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By William J. Campbell

The purpose of this investigation was to develop a rapid, accurate method of analysis for small amounts of calcium in wolframite concentrates. This analysis is necessary to determine if the wolframite concentrates meet United States National Stockpile Specification P-57R2, which limits the calcium content to 0.2 percent. Because of the small depth of the sample analyzed in fluorescent X-ray spectrography, the calcium Kaline intensity was a function of the chemical composition of the calcium-bearing particle as well as the total matrix composition. This particle-composition effect was particularly important in this analysis, as the calcium may be present as a carbonate, tungstate, phosphate, etc. Three methods of preparing the sample eliminated the variation of calcium Ka intensity with mineralogical occurrence: (1) Reduction in particle size by extensive grinding, (2) chemical fusion with sodium carbonate, and (3) solution of the calcium by an acid attack.

Jan 1, 1958

Thermal pretreatment can significantly improve industrial comminution operations by reducing energy requirements and increasing mineral liberation. The effect of pretreatment using conventional and dielectric heating followed by quenching on the fracture properties of a number single and multiphase brittle materials has been investigated. The reduction in the impact fracture energies and particle strengths with and without pretreatment has been measured in precise single-particle experiments using the Ultrafast Load Cell. Variations in the fragmentation pattern caused by different pretreatments were assessed by measurements of the progeny size distributions. The differences in the effect of thermal treatment on single and multiphase materials are discussed based on the experimental results.

Jan 1, 1995

By S Versace, D Arnott, D Bojcevs, A Shaw

The George Fisher deposit is a significant sediment hosted silver-leadzinc resource located 2 km north of the Hilton Mine in NW Queensland. The George Fisher feasibility project involved the completion of underground and surface drilling programs to delineate Measured and Indicated Resource which could be converted to an Ore Reserve through mining and commercial studies. The geological information which was collected and used for the feasibility study included a major program of diamond drilling, predominantly from underground sites, but with some drilling also completed from surface. All drillcore was geologically and geotechnically logged, sampled and assayed. Data was also collected from underground cross-cut and drive development which was mapped for rocktype, ore distribution, structure and geotechnical condition. This new geological data, generated during the Pre-Feasibility and Feasibility stages, was combined with results of all previous drilling campaigns in the George Fisher area to produce a comprehensive database on which geological modelling and Resource estimation could be based. To allow fast and accurate collection and utilisation of data from the drilling program, digital collection processes were used where possible. This resulted in rapid data entry into the project database, significantly enhanced data quality, 100 per cent data ownership within the project team and increased productivity levels. Processes used during the project data collection program are described, lessons learned are related and suggestions for ænext timeÆ are listed using the benefit of hindsight.

Jan 1, 1998

By Karl-Heinz Frohne

This report presents the findings of a study of a portion of the Clover-Rush Run oilfield located in Roane County, W. Va. The study was made to investigate the possibilities of secondary oil recovery in the Big Injun sandstone underlying the William Kaufman lease. Reservoir properties, original reserves, and primary oil recovery are also presented. The investigation is based on a core analysis and related laboratory tests, well records, field production data, and subsurface information from the Kaufman property. A theoretical primary oil recovery of 9.7 percent of original oil in place is predicted for the reservoir. A waterflood performance prediction of a hypothetical pilot area was made by use of a computer. The prediction showed that, based on laboratory oil water relative permeability curves, the water-injection time needed to initiate oil production is excessive and that the stabilized water-injection and corresponding oil-production rates are very low. This precludes waterflooding the reservoir on an economic basis. A prediction for secondary oil recovery by gas injection was attempted but could not be completed because essential reservoir data were not available. In July 1965, the lease operator initiated, and is currently conducting, a gas-injection program, but there had been no increase in oil production up to November 1966.

Jan 1, 1967

By Gennaro G. Marino

As part of the development of a shopping center in West Virginia, a significant bench had to be cut into a mountainside that was over 700 ft. high. As a result, a steeply stepped, over 400-ft.- high wall was created. The high wall exposed old abandoned room-and-pillar coal workings at the toe of the cut. Because of exposure to the elements, the mine openings began to severely deteriorate with significant potential of undermining of the rock cut face and causing a large rock fall(s). Exacerbating this wall problem was a set of fairly planar sub-parallel and sub-vertical joints creating, in essence, thin rock slabs. Also present were stress relief fractures that were observed in the exposed pillars. Given the proximity of the project building to this high rock face, mitigation of the rock fall potential was deemed necessary. In order to prevent continued damage and deterioration of these exposed mine entries, the rubblized openings were filled with bulkhead grout and pressure injected with grout. The total amount of grout installed in these openings was about 3,945 CY. Also, a rock drape was attached to the entire face to mitigate small rock falls from natural causes. There also existed another level of mining below the ground surface and under an existing building at a depth of about 160 ft. Under a portion of the building, the pillars in these old works were second mined, and the building seemed to have been already affected by limited subsidence above this area. Also, calculated pillar safety factors in this high extraction section of the mine were too low. Consequently, these old works were stabilized by saturation grouting. An indication of overall roof distress was the significant fracturing encountered in the bedrock overburden during the drilling of the injection holes and the volume of grout placed in these holes. The total grout installed in the high extraction section of the lower mine was about 6,660 CY. This paper describes the investigation and the grouting techniques employed at the rock cut face and under the existing building to mitigate continued damage to avoid future subsidence problems at the face and the building premises.

Jan 1, 2013

By Maija-Leena Metsärinta

The behaviour of copper and lead in zinc roasting has been studied in laboratory scale roasting experiments as well as in large scale trials in an industrial fluidized bed, with the background of Outokumpu Kokkola Zinc smelter. Commercial zinc concentrates with a low and high ( up to 3 wt % ) copper content and with a low and high (up to 3.5 wt % ) lead content were oxidized to various desulphurisation degrees in the fluidized bed to establish the reaction mechanisms and the paths for copper and lead oxidation in the roasting. Influences of the agglomerate size on the roasting kinetics and micro-scale phenomena were also determined. Optical microscopy was used on the calcine and the findings are presented as numerous photographs of the polished cross sections. SEMIEDS techniques were used for analyzing chemically the phases and particle morphologies present in the samples. Computational thermodynamics was applied to the complex phase equilibria occurring during roasting in the agglomerating calcine. A complete oxidation of zinc concentrate with a high copper and lead content requires a careful control of oxygen coefficient in the roasting in order to maintain a stable operation of the fluidized bed. Oxygen coefficient thus seems to have a significant impact on the hydrodynamic stability of the fluidized bed with fine raw materials.

Jan 1, 2003

By Yvette Heritage

"The risk of fatalities from rib failure is still prevalent in the coal mining industry. This risk has prompted further research to be conducted on rib deformation in order to understand the mechanisms of rib failure, with the long-term objective being to improve rib support design. This paper presents the results of ACARP research project C25057, which investigated the mechanics and drivers of rib failure. The results of rib deformation monitoring at three different mines in Australia provides rib deformation characteristics for overburden depths ranging from 160 m to 530 m. Monitoring includes deformation during development drivage conditions and during the longwall retreat abutment stress environment. The rib deformation monitoring covered three different seams: the Goonyella Middle Seam, Ulan Seam, and Bulli Seam in the Bowen Basin, Western Coalfield, and Southern Coalfield, respectively. The observed mechanisms driving the rib deformation ranged from bedding shear failure along weak claystone bands to vertical shear fractures to kinematic failures driven by shear failure dilation. The variation in mechanisms of rib failure, together with the seemingly consistent method of rib support design, prompts the question: What exactly is the role of rib support?INTRODUCTIONThe current risk of rib fatalities in the coal mining industry has prompted further research into understanding the mechanisms of rib failure. Three Australian mines assisted further research by providing sites for rib deformation studies as part of the Australian Coal Association Research Program (ACARP) project C25057. The mines included in this study were Moranbah North Mine, Ulan West Mine, and Appin Mine. This paper provides key results of the rib deformation monitoring relevant to assessing the mechanisms of rib deformation.The approach of monitoring rib deformation and rib support loads was used to measure and characterise the dynamic rib deformation present in both development and longwall retreat stress environments. The characterisation of rib deformation, together with rock failure modelling, was used to determine the mechanisms for failure within the rib and to assess the interaction of rib support with the failure process. The mechanisms of rock failure are considered an important factor in understanding the drivers for the failure. Consideration of the site-specific failure mechanisms can provide for a more tailored support design."

Jan 1, 2018

By Anatoly Usov

The detailed researches of a broad circle of problems connected to development of the electric pulse method destruction materials (EPD) of a various nature and area of use are executed. The electrical and power characteristics of process, physical fundamentals of selectivity of a breakdown and destruction are investigated, the device of electric pulse (EP) disaggregation and ?omminution of materials are developed, the technological efficiency of disintegration of industrial minerals estimated. Due to its technological advantages, the EPD could have a great potential in minerals mining and processing technologies. Low specific power and weight-and-size characteristics of EP installations based on the existing out-of-date electric equipment are at present the main reasons hindering the effective application of the method in mining and processing technologies. The main studies carried out in Russia in the field of electro technical equipment development for EP technology are presented. The pulse capacitors service life affects greatly the economic efficiency of the process because the capacitors cost accounts for a considerable, and in some cases, the most part of the operational costs. Determined and analyzed in the study are the ways which could significantly improve the specific characteristics of high voltage pulse generators (VPG), such as to use of high-frequency voltage transformation to develop a charger; to use pulse transformers (PT) with iron magnetic circuits made of materials characterized by high magnetic permeability, in pulse generating circuits; as well as to use special ways which could produce voltage pulses with a short front. The experiments have proved the possibility to adapt these technological solutions for EP devices, and a further strategy of the EP technologies development and application has been suggested on this base. Keywords: electric pulse disaggregation, electric pulse installation, charger battery, high voltage pulse generator

Sep 1, 2012

By P. J. Petit

"The complex planning required to achieve any planned production yields multiple and dissociated responses over the life of project (LOP). The customary decision-making process negates the possibilities of developing optimized and integral solutions from operating levels up to business and strategic levels. This results in an inefficient project or overall underperformance of the operation.In the project setting, disconnected trade-offs and improved performance studies become inadequate, because they are site-specific and use only a few comparative parameters. They are often based on a small data-set.Decisions taken to achieve overall objectives require the correct determination and dissemination of key performance indicators (KPIs). The KPIs indicate efficiency in operation, whereby the marginal rate of technical substitution corresponds to the rate of production. It is the necessary condition for optimization. Performance realization for sustainability follows optimization modelling, the latter often being presented with financial results such as business net present value (NPV). It considers techno-financial constraints and provides a strategic and aligned outlook of KPI decisions for an enhanced and integrated outcome.This paper explains a mining case study that is rendered efficient, and through business optimization (BO) short-term and sustainable targets are reached. Business optimization increases the NPV by 14.7%. This is achieved by challenging conventional decision-making associated with maximizing business value by including environmental externalities within the LOP."

Jan 1, 2016

By Maija-Leena Metsiirinta

The behaviour of copper and lead in zinc roasting has been studied in laboratory scale roasting experiments as well as in large scale trials in an industrial fluidized bed, with the background of Outokumpu Kokkola Zinc smelter. Commercial zinc concentrates with a low and high ( up to 3 wt % ) copper content and with a low and high ( up to 3.5 wt % ) lead content were oxidized to various desulphurisation degrees in the fluidized bed to establish the reaction mechanisms and the paths for copper and lead oxidation in the roasting. Influences of the agglomerate size on the roasting kinetics and micro- scale phenomena were also determined. Optical microscopy was used on the calcine and the findings are presented as numerous photographs of the polished cross sections. SEM/EDS techniques were used for analyzing chemically the phases and particle morphologies present in the samples. Computational thermodynamics was applied to the complex phase equilibria occurring during roasting in the agglomerating calcine. A complete oxidation of zinc concentrate with a high copper and lead content requires a careful control of oxygen coefficient in the roasting in order to maintain a stable operation of the fluidized bed. Oxygen coefficient thus seems to have a significant impact on the hydrodynamic stability of the fluidized bed with fine raw materials.

Jan 1, 2003

By R. Hendrickson

In the 1940's a top blown water-cooled oxygen lance was developed to inject oxygen into liquid iron. This process, the LD or BOF process technique, today is used in 65% of the world's steel production, and represents the largest oxygen market for temperature enhancement in steel and non-ferrous smelting applications. There are three major approaches to the use of oxygen in metallurgical processes: (1) general enrichment of the air supplied to burners or tuyeres, (2) under-flame enrichment or injection, and (3) the use of an auxiliary oxy-fuel burner as a heat source. With each of these techniques there are technical and economic trade-offs.

Jan 1, 1990

By Brian T. Hamilton, Richard Piliounis, Cian Murphy

"The Eglinton-Crosstown Light Rail Transit line is a 19-kilometre corridor with a 10-kilometre underground portion currently being constructed by Metrolinx in Toronto through a densely populated urban environment. Tunneling works are being completed through two separate design-bid-build contracts that include consideration for a phased handover to a follow on contractor who will take ownership of the tunnels, including warranties, and will complete the stations and remainder of the system through a PPP delivery model including maintenance of the system for 30 years. Warranty provisions, settlement apportionment, tunnel leakage, potential delays and conflicts between contractors are just some of the risks the team managing tunnel contract integration had to consider when developing the PPP contract. This paper will present an overview of how these risks were assessed and allocated through the contracts and the strategies adopted to minimize risks to Metrolinx while ensuring successful procurement was maintained. INTRODUCTION The Big Move is a 25 year, $50 billion ($-CAD) plan for coordinated and integrated transportation in the Greater Toronto and Hamilton Area (GTHA) in Ontario, Canada. This plan has been initiated by Metrolinx, a division of the provincial government of Ontario, and its vision, goals and objectives are rooted in creating a high quality of life; a thriving, sustainable and protected environment; and a strong, prosperous and competitive economy for the GTHA. The Big Move will triple the length of rapid transit service in the GTHA to 1,725km, significantly increase the percentage of the GTHA population living within two kilometers of rapid transit, reduce commute times to an average of 77 minutes per person per day and decrease greenhouse gas emissions from passenger transportation per person by 29%. Work is currently underway on several projects and more than $16 billion ($-CAD) of the planned investment has already been committed. A key project that forms part of this commitment is the Eglinton Crosstown Light Rail Transit (LRT) Project which is being delivered in the City of Toronto under Metrolinx’s Rapid Transit (RT) Program. This complex and sizeable undertaking has been broken into a number of separate contracts comprising: LRT Vehicles contract; Eglinton West Tunnels Project; Eglinton East Tunnels Project; and a Public-Private-Partnership (PPP) contract to complete the underground stations, at-grade stops, all rail infrastructure and systems and to maintain the entire system for 30 years. The PPP contract, which includes an initial capital portion of approx. $5.1 billion ($-CAD), has recently been awarded to Crosslinx Transit Solutions, a Special Purpose Vehicle (SPV) consortium comprised of SNC Lavalin, Aecon, Dragados and EllisDon."

Jan 1, 2016

By P. M. Tait, N. A. Warner

"The refining of thermally produced zinc is currently performed using a highly energy intensive and arguably outmoded process, distilling zinc under atmospheric pressure at temperatures of 900°C to 1000°C. In order to produce refined zinc more profitably and with less environmental impact a new process has been proposed. This process is generic to all thermal zinc smelters and aims to match the purity of zinc from current technology (99.99%-99.999%). The objective is to perform all separation processes using only the heat contained in the smelter product stream. Vacuum conditions are extensively used lowering operating temperatures and enhancing separations. As part of this process zinc is distilled under vacuum from high concentration obtaining a refined product with respect to lead content. A mathematical model has been developed from fundamental principles to describe this stage, the distillation of zinc across a temperature difference between two circulating zinc streams in open channels under vacuum. Heat for the distillation is supplied by the liquid phase, necessitating a large recycle to maintain high operating temperatures, and keep zinc concentrations high. In determining this model and the operating conditions required, relationships between temperature, pressure and composition are considered.IntroductionCurrent technology (the Refluxer) used to refine thermally produced zinc is both expensive and highly inefficient. At present 80% of the worlds zinc is produced via the electrolytic process reflecting the poorer performance of the thermal route, the zinc-lead blast furnace and Refluxer. A new process is proposed to overcome the drawbacks of current processes. These drawbacks are both economic and environmental. The Refluxer requires 6.6 GJ of energy to refine one tonne of SHG zinc 1, other disadvantages of the Refluxer stem from high operating temperature, around 900°C, and liquid zinc being highly corrosive towards ferrous metals. The Refluxer is constructed from silicon carbide sections which join together by means of flat machined faces making liquid metal leaks inevitable. The Refluxer columns are very sensitive to thermal cycling, thermal shock and mechanical vibration, which easily lead to structural failure. To avoid thermal stress on the columns the feed rate and feed temperature need to be kept constant which means the feed baths to the columns must be able to accept solid and liquid feed as the Refluxer has to operate when the smelter is shut down."

Jan 1, 1998

By C. R. Fast, G. C. Howard

The loss of fluid to the formation adjacent a fracture governs the areal extent of the fracture and the success of hydraulic fracturing as a production stimulation technique. The three flow mechanisms which control this loss are the result of the viscosity of the fracturing fluid and the permeability of the formation to the fracturing fluid, its wall building properties, and the combined effects of viscosity and compressibility of the reservoir fluid. The effects of these flow mechanisms can be evaluated in terms of a fracturing fluid coefficient, the fundamental concepts of which are developed in the paper. The fracturing fluid coefficient, which may be used in calculating the areal extent of fracturing, affords a direct measure of the effectiveness of fracturing fluids. The area of hydraulically created fractures is in-creased as the coefficient is de-creased. The fifteen-fold variation noted in this coefficient for the commercially available fracturing fluids tested resulted in a six-fold difference m the calculated areal extent of the fracture system.

Jan 1, 1961

By S. Shairp

The first commercial application of the Dynatec two-stage zinc pressure leach process commenced operation at the metallurgical complex of Hudson Bay Mining and Smelting Co., Limited in Flin Flon, Manitoba in 1993. A key feature of the successful leaching operation is the presence of iron in solution, which facilitates oxygen transfer in the autoclaves and enables rapid oxidation of zinc sulphide minerals. At the same time, the solution from which zinc is recovered must be essentially iron free. Precipitation of iron from the solution starts in the autoclaves and is completed in subsequent atmospheric purification steps. Conveniently, these iron precipitation steps also remove nuisance elements such as arsenic and fluoride from the solution, while producing solids with good liquid-solid separation characteristics. This paper provides an overview of the current operations in Flin Flon, with particular reference to the behaviour and deportment of iron throughout the zinc plant.

Jan 1, 2006

By J W. Glatthaar, M Mavotoi

The occurrence of fluorine in the copper/gold concentrates produced by Ok Tedi Mining Limited has provided a series of challenges to metallurgists since 1988. Although fluorine is distributed throughout the gangue minerals contained within Ok Tedi ores, itsÆ presence in talc and phlogopite (naturally floating fluorosilicates) has proven to be the predominate sources of fluorine in the final concentrate. Initial treatment for the fluorosilicates consisted of the use of a carboxy-methyl cellulose depressant added to the flotation cleaners. This was superceded in 1998 with the installation of a fluorine reverse flotation process for the removal of naturally floating fluorosilicates from the final concentrate when the fluorine content of the final concentrate exceeds smelter-defined trigger points. The fluorine reverse process is similar to by-product molybdenite concentrate production in that sodium hydrosulfide is used to depress copper/gold flotation whilst allowing the fluorosilicates to float. The process was installed in two parallel modules (to match the existing grinding/flotation modules at Ok Tedi), each consisting of a closed rougher/cleaner circuit configuration. Both rougher and cleaner cells are Jameson Cells from MIM Process Technologies, with the selection based on both processing characteristics and available construction space. This paper discusses both the nature of fluorine in-, and its removal from-, Ok Tedi copper/gold concentrates.

Jan 1, 2003

By W Roy

When it comes to plan implementation and securing success in organisations in the 21st century, if there was such a thing as the secret to success it would be effective communication. Commoditisation brings financial, operational and cultural advantages to organisations that use effective communication. Effective communication tools turn æpeople problemsÆ into system control solutions, removing personality clashes that hide procedural malfunctions. By introducing communications frameworks available in the market place today, and case studies of their use, this paper provides insights into the successes available to organisations courageous enough to redefine their communications for the 21st century.

Jan 1, 2006

By George R. Pratt

Although the title of this paper focuses attention to the Winnipeg coal market the following remarks should be considered applicable not only to conditions in Winnipeg but to the whole western coal industry. Technical descriptions of coal and coal-burning have been omitted. These details are already covered in other numerous publications. In discussing a market the first consideration must be the product which is required to be sold. The class, quality and price at the point of origin must be taken into account and therefore this feature will be discussed before proceeding to outline conditions in the Winnipeg local market. The writer thinks of coal as a manufactured article, not, as it is generally considered, a fuel to be dug from the ground and dumped into the consumer's bin. The work of manufacturing must be considered in detail:- 1. Consider first the coal as it is in the ground: (a) What is its fuel value? (b) Where is its market? © With what will it be in competition? 2. Consider secondly: (a) What it will cost to mine the coal. (b) What has to be done to prepare the coal for market after it is mined. This must be considered in conjunction with the answer to question 1 ©. 3. Thirdly, consider the method of business to be adopted by the producer:- (a) Is it proposed to build a market on price? Or (b) On quality?

Jan 1, 1925

By F. J. Sotillo

Mineral processing requires good classification of particles to attain an adequate separation of minerals. This is of utmost importance in the case of sulfide minerals. An ideal classification is obtained when particles are separated at a given mesh, which is fixed according to the characteristics of each sulfide ore. Under these ideal conditions, particles coarser than the mesh of separation are recovered in the underflow, whereas particles finer than the mesh of separation are recovered in the overflow. This paper presents the results of pilot plant tests that were performed on Ag-Pb-Zn and on Ag-Au Peruvian sulfide ores using a Density Separator, and the comparison of these results with those obtained using hydrocyclones, under similar operating conditions. The results show that the ratio of circulating load is reduced by 50% by using a Density Separator with respect to that obtained by using hydrocyclones. Moreover, the effect of the improvement in the separation efficiency obtained by using the Density Separator on the kinetics of flotation is also shown. Silver recovery of the Ag-Pb-Zn ore increased by 18% whereas gold grade in the concentrate of the Ag-Au ore is doubled.

Jan 1, 1998

By Richard L. Ashbrook, John F. Wallace

Several high-temperature eutectics of cobalt and nickel alloys were modified by small additions of selected elements. Thes-e alloys were compared to unmodified melts for microstructural variations. A few modified compositions were selected on the basis of structure and their tensile and stress-rupture behavior determined. The results of stress-rupture tests in air at 1800 F and room-temperature tensile tests of four high-temperature eutectics showed modification capable of producing substantial improvements in properties. The microstructures were altered and mechanical properties improved by: a.) dispersing a subordinate phase more uniformly throughout the matrix; b) replacing large continuous -network or platelike constituents with small equiaxed discontinuous phases; and c) by forming new, finely divided phases. tHE term "modification" is most commonly used to describe the refinement in microstructure of the Al-Si eutectic that occurs as a result of rapid cooling from the melt or on slow cooling after treatment with small amounts of sodium.1 "Modification" has also been used to describe the change from flake to spheroidal graphite in the austenite-graphite eutectic of cast iron.2 This change of graphite shape is accomplished by small additions of cerium or magnesium.3 Other systems have also been shown to be capable of modification, for example: Pb-Sn by copper;4 Al-Cu by sodium;5 Al-Mn by sodium;5 and Pb-Sb by aluminum.5 Although modification of Al-Si alloys and cast irons is usually accompanied by improved mechanical properties, a general definition of modification has been suggested to include the effect of small quantities of impurity elements on the microstructures of all eutectic alloys, regardless of the effect on the mechanical properties.6 In this paper, the term "modification" is employed in a broad sense to include the formation of third phases or even the supplanting of one of the binary eutectic phases by a third phase. The mechanism of modification, as for any solidification phenomenon, must be considered primarily in terms of nucleation and growth. Although both nuclea-tion and growth mechanisms are required to explain all the phenomena observed in connection with the solidification of modified eutectics, various investigators have usually favored one or the other.7"16 It has been shown that modification of a binary eutectic can be effected by addition of a solute element that has greatly different distribution coefficients or k values in the two phases of the eutectic. Under these conditions, differences in the temperatures at the solid-liquid interfaces of the two phases retard the growth of one phase with respect to the other.4 It has also been shown that increased undercooling favors a transition from a rodlike eutectic to a globular eutectic.17 A mechanism proposed for the transition from lamellar to rodlike eutectics depends on the concept of constitutional super cooling.18 The modification of eutectic alloys may be of interest for high-temperature service as well as at room temperature. Although "high-temperature eutectic alloys" may appear to be a contradiction in terms, many eutectic systems, including those studied in this work, have melting points in excess of 2400°F. One of the mechanisms by which high-temperature alloys are strengthened is dispersion of a relatively brittle phase such as an oxide, carbide, or an inter-metallic compound throughout a ductile matrix. For a given volume fraction of dispersed phase, strength is increased by decreasing the size and spacing of the dispersed particles.19'20 Furthermore, room-temperature ductility may also be increased by changing the shape of a brittle dispersed phase from platelike to equiaxed or spheroidal.8 Overaging and redissolving of the secondary phase limit the maximum temperature to which precipitation-hardened alloys can be used. However, in a binary eutectic system, both phases coexist up to the melting point. Although all eutectic structures are not completely stable,21 a dispersion-hardened cast high-temperature alloy might result if a fine distribution of one of the eutectic phases could be obtained during solidification. An additional reason for interest in eutectic alloys is their excellent castability.22 Since eutectic alloys, like pure metals, freeze at a single temperature rather than over a range of temperatures, their castability is superior to solid-solution alloys with long liquidus to solidus ranges. The purpose of this research was to study the effects of small solute additions on the microstructure and mechanical properties of a number of high-melting-point eutectic compositions.

Jan 1, 1967