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By E. L. Vickers

Over the years, the pure theorist in economic analysis has accumulated a formidable array of facts in bringing his subject matter under control. Business managers and mining engineers are aware of the theorist's weapons, but the question of applying them to the mastery of practical problems seems hardly feasible, especially in view of the almost innumerable variables plaguing the everyday scene in the mining enterprise. One such sophisticated tool of long-standing in the theorist's arsenal is marginal analysis. Equally long-standing for the operating company and valuation engineer is the problem of defining the cut-off grade the point below which a mineral re- source ceases to be economically amenable to extraction. In other words, what part of a mineralized body of rock is ore and what is waste?

Jan 6, 1961

By M. B. C. Brandt

The near-surface wave attenuation factor k (kappa), which describes the attenuation of seismic waves with distance in the upper 1–3 km of the Earth, was determined for the Far West Rand gold mining area using seismic data recorded by station Parys (PRYS) of the South African National Seismograph Network. Twenty micro-events in the magnitude range 0.7 ? ML ? 1.8 for the period 1 July to 15 November 2015 were analysed. For the analysis a 10-second window for the S phase portion of the vertical component seismogram was selected. The result was an average k = 0.048 ± 0.014 s, which is much higher than for a stable continental region where k = 0.006 s. This is because the assumed Brune source model is inappropriate for describing mining-related events that often have moment tensors with a volumetric (implosive) component. The average k was calculated to be 0.098 ± 0.038 s for explosions of a similar magnitude. This higher value derived for mining-related k may be employed as a means of correcting the Brune source spectrum to calculate seismic moment as well as corner frequency for events in the mining areas of South Africa.

Jan 1, 2017

By K. J. Kruger

Aluminium alloys have gained popularity in many industries due to their high strength and low weight. One shortcoming of aluminium alloys is their poor resistance to abrasion and erosion wear compared to materials such as stainless steels. In this project, aluminium alloy 2014 (AA2014) was coated with a 1.5 mm thick laser-deposited layer composed of silicon, copper, and aluminium with the aim of increasing the wear resistance. The amount of silicon, copper, and aluminium added to each sample was determined by a mixtures model. It was discovered that the Al-Cu system is very sensitive to silicon additions and that wear resistance depends on the primary phase to solidify as well as on the final phase distribution. Two primary phases were identified; alpha aluminium and theta intermetallic. It was observed that the clad layer increases both the hardness and wear resistance of AA2014, and that the material solidifying as primary alpha aluminium displayed a lower hardness but higher wear resistance than the samples containing primary theta phase. All clad layers performed better in terms of wear resistance than the unclad samples. The knowledge gained and principles used in this project could be applied to many other aluminium alloys.

Jan 1, 2014

By Stephen Chryssoulis, Stamen Dimov

Detection and quantification of precious metals (Au, Pd, Pt, and Rh) in spinels and silicate minerals is important for establishing the maximum attainable recovery by sulphide flotation. To achieve this goal subpart per billion (ppb) detection limits are required plus the ability to quantify results. Existing quantitative microbeam techniques (EPMA, PIXE, SIMS, TOFLIMS) have limits of detection in the O. l-200ppm range. Time-of-flight resonance ionization mass spectrometry (TOF-RIMS) is a microbeam analytical technique that allows for the identification and quantification of atomic species in very small quantities. It utilizes a tunable laser source for resonant excitation and ionization of a particular element of interest and has some unique features: elemental selectivity, linear response over a large dynamic range and very high sensitivity. The analysis consist of three steps: (i) the solid sample is vaporized by laser ablation to form a plume containing neutral atoms, (ii) the neutral atoms of a specific atomic element in the plume are resonantly excited and ionized by another tunable laser, and finally (iii) the ions created are mass analyzed in a time-of-flight mass spectrometer. A TOF-RIMS mass spectrometer was developed at AMTEL for trace element analysis of Au, Pd, and Rh in minerals. The spectrometer was calibrated using homogeneous CANMET and NIST reference samples covering three orders of magnitude in concentration. Attained minimum detection limits (MDL=2cr of the background) are in the low ppb range.

Jan 1, 1999

By V. V. Morozov, Ganbaatar Zorigt, Delgerbat Lodoy, Y. P. Morozov

"At the processing plant Erdenet, a new facility for advanced ore diagnostics in-stream (at the conveyor), based on optical analyser of mineral composition, was tested. Such systems provide highly accurate in-stream measurements of ore properties. The system provided information on the ore mineralogical composition, the particle size distribution and the impregnation of minerals. A special flatbed facility for optical spectrum-based estimation of fine-crushed ore has been developed, being incorporated into the existing system of ore sampling and analysis. Application of the flatbed facility renders possible a high accuracy of determining ore mineralogical composition. High precision of the optical spectrum-based estimation is achieved using special devices, installed in the sampling and the sample analysis flow sheet, applied by the technical control department. Modern systems for optical spectrum-based estimation of ore grade provide a basis for effective automated control of ore benefication processes, based on the principle of advanced ore grade control. Process management task of grinding and flotation was to choose options that take into account the composition and grade of the ore coming. The calculation data array comprises consumption of reagents, ore processing, grind size etc. The systems implemented at the processing plant contributed to increasing copper and molybdenum recovery. INTRODUCTION In-stream ore grade analysis is a new trend in effective control of ore benefication processes. This is realised based on radiometric measurements in the X-ray and visible spectrum regions, in which mineral components of the initial ore (Sbárbaro and Villar, 2010) or the benefication products become apparent (Hyotyniemi and Ylinen, 1998; Haavisto and Hyötyniemi, 2010). An important advantage of such methods is in-stream measuring ore parameters, including mass fractions of individual minerals, which makes it possible to use the information obtained in the processes of automated control."

Jan 1, 2018

By K. G. Wang, M. E. Glicksman, P. Crawford

"We formulate the mathematical solution to late-stage multi particle diffusion in finite systems. The transition from finite system behavior to that for an infinite system is established. Large-scale simulations are reported regarding the dynamics of phase coarsening. Even in the case of a small volume fraction (Vv = 10-4), the particle size distribution is broader than that for the well-known Lifshitz-Slyozov limit at zero volume fraction. We also report the first simulation studies of extremely low volume fraction, for which corresponding experiments, as well as other simulations, do not exist at present for comparison. However, in the case of moderate volume fractions (Vv = 0.1), the fiucutations in the volumetric growth rate of particles are extracted from our simulations. These simulations provide additional insight into the statistical nature of diffusion interactions, including multiparticle stochastics during microstructural evolution.IntroductionPredicting microstructure evolution in alloys remains one of the cornerstones of materials science. Phase coarsening is a common process in microstrucural evolution that leads to a decrease in the excess total interfacial energy of the system. The system typically consists of separate and identifiable units, or domains, such as second-phase particles distributed in a matrix. During phase coarsening, larger particles grow at the expense of small particles. Over time, this ""competition"" results in an increase in the average size of the particle population, and in a concomitant decrease in the number of particles.Particle size and microstructure of many cast alloys depend on similar coarsening processes. Indeed, properties of these materials, such as strength, toughness, ductility, and electrical conductivity, depend on the material's average particle size and particle size distribution (PSD). Understanding and controlling microstructures in two-phase systems are clearly of widespread technological importance."

Jan 1, 2001

By L Neems

In conjunction with Orica Explosives, Worsley Alumina have managed a program of continuous improvement to their cap rock blasting over the last two years. Blasting conditions are challenging because of the hard and shallow nature of the material. Blasting costs must be controlled and the environmental consideration of noise and dust is critical. Worsley have sought to determine the optimum balance between drilling and blasting costs and fragmentation. As the cap rock has few inherent weaknesses, loader productivity is strongly controlled by the degree of fragmentation from blasting. The optimum blasting solution is also constrained by maintaining airblast levels at the surrounding residences below 115 dBL . The major blast design parameters optimised during the program were stemming type, stemming length, powder factor and blasthole diameter. A series of carefully managed trial blasts were fired during 1997 and 1998 to quantify the effect of these parameters. Fragmentation was digitally measured using OricaÆs Powerseive G technique. Shovel productivity, airblast levels and blasting costs were also quantified. As a result of the project, Worsley now have an increased knowledge of the key parameters driving blast performance, and their consequent impact on downstream processes, the environment and total mining cost.

Jan 1, 1999

By Neil Rowlands

Particle liberation studies are commonly used in the determination of the proportion of locked and liberated phases in ground ores at various stages of mineral processing. These studies may range from a qualitative assessment of a polished specimen in an optical microscope to a full quantitative analysis of the liberation characteristics of fine grained complex sulfide ores using scanning electron microscopy and high level image analysis. However, the conversion of quantitative data to meaningful information on a mill operations level is by no means a simple task. This paper reviews the errors inherent in the SEM/Image Analysis technique and looks at the various methods available to minimize errors in data collection.

Jan 1, 1992

The relationships between Aboriginal Traditional Owners and mining companies have often been mired in dispute, particularly since the High Court Mabo decision and the Native Title Act of 1993. In the Pilbara region, Rio Tinto Iron Ore (RTIO) impacts the traditional country of 12 Aboriginal Traditional Owner/language groups. Over the past 12 years the company and the Traditional Owners have negotiated and settled several significant land use agreements including the Yandi Land Use Agreement over the Yandicoogina mine in 1997, between Hamersley Iron (now Rio Tinto Iron Ore) and three language groups û the Bunjima, Nyapaili and Innawonga people and the Eastern Guruma Indigenous Land Use Agreement (ILUA) of 2006. These substantive agreements are now being followed by a new generation of region wide ILUAs which are close to conclusion. Arising from these regional agreements is a new framework for engagement which has been informed by the implementation of the previous agreements in the Pilbara and across the Rio Tinto group of companies. They are driven by both a company desire to have a consistent approach to engaging with Traditional Owners and the Traditional Owners wanting to have a similarly transparent and consistent standard of performance by the company in implementing the agreements which can deliver improved employment, cultural heritage engagement and direct and indirect benefits for the life of mining by the company. During the past three years the growth in the Pilbara, Western Australia brought new opportunities with people flocking to the region for employment flowing from the mining boom. Housing was at a premium and FIFO (fly-in, fly-out employment arrangements) was developed as a method to manage the general growth and demand for skills. Despite the recent down turn in the world economy since September 2008, which has reduced demand for minerals, the Pilbara continues to enjoy high levels of employment and as a result there is still significant pressure on housing and services provision. Although there has been vast economic growth in the Pilbara not only by mining companies but also oil and gas companies, the 2006 census data indicated that the direct benefits of improved employment, business development and engagement in the mainstream economy continued to exclude Aboriginal people. Indigenous people constitute a significant proportion of the population in the Pilbara region, some 6000 people û currently 14 per cent of the population rising to 18 per cent by 2015 û yet they remain at the bottom of the socioeconomic scale. More than 40 years of mining has returned relatively little to this group of people who are the permanent residents of the region and are connected through their traditional culture to this country (Taylor and Scambary, 2005). Ensuring local Aboriginal participation in the mainstream economy has been a challenge for resource companies, Traditional Owners and local residents in the Pilbara. The case study explores the relationship between a mining company û Rio Tinto Iron Ore and the Traditional Owners of the Pilbara. It examines two projects that have been developed to engage Indigenous people in the development of their region and through regional representation and business development to build a sustainable future for themselves and their future generations and at the same time ensure social cohesion to support social licence to operate. The case study also examines the process that was followed by Rio Tinto Iron Ore and its operations in undertaking a regional agreement for land access, participation and the integration of local Indigenous people into their business and the local economy.

Jan 1, 2009

By M Berry

Many mining companies routinely use benchmarking to review their operational activities and associated costs. The aim is to measure operational performance against industry norms, and identify areas where a company is performing better or worse than industry best practice. The goal is continuous improvement.In general, mine technical services, including mining geology activities, are not routinely benchmarked. There are exceptions, such as the cost of drilling per metre and the average discovery cost per unit of metal, but generally mining geology activities are only included indirectly in mining benchmarking studies.Aspects of benchmarking can play a critical role in assisting mining geologists to improve the efficiency and effectiveness of the services they provide. Industry norms for many generic mining geology functions have not been developed and measured, and therefore it is impossible to use external benchmarking to assess performance against other mines. But when used in parallel with quantifying the value of mining geology functions and establishing strategic goals for the team, key components of benchmarking methodology can provide essential feedback on how a team is performing against these strategic goals.CITATION:Berry, M, 2014. Benchmarking – does it have a role in improving the performance of mining geology?, in Proceedings Ninth International Mining Geology Conference 2014 , pp 361–366 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By S. Uddin

Microsegregation manifests its effect on microstructural evolution of cast or welded alloys which in turn influences their important mechanical and electro-chemical properties. In the above context, mathematical models of microsegregation have proven to play an important role in estimating the nature and predicting the effects of this phenomenon in wide varieties of solidification processes. Microsegregation models are useful in designing new commercial alloys, in estimating the homogenization time for the post-process heat treatments and in many other practical applications. In this study, two semi-analytical models of microsegregation were developed to predict the concentration field of solute in the liquid and solid regions for dendritic solidification of binary metallic alloys. Both models assume that the growing dendrites are cylindrical in shape. This assumption is more realistic compared to the common assumptions of plate like dendrites that most of the earlier researchers employed in their microsegregation modeling study. The solute redistribution profile, in the developing solid layer, necessary to determine the back diffusion parameter was derived from Fick's second law for the model without coarsening. The application of this parameter in a wide range of conditions and the use of its basic form in the model with coarsening has been verified. The concept of coordinate transformation and enhancement of back-diffusion Fourier number were used in deriving the model which took into account the coarsening of dendrites. The models are then extended to deal with rapid solidification and peritectic transformations and the results were compared with relevant experimental data for Aluminum and other alloys. A good agreement between model predictions and experimental results was found.

Jan 1, 2007

By L. E. Veki, S. M. Luukkanen, J. P. Karvonen, J. O. Leppinen

Today there is a consensus that xanthate adsorption on sulfide minerals is primarily controlled by redox reactions occurring at specific potentials on these semi-conductive minerals. Consequently, it is possible to control xanthate adsorption by controlling electrochemical conditions in the system by using oxidizing and reducing agents. The scope of this study was to investigate the possibilities to increase the selectivity of Cu-Fe-Zn ore flotation by applying electrochemical control in the conditioning of the flotation feed. In this work, mild steel grinding in a nitrogen atmosphere was used as the basis to provide a negative starting potential and minimize the amount of oxidation products on sulfide mineral surfaces. To study how different potential levels affect flotation results, a controlled conditioning procedure was utilized maintaining potential at a desired level by titrating the pulp with air. Xanthate adsorption kinetics during conditioning was examined by taking pulp samples for spectrophotometric analysis and laboratory flotation tests were conducted for samples that underwent the controlled conditioning procedure in the potential range of -200mV to +200mV vs. SHE. A clear correlation was detected between chalcopyrite recovery and the potential during controlled conditioning indicating that there was a constant increase in chalcopyrite recovery when the potential was shifted to more anodic values. It is possible that utilizing potential control in the conditioning stage, a smelter grade copper concentrate can be achieved directly in rougher flotation without cleaning stages. Conditioning in favorable conditions had significant positive effects on flotation selectivity of chalcopyrite. The improvement in copper concentrate grade being predominantly caused by the depression of pyrite. By applying the controlled conditioning procedure pyrite recovery in rougher flotation was reduced even low as under 1%, while in the tests without controlled conditioning, pyrite recovery varied between 7.5 – 65.7%. The result of this work indicate that affecting collector adsorption by electrochemical control in the conditioning stage can provide significant improvement in sulfide mineral flotation and industrial applications could lead to decreased chemical consumption, reduced equipment and maintenance costs.

Jan 1, 2018

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By K. S. Gritton

The U.S. Bureau of Mines has investigated methods for extracting metals from a variety of arsenic-containing smelter flue dusts. One proposed flowsheet includes a sulfuric acid leach, a cooling step to precipitate hydrated copper sulfate, and a reduction-precipitation of As2O3. Arsenic extractions greater than 90 pct were achieved, while copper extraction ranged from 50 to 85 pct under the conditions examined. Copper was removed from the leach solutions by crystallization followed by SO2 precipitation of arsenic which resulted in a 98 to 99.9 pct As2O3 product. Other metals, such as lead and zinc, were concentrated in the leach residue or in other byproduct streams for recovery of their valuable metal contents.

Jan 1, 1990

By Elzbieta Mielczarski, Jerzy Mielczarski, Jan Drzymala, Yann Duvalm

Polyethylene glycol monoalkyl ethers (CnEm) render quartz hydrophobic while feldspar remains hydrophilic. As a result quartz can be separated from feldspar in small frothless flotation devices such as the Hallimond tube. The separation can be accomplished at room temperature at pH < 7 and C16E33 concentrations between 10-5 and 10-4 M for quartz particles smaller than 0.4 mm. No separation is observed when feldspar ore containing about 60 % of feldspar and 40% of quartz is subjected to flotation in a laboratory flotation machine. The reason for the lack of separation is a low hydrophobicity of quartz in the presence of polyethylene glycol monoalkyl ethers and high intensity of mixing in the flotation machine. The flotometric tests showed that the contact angle of quartz in monoalkyl ethers of polyethylene glycol solutions is less than about 18 degrees and depends on the structure and concentration of the ether and the pH of the system.

Jan 1, 2003

By Ghislain Bournival, Cagri Emer, Seher Ata

"It is well known among flotation practitioners that the contact angle can be correlated with the amount of material recovered from feed by flotation. The contact angle of solids can easily be modified by the addition of a collector. However, some collectors also have frothing properties thus altering the solid and bubble surface properties simultaneously. To avoid this problem, a technique has previously been used in which silanol groups are attached to the surfaces of the particles, but this method has its own problems. In this work, silica particles with various surface hydrophobicities were prepared using an esterification process. By using alcohols with different hydrocarbon chain lengths, from 4 to 12 carbon atoms, surfaces with a wide range of contact angles could be prepared. The technique was used in the modification of silica particles that were tested in a fluidized bed flotation column, and a laboratory mechanical flotation cell. In parallel experiments, dodecylamine (DDA) was used as a collector. It was found that irrespective of the type of flotation machine and surface preparation method, there was a close correspondence between flotation recovery and the contact angle of the particles. The silanation process has known drawbacks relating to the presence of moisture during the reaction, and the stability of the silane coating after it is been prepared. Esterification does not suffer from these disadvantages. This work has shown that the esterification technique is a robust alternative method for preparing hydrophobic quartz surfaces."

Jan 1, 2014

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines-developed induction slag melting process is of concern to the titanium industry. The objective of the research was to determine the effect of removing the nonconductive molten calcium fluoride (CaF2) slag used as an insulator between the titanium and the segmented copper crucible. The data were obtained from single-induction-melted ingots prepared with no CaF2 insulating slag and an ingot prepared with the normal addition of 4 pct CaP2 slag. The results showed that the mechanical properties of single-induction-slag-melted and annealed Ti-6AI-4V alloy exceed the minimum values specified in "Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H." High-cycle, tension-tension fatigue testing yielded similar results. The data from 44 of the 45 specimens were contained within the typical scatter band for fatigue data on wrought Ti-6AI-4V alloy. Although the removal of the insulating slag is a desirable change, the data from the specimens with the previously standard 4 pct slag addition showed no detrimental effect from the slag inclusions.

Jan 1, 1988

By M. L. Matt

The Pittsburgh Safety and Health Technology Center of the Mine Safety and Health Administration has developed the Mine Emergency Responsiveness Development (MERD) program to improve the reaction and response of mine personnel in mine emergency situations. The MERD program simulates problems that may be encountered in underground mine fires, underground mine explosions or surface mine accidents. Since its inception in 1982, the MERD program has been presented to MSHA, Industry, Labor and State Government Personnel. The program is extremely versatile and is easily adapted to suit various training requirements. It gives the participants the opportunity to experience some of the emotions, frustrations and successes of a mine emergency in a controlled environment without having to be involved in one. Past participants have indicated that this training has better prepared them in actual emergency situations through increased awareness and advanced preparation of plans and resources. In 1992, a Mine Simulation Laboratory, which simulates a coal mine and metal/nonmetal mine, was built to improve training for mine emergencies and prevention and fighting of mine fires. This facility has been included in the MERD Program to provide realistic and practical training for mine rescue teams and MERD participants in advanced mine emergency operations. This paper presents an overview of the MERD program.

Jan 1, 1993

"Decreasing gold-in-ore grades is one of the main drivers of poorer productivity and rapidly escalating unit costs. Grinding costs, water use and reagent consumption are all intimately related to the ore grade processed. Various pre-concentration technologies have been developed that can be applied at various stages of crushing prior to ore grinding. This paper will review the amenability of ores to coarse particle barren gangue rejection for fine crush sizes in the pumpable particle size range (i.e., particles between 5 mm and 0.3 mm in size). The liberation of oxide gangue achieved during crushing is evaluated by proxy using sink-float analysis and the deportments of gold, sulfur, and arsenic into sinks and floats are monitored. Amenability of gangue rejection by continuous gravity separation is evaluated after various crushing modes (vertical shaft impact crushing, cone crushing, and HPGR crushing). The potential to identify coarse particle mineral association and liberation using three-dimensional x-ray computed tomography will be discussed.INTRODUCTIONThe aim of research in this area is to explore some of the attributes which make some ores amenable to preconcentration, or rejection of a significant component of the feed mass to tailings at a coarse liberation size. Characteristics such as ore type, mineralogy, breakage pattern, particle shape, and liberation characteristics may need to be examined to identify amenability to pre-concentration amenability.It is intended to focus on continuous gangue rejection in the pumpable size range (0.3–5.0 mm) as this remains one of the key opportunities to reduce processing costs through a combination of techniques including screening (for mineral differentiation rather than size classification only) and gravity separation (using jigs). This is to be contrasted to conventional preconcentration as performed with automatic ore sorters."

Jan 1, 2016

By Melinda Channel, Alan W. Weimer, Jonathan R. Scheffe

"There is a need to develop cost effective renewable energy processes for the production of clean fuels that can simultaneously mitigate the U.S. energy/global environmental security issue. If H2 can be obtained cost effectively via the splitting of water using concentrated sunlight, then it’s possible to operate a fuel cell using renewable H2 or to synthesize other fuels based on renewable H2 for generating electricity or for running internal combustion engines. For example, H2 can be reacted with sequestered carbon dioxide (CO2) to produce syngas (H2/CO) via reverse water gas shift (RWGS), i.e. H2 + CO2 ? CO + H2O. The syngas can be catalytically methanated to form synthetic natural gas (SNG) or it can be catalytically reformed to produce liquid fuels such as “green” gasoline via the MTG process (syngas? methanol ? gasoline). The desert SW United States is home to world class sunlight. Fundamental ferrite thermodynamics will be reviewed, an example of the beneficial effect of ferrite surface area on reaction kinetics will shown, and process economics will be investigated for a 100,000 kg/day facility to produce H2.Introduction and Background ThermodynamicsSpinel ferrites of the form MxFe3-xO4, where M generally represents Ni, Zn, Co, Mn, or other transition metals, have been shown to be capable of splitting water according to the two step cycle shown below:MxFe3-xO4 + solar thermal energy ? xMO + (3-x)FeO + 0.5 O2 (1)xMO + (3-x)FeO + H2O ? MxFe3-xO4 + 2H2 (2)This is an inherently clean and sustainable process, as the only net inputs are solar energy and water, and the net outputs are hydrogen and oxygen. Ferrite water splitting cycles are advantages compared to other high temperature water splitting cycles, such as the ZnO/Zn and Mn2O3/MnO cycles, because thermal reduction has been demonstrated at significantly lower temperatures[1, 2]. As a result, overall efficiency may be increased due to the fact that radiation losses increase as the fourth power of temperature, and material considerations for reactor design should be more flexible. Additionally, cycle repeatability has been demonstrated with relative ease as compared to other thermochemical cycles [3-6]. However, the amount of hydrogen per mole that is generated is significantly less than for other high temperature thermochemical cycles due to the fact that only Fe3+ is capable of being reduced at the temperatures of interest[6]. In addition, water oxidation kinetics appear to be very slow, likely due to diffusion or surface area limitations created by near surface oxidation [6, 7]."

Jan 1, 2010