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By Andreas Rubo, Stephen Gos

Over the past couple of decades several endeavours have been made to develop lixiviants with the intention of replacing cyanide in gold leaching. In 1980s these endeavours were largely economically driven, due to cyanide shortages at that time. In more recent times, the driving force has shifted to occupational health and environmental considerations. It is often argued that the high acute toxicity of cyanide alone makes it worthwhile considering to replace it completely by less toxic alternative lixiviants. This has led to having to consider more criteria in the choice of any alternative lixiviants, which have often not been taken into account in the past. The intention of this paper is to review these alternative lixiviants and also review the criteria, which have ultimately led to most of these lixiviants never having found any large scale application, if they passed laboratory stage at all. It is also intended to show, that by handling and treating cyanide in a proper manner, the overall profile for the use of cyanide compared to these alternative lixiviants is very favourable. The question to really be answered is whether there is actually any chemical or process applicable to gold leaching that does not show the high toxicity potential of cyanide and that is still favourable with regard to looking at a broader spectrum of criteria and not only acute toxicity.

Jan 1, 2000

By W. P. Rumancik, C. P. Lazzara, A. C. Smith

The United States Bureau of Mines (USBM) developed SPONCOM to aid in the assessment of the spontaneous combustion risk of an underground mining operation. A prior knowledge of the spontaneous combustion risk of the coal and factors that increase that risk can be useful in the planning and development of proactive monitoring, ventilation, and prevention plans for the mining operation. Interactive data input screens prompt the user for information about the coal's chemical and physical properties, the geologic and mining conditions encountered in the mining of the coal, and the mining practices employed. During the input process, 'expand' screens provide the user with specific information on each input parameter. This information includes a description of the parameter and its effect on the overall spontaneous combustion risk. The program logic determines the coal's relative spontaneous combustion potential, based on the coal's proximate and ultimate analyses, and heating value. The program then evaluates the impact of the coal properties, geologic and mining conditions, and mining practices on the spontaneous combustion risk of the mining operation. The program output provides details on each factor that increases the risk of spontaneous combustion.

A considerable debate has arisen regarding the best route for the beneficiation of iron ore. Supporters of jigging technology claim that although the technology is old, due to recent advances in jig control and a better understanding of the separation processes within jigs, it offers significant advantages over dense medium separation, especially in terms of reduced capital and operating costs and simplicity of design. Supporters of dense medium separation claim that this technology is proven to provide the best possible separation and that the gain in efficiency over the life of the plant, compared to that of a jig, will more than offset any differences in capital or operating costs. The truth is that both viewpoints are valid and that the choice is ultimately determined by specific characteristics of the ore being treated. Factors that need to be taken into account in deciding upon the correct option include the size/density distribution of the ore to be treated, the different size fractions which must be treated (lumpy or fines), differences in yield at grade, plant layout and capital and operating costs. Each of these factors will be discussed in detail and a case study for both lumpy and fines will be presented.

Jan 1, 2007

By Weston Bourret

The need for wartime supplies of uranium for the Manhattan Project prompted a 1944 study of uranium in South Africa. Uraninite had been reported by R.A. Cooper in 1923 in a Witwatersrand heavy- mineral concentrate, and the search for uranium, therefore, included the district's 30 operating mills. The method of investigation was simple: take bulk concentrate samples from the Wifley tables and determine their mineralogy. Samples were taken on a daily basis, although weekly composites also were taken of some mills. In 1944, most mills had simple gravity circuits and produced (I) a gravity concentrate, and (2) an all-slime [-75 pm (-200 mesh)] product. The tonnage throughput was known, and from that, head assays could be calculated. Concentrate samples were sent to the United States for chemical analyses. A Geiger counter set up in a Johannesburg hotel room provided preliminary data. The early data showed uraninite to be widespread. Microscopic, mineragraphic, and siezing tests were all under- taken in Johannesburg. Ultimately, tests led to a high grade (+90%) uraninite concentrate. Platinum and other heavies were the impurities. In seven months, the investigations had reached the stage where it was possible to forecast an annual production of 5.4 to 7.3 kt (6,000 to 8,000 st) of U3O8. The estimate is still realistic. Additional details are found in Bourret (1981).

Jan 1, 1991

By A. N. Mitinsky

Discussion of the paper of A. N. MITINSKY, presented at the San Francisco meeting, September, 1915, and at the New York meeting, February, 1916, and printed in Bulletin No. 104, August, 1915, pp. 1697 to 1705. ALBERT SAUVEUR, Cambridge, Mass.-The author expresses the belief that steel will not fail under fatigue when subjected to ultimate stresses unless the stresses exceed the elastic limit or the limit of proportionality. I think this statement is contrary to the evidence. It is conceivable, however, that a stress ever so small does produce a permanent set, although so slight that we cannot detect it with the instruments at our disposal. Nevertheless the repetition of this small stress a great many times will finally break the piece and the nearer, we approach what we call the elastic limit, the quicker will the piece break under fatigue. J. W. RICHARDS, So. Bethlehem, Pa.-I would like to ask Professor Sauveur whether there is a similar indefiniteness about the limit of .proportionality as there is about the elastic limit. ALBERT SAUVEUR.-Yes; I believe it also depends upon the delicacy of our instruments. J. W. RICHARDS.-If that is so then we are as badly off by adopting the limit of proportionality as a criterion as we are by adopting the elastic limit.

Jan 5, 1916

By S. R. LaBrooy, M. C. Costello, A. C. Bax

Nickel is present in a number of gold ores in Australia, Africa and the United States. The effects and behaviour of the nickel during the cyanidation and adsorption processes, and also during the elution and electrowinning processes have been examined by a number of researchers, usually as a part of a larger investigation. This paper examines the available data on the behaviour and effect of nickel during cyanidation and its associated unit processes. The presence of nickel is often not considered to be particu­larly important as it does not cause the same degree of problems across the circuit as those experienced in the presence of copper. It can however lead to increased cyanide consumption during leaching, and reduced adsorption of gold onto carbon. A proportion of nickel cyanide may be removed from carbon prior to elution by carrying out a hot (90° C) acid wash. The nickel which remains on the carbon will be partially eluted during the main elution step, and, dependent on its concentration in the pregnant solution, part of it may be deposited during electrowinning. There is always a risk that any nickel remaining on the carbon after the elution step will be reduced to metallic nickel during the regeneration step. This may ultimately result in an increasing base level of nickel on the carbon, as metallic nickel is insoluble in both cyanide and hydrochloric acid.

Jan 1, 1995

By Victor F. Hollister

This first section of case histories of mineral discoveries, Vol. 3, covers some of the milestones in porphyry copper and skam exploration successes. It was during the era of these discoveries that large, complex exploration departments emerged as permanent adjuncts of large mining companies. The discoveries helped shape how and where exploration activity was conducted. Probably the most important factor in exploration success is management. Few management people are mentioned in this section or in any exploration history, yet the distinction between success and failure ultimately rested with the decisions they made. One of the most successful groups was initiated by Roger Straus and Herbert Brownell when they sought to make Asarco into an important metal producer. Relying on Clem Pollock and L.H. (Bill) Hart to identify and push worthwhile projects, the Asarco management remade the company. Asarco will benefit from exploration successes com- pounded by that team for years to come. Duval is an example of a management that decided to add metal production to its industrial minerals output. When Page Morris was president, that company opened three major porphyry copper mines and became an important factor in metals. Under the Monis management team, Duval became a leader in exploration. At the other end of the scale are managements that snatched defeat from the jaws of victory and by so doing changed the character of their companies in other ways.

Jan 1, 1991

By T. R. Twiddle

The sequential flotation of copper, lead, and zinc in that order is practised at the Broken Hill Concentrator of the Black Mountain Mineral Development Company (Pty) Limited. The minerals of economic importance are chalcopyrite, galena, and sphalerite, with associated silver. The targets for recovery and grade in the lead and zinc circuits were reached quite readily after start-up, but the copper circuit failed to meet the performance requirements with respect to both recovery' and grade. The original circuit for copper is described, together with the subsequent investigations and modifications that were required to produce acceptable metallurgical results. Circuits for semi-bulk and bulk flotation were tried, and the effect of the oxidation state of the pulp was investigated extensively and found to be all important. Tests were conducted on the depression of lead in the cleaning circuit by the use of sodium dichromate, and on heating with the addition of sulphurous acid. The latter technique was ultimately the more successful. The proportion of fresh to recycle water entering the circuit was shown to be important. The original reagent regime was altered and augmented. A more recent problem has been the contamination of the ore with cemented backfill. The changes that this new condition necessitated are described. Success has been measured by a continuous improvement in the economics of the copper recovery.

Jan 1, 1984

By José Carlos A. Cintra

This paper addresses a new experimental procedure to measure the shaft friction and the base resistance of bored piles during static load tests. It is proposed that a set of polystyrene foam discs, placed between the shaft and the base of the pile, be used instead of the usual instrumentation. Throughout the initial stages of the loading test, the foam discs will allow only the mobilization of the shaft friction. The load x settlement curve clearly shows that the shaft friction vanishes at low settlement values. As the load test proceeds, the base resistance is also mobilized. This procedure was used in two belled piles bored at the Experimental Foundation Field of the University of São Paulo, at São Carlos, Brazil. Both piles were 8 m long and had a shaft diameter of 0.6 m. The enlarged base had a diameter of 1.5 m and a height of 0.9 m. Twenty foam discs with a thickness of 20 mm each were placed between the enlarged base and the shaft of the pile. The load tests indicated ultimate shaft frictions of 28 and 30 kPa for measured settlements of 8.98 and 7.39 mm. Base resistance values at failure were 617 and 499 kPa, for a chosen settlement of 10% of the pile base diameter. The proposed approach seems to be straightforward, efficient and inexpensive.

Jan 1, 2002

By Jakub Kaczorowski

In the production of Mn-alloys, the Boudouard reaction significantly influences the mass and energy balance. The endothermic nature of this reaction requires more energy for the process, while the direct consumption of carbon is reflected in the greater demand for carbonaceous raw materials. Therefore, it is desirable to eliminate or suppress the reaction. The kinetics of the Boudouard reaction are a function of many factors, of which coke properties and the conditions around the particles (i.e. temperature, gas composition) seem to be the most important. In the present study properties of selected single source and commercial metallurgical cokes are compared with reactivity results. The single source cokes represent a single coal that has been carbonized in a laboratory scale furnace. The commercial cokes are products of carbonization of coal blends under industrial conditions. The coke properties include proximate, ultimate and ash analysis. Also, coke petrography with carbon forms is included. The reactivity tests were performed on different particle sizes at various temperatures, gas compositions and gas flow rates. The experimental parameters were chosen to simulate the conditions in an industrial furnace. The results show that highly graphitized structure of cokes, minimal surface area and a low concentration of ash retard the reactivity. Of the other factors, the temperature and the gas composition have the greatest impact on the reactivity.

Jan 1, 2006

By W. F. Baldwin

The timing circuit generally employed in Carter Reservoir Behavior Analyzers consists of a synchronous motor driven cam which actuates a microswitch. A mechanically actuated timer of this type has several inherent disadvantages, among which are the following: 1. The first time interval may not be of uniform length, depending on the exact position of the cam at the conclusion of a previous run. 2. The positioning adjustments on the microswitch lever arms are critical and require periodic readjustment. 3. The mechanical system is subject to wear which will ultimately impair its accuracy. It was therefore considered desirable to devise an alternate method which would eliminate these difficulties without introducing others that would be equally troublesome. This note describes the design of an electronic timing device which has been incorporated in the analyzer constructed by the Field Research Laboratories of Magnolia Petroleum Co. The electronic timer circuit is built around a simple neon glow tube relaxation oscillator, the complete circuit diagram of which is shown in Fig. l. The operation of the circuit is as follows: Condenser C, is charged to the critical firing voltage of the neon glow tube VR-75 by battery B1 through resistors R1 and R2. When the neon glow tube fires, the condenser C, is discharged, The charging cycle then repeats itself,

Jan 1, 1950

While there is reasonable agreement on the basic chemistry of the slag fuming process, there has been an on-going debate for nearly 50 years as to the nature of the rate controlling factors in its industrial application. There have been advocates in the technical literature for thermodynamic limitations on the one hand or kinetic limitations on the other. The different viewpoints result in very different predictions as to the technical and commercial potential of the process. A resolution of the debate becomes of importance as pyrometallurgical processes are advocated as a means of extracting environmentally deleterious elements from metallurgical wastes. The present paper reviews the arguments in favour of both equilibrium and kinetic control and puts forward the view that much of the evidence for limitation of the process by kinetic factors under all conditions is unconvincing. It is maintained that the process can approach thermodynamic equilibrium under industrial conditions and that this determines the ultimate limitation on its technical performance. It is acknowledged, however, that kinetic considerations may cause the batch process to fall well short of performance predicted on thermodynamic grounds. The strong process limitation arising from the influence of chemical thermodynamics on the likely outcome of a hypothetical continuous fuming process is contrasted with optimistic forecasts resulting from the extrapolation of process models based only on kinetic considerations.

Jan 1, 2000

By Leslie Taylor, R. Reed Skagga, William Gault

The ultimate aim of our overall task, of which the effort described in this paper is a part, is to be able to model the impulsive output of buried charges and the response of targets of interest. It is not practical or cost-effective to determine the response of all targets of interest to buried charges of all sizes by testing them. In order to have confidence in our models, however, they must be validated by a modest number of tests. A critical element in modeling the response of a target is the ability to model the loading function. The load a buried charge applies to a target above it when the charge detonates can be characterized in terms of the vertical impulse. The vertical impulse is a function of the size of the charge, its depth of burial, and the properties of the soil in which it is buried. The primary objective of the effort described in this paper is to determine the load a known charge places on a non-responding target so the data can be used to validate our models.

Jan 1, 2005

By Victor F. Hollister

This section on case histories of discoveries of volcanic-associated and volcanogenic massive sulfide deposits is divided into a preliminary discussion of models and then into three parts: Kuroko- type, Anyox-type, and shale-hosted. The separation is made to accommodate the use of exploration models, and these may not coincide with genetic models discussed in the literature. The exploration models grew as knowledge was gained concerning ore guides and ore controls in the volcanic-related deposits. The evolution of the genesis of massive sulfide deposits in volcanic terranes from a replacement to a syngenetic hypothesis in the 1950s and 1960s necessitated changes in exploration approaches in ore search. The acceptance of a syngenetic origin for conformable or concordant sulfide masses led to more widespread adoption of stratigraphic ore guides. 'The occurrence of epigenetic stringer ore with and stratigraphically below many conformable massive sulfide deposits did not diminish the importance of stratigraphic ore controls. Proximal conformable sulfide masses were formed near their seafloor hot spring source and normally are underlain by epigenetic sulfides: whereas. distal conformable sulfide masses were deposited away from the hot spring and may have no associated feede; zone. Industry groups that early recognized the syngenetic nature of volcanogenic massive sulfides were responsible for discovery of some of the large and economically significant deposits. Ultimately, the rest of the geological profession accepted the leadership of the early iconoclasts.

Jan 1, 1991

In the last few decades, a considerable amount of effort was directed at accurately determining the coal pillar strength to use for safely designing coal mines. The outcome of this early work was the well known Obert-Duvall, Holland-Gaddy, Bieniawski, and Salamon-Munro equations for coal pillar strength. All of these equations were developed for, and were calibrated with, pillars in a large room-and-pillar area such that the loading could be determined using the "tributary-area" theory. In order to account for the abutment loads associated with full-extraction mining, the empirical methods have typically adopted a simple conceptualization of the abutment load through use of an "abutment angle." Short of a complete numerical or analytical analysis of the coal seam and surrounding strata, very little work has been Fretted toward refining the empirical analysis of pillar loading. It appears that the vast majority of the research has been directed at determining the pillar strength, the numerator of the safety factor equation, when the denominator of the safety factor equation, the pillar loading, plays an equally important role in pillar design. This paper will address the deficit of pillar loading research by exploring the accuracy of the empirical abutment load calculations using insight provided by an elastic overburden model, a laminated overburden model and field observations. Ultimately, it is determined that a constant abutment angle probably over-predicts the abutment load as the mining depth increases.

By Bernardo J. Jiménez, Harlem Lora, Roberto Acosta Mora

Circunvalacion Norte project is currently the most important infrastructure project in Costa Rica. It is the last segment of the urban perimeter highway. Site investigation of local geotechnical conditions were studied by SPT, CPT, pressuremeter tests and boreholes. A static load test was executed as a proof test with an associated ultimate resistance of 12056 kN (2710 kips). Drilled shaft design was done using PMT tests and axial nominal resistance varied between 4000 kN (900 kips) and 6000 kN (1350 kips). A total of 416 drilled shafts were constructed in 15 months with drill performance of 32 m/day (105 ft/day). Drilled shaft lengths varied between 4,0 (13 ft) m and 40,0 m (130 ft). Selfconsolidating concrete was used to achieve an adequate workability even in high densities rebar cages. Several site conditions proved the importance for maintenance of the working platform, predrilling of rock sockets and having spare parts to avoid increase in project’s cost. New procedures were taken to prevent concrete segregation on excavations near underground water flow. Monitoring the quality of the shafts from CSL test showed less than 3% of the shafts presented a considerable anomaly, which proved that the adopted construction method and materials were adequate. For the concrete anomalies, successful remediation was performed by means of grout at the base of the shaft with two different types of drilling methodology depending on the concrete anomaly.

By Herbert A. Wendel

Reaching the miner with safety education" is R the ultimate goal, the main objective, of every safety program in the mining industry. If we can get safety education to every worker, and it is properly learned, enforced and obeyed, we should eliminate at least 85% of all potential accidents. We should then have very few accidents as a result of unsafe behavior, which, in turn, would allow us to concentrate most of our future efforts on preventing the types of accidents which are caused by faulty or defective machinery, equipment, tools and materials. An uninformed or uninitiated person would think that it should be a rather simple process to reach the miner with a safety education. Theoretically he would be right because here we get involved in a matter of semantics. When we say "reaching the miner with safety education" we actually mean that this education must also be accepted and learned by the miner; we intend to mean that safety must be observed and followed at all times. But in order to realize our complete meaning of the phrase, we must find the solution for a number of problems and obstacles which are well known to management and safety personnel.

Jan 1, 1965

By D. A. Peterson

Laboratory testing was completed to determine the effectiveness of a fiberglass cable bolt (FCB) as a cuttable rock support for a continuous, hard-rock mining method. The FCB consists of four Polystal tendons combined in a node/antinode fashion, with polyvinyl chloride (PVC) spacers forming the anti-nodes. The largest ultimate pull-out load achieved by the FCB was 22 t (48,400 lb) at 89% of the tendons' theoretical pullout load. This premature tendon failure is accredited to: • differential stresses within the tendons and • differential tendon displacement. An increase in pull-out resistance for a given embedment length is due to: • increased bond area, • reduced interfacial shear and • "wedge" effect. The critical embedment length was found to be 40% less than for conventional steel cable bolts (SCB) at a 127-mm (5-in.) node spacing. An FCB can have up to a 92% increase in load-carrying capacity over a conventional SCB at equal embedment lengths. The load carrying capacity is equivalent to SCB at a 960-mm (37.8-in.) embedment length. Though the FCB is 7.5% more expensive than the conventional SCB (installed), this cost may be offset by increased performance. FCBs are a potentially viable support alternative for continuous hard-rock mining.

Jan 1, 1993

By James M. Riddle

INTRODUCTION Block-caving mines are generally large operations. Calculating the quantity and value of mineral present and determining the economic limits to mining are complicated processes requiring much time and effort. If these processes are to be worthwhile, they must be accurate and reliable. Success in planning may increase the economic returns significantly. Since capital investments in block-caving mines are generally quite large, and development may span several years, quicker and more accurate methods of mine layout are very worthwhile to the mining industry. The purpose of this study is to develop an approach to the evaluation and layout of block-caving mines. The study included development of a simple approach to modelling ore reserves and a rapid, dynamic programming solution for optimum ultimate mining limits. TRADITIONAL APPROACHES TO BLOCK-CAVING MINE LAYOUT General discussion of techniques of calculating and valuing ore reserves can be found in the literature, (1-4). Mining limit approaches have been investigated by many and follow five general methods: 1, Moving cone method (5) 2. Graphroriented technique (6,7) 3. Dynamic programming technique (7,8,9) 4. Network flow method (10,11) 5. Pillar method (12) Of these investigations, only two were developed for underground mining applications, those of Sharp (9) and Riddle (11).

Jan 1, 1977

By Richard A. Williams

The design, modelling and simulation of solid-liquid mixers remains one of the least advanced aspects of minerals processing, due to difficulties in quantifying complex slurry hydrodynamics from first principles, and in acquiring reliable experimental data for model verification and development. This contribution describes the application of electrical resistance tomography (ERT) for three dimensional imaging of the concentration of mineral particulates in a slurry mixer as a function of key process variables (particle size, impeller type, agitation speed). It is demonstrated how ERT can provide a wealth of detailed data to allow model development, which ultimately will lead to much improved design capabilities and the generation of mixing models which could reside within Particle Process Simulators. This principle is illustrated using descriptions of mixer behaviour based on an empirical approach, although the measurement methodology described is equally suited to development of computational fluid dynamics models, cellular models or design approaches based on artificial intelligence. The experimental data can be built into a visualisation data bank, which acts as a "process toolkit" by allowing a library of process responses to be catalogued. Hence these data can be accessed for the purposes of model development, equipment selection, optimisation of operating conditions or testing on-line control strategies.

Jan 1, 1995