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By D Maconochie, S Pradhan, M Reed

The Waterview Connection will provide a high-quality strategic alternative to State Highway One and complete Auckland’s Western Ring Route connecting State Highways 20 and 16. The project includes twin three-lane motorway tunnels 2.4 km long and 13.1 m internal diameter (ID). The tunnel construction started in November 2013 using the tenth largest earth pressure balance (EPB) tunnel boring machine (TBM) in the world. The tunnels will pass beneath urban and greenfield areas as well as a major local arterial road. The project is being delivered by an alliance of constructors, designers and the New Zealand Transport Agency. This paper describes some of the key innovative and cost saving design solutions that have been achieved through collaboration in the alliance environment with the construction team, owner’s verifier, the segmental lining precast suballiance and the M&E suballiance for the underground works. The key design elements of the tunnel comprise a three-lane roadway, invert culvert and backfill, precast segmental lining, sixteen mined cross passages including a low point sump cross passage and steel segments for opening to the cross passages. This paper reviews interdisciplinary design integration and the economies achieved in the permanent works tunnel lining design, including reduction in lining thickness and optimising reinforcement, cross passage separation of 150 m, efficient design of the invert culvert and backfill design, main drainage pipe and low point sump. The paper also describes the attributes of the TBM and the invert culvert construction methodology.CITATION:Pradhan, S, Maconochie, D and Reed, M, 2014. Tunnel design in an alliance for Waterview Connection, New Zealand, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 425–430 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By P. G. Corser

A gold and silver open-pit mine located in northwestern Chile contracted ACZ in 1991-92 to assess the stability of their spent ore pile and to determine the cause and magnitude of cyanide contamination associated with leaching operations. The mine is a conventional open-pit located at an elevation of approximately 4,800 meters (m.) (15,744 feet). A spent ore pile is located approximately 2,000 m. southwest of the mine and approximately 1,000 m. northeast of the active pad and plant facilities. The pile was constructed on a gentle northwest slope dipping 12 to 13 degrees. The pile is bordered by a small river to the northwest and by a larger river to the northeast. Both rivers eventually flow into Bolivia. Heap leaching and processing commenced at the mine in 1988. Since 1988, nearly 6.0 million tons of ore at an average grade of 1.96 grams/ton (0.07 ounces/ton) of gold and 52 grams/ton (1.83 ounces/ton) of silver have been treated by cyanide heap leach methods with zinc (Merrill Crowe) precipitation. In approximately three years of operation, the mine has yielded more than 225,000 ounces of gold and over 1.5 million ounces of silver. Currently ore is agglomerated and hauled to the leach pad by truck and is top loaded to produce a 5-meter lift height. Four contiguous reusable (on/off) leaching pads were constructed with an asphalt layer above a carefully compacted sub-base of High Density Polyethylene (HDPE) liner and screened fines. Leach solution of pH 10-11 containing 1.2 to 1.5 gram/liter of cyanide is applied to the heap at a rate of 10 liter/hour/square meter for a total active application period of 30 days. Leached (spent) ore is transferred to the spent ore pile located approximately 1,000 meters to the northeast. The pile currently contains approximately 6 million tons of spent ore. The pile liner, which has been constructed over a prepared sub-grade consists of three geosynthetic layers (geotextile/flexible membrane liner/geotextile). Long term objectives include washing the pile to recover an additional 3 to 4 percent gold and silver.

Jan 1, 1993

By J. J. Rush

Neutron scattering and analysis techniques are extremely powerful, often unique, probes for the characterization of the amount, location, bonding states, and dynamics of hydrogen in all classes of materials. Developments over the past decade at the NIST Center for Neutron Research and elsewhere have greatly increased the sensitivity and dynamic range of neutron methods. In this paper, we provide a flavor of the capabilities of modem neutron instrumentation for the study of hydrogen in a number of technologically interesting systems, including metal hydrides, fuel-cell materials, fullerenes, and disordered carbons.

Jan 1, 2002

By R. W. Harnmack

Hydrogen sulfide generated by the anaerobic respiration of sulfate-reducing bacteria was used to treat pH 2.2 water from the abandoned Rio Tinto copper mine in Nevada. The untreated water contained 550 mg/L Fe, 140 mg/L Al, 90 mg/L Cu, 80 mg/L Mn, 60 mg/L Zn, 4 mg/L Co, and 2 mg/L Ni. The bench-scale treatment system examined consisted of a bioreactor for H2S generation and three precipitator/clarifier units for metal sulfide precipitation and recovery. The treatment system reduced the concentrations of all metals except Mn to less than 0.1 mg/L. Manganese concentrations were reduced by 96 percent to 3.3 mg/L. A CUS/SO concentrate (33 pct Cu) and a ZnS/5° concentrate (28 pct Zn) were produced that may be suitable for metal recovery at existing smelters

Jan 1, 1994

By T. M. Dreher

The difficulties associated with the operation of a classical rhodium refining process have prompted many attempts to develop a viable solvent extraction flowsheet for rhodium. Recent investigations at McGill University have involved the activation of rhodium prior to its solvent extraction. The role of activation is to convert the aquochloro complexes of rhodium to a form extractable by conventional solvent extraction reagents. In the novel separation scheme identified, chloro complexes of rhodium are converted to bromo complexes, which undergo aquation to a lesser extent, making them more easily extracted. Rhodium is then extracted using Kelex 100, and stripping is achieved by use of a concentrated chloride based solution. Separation of rhodium from iridium is achieved by either prior reduction of Ir(IV) to Ir(III), as the latter is not extracted, or via co-extraction and differential stripping. A conceptual flowsheet for the refining of rhodium using this method is proposed.

Jan 1, 1998

By W. Kasprzak

Modern light metals processing technologies are very complex and involve a diverse set of variables that must be quantitatively evaluated. The most effective way to design new casting processes that deliver specified metallurgical and mechanical properties is to develop a method of simulating the "real-time" process within a test sample of sufficient size. The results can then be analyzed and the required optimizations can be performed. This paper presents a novel method of simulating the industrial casting processes in a laboratory environment using an experimental apparatus based on the principle of high frequency induction heating. The applicability and accuracy of the proposed analytical method is demonstrated, for example, by simulation of the solidification and heat treatment of a test sample composed of two dissimilar materials. The simulation can be used to develop a stress model for an engine block made from an aluminum based alloy with iron cylinder liner inserts.

Jan 1, 2002

By S. D. Van Nort

The Grasberg porphyry copper-gold deposit of Freeport Indonesia Inc., an 81% owned subsidiary of Freeport-McMoRan Inc., lies within the Ertsberg Mineral District in central Irian Jaya, Indonesia. The Grasberg deposit was discovered during a drilling campaign initiated in early 1988. Production at the open pit Grasberg deposit commenced in December 1989. The Grasberg copper-gold orebody is contained with a young igneous complex of dioritic composition which intrudes limestones of the Tertiary New Guinea Group. Alteration is typical of porphyry copper deposits worldwide except that higher grade primary chalcopyrite with significant gold values is associated with a centrally located zone of strong quartz stockwork.

Jan 1, 1991

By E. Karampinos, P. Morissette

"INTRODUCTION Ground support is a critical element in maintaining the stability of mining drives in deep and high stress mines. In challenging ground conditions, it is necessary to continuously explore ground support strategies that can control the resulting large deformations. It is an objective of mining operations to optimize the ground support by selecting both appropriate systems and the time of installation of each reinforcement element. A successful ground support strategy will result in the use of a system that ensures both the structural and operational integrity of the excavations and mitigates the need for rehabilitation. Preliminary ground support design is often based on empirical observations and methods. Once a design is implemented, field trials, observations and in situ pull tests are used to fine tune or improve the design. Although not often employed during this process, numerical modelling can provide helpful insights on the impact of different ground support strategies. In this respect, it is possible to explore the use of multiple options before selecting the most promising ground support system for implementation in field trials. The challenges associated with the numerical modelling of rock support for mines have been described by Lorig and Varona (2013) and Potvin (2017). The employed numerical models should capture all potential failure modes of reinforcement over the mining sequence of the excavation. In particular, it is important to emulate the observed in situ ground support performance, as well as the influence of the installation sequence of the support. However, the time and expertise required for this type of modelling of ground support is not often available at mine sites. Even when the expertise is available it requires a major time and commitment of resources to set up, run and calibrate the sophisticated models capable of explicitly capturing the behavior of ground support. Rock reinforcement is an integral part of all ground support systems used in underground mines. Long flexible tendons can reinforce the rock mass deeper into the walls and create a thicker reinforced shell around the underground excavation. This paper focuses on the optimization of the cable bolting strategy in squeezing conditions at the LaRonde Mine by integrating the 3D distinct element method (DEM) in the design process. A calibrated numerical model is used to investigate a series of cable bolt configurations and provide recommendations for the ground support design."

Jan 1, 2018

By T. A. Moss

The installation of equipment and structures at mines often requires the evaluation of unique loading and operating conditions. Consideration of these unusual features is required throughout design and construction and into operation. The necessity for employing sound civil, structural and mechanical engineering techniques to the design of structures and equipment is well understood. However, the influence of geotechnical factors on the overall behavior during construction and operation of these facilities is less appreciated. Mine operators routinely perform exploratory drilling for the purposes of defining ore deposits. These exploration activities can be extensive and often include provisions for assessment of subsurface conditions as they relate to the mining operation, i.e., requirements for ground support. All of these factors are important to the economics of the mine and are well justified. Surface facilities are provided to access and service the mine and they play an important role in the successful development and operation of a project. Headframes, hoist foundations and shaft collars, in particular, are examples of unique installations encountered at underground mine sites. The design and above surface behavior of these facilities can be analyzed with the usual fundamental engineering practices employed throughout the engineering professions. This requirement during the project development is understood and adopted. Unfortunately, near surface exploration for the purposes of assessing soil and rock conditions for foundations are often given a reduced priority and less consideration. This paper is aimed at providing an outline into the benefits and importance of performing such explorations and to provide a brief discussion of the merits of such an approach. References in the paper relate particularly to shaft headframes, hoists and shaft collars but the issues raised apply equally well to other installations of a similar nature, e.g. milling equipment.

Jan 1, 1992

Gold rooms represent a high security area and preventing theft is a challenging task. Where gravity concentrates or high value unit intermediate products are present, particular and specific security procedures must be put in place. This paper describes the development and implementation which reflects best practice in gold room security. Procedures involving key holder systems, key locks, swipe cards and double locks preventing any one person having access to the gold room, including specific procedures for gravity gold concentrators, will be addressed. The use of monitoring and how to deal with alarms and potential hold ups will be reviewed. The use of cameras and archival DVD recorders is common in gold rooms. The use of electronic surveillance, movement detectors, seismic monitors and the two person policy and gold room entry procedures are described, including how to deal with visitors. The importance of confidentiality regarding smelting and gold pick-up days, plus strategies employed to minimise storing large quantities of gold on site will be presented. The role of metallurgical accounting in providing quality auditable information and the minimum standards of record keeping required is discussed. The role of the Gold Squad will be outlined. Regular auditing and risk analysis and several case studies are cited where security was deficient or improved.

Aug 1, 2010

By R. Liu

As Building Information Modeling (BIM) becomes widely adopted by the construction industry, it holds undeveloped possibilities for supporting Facility Management (FM). Some FM information systems on the market claim to address the needs for FM requirement. However, the question of whether the functionalities provided by the current BIM-based FM software companies are those actually required by the FM Professionals still need to be answered. The data is required by FM professionals in the operation and maintenance phases of facilities and type of maintainability problems that frequently occur, which can be solved early in design phase, have not yet been addressed. The aim of this paper is to clarify the frequently occurring maintainability problems and to investigate the potential areas that can use BIM technology to solve the maintenance problems in early the design phase. A survey was conducted to collect perspectives from the industry practitioners for the maintenance problems and their frequency. The survey results indicated that maintainability considerations should be taken into consideration during the facility design phase. The results also address the perceived areas by practitioners that need maintainability consideration in design phase

Aug 1, 2013

By A. K. Clarke

In any treatment process that requires a coarse feed material to be reduced to a fine size by crushing and/or grinding it must be determined whether a wet or dry comminution system should be utilized. All factors must be evaluated in reaching the decision. Among these factors are: 1) Ecology and Plant Environment: Unfortunately in many instances the decision on wet or dry is based on prejudice resulting from an unnecessary fear of dust. The writers submit that this fear, although once justified, is no longer valid because technology and equipment is now available to collect dust to meet any standard. When dry grinding is used it is very often possible to discard a portion of the waste product in a dry state. This will decrease the size of the tailing pond required. As pollution control standards increase it becomes increasingly difficult to clean up water from tailing ponds. 2) Operating Costs: Steel wear is often five or more times greater in wet grinding than in dry grinding. This is mainly due to corrosion. The evaluation of the economics of dry grinding must of course include the air system and dust collection; similarly in a wet grinding plant related pumping and material handling costs should be included. Pumping costs are often overlooked. This assumes water is made to flow for nothing. Pumping can account for 20 percent of the power consumption in the grinding plant. Large scale comparative tests were conducted in a wet and dry commercial plant in 1970. The same ore was used for both tests. With all factors included in both plants the dry system showed lower horsepower per ton.

Jan 1, 1971

By Natalie White, Joel Asp, Allyz Kramer

"Minnesota has robust reclamation standards and have proven results in the taconite mining industry. Reclamation of overburden spoils, lean ore spoils and fine tailings from taconite production has generally been successful on the Iron Range, using a low input standard reclamation practice. Success at reestablishing vegetation on these landscapes is likely due to fairly favorable chemical and physical properties (e.g., few limitations due to acidic generating materials, metal toxicities and water and nutrient holding capacities). However, coarse tailings reclamation has proven more difficult, presumably due to lower nutrients and challenges with moisture holding capacities. Research efforts conducted since 1990 have struggled to develop a reclamation strategy for coarse tailings that meets the Minnesota Mineland Reclamation Rules, Chapter 6130. However, new breakthroughs in scram mining technologies are producing fine and coarse tailings that have not been encountered nor reclaimed in northern Minnesota. Scram mining in Minnesota is defined as those mining operations that produce natural iron ore concentrates. Innovative research is underway to investigate and determine successful reclamation strategies to reclaim scram mining tailings from these scram mining operations. The research program is conducted through collaboration with SEH, Prairie Restorations, Inc. (PRI) and Mining Resources, LLC with funding support from the Iron Range Resources and Rehabilitation Laurentian Vision Partnership minescapes grant program.The research program was divided into three phases:Phase I. Bench-scale testing to identify successful treatments to reclaim and restore scram tailings through evaluating surface soils amendments, viable seed mixes and plant germination, growth and densities. Phase I was completed in early 2015.Phase II. Field-scale pilot trial to test larger scale effectiveness of the treatments deemed successful in Phase I and test various vegetative assemblages and planting techniques focused on the unique challenges with scram tailing basins. Phase II was completed in late 2016 with a summary monitoring report.Phase III. Produce a technical report of results for the research undertaken in this study, as well as compile prior reclamation results used during previous Minnesota iron mining reclamation projects on tailings basin applications. Phase III was completed in 2017 with a summary monitoring report and recommendations."

Jan 2, 2018

By W. S. Hegler

Introduction The San Antonio mine is on the north shore of Rice lake, thirty miles east of lake Winnipeg and 120 miles northeast of the city of Winnipeg. Since production was started in 1932, about 2,000,000 tons of ore have been mined. Currently in progress is an extensive development programme which involves 11,500 feet of crosscuts, 3,800 feet of raises, 1,753 feet of shaft sinking, and 160,000 cubic feet of slashing, all in footwall waste rock. It is the purpose of this .paper to indicate the necessity for this work and to describe the methods employed to carry it out. Where unknown factors are as prevalent as they are in the average Canadian gold mine, a definite answer cannot be given as to what is the most economical and efficient system for mining dipping deposits. At San Antonio, the host rock for the orebodies, locally termed basalt, occurs as a sill some hundreds of feet in width and dipping at approximately 45 degrees from surface to an unknown depth. It may be assumed that it continues well below the lowest depth established to date by diamond drilling. At present, a vertical winze (No. 3 winze) hoists the ore from the 2,360-foot level to the 1,600-foot level, on which it is hauled about 900 feet to No. 3 shaft, also vertical, and there hoisted to the mill bins on surface. To maintain ore reserves at a five-year figure, at full production, additional deep exploration was required immediately. It was decided to sink No. 4 winze, a vertical opening of the same size as the other operating shafts, to provide ten additional levels (17 to 26) at 150-foot intervals, with additional depth to allow for an underground crusher installation and usual loading-pocket facilities for three-ton skip-hoisting. The winze was bottomed at 1,753 feet below the collar, at a depth of 4,117 feet below surface, and is the deepest man-sized opening in Manitoba.

Jan 1, 1949

By B. S. Terry

Experiments have been conducted to assess the feasibility of capturing bearing emissions arsenic with CaO during the roasting of enargite (Cu3AsS4). Enargite/CaO mixtures have been heat treated in air, nitrogen or oxygen for various times and the products of reaction analysed by X-ray diffraction and cleaned analysis. The results show that substantial capture of arsenic can be achieved via the formation of calcium arsenates and/or calcium arsenides. In addition significant capture of sulphur is achieved by the formation of calcium sulphate andlor sulphide. Complete conversion to copper sulphide with total removal of arsenic can be achieved within 30 minutes at 700°C. Further heat treatment in air or oxygen leads to the formation of copper oxide and copper oxysulphate. Without optimisation of reaction conditions, it has proved possible to achieve retention of in excess of 85% of the arsenic content of enargite in the form of calcium arsenates.

Jan 1, 1994

By Deming Wang, R. A. Overfelt

"The oscillating cup viscometer has become a dominant technique to measure the viscosities of high temperature molten metals. Unfortunately, the viscosity estimation model from the observed logarithmic decrement and period of the oscillation is very complicated. There are still large discrepancies of viscosity estimation values between using different measurement facilities and using different viscosity estimation models for a same molten metal. The purpose of the paper is to evaluate the accuracy of an oscillating cup viscometer in Auburn University. Two well known viscosity estimation models, Roscoe's and Torklep's equations, are compared and discussed. The theoretical literature for the fluid flow inside an oscillating cup is reviewed and a more accurate working equation for the Auburn oscillating cup viscometer is developed. Some design parameters of the oscillating cup viscometer, which directly affect the accuracy of viscosity estimation by using the working equation, are discussed. In addition, applications and experimental measuring data are presented in the paper for several different commercial alloys, such as aluminum alloys: A319, A356 and A201, nickel-base super alloys: In713 and In718, and casting irons, C40 Gray Iron and Ductile Iron.1 IntroductionThe oscillating cup viscometer is the most important and has been most frequently used in viscosity measurement for high temperature liquids [1-4]. The principal advantages of this technique over others are its mechanical simplicity and the ability to measure the time period and amplitude decay with great precision. In the viscometer, a high temperature liquid (such as a molten metal) is contained within a crucible suspended by a wire to form a torsional pendulum, which induces torsional oscillation motion. This motion is damped primarily by viscous dissipation within the viscous liquid inside the cup. The viscosity of the liquid can be calculated by an analytical or numerical solution ofthe equations of motion of the oscillating cup system."

Jan 1, 2001

By E. P. Williams

"Prince Edward Island, Canada's smallest Maritime Province, is located in the southwestern part of the Gulf of St. Lawrence. The Province is more or less centrally located in the Maritimes Basin, a large intermontane basin within the Appalachian orogenic belt. The Maritimes Basin is subdivided into sub-basins and uplifts which exhibit two dominant structural trends: east and northeast. The Basin is known to be petroliferous because of the seeps, shows, oil shales and albertite found in southern New Brunswick and northern Nova Scotia and the gas and oil produced from the Stony Creek field near Moncton, New Brunswick.Permian beds are exposed on the Island, mostly along sea-cliffs. A maximum thickness of about 5,000 feet of red beds -shales, sandstones and conglomerates -make up the sequence. Over most of the Island, the Permian section is much thinner. Four key wells (Mississippian tests) and several shallower tests have been drilled. The Pennsylvanian-Mississippian section thickens rapidly off the Port Hill Uplift at the northwest, where it is less than 4,600 feet thick, and continues to thicken to about 20,000 feet in the Cumberland Basin at the southeast. Geological and geophysical data combine to give us the structural picture of the deeper beds.Prospective reservoir rocks are primarily in the Missis-sippian Horton and Windsor groups. Prospects are:-1. on or over structural highs in the basement; 2. on anticlines or fault highs; 3. over or peripheral to salt domes or salt-core anticlines; 4. at truncation pinchouts of Mississippian prospective beds; 5. in basal sandstone or granite wash on the pre-Carboni-ferous basement; and 6. in facies traps at changes from sandstone to shale or porous to tight carbonate rocks."

Jan 1, 1967

By S. Neogy, M. Gupta, D. Srivastava, V. Kain, S. Roychowdhury, R. C. Prasad, G. K. Dey

"Austenitic stainless steels are an important material of construction for Boiling Water Reactors (BWR). These stainless steels are amenable to strengthening by strain hardening. Various deformation modes at different test temperatures and strain become active. In the present investigation type 304LN stainless steel was used in the annealed and strain hardened condition. Thin foils were prepared from gauge section for transmission electron microscope (TEM) investigation after tensile testing at room temperature and at 288°C. TEM investigation reveals that twinning is the major mode of deformation for the tests done at room temperature while dislocation cross-slip is the major mode of deformation at higher temperature. Stacking faults were also observed to a limited extent. The extent of twinning was much higher for the tests done using the rolled material. The formation of martensite in the stainless steel due to straining was investigated by the analysis of selected area diffraction patterns.IntroductionAustenitic stainless steels (type 300 series) are an important material of construction in Boiling Water Reactors (BWR). These stainless steels cannot be heat treated but can be strengthened by cold working [1]. Nitrogen alloying of these stainless steels result in high strain hardening rates and higher strength without any loss in toughness [1]. Stress Corrosion Cracking (SCC) in BWR of these types of stainless steels have been attributed to surface strain hardening and strain hardening ofregions adjacent to constrained weldment [2].The test temperature [3, 4], prestrain [5] and nitrogen level [5] has been reported to affect the deformation mechanism during tensile testing. Byun et al. [3] have reported the formation of martensite, dislocations, stacking faults and twinning during tensile deformation, the extent of each depending on the test temperature. Strain localisation has been reported to occur during tensile deformation in irradiated stainless steels [ 6]. The behaviour of rolled material during tensile testing is similar to that of irradiated material to a large extent [3]. Austenitic stainless steels are low stacking fault energy (SFE) materials in which various types of microstructures have been reported to form during tensile deformation and the strain is also highly heterogeneous in nature in these stainless steels which aides SCC in BWR environment to a large extent [7]. During cold working of austenitic stainless steels second order twinning has also been reported [8]. Knowledge about the deformation mechanisms operative in the strain hardened austenitic stainless steels during tensile testing at different temperatures is essential to understand the material deformation behavior and the present study aims at enhancing the existing understanding."

Jan 1, 2011

By W. C. McBee

Over the past several years the Bureau of Mines has developed a sulfur concrete (SC) technology in which chemically modified sulfur is mixed with suitable mineral aggregates to produce construction materials that are resistant to corrosion by acids and salts. Modified SC materials have been tested in actual operating conditions in 50 corrosive process environments at 40 commercial plants. SC components ranging from small test coupons to 4-ton acid sump tanks were fabricated and installed at plant locations where chemical corrosion was destroying conventional concrete materials. Through cooperative agreements with several companies, floors, retaining walls, and foundations were cast in place us-ing SC materials, then monitored for resistance to corrosion and retention of strength properties.

Jan 1, 1983

By R. Hogg, S. Chander

"The distribution of the wettability of coals of different rank was determined by measurements of contact angles for individual particles. The contact angle was estimated from the equilibrium partitioning of a particle at the water/air interface. Using this technique contact angles were determined for a larger number of particles from a given sample and a frequency distribution of contact angle was obtained. The contact angle distribution was broad for all the coals tested with included an anthracite, a hvA bituminous and a sub-bituminous coal. In comparison, spherical particles of polymethylmethacrylaie gave a much narrower distribution. The distribution for irregular polyethylene particles was somewhat broader than that for the polymethylmethacrylate spheres but broader than that for the polymethylmethacrylate spheres but considerably narrower than that for coal. The broader wetting distribution for coal was attributed to differences in surface chemical properties.INTRODUCTIONA knowledge of the wetting properties of coals is very useful in coal cleaning by flotation and other processes in which separations are based on differential surface properties. The various methods available for measuring wetting characteristics include: contact angle, 1-2 time, time, 3-5 bubble attachment, 6 film flotation,7 displacement pressure, 8-9 penetration rate, 10-11 bubble pick-up, 12 induction time, 13 imbibition time, 14 and calorimetry. 15-16 Of all these methods, however, the measure¬ment of contact angle by the sessile drop and captive bubble techniques have been most widely used. Brady and Gauger"" demonstrated through the use of the contact angle method that the natural hydrophobicity of coal varied greatly from sample to sample. Subsequent experiments showed that this difference correlated well with rank, the larger contact angles generally being associated with the higher rank coals. 18-19 More recent studies by Aplan and co-workers' show that the wettability of various ranks of coals as determined by sessile drop and captive bubble methods is a more complex function of rank. The hydrophobicity of coal usually increases with rank up to about 80% fixed carbon (dmmf) and then decreases."

Mar 1, 1992