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By J. B. Ackerman, J. D. Miller

Alunite [KA13(S04)2(OH)6] is a promising non-bauxitic aluminum resource, the domestic reserves of which are estimated to be 800 x 106 tons at 35 percent alunite. The major gangue mineral associated with alunite is quartz. The thermochemical process that has been developed for treatment of this ore does not provide for the initial removal of gangue prior to processing. In this regard, it may be desirable to concentrate the ore to gain significant technical and economic advantages. Experimental results indicate the effectiveness of an oleic acid flotation technique and exemplify the problems encountered in fine particles processing. These results show that the quality of separation studied as a function of temperature, collector addition, and depressant addition is dependent on the degree of liberation achieved during size reduction. At coarse grinds the quality of separation was limited by the presence of locked particles while for finer grinds where more extensive liberation is achieved, better separations were obtained. The degree of liberation for each size interval was determined by an SEM/energy dispersive x-ray technique and found to be independent of the extent of size reduction, suggesting that liberation occurs by indiscriminate fracture and not by detachment. Up to 89 percent liberation was realized for a minus 400 mesh grind. Under these circumstances, the quality of separation appears not only to be limited by the remaining locked particles, but, also, by contamination of the alunite concentrate with fine quartz gangue (< 2µm). The best separation for the minus 400 mesh grind was a rougher recovery of 88 percent with a grade of 65% alunite at 50°C.

Jan 1, 1980

By H. A. Stacy

THE ability of galvanized sheet steel to withstand severe bending is of very great importance as relates to all such sheet material which, in service, is not used in the flat condition in which it is purchased. A "bend-test" clause is found in, all specifications for material of this kind. In the attempt to draw up a specification for galvanized sheet steel the subcommittee of the Federal Specifications Board having this work in charge, soon found that there was a surprising lack of published data and apparently very little available from manufacturing sources upon which to sustain or reject the various requirements embodied in the tentative specification which, in turn, had been based largely upon other specifications submitted to the subcommittee for this class of material. Specifications from 25 sources were received; 10 Government specifications, 10 from private users of such material, and five from manufacturers. The main points raised were: (1) The minimum mandrel thickness, expressed in terms of the thickness of the sheet tested, over which sheets with different weights of coating can be bent 180°, without serious damage to the coating; (2) the minimum radius of curvature on the inside of the angle in 90°-bends in such material; (3) effect of double seaming on the coating; (4) uniformity in the thickness of coating over a sheet, particularly as relates to the results of bend tests. In view of the uncertainty existing, it was considered very desirable for the subcommittee to conduct a series of tests in order to secure reliable information.

Jan 10, 1926

By R. G. Fleck, W. R. Webb

Iron ore mining in the Adirondack region of northern New York dates back to the Revolutionary War. It is recorded that Benedict Arnold in his campaigns in the Lake Champlain area during the American Revolution utilized the local ores to produce armament and cannon balls. Through the efforts of early pioneers, the iron mining industry in northern New York gained impetus so that in the 1880&apos;s mines in the area accounted for nearly one fourth of the iron ore produced in the United States. Both magnetite and red hematite ores were mined during this period. With the discovery of the Lake Superior ores, the iron ore industry in New York started to decline and remained relatively unimportant until 1938. Modern day methods of mining and beneficiating sufficiently high tonnages of low-grade ores to justify the large expenditures for plant and equipment prompted a resurgence in northern New York mining. During the past several years, the production of iron ore from the Adirondack magnetites has greatly increased, and production which amounted to .6%, of the United States total during the 1918-1928 period (Mining and Metallurgy, November 1943) has been increased to 2.85% of the total in 1948. Today, Republic Steel is mining in the Port Henry-Mineville and Lyon Mountain areas; the

Jan 4, 1950

By F. R. Hensel

THE alloy under discussion is a nickel-silicon bronze and is one of many age-hardening or precipitation-hardening FIG. I.-EFFECT OF QUENCHING AND AGING TEMPERATURES ON HARDNESS OF TWO TYPICAL NICKEL-SILICON BRONZES, NO. 2351 AND No. 2362. copper-base alloys. The hardening con-stituent is a nickel-silicon compound.1 The quenching temperature necessary to pro-duce hardening by a subsequent aging treatment is a function of the composition and extends from about 700&apos;C. to ()50&apos;C.; the aging temperature range extends from 400° to 600°C. The work carried out by the authors of this paper was confined to cast alloys having compositions within the ranges of 1.5 to 3.00 per cent Ni; 0.4 to 0.75 per cent Si; balance, copper.

Jan 1, 1940

By A. A. Schweizer

A method to improve the quality of Magmont zinc concentrates to become acceptable feed to an electrolytic zinc refinery is described. The magnesia content of zinc concentrates produced was too high due to particle locking with sphalerite in coarse fractions. Regrinding the concentrates to a very fine particle size and then refloating the sphalerite was chosen to eliminate a sufficient amount of the magnesia to make the concentrates acceptable.

Jan 1, 1984

By T. B. Counselman

WHEN one thinks of Minnesota iron ore, one thinks of big open pits, where high- grade ore is simply scooped up with a power shovel, loaded into cars, and hauled away for shipment to the blast furnace. On the western end of the Mesabi range, however, are large tonnages of iron ore which contain too much silica to be used directly in the blast furnace, and these ores must first be concentrated to a purer form. The Mesabi range is about 100 miles long and a maximum of 3 miles wide. The iron formation, which in its unaltered form is called taconite: consists of a banded iron- bearing chert. Where the high-grade ore bodies occur, these have resulted from folding and cracking with sub- sequent leaching out of the silica, leaving the iron oxide behind. The big open pits and the underground mines are situated in these concentrations.

Jan 1, 1941

BENEFICIATION AND CONCEN&apos;TRATION; FROTH FLOTATION U.S. 4,069,144 - In the froth flotation beneficiation of phosphate rock using at least an acid flotation step and an amine flotation step, the crude ore is dried either during transport or storage or by air circulation immediately prior to classification, and the dried ore mixed with water and classified prior to flotation The preliminary drying substantially eliminates the usual problems with clay slimes G. C. Johnson and A. E. Schweizer, assigned to Mobil Oil Corp. Jan 17. 1978. 4 pp (209- 11) . Filed 1 1-19-75 (633,535).

Jan 1, 1979

US 4,132,635 -In the froth flotation beneficiation of low- grade siliceous iron oxide ore, an aqueous pulp of undeslimed ore is conditioned first with a reagent formed by incorporating a water-soluble polyvalent metal salt into an aqueous solution of sodium silicate and then with oleic acid or other anionic collector and optionally pine 011 or other frother. The conditioned pulp is subjected to flotation to concentrate Iron oxide values in the froth D. C. Yang, assigned to Michigan Technological University Jan 2, 1979 7 pp (209-1 66) Filed 1-1 3-77 (759,094) Drawing below.) [ ] US 4,133,038-In the froth flotation beneficiation of copper sulfide ore or other ores, an aqueous suspension of a mineral sample of uniform grain size and composition is conditioned with a strongly adsorbable collector in an amount which is a fraction of the amount sufficient to create a monomolecular layer on the mineral grains, and the conditioning continued until the entire amount of collector is adsorbed The conditioned pulp is subjected to flotation, the floated particles separated at timed intervals, and the flotation rate coefficient determined. By varying the degree of adsorption in repeated treatments, the dependence of the flotation rate coefficient on the degree of adsorption may be determined A Nieml Jan 2, 1979 10 pp (364-502) Filed 12-7-77 (858,353) Priority Finland, 5-26-75 (75/1,525) Same: British 1,533,723, dated Nov 29, 1978 Same Canadian 1,065,066, dated Oct 23, 1979 US 4,133,746System and method for maintaining substantially steady state conditions in the froth flotation beneficiation of copper ore, molybdenum ore, or other metal ores The mass flow of flotation concentrate from the cell is monitored continuously, and the rate of admission of aeration air into the pulp in the cell is varied inversely with respect to variations in the mass flow control of rougher flotation cells is accomplished with a single valve G W Dopson, assigned to Magma Copper Co Jan 9, 1979 6 pp (209-1) Filed 11- 23-76 (744,306

Jan 1, 1980

US 4,186,083-An improved collector for use In the froth flotation beneficiation of phosphate rock, barite, fluorspar, scheelite or Iron oxide ore comprises 70 to 99.9% by weight of tall oil fatty acid or the like and the remainder a described anionic perfluorosulfonate compound. Reagent consumption is lessened, and high recovery at high grade is effected. S.S. Wang, E.L. Smith, Jr., and E. F Huliganga, assigned to American Cyanamid Co. Jan 29, 1980. 4 pp. (209-166). Filed. 12-21-77 (863,034).

Jan 1, 1982

US 4,181,703-Removal of magnesium impurity from phosphate rock. Crushed screened ore containing more than 0.3% by weight of magnesium is slurried with sea water, acidified with sulfuric acid to a pH value not lower than 2 5, and filtered and washed before the neutralization point is reached. W. Wengeler, F. Wolstein, and E. Hoffman, assigned to Uhde G.m.b.H. Jan. 1, 1980 4 pp (423-167) Filed: 11-18-77 (852,918)

Jan 1, 1982

By E. H. Tenney

A discussion of the probable future use of coal for power development involves the study of several basic factors, such as future demand for power, the quantity and availability of fuels in direct competition with coal, the price of coal, and a closely related factor—the efficiency and cost of fuel utilization. Predictions based on purely statistical analyses of past coal consumption have definite limitations. For example, statistics showing the relation between coal utilization and total energy consumption from all sources between the years 1890 to 1930 indicate that during that period the energy consumption per person in the United States increased five times, while the coal consumption per person increased only twice1, and there has been an actual decrease in per capita coal consumption since 1920. Figures such as these, compiled by authentic agencies, emphasize the need for caution in attempting estimates as to the future use of coal, and, incidentally, would seem to offer little basis for optimism in the coal industry. They also suggest the value of analyzing broadly the part played in the past by the related factors of power consumption, competitive fuels, coal prices and the efficiency of utilization. Proper weight must also be given in such a study to the present status and limitations of power-plant developments, arid to the question of what the coal industry itself can do to further its own interests arid influence the consumption of its product.

Jan 1, 1936

By E. H. Tenney

A discussion of the probable future use of coal for power development involves the study of several basic factors, such as future demand for power, the quantity and availability of fuels in direct competition with coal, the price of coal, and a closely related factor—the efficiency and cost of fuel utilization. Predictions based on purely statistical analyses of past coal consumption have definite limitations. For example, statistics showing the relation between coal utilization and total energy consumption from all sources between the years 1890 to 1930 indicate that during that period the energy consumption per person in the United States increased five times, while the coal consumption per person increased only twice1, and there has been an actual decrease in per capita coal consumption since 1920. Figures such as these, compiled by authentic agencies, emphasize the need for caution in attempting estimates as to the future use of coal, and, incidentally, would seem to offer little basis for optimism in the coal industry. They also suggest the value of analyzing broadly the part played in the past by the related factors of power consumption, competitive fuels, coal prices and the efficiency of utilization. Proper weight must also be given in such a study to the present status and limitations of power-plant developments, arid to the question of what the coal industry itself can do to further its own interests arid influence the consumption of its product.

Jan 1, 1936

By John T. Crawford

Much has been written of late regarding the flotation of coal as a means of reclaiming the valuable portion of the fines encountered in nearly all methods of coal preparation. Whether the process be wet or dry, whether the dust be sent through the entire process or removed prior to the cleaning by some such method as screening or aspiration, one of the final products consists of a considerable proportion of — 48-mesh material. The percentage of this —48-mesh material depends upon the mining method, transportation, storage, and method of preparation. The tonnage of this dust material ranges from 1 to 10 per cent of the total output of the cleaning plants. Four methods of disposal are available for this coal: 1. Disposal with the refuse from the plant. 2. Addition, after being reclaimed from the wash water, or dust collectors, without cleaning to the larger sizes. 3. Separate disposal as a pulverized fuel. 4. Cleaning so that addition to the larger sizes benefits the product as a whole. It is also true that flotation in one form or another is the only known way to effectively clean this material. While some processes do a reasonable cleaning job down to and including +l00 mesh, by far the greater majority stop at or short of the + 48-mesh size. Much of the literature on coal flotation passes by the fred pulp density and size by merely stating that the feed varies from 20 to 30 per cent solids and that the size range is from — 1/4 in. or — 1/8 in. to 0. Small wonder then that some operators with entirely different conditions, and not knowing the machine capacity, throw up their hands in despair when flotation is mentioned. Too much parallel is drawn between flotation methods as applied to ores and as applied to coal, to the detriment of the latter. In the flotation of metalliferous ores the feed pulp density ranges from 20 to 30 per cent solids, depending upon the amount of mineral to be floated and upon the size analysis. Thus where 2 to 5 per cent of the

Jan 1, 1936

By John T. Crawford

Much has been written of late regarding the flotation of coal as a means of reclaiming the valuable portion of the fines encountered in nearly all methods of coal preparation. Whether the process be wet or dry, whether the dust be sent through the entire process or removed prior to the cleaning by some such method as screening or aspiration, one of the final products consists of a considerable proportion of — 48-mesh material. The percentage of this —48-mesh material depends upon the mining method, transportation, storage, and method of preparation. The tonnage of this dust material ranges from 1 to 10 per cent of the total output of the cleaning plants. Four methods of disposal are available for this coal: 1. Disposal with the refuse from the plant. 2. Addition, after being reclaimed from the wash water, or dust collectors, without cleaning to the larger sizes. 3. Separate disposal as a pulverized fuel. 4. Cleaning so that addition to the larger sizes benefits the product as a whole. It is also true that flotation in one form or another is the only known way to effectively clean this material. While some processes do a reasonable cleaning job down to and including +l00 mesh, by far the greater majority stop at or short of the + 48-mesh size. Much of the literature on coal flotation passes by the fred pulp density and size by merely stating that the feed varies from 20 to 30 per cent solids and that the size range is from — 1/4 in. or — 1/8 in. to 0. Small wonder then that some operators with entirely different conditions, and not knowing the machine capacity, throw up their hands in despair when flotation is mentioned. Too much parallel is drawn between flotation methods as applied to ores and as applied to coal, to the detriment of the latter. In the flotation of metalliferous ores the feed pulp density ranges from 20 to 30 per cent solids, depending upon the amount of mineral to be floated and upon the size analysis. Thus where 2 to 5 per cent of the

Jan 1, 1936

By Allen J. Johnson

With a realization of the rapidly increasing importance of automatic stokers as a medium for domestic heating, the Anthracite Institute Laboratory has conducted extensive investigations, over a period of several years, to determine the various outstanding characteristics of stoker design and performance. The purpose of this paper is to summarize these findings as a guide to current practices. Stokees Investigated One or more models of the underfeed stokers listed below were included in the various phases of this investigation: Beckley Gilkoal Burnwell Iron Fireman Combustioneer Motor Stokor Electric Furnace Man Norristown Super-stoker Erie Heat Generator Whitney Fire Ball (Tests Incomplete.) Fuel Saver Principles of Construction.—The operating principle of the leading makes of underfeed stokers is similar (Fig. 1). A plunger1 or slowly revolving worm2, conveys the buckwheat or rice sizes of anthracite to the center of a specially constructed tuyere pot where air is admitted to the coal through suitable ports of varying design. As the fuel burns, it is slowly forced to the outside circumference of the tuyere by the pressure of the incoming coal; eventually the ash falls over the edge of the pot, either entirely by gravity or aided by mechanical sweepers. In at least one model, the entire firepot revolves. While various special details have been included in the design of a number of stokers, they do not affect the general principles as described above, and therefore have not been included in this discussion.

Jan 1, 1936

By Allen J. Johnson

With a realization of the rapidly increasing importance of automatic stokers as a medium for domestic heating, the Anthracite Institute Laboratory has conducted extensive investigations, over a period of several years, to determine the various outstanding characteristics of stoker design and performance. The purpose of this paper is to summarize these findings as a guide to current practices. Stokees Investigated One or more models of the underfeed stokers listed below were included in the various phases of this investigation: Beckley Gilkoal Burnwell Iron Fireman Combustioneer Motor Stokor Electric Furnace Man Norristown Super-stoker Erie Heat Generator Whitney Fire Ball (Tests Incomplete.) Fuel Saver Principles of Construction.—The operating principle of the leading makes of underfeed stokers is similar (Fig. 1). A plunger1 or slowly revolving worm2, conveys the buckwheat or rice sizes of anthracite to the center of a specially constructed tuyere pot where air is admitted to the coal through suitable ports of varying design. As the fuel burns, it is slowly forced to the outside circumference of the tuyere by the pressure of the incoming coal; eventually the ash falls over the edge of the pot, either entirely by gravity or aided by mechanical sweepers. In at least one model, the entire firepot revolves. While various special details have been included in the design of a number of stokers, they do not affect the general principles as described above, and therefore have not been included in this discussion.

Jan 1, 1936

By P. Nicholls

Though the burning of fuels extends far back into antiquity, and though fuel beds are the most common and widely distributed example of chemical actions and engineering practice, there has been little attempt to group fuel beds by types or to define the principles associated with them. This paper does not profess to cover completely the subject of fuel beds. It suggests some of the over-all principles of the two more common types. No new investigational data are included, but the deductions are largely based on a recent publication of the U.S. Bureau of Mines&apos;. Definition of Types There are three primary types of fuel beds: (I) Underfeed, in which the fuel and the air move in the same direction; (2) overfeed, in which the fuel and the air move in opposite directions; (3) crossfeed, in which the fuel and the air move at right angles to each other. The principle that fixes the type is the relation between directions of the flow of fuel and of air. Fig. 1 shows the three types diagrammatically. All other types are compounded of these three in a simple or more or less complex manner. It does not follow that these three type designations are limited to the methods used in representing them in Fig. 1; they may be turned in any direction, and as long as the relative directions of the fuel and air are the same the type is not changed. For example, A as shown .resembles a pot-type stoker, but the air and fuel can move downward as in the so-called smokeless heating boiler furnace. Also, C can be placed horizontal, as in chain-grate stokers. For this reason, the terms used to designate the three types are not all that could be desired; more logical ones could be coined, but those used probably are satisfactory until the discussion of fuel-bed types becomes more common.

Jan 1, 1936

By P. Nicholls

Though the burning of fuels extends far back into antiquity, and though fuel beds are the most common and widely distributed example of chemical actions and engineering practice, there has been little attempt to group fuel beds by types or to define the principles associated with them. This paper does not profess to cover completely the subject of fuel beds. It suggests some of the over-all principles of the two more common types. No new investigational data are included, but the deductions are largely based on a recent publication of the U.S. Bureau of Mines&apos;. Definition of Types There are three primary types of fuel beds: (I) Underfeed, in which the fuel and the air move in the same direction; (2) overfeed, in which the fuel and the air move in opposite directions; (3) crossfeed, in which the fuel and the air move at right angles to each other. The principle that fixes the type is the relation between directions of the flow of fuel and of air. Fig. 1 shows the three types diagrammatically. All other types are compounded of these three in a simple or more or less complex manner. It does not follow that these three type designations are limited to the methods used in representing them in Fig. 1; they may be turned in any direction, and as long as the relative directions of the fuel and air are the same the type is not changed. For example, A as shown .resembles a pot-type stoker, but the air and fuel can move downward as in the so-called smokeless heating boiler furnace. Also, C can be placed horizontal, as in chain-grate stokers. For this reason, the terms used to designate the three types are not all that could be desired; more logical ones could be coined, but those used probably are satisfactory until the discussion of fuel-bed types becomes more common.

Jan 1, 1936

By E. G. Bailey

The bituminous coal industry faces a real problem, if it desires to retain the position in the power-generation field to which it is economically entitled. More power is probably produced today for electrical energy, for steam-driven and steam-heating industries and processes, for transportation by rail, water, highway and air, collectively, than ever before, and yet the total bituminous coal production has decreased about 38 per cent, from 575,000,000 tons in 1926 to 357,500,000 tons in 1934. It is not the intention of the writer to recommend coal as a fuel for automobiles and airplanes, but rather to point to these forms of transportation as being responsible in a very measurable degree for reducing the coal consumed by railroads. Petroleum products may still further reduce consumption of locomotive fuel through the extension of the use of Diesel-driven trains. Oil-burning steam-driven locomotivcs are replacing coal in some places, where railroads operating high-speed passenger trains are willing, temporarily at least, to pay a premium for the fuel that is low in ash and produces less smoke and practically no cinders. In the navy and ocean-going passenger ships, oil is so firmly established, and has such definite advantages over coal as formerly fired, in steaming radius, in ease of bunkering, cleanliness, and reduction in firing labor, that very outstanding developments in the handling and burning of coal will be rcquired in order to replace oil. For freighters on the Great Lakes, coal is the logical fuel, but there is great and immediate need of radical improvements in its use, else that market also may be lessened. It is not within the scope of this paper to discuss in detail bituminous coal for either locomotive or marine use, but, rather, generation of power in stationary plants, consisting of electrical generating stations and that very large group of miscellaneous industrial plants, such as paper, rubber, textile, steel and other industries that use electrical, mechanical, and steam power, derived from either hydro or some form of fuel.

Jan 1, 1936

By E. G. Bailey

The bituminous coal industry faces a real problem, if it desires to retain the position in the power-generation field to which it is economically entitled. More power is probably produced today for electrical energy, for steam-driven and steam-heating industries and processes, for transportation by rail, water, highway and air, collectively, than ever before, and yet the total bituminous coal production has decreased about 38 per cent, from 575,000,000 tons in 1926 to 357,500,000 tons in 1934. It is not the intention of the writer to recommend coal as a fuel for automobiles and airplanes, but rather to point to these forms of transportation as being responsible in a very measurable degree for reducing the coal consumed by railroads. Petroleum products may still further reduce consumption of locomotive fuel through the extension of the use of Diesel-driven trains. Oil-burning steam-driven locomotivcs are replacing coal in some places, where railroads operating high-speed passenger trains are willing, temporarily at least, to pay a premium for the fuel that is low in ash and produces less smoke and practically no cinders. In the navy and ocean-going passenger ships, oil is so firmly established, and has such definite advantages over coal as formerly fired, in steaming radius, in ease of bunkering, cleanliness, and reduction in firing labor, that very outstanding developments in the handling and burning of coal will be rcquired in order to replace oil. For freighters on the Great Lakes, coal is the logical fuel, but there is great and immediate need of radical improvements in its use, else that market also may be lessened. It is not within the scope of this paper to discuss in detail bituminous coal for either locomotive or marine use, but, rather, generation of power in stationary plants, consisting of electrical generating stations and that very large group of miscellaneous industrial plants, such as paper, rubber, textile, steel and other industries that use electrical, mechanical, and steam power, derived from either hydro or some form of fuel.

Jan 1, 1936