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By Albert L. Toenges

ALMOST all of the coal used for metallurgical purposes west of the Continental Divide is ruined from the Lower Sunnyside bed in Carbon County, Utah. Coke produced from Lower Sunnyside coal and used in western steel plants is weaker structurally than coke used elsewhere in this country. For this reason, western coal operators and steel manufacturers are anxious to develop new areas of coking coal of better quality than the coal produced from the Sunnyside bed. Early in the war, the Bureau of Mines undertook an intensive investigation of western coals to (a) develop additional reserves of coking coal to supplement proved reserves in the Sunnyside bed and (b) develop, if possible, reserves of coal with coking qualities superior to Lower Sunnyside coal. Results of investigations in the Kemmerer district, Wyoming,9 and in the Minnesota Creek area, Gunnison County, Colo.,10 have been published.

Jan 1, 1952

By Hamid-Reza Manouchehri

Mining & Sustainability? A Paradox?! ? Production: gradually or exponentially increasing (giant mining) ? Ore Grades: gradually declining, ? Open Cut Mining: now widespread, likely to be sustained in the future though the long-term is hard to predict as new mineral deposits are likely to be deeper ? Waste Rock / Overburden: increasing rapidly, likely to be sustained in the future and closely linked to open cut mining, especially for coal and base metals ? Economic Resources: commonly increasing but some remain stable or gradually declining, future is linked closely to exploration, technology and economics; Increasing population, changing life style and technology development, ultimately result in sustainability in mining industry to hang in the balance and continue.

May 1, 2013

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) measurements provide direct evidence for the involvement of Cr(V) in the reduction of Cr(VI)· by NAD(P)H. Addition of hydrogen peroxide (H2 O 2) to NAD(P)H-Cr(VI) reaction mixtures suppresses the Cr(V) signal and generates hydroxyl (·OH) radicals (as detected via spin trapping), suggesting that Cr(V) reacts with H2O 2 to generate the ·OH radicals. Reaction between H2O 2 and a Cr(V)·glutathione complex, and between H2O 2 and several Cr(V)-carboxylato complexes also produces ·OH radicals. These results suggest that Cr(V) complexes catalyze the generation of ·OH radicals from H2O 2, and that ·OH radicals might play a significant role in the mechanism of Cr(VI) cytotoxicity. KEY WORDS: ESR. spin trapping, Cr(VI) reduction, Cr(V), hydrogen peroxide, free radicals.INTRODUCTIONThis communication reports an ESR spin trapping detection of hydroxyl ( OH) radicals.in reactions between some Cr(V) complexes containing biologically important ligands and hydrogen peroxide (H2O 2 ). This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step in the mechanism of Cr(VI) toxicity, the reaction· mechanism is not yet clear. 1 Mutagencity has been well documented for Cr(VI) via various bacterial assays, while Cr(III) has been shown not to be mutagenic.2 • 3 Since it has been reported that compounds containing Cr(VI) do not react with isolated DNA,4 the reduction of Cr(VI) by other cellular constituents has been thought to be important in the mechanism of Cr(VI) induced DNA alteration.1·4 • 5 For cellular systems earlier studies include those on the reduction of C~(VI) by microsomes,6-8 rat liver DT-diaphorase,9 and aldehyde oxidase. 10 Regarding the reduction mechanism, Jennette used ESR spectroscopy to show that a long-lived Cr(V) complex is formed as an intermediate in the microsomal reduction of Cr(VI) in the presence of NADPH.8 She postulated that Cr(V) is the ""ultimate"" carcinogenic form of chromium compounds. This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions.11 - 19 More recently, however, it has been suggested that oxygen-derived radicals generated during the Cr(VI) reduction are the species responsible for the DNA alteration.20.2• To the best of our knowledge, however, no information is available on the generation of such radicals in the reduction of Cr(VI) under biologically relevant conditions, except some preliminary results on the glutathionyl (GS·) radical formation in the reduction of Cr(VI) by glutathione (GSH). 11 - 19 We, therefore, undertook a systematic investigation of the reaction of Cr(VI) with NAD(P)H, GSH, ix-hydroxycarboxylic acids, and H2O 2 • NADPH was chosen as a model reductant because of its ubiquitous existence inside the cells, its critical role in the enzymatic Cr(VI) reduction,1·6-9 its representation of important cellular Cr(VI) reductants, and its ability to reduce other metal ions.22 GSH was chosen as another model Cr(VI) reductant because GSH also exists inside cells, it represents another important category of cellular Cr(VI) reductants, the thiols, and it also plays an important role in the Cr(VI) toxicity .1• 1 ""- 19.i3.i4 For further clarification, we also studied the reaction of Cr(VI) with several '1'.-hydroxycarboxylic acids in the presence of H2O 2 since these acids are definitively known to reduce Cr(VJ) to form stable, isolable Cr(V).25 .2 6 The results obtained indicate that Cr(V) complexes, produced in the reduction of Cr(VJ) by cellular reductants, react with H2 O 2 to generate ·OH radicals, which might be the initiators of primary events in Cr(VI) carcinogenicity."

Jan 1, 1990

By J. W. Motter

Currently, virtually all new electric power generation systems under construction are designed with natural gas as the primary fuel. Factors driving these construction decisions involve sustained low prices for natural gas, environ-mental (and consequent regulatory) risks associated with the use of coal for power generation, and relatively high costs of construction for conventional coal-fired power plants. Despite the unarguable abundance of coal in the US. and worldwide, a fundamental question arises: What will be the role of coal in electric power generation in the 21st century? Congress, recognizing the vital and strategic importance of preserving the coal option for electric power generation, authorized the Clean Coal Technology Program. This pro-gram, with original funding in excess of $2,500 million, is intended to promote the demonstration and commercialization of a new generation of clean, efficient coal-based energy technologies through collaboration and partnering with private industry. The two technologies being demonstrated under this program which are the key to the continued use of this nation's huge coal reserves are coal gasification and the pressurized fluid bed. Either or both of these technologies, coupled with a combined cycle will pro-vide the continuing future coal option, while responding to increasingly more restrictive environmental standards. Recent Congressional budget-cutting efforts, however, could threaten the effectiveness of that model program, and ultimately other subsequent government-industry collaboration.

Jan 1, 1996

By K Ehrig, V Liebezeit, E Macmillan

The results from metallurgical test programs are used in feasibility studies for design of new plants and brownfield expansions, in long term mine plans, and to make decisions in an operating plant. There are many elements which contribute to a well-constructed test work program. Ultimately, understanding the accuracy and precision of the test work results is critical to ensuring good decision-making at various phases of a project.Every resource drilling and associated assaying program will have a quality assurance / quality control (QA/QC) component, however this often seems to be overlooked in metallurgical testing programs. The principles of “international standard” or “certified reference material” samples and replicate/duplicate testing can be applied to metallurgical programs, although there are metallurgical-specific considerations in both generating and analysing the data.This paper will describe the QA/QC program carried out within the Olympic Dam geometallurgy program. It will present results in the form of case studies from ten years of testing of replicates and bulk reference samples for industry-standard comminution tests as well as laboratory flotation and leaching tests. The Olympic Dam geometallurgy quality control program has enabled quantification of the precision of metallurgical testing and improved our understanding of the best possible modelling results given the underlying dataCITATION:Ehrig, K, Liebezeit, V and Macmillan, E, 2017. Metallurgical QA/QC – who needs it? The Olympic Dam experience, in Proceedings MetPlant 2017, pp 31–44 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By John P. Capp

Information is summarized on the major uses of fly ash and prospects for utilization in agriculture and in brick and mineral-wool manufacture. Technological aspects of utilization are discussed and references are given to the work of many of the leaders in the fields of fly ash production, processing, and utilization.

Jan 1, 1970

By E. C. Tarpley

The Federal Bureau of Mines has studied solvent extraction as a means of concentrating the mineral components in coal. Solubilities of a number of American coals were determined using abietic acid as a solvent. The effect of rank on solubility was investigated, and maximum solubility was found with coals of intermediate rank. Vitrinite is the most soluble petrographic component; fusinite, micrinitc, and exinite are nearly insoluble. Spore exines also have a low solubility. Abietic acid is a hydrogen donor and reduces pyrite to ferrous sulfide. Mild hydrogenation of high-molecular-weight fragments of the coal structure to those of lower molecular-weight probably contributes to the solvent action. Even where solubility of the coal substance exceeds 90 percent, contamination of the mineral matter with coal makes identification of the mineral components difficult. Further separation might be possible by the application of float and sink techniques to the residue. INTRODUCTION Work n the solvent extraction of coal is conducted to recover commercially useful products and to characterize coal;. and obtain information on their structure. Some coals, particularly those of low rank, contain waxes, resins, and humic acids which can be removed by solvent extraction and find varied industrial uses. In World War II, solvent extraction of coal was conducted on a commercial scale in Germany to obtain a low-ash feed material for hydrogenation and to produce electrodes carbon for the aluminum industry.4 5/

Jan 1, 1960

By R. Q. Honaker

Recent research has shown that enhanced gravity separators provide the opportunity to effectively clean I mm x 37 micron coal. At Southern Illinois University, a detailed experimental program was performed on a continuous Falcon Concentrator, which was found to achieve separations at mass throughput capacity values in excess of 100 tonnes/hour. The apparent particle separation density for I mm x 73 micron coal was about 1.60 with relatively high efficiency (Ep = 0.12). Typical ash and sulfur rejection values of 85% and 70%, respectively, were achieved while recovering 85% of the combustible material. Metallurgical and efficiency data from the evaluation are presented in this publication.

Jan 1, 1998

By Michael A. Trevits

A mine fire represents one of the most dangerous and challenging safety issues facing underground mine operators. Given the right circumstances, a mine fire can occur at any location in the active or abandoned mine workings, can quickly grow beyond control, and threaten the welfare and livelihood of the entire underground workforce. The National Institute for Occupational Safety and Health (NIOSH), in partnership with the Mine Safety and Health Administration (MSHA), has been conducting an in-depth program of research addressing mine fire prevention, early and reliable fire detection, and mine fire suppression technologies. One portion of this program is focused on understanding the characteristics of mine fire combustion products and flame spread through large scale deep-seated (firmly established) fire tests and use of computational fluid dynamics (CFD) modeling. In this study, two deep-seated fire tests were conducted; one fire consisted of coal material and the other utilized the two most abundant fuel sources found in a coal mine: coal and wooden cribbing blocks. The fires were burned to completion while the combustion products were collected and analyzed. In addition, an array of thermocouples was placed within the body of the material to measure flame spread rate. The coal fire test information was then used to develop a CFD model of the fire. This paper describes the fire tests, provides insight into characteristics of flame spread, and presents the CFD modeling work results.

Jan 1, 2009

By Houquan Zhang, Ming Li, Guimin Zhang, Bei Zhang

"The support quality of bolts in deep roadways is one of the important factors for efficient and safe coal production. A new kind of non-destructive testing technique and equipment was used to monitor the axial bolt load in real time in deep roadways. Based on the test results, the working status of bolt support in deep roadways was evaluated. The research results show that the variation characteristics of axial bolt load is consistent with the distribution characteristics of rock pressure no matter whether it is in the initial support stage or mining disturbance stage. The axial load of bolts located 20m outby the development face has an overall rising trend within 3-5 days after installation. Within a certain distance in the front abutment pressure zone in front of the face, the axial bolt load increases with the advance of coal extraction. When coal and rock in the abutment pressure zone yield, the axial bolt load is dropped correspondingly. This kind of non-destructive testing technique provides an advanced means of detection and evaluation on bolt support quality.INTRODUCTIONMany coal seams more than 800m deep are being mined in eastern China. Roadways of large cross-section are being developed in coal seams more than 600m deep in western China (Kang et al. 2014). Moreover, these roadways are commonly supported by roof bolts and have encountered many support problems, including soft rock strata, intense mining disturbance, and abnormal tectonic stress. The stability of its surrounding rocks is difficult to maintain, the roof bolt even fails before mining (Shen 2014; Jiang et al. 2015). Therefore, it is very important to develop an effective method to detect the bolt quality in real time and evaluate the bolt's safety status.During installation of roof bolt, the installation quality is heavily affected by installation equipment and tools, field conditions, and operators' skills (Li et al. 2005; Shan 2009). The anchorage length will be shorter than the designed one if the resin cartridges are pushed to the bottom of excessively long drill hole and stay there without being shredded and mixed. The support function of the bolt would be weakened by the shorter anchorage length."

Jan 1, 2016

By John Canterford

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15,000 t/a magnesium alloy production facility in Nanjing, China, Site construction commenced in February 2005 with installation of all major components completed by the end of October 2005, Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005, Since that time ramp-up to the name plate capacity has been undertaken, This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

By Harry Teicher

The subject of Specialty Silica Products could encompass a broad range of materials, some of which would be familiar to members of the Society of Mining Engineers. With the concurrence of your chairman, I have chosen to limit my remarks to synthetic materials, not including such siliceous materials as diatomaceous earth, asbestos, quartz and clays. For purposes of discussion, I have classified Specialty Silica Products into two groups -- powders and liquids -- which I will discuss in that order and which are categorized in Figure 1. The synthetic silica powders are amorphous to x-rays and are manufactured by various processes resulting in products of a wide range of physical and chemical properties, as well as functional performance and applications. Applications or functional properties are generally dependent upon such physical properties as micron-sized particles exhibiting large surface areas per unit weight and low apparent bulk density. Their presence in various systems modify surface properties. As summarized in Figure 2, they act as viscosity modifiers, flow conditioning agents, anti-slip agents, anti-blocking agents, flatting agents in surface coatings, reinforcing agents in polymers such as silicone rubber and numerous other applications. Although the various types of silicas exhibit various levels of functional performance in these end uses, they are not usually equally effective as direct replacements and I will briefly discuss the various types of materials.

Jan 1, 1974

By Rouzbeh Vakili, Adel M. Hanna

"The application of piled raft foundations has significantly increased during the last few years. In this system, the raft and the pile group collectively transfer the applied building load to the underlying soil layers. Determination of load sharing between the raft and the piles derives the complexity of piled raft designs due to its multi-parameter nature. These parameters are but not limited to: soil density, pile length, pile spacing, raft geometry, and piles installation technique. This study is to examine experimentally the effect of sand density and pile installation techniques on the load sharing mechanism. Experimentally, tests were conducted on a square rigid raft with a single pile in sand under three different soil densities; 30%, 45%, and 60%. The experimental results are used to determine the pile and the raft shares in non-displacement and displacement piled raft systems. The results of this study reveal that soil density changes the load sharing of displacement piled raft; the pile share increases in higher soil density. However, this is not the case in non-displacement piled raft and load sharing is independent of soil density in working loads.IntroductionThe piled raft foundation is a combination of shallow and deep foundation which transfers the superstructure load to the soil by a complex soilstructure interaction. The interacting mechanism among foundation elements and their surrounding soil is illustrated schematically in Figure 1 and could be classified into two categories: (1) pile-soil-pile and (2) pile-soil-raft. The pile-soil-pile interaction is the same as the free standing pile group and is a function of pile spacing and pile installation method. Pile-soil-raft interaction, which only involves in piled raft foundation design, could be affected by: the length, spacing, and roughness of the pile, the rigidity and dimension of the cap, soil condition, and the pile installation method. Pile-soil-raft interaction could have favourable and unfavourable effects on bearing capacity and settlement, respectively. The pressure between the cap and the soil favourably increases the horizontal stress on the pile shaft and consequently increase the shaft resistance. Whereas, this pressure induces negative skin friction on the piles which increases the settlement. The pile-soil-raft interaction mainly controls the load sharing mechanism of piled raft foundation when pile spacing (S) is more than 3.5dp."

Jan 1, 2017

By Tacio Ferreira

How state-of-the-art software, data analysis and communication applied to drilling and blasting techniques have have allowed quarries in the Midwest of the United States to improve results downstream

Feb 1, 2020

By John Vickers, William H. Hover, Paul C. Schmall

"Any sudden subsurface issue that threatens the stability of existing buildings or infrastructure is cause for immediate investigation and prompt remedial action. Nowhere is this more true than the nation’s dams and levees. A breach of any kind, no matter how small initially, has the potential to be catastrophic and impact a wide downstream area. Addressing the problem quickly and effectively is therefore critical. When a turbid water discharge developed from a rock drainage embankment at the toe of the earthen dam impounding Cannonsville Reservoir, near Deposit, NY, the source of the problem was quickly identified as resulting from an artesian water release from an underlying permeable silty sand and gravel formation during drilling of three exploratory boreholes in preparation for construction of a hydroelectric plant at the downstream toe area of the dam facility. Work was halted, intense 24-hour monitoring was implemented, and as a risk reduction measure NYCDEP began to draw down the reservoir’s total storage at a rate of a billion gallons per day. Input sought from contractors within the geotechnical community helped result in the design and development of a deep well system to control the artesian pressure. Once this primary objective was accomplished, modified compaction grouting was performed at the borehole locations to densify loosened soils, fill any voids created by the discharge activity, and seal off the permeable aquifer. This paper discusses the dewatering program, specialized drilling techniques required, monitoring and verification of pressures within the dam, and the grouting program.BackgroundCannonsville Dam, owned and operated by the New York City Department of Environmental Protection (NYCDEP), is located in Deposit, New York on the West Branch of the Delaware River and impounds the Cannonsville Reservoir. Built between 1959 and 1964, the dam has an impervious central and upstream core zone keyed into the glacial till foundation, a semi-pervious downstream embankment zone, and a rockfill toe and is approximately 2,800 ft (853.4 m) long and 175 ft (53.3 m) high. The dam is formed by two embankment sections. The left section forms the main embankment blocking the main river channel, while the right section is constructed over a topographic saddle or low ridge. Reservoir level is actively influenced by withdrawals through the West Delaware Tunnel, based on water supply need. Under normal circumstances, water is continuously discharged downstream to the Delaware River."

Jan 1, 2016

By Harry Asche

Tunnels are frequently specified by owners to be designed to a structural code, often a bridge code. In the USA, AASHTO have created a tunnel code, based on structural principles, the AASHTO LRFD Tunnel Design Specification. The Load Resistance Factor Design method (LRFD) described in the AASHTO title is an approximation to the probabilistic design of structures, based on the independence of load and resistance. This methodology is well known to be problematic in geotechnical design, but it is widely used. The paper considers the difficulties of this approach and describes alternative approaches that would result in more appropriate designs for tunnels.

Jun 13, 2021

By Mark D. Fuhriman, Parham Khoshkbari, Robert Fosse

Drilled displacement piles are becoming an increasingly common deep foundation choice for their relatively simple installation methods, applicability to a wide range of subsurface conditions, and versatility. The installation method includes drilling and displacement of the soil followed by delivery of fluid cement grout under pressure, and placement of steel reinforcing to complete the pile. Because the installation method uses blind processes that do not permit direct observation of the pile, it is desirable to employ redundant testing tools to complement good construction techniques and inspection practices to ensure integrity of the piles. This paper examines the use of a range of integrity testing tools used for pile installations at a major office campus development. Because the integrity of a drilled displacement pile and its performance depend to a large extent on the skill and experience of the installation crew, the paper explores how use of multiple practical tools, including automated monitoring tools on the pile installation equipment, thermal integrity profiling, and high-strain dynamic testing, ensure structural integrity of the completed piles and how redundant integrity testing methods complement good construction and inspection practices add confidence in the quality of the foundation system.

Sep 8, 2021

By Alexander Scheuermann, Martin D. Larisch, David J. Williams

"Drilled displacement piles (DDP) have been used around the world for decades as foundation elements for structures and embankments. Typically the pile toes are designed to penetrate into stiff or dense soil formations to achieve sufficient base resistance. Recent research at The University of Queensland in Brisbane, Australia has discovered that the in situ stress conditions in stiff to hard clays is directly related to pile installation rates, which in turn are a function of the piling rig capacity and ground conditions. With adequate and constant pile penetration rates in situ stress conditions in the stiff to hard clay are increased by about 40%, resulting in significantly higher pile capacities. If pile penetration rates are too slow the in situ stress conditions are reduced considerably by remoulding and shearing of the clay, potentially causing reduced pile capacities. The paper presents the results of full-scale test piles at a stiff to hard clay site installed using different full-scale piling equipment.INTRODUCTIONDrilled displacement piling (DDP) is a piling technique in which a hollow stem, fitted with a purpose built displacement tool at the bottom, is drilled into the ground. Dissimilar to non-displacement piles, like Continuous Flight Auger (CFA) piles or conventional rotary bored piles drilled with kelly bars, the soil is not excavated during the DDP penetration process, but is displaced laterally and to a lesser extent vertically. The cavity created by the drilling tool is filled with highly workable concrete during the extraction process. The DDP technique is very economical providing high production rates and creating only marginal drill spoil, which has led to its increased global usage during the last decade. The typical DDP installation process is described in Figure 1."

Jan 1, 1900

By Michael L. Wayman

Native copper is copper which exists in nature in elemental, metallic form, rather than being chemically combined as is the case with the more usual oxides, sulphides, carbonates, etc. Several other metals, including gold, silver and platinum also occur in native form as do, rarely, iron, lead and mercury; a few naturally occurring native metal alloys, notably electrum (gold-silver) and tumbaga {gold-copper or gold-silver-copper) are also known. An analysis of the relative availabilities of native metals as nuggets in a useful size range111 shows native copper to be by far the most abundant of the native metals, exceeding both gold and silver by at least two orders of magnitude. While such an estimate is crude, it serves to illustrate why copper was one of the first metals to have been used by ancient peoples. Native copper is known to occur on all inhabited continents, although its exact occurrence and abundance in ancient times cannot be unambiguously determined because many surface deposits may have been totally exploited and are therefore no longer identifiable. It is clear, however, that native copper does or did occur in all areas inhabited by the early metal-using cultures, for example in the Andes, in Central America and in the Near East. It is remarkable that most of the world's native copper occurs in the deposits of the Lake Superior region, primarily on the Keweenaw Peninsula of northern Michigan and on Isle Royale, an island in Lake Superior some 50 miles north of the Keweenaw deposits. Canadian deposits of native copper are found in Newfoundland and Labrador, Nova Scotia, Quebec, Ontario, British Columbia, the Yukon and the Northwest Territories (on Victoria Island, Bathurst Inlet and the Coppermine River area). It was to locate the latter deposits that the explorer Samuel Hearne was sent overland from Hudson's Bay in 1770; they were also surveyed by Sir John Franklin's expeditions in the 1820s.

Jan 1, 1999

By M Franklin, C Puglisi, S Fitch

Implementation of a well planned and executed Management Operating System (MOS) can result in widespread improvements to operational performance but its success relies heavily on the investment by and engagement of the larger workforce with the project. Over the seven month period of the Telfer MOS project, significant improvements were achieved; a 20% increase in monthly hoisted tonnes from the open stope and sublevel cave operations and a 45% increase in square metres of ore extracted from the narrow vein operation. The Telfer MOS was undertaken with the intention that the project wasn’t solely about producing new tools, it hinged on the investment and behaviours of the personnel affected by these tools and alterations. To ensure that the project ran smoothly, the Byrnecut senior leadership team and their operators were heavily involved in the project’s development. In the initial stage, Telfer’s MOS project determined that the quality and accuracy of the information received in the form of radio calls to mine control and completed operator plods was questionable. This required an overhaul of the data collection and verification process in the form of altered operator plods, which was then cross referenced with the operator’s radio calls to mine control. Once the data collection and verification process was implemented, the Telfer team was then able to produce several tools with the aim of providing visibility to the data being captured and its implications. These tools allowed the mine foremen to determine whether equipment was being under-utilised and where they should focus their production efforts to meet monthly targets. Whilst the initial underground project is now complete, the implementation of MOS across the entire site is ongoing with significant operating improvements occurring.

Mar 15, 2021