Politically, too, the unions are more powerful today than they ever were. On the basis of their strength, one may expect that some of the demands that the labor unions will make in the not distant future will be granted. It is, therefore, quite evident that before long, particularly when the curtailment in war production reaches about 40 per cent, this country will be confronted with a serious labor problem.

Jan 1, 1945

By Harry P. Hohenadel

DURING the past few years the amazing developments of the chemical industry have inspired so much publicity that the feature writers assure us that we are entering a "Chemical Age," industrially as important as the "Steel Age" and the "Electric Age," so-called. Whether or not these assurances are overstatements, it is a fact that the expansion of the chemical industry during the past 25 years has been enormous. The Chemical Bureau of the War Production Board calculates the value of chemicals produced during 1944 at $8,300,000,000, no small sum even in inflated dollars. As concerns us of the Southwest oil and gas country, four significant trends of the chemical industry are most important. (1) Many of the recently developed chemical products are new creations, not substitutes,. as new and original as the invention of the light bulb, and with a field for exploitation almost as wide. (2) Many of these chemical products will enter the mass consuming markets, which require enormous tonnages of products, and such markets are setting up an industrial demand for chemicals on a mass volume basis, compared to the relatively high-priced low-volume basis ordinarily considered as the chemical outlet of the past. (3) Most of the processes involved in producing these chemicals are adapt. able to the use, all or in part, of natural gas, oil, or refinery gases as raw mate-

Jan 1, 1945

By Verya Nasri, Behrouz Esmaeilkhanian, Mohammad Motallebi

The Mount Royal Tunnel (MRT) is a 100-year-old railway tunnel located in Montreal, Canada. The tunnel is approximately 5 km long, 8.7 m wide and 5.5 m high, with a constant 0.6% grade. This existing tunnel will be used by the new Montreal light rail transit network, Réseau Express Métropolitain (REM). This requires the tunnel to be inspected, rehabilitated and made compliant to the recent safety standards. This paper presents the details of the structural inspection and rehabilitation of the tunnel along with the repair methods, addition of a center wall as well as the enlargement of the tunnel section.

Jun 13, 2021

By Aditya Ayithi, William G. Ryan, Dean Herbst

"For rock socketed drilled shafts, it is a common practice not to include the frictional resistance of overburden soils into the nominal capacity estimation. The primary reason often being cited is “overburden soils resistance is negligible compared to that of rock socket resistance.” However, in certain geological conditions, where the rock layer is located at greater depths, friction resistance from overburden layers can be significant. In addition, at such great depths, shaft drilling becomes very complicated and expensive. In these situations, considering the resistance of the overburden layers can be an economic alternative.This paper presents a case study of an Osterberg cell (O-cell) load test conducted on a 161.8 feet long and 78-inch diameter instrumented test shaft. Based on initial designs, a 72-inch diameter rock socket of lengths 23 and 26 feet was required to provide a LRFD factored friction resistance of 3,200 kips. The load test results revealed that the material in the 72-inch diameter socket does not represent a true rock. However, the test results also proved that the factored friction resistance of overburden layers is greater than the required design resistance. Based on the load test results, it was decided to allow the overburden soils frictional resistance to be considered in the shaft design, resulting in significant economic savings.INTRODUCTIONRock socketed drill shaft design guidelines of various State Department of Transportation (DOTs) agencies allow friction and/or end bearing resistance of only the rock socket portion into the design capacity estimation. It is typical to neglect the frictional resistance of overburden soils. However, in certain geological conditions where the rock layer is at greater depths, friction resistance of the overburden soils can be significant. In this case the friction resistance of overburden soils was verified via the specified instrumented O-cell test program and then used as part of the design capacity.PROJECT DESCRIPTIONAs part of I-29 improvement project, Iowa Department of Transportation (Iowa DOT) planned to replace the dual four lane bridges that cross the Floyd River in Sioux City, Iowa with dual six lane bridges (Fig. 1). Expected benefits from this improvement include improved safety, traffic operations and roadway infrastructure conditions.BRIDGE SUBSTRUCTUREThe project consists of two individual bridges; a new south bound bridge and a new north bound bridge. The south bound bridge is 646-ft long and the north bound bridge is 644-ft long. Both are six-span, pretensioned and pre-stressed concrete beam bridges of varying width. Bridge foundations were designed such that the abutments of both bridges will be supported on driven steel piles and the bridge piers will be on drilled shaft foundations."

Jan 1, 2016

By F. G. Clapp

IT is to be hoped that no casual reader will erroneously refer to the latest publication' of the Division of Public Relations of the American Petroleum Institute, as being "Petroleum Facts and Fancies." The facts are so faithfully derived and the figures are so authentically sponsored by the highest sources that no person can read this valuable volume (287 pages and numerous tables) without being convinced that every- thing therein set forth is "the truth and nothing but the truth." Yet, having read the volume from the perspective of the world's petroleum industry and with a critical attitude that comes from years of study of the subjects discussed, I find myself tempted to cogitate and to envisage a few of the fancies that come to mind as a fitting sequel.

Jan 1, 1929

By W. M. Ross

AMONG the comparatively few A radical changes in mining equipment in recent years is the introduction and use to an ever greater degree of detachable bits for rock drills. Just how great the possible field for economic application of this innovation is, and to what ex- tent detachable bits are used instead of the conventional type of drill steel, are matters of conjecture. Just as a rough approximation, one might conceive that at least three-quarters of the drilling done in mines today could better be performed by steel with detachable bits, instead of only about one-quarter as at present.

Jan 1, 1939