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By Francis Foley

IN THE first report1 disks of steel of- known composition and history were exposed, under carefully prescribed conditions, to impacts of explosion products resulting from the explosion of 50-gm. charges of explosives having well-determined rates of detonation, or to, impacts of a weight of known mass, falling through measured distances. There were available at the Bureau of Mines Experiment Station five explosives, having rates of detonation of 5716, 4470, 3190, 2296, and 1523 meters per second. It being desired to continue this exposure downward, and no explosives with a lesser rate of detonation being at hand, resort was had to the impact of a falling weight, the differences in the velocity of impact being attained by varying the height from which the weight was allowed to fall. It was expected by this means to demonstrate experimentally that the development of Neumann bands was determined by the suddenness of the deformation of the metal in which they were produced. But while progressive deformations were obtained with the explosive charges, the falling-weight method failed because the tup was progressively deformed, also the disks were so flattened as to be unfit for metallographic examination. A return, therefore, has been made to the use of explosives as the source of energy, an air-gap being interposed between the charge of explosive and the disk, as the effect diminishes as the function of the distance between the charge and the object on which the products of its explosion, or the shock wave from its detonation, impinge. The details of the arrangement of the tests by the air-gap method were the same as those described by Foley and Howell,2 except that after the system had been set up and the desired apparent specific gravity for the explosive

Jan 2, 1926

By Takahide Wakamatsu, Douglas W. Fuerstenau

Contact angles on alumina are related directly to the adsorption of alkyl sulfonates at the solid-water interface and thus are strongly controlled by the pH of the solution, the concentration of surfactant, and the number of carbon atoms in the alkyl chain. As the pH of the solution is increased above the point of zero charge, sulfonate adsorption ceases and alumina remains hydrophilic. However, in neutral and acidic solutions, contact angles increase markedly in magnitude when the adsorbed sulfonate ions form hemimicelles at the solid-water interface. Under a wide variety of solution conditions, a limiting value of the contact angle is attained at the point of reversal of the zeta potential. Finally, contact angle phenomena are empirically correlated with the sulfonate adsorption density through the work of adhesion.

Jan 1, 1974

By E. A. Anderson

IN another paper1 the writer has shown that the low permissible maximum fiber stress in a loaded zinc sheet demands a much closer support spacing than is used for steel. The limiting fiber stress in 13-gage (0.032 in.) sheets having a 1-in. depth of corrugation was found to be about 5000 lb. per sq. in. on a 37-in. span under a load of 40 lb. per sq. ft. Corrugated steel sheets are commonly laid with spans varying from 48 to 60 in. In order to increase the span in 13-gage zinc to 54 in. (a common spacing) the metal must be capable of withstanding, under long-continued loading, a maximum fiber stress of about 10,000 lb. per sq. in. This is known to be impossible with unalloyed zinc. In this paper the writer describes a series of experiments leading up to the development of an alloy capable of safely sustaining this fiber stress. The effect of alloying on the slow creep of zinc was studied by means of static tensile tests, accurate determinations of apparent elastic limits and finally by means of loading tests on full-size roof sections. Two industrial buildings roofed with alloyed zinc sheets on spans involving fiber stresses in excess of 10,000 lb. per sq. in. have been under observation for over two years without signs of sagging.

Jan 1, 1929

By John L. Lamont, Walter Crafts

STUDIES of the effect of composition of steel on hardenability by Grossmann,1 and as-quenched hardness by Field2 and by the authors,3 have made it possible to predict the results of quenching when the composition and cooling rate are known. In order to extend the application of the hardenability calculation to the quenched and tempered condition in which steel is finally used, a survey has been made of the hardness changes caused by tempering. From this study a method has been developed for the prediction of hardness and tensile strength of steel in the tempered condition. The method of calculation was developed from Rockwell C hardness tests on quenched and tempered Jominy specimens and is expressed in Rockwell C hardness units. It is of an additive type in which the degree of softening from as-quenched hardness is estimated. Tempered properties may be calculated within about plus or minus 5 Rockwell C hardness or plus or minus 15,000 lb. per sq. in. tensile strength. This degree of accuracy is less than that necessary for the control of heat-treatment, but is adequate for the comparative evaluation and selection of alloy steels. The formula indicates that tempered hardness is primarily dependent on as- quenched hardness and, as in the hardening reaction, the progress of tempering is controlled mainly by the carbon content- Alloys tend to retard softening by a secondary hardening mechanism in which the alloy appears to migrate from ferrite to the carbide phase. The factors for the effects of alloys in tempering vary so much from the effects of alloys in hardening that different steels of equivalent hardenability may, after lie heat-treatment, differ considerably in tensile strength. PROCEDURE In developing the method for calculating tempered Rockwell C hardness, simple and complex steels were tested over a range from 0.08-to 0.65 per cent carbon and up to 2.68 per cent manganese, 2.18 silicon, 3.50 chromium, 4.94 nickel, and 1.06 molybdenum. The steels were made as small induction-furnace heats at the Union Carbide and Carbon Research Laboratories, Inc. The accuracy of the method was finally checked on a variety of carbon, low-alloy and high- alloy types of heat-treating steels produced under commercial conditions. The method was based on a study of tempered Jominy bars, and its validity was tested by correlation with the center hardness and tensile strength of oil-quenched and tempered bars from ¼ to 4 in. in diameter. The method of calculation was derived from the differences in Rockwell C hardness between as-quenched and quenched and tempered Jominy specimens. Prenormalized Jominy hardenability specimens quenched from a normal temperature for austenitization were used to obtain a range of as-quenched Rockwell C

Jan 1, 1946

For some time attempts have been made to improve drilling efficiency (and therefore reduce costs) by introducing certain reagents to the flushing medium. Much of this interest is the result of the Russian book, Hardness Reducers in Drilling, by Rehbinder, Schreiner, and Zhigach, published in 1944. Before embarking on full-scale drilling tests, it was decided to investigate the effects on the tensile strength; these results would help in the selection of the proper reagent and its optimum concentration. Selection of Tensile Strength Testing A drilling system basically performs two separate operations: 1) Breakage of rock. 2) Removal of the broken pieces of rock. Both affect drilling and drill performance but are distinct and separate phases of the process. Causing rock to break during drilling is a matter of generating sufficient stress with a drill bit to exceed the strength of the rock. This strength of the rock may be termed its drilling strength; it is not equivalent to any of the well-known strength parameters. Various criteria have been employed to measure the efficiency of a given drilling system or for comparing different systems and one of the most important criteria is "speed of drilling." Speed of drilling is a function of drilling strength of the rock. Many researchers have tried to correlate the speed of drilling with the strength properties of rock and compressive as well as tensile strength values have been found to give reasonable correlation." As the strength of rock drilled increases, speed decreases. As the Brazilian testing requires the least amount of core, this test was selected. Material Tested Broken Hill lode quartzite has been used in these tests. It is composed chiefly of quartz with varying amounts of sericite, pyrrhotite, chalcopyrite, galena, and garnet. The total porosity of this quartzite is about 11%.

Jan 1, 1973

By R. W. Smith

An amine used as a collector in a commercial flotation process is usually a rather impure substance. The differences in ionization constants and solubilities of various amines undoubtedly affect their collecting power or strength. This investigation explores some of the differences among several amines of similar (although not precisely the same) chain lengths. An attempt is made to relate the differences to both observed contact angle and Hallimond tube flotation behavior in quartz systems.

Jan 1, 1974

By Hugh O?Neill

IN PREVIOUS papers,1 the author has reported the results of experiments on the straining in tension of a single crystal test piece, about 0.6 in. long, of vacuum-melted electrolytic iron containing 1.8 per cent. of silicon. The crystal was originally in the "as cast" condition, and was stressed slowly along a tetragonal axis so that slipping along conjugate gliding planes finally transformed the original cylindrical portion into a pair of fracture wedges. One of these fracture wedges was sectioned along the stress axis in a plane at right angles to the edge of the wedge. A metallographic study of this plane of -section led to the conclusion that slip had taken place in the (111) direction along (112) planes making a V shape with the stress axis. The present paper describes the results of scratch-hardness tests conducted on the same section, in order to determine the distribution of strain hardness therein, followed by annealing, and considers the resulting variations in hardness. These observations supplement those made by Krivobok2 on similar material reduced 25 per cent. by hammering (i. e., by impact) in the cold. In order to investigate ageing effects, two small crystals of the same alloy were also tested.

Jan 1, 1928

By H. F. Silliman, Daniel R. Hull, Earl W. Palmer

THE brass-rolling industry has not had a great deal of experience with antimony in its product. There have been some recent excursions with antimony as a corrosion inhibitor in tubes, but in sheet brass it has been regarded with apprehension and generally avoided. This is not to say that [ ] contaminations have never occurred, and probably a great many brass mill men have had their own ideas on the effect of such contamination. Our own views were based upon certain experiences some years ago with strip castings that split lengthwise in the early stages of rolling. The nature of this splitting is shown in Fig. I, from a photograph taken in 1922 as a record of 20 bars of 65-35 common brass made with an antimonial brand of copper. These bars were cast 6 ¾ in. wide by 1 in. thick by 45 in. long. In the first pass through the rolls, 19 of the 20 split lengthwise throughout their length, while each half curved outward in a wide arc as it emerged from the rolls. [ ] In those days, if splitting was not a frequent occurrence, it was not unfamiliar. One can recall periods of short duration when large amounts of common brass would behave in this way. There was nothing imaginary about these spells. The affected metal would split lengthwise in the breaking rolls, and no maneuvering of mill practice made any difference. The condition would descend like a plague, demoralize the mill for several days, and disappear. It is doubtful if anyone knew the cause-however many explanations may have been current. In 1921 a quantity of split brass was traced to the use of fired small-arms

Jan 1, 1943

By P. B. Bucky

IN previous publications1 it was shown that a scalar model of any weighty structure, where the stresses produced are mainly due to gravita-tional forces, will behave similarly to its prototype if the model and proto-type material are the same arid the model is placed in a centrifugal field of force (substituted for the gravitational field) which has been increased in the same proportion as the linear model scale is decreased. This principle is now being applied to a study of the behavior of mine structures in an attempt to determine the laws that control them. The importance of using models as a means of solving mining problems has been discussed previously, yet it may be well to reiterate here that this method of research and type of solution have been productive of far-reaching results in other engineering fields, notably those of hydraulics and aerodynamics. Model research is a comparatively cheap and time-saving method of checking practical experience. Up to the present time the best guide to what will happen underground has been the judgment of the man who has observed most and been longest acquainted with the local conditions. His experimental work underground is limited by the elements of cost, time and danger, while failure is seldom permissible. In a model, as in a test tube, all elements that affect the solution of a problem are under definite control. Each element may be varied independently at will and its effects noted. Experimental work on a small-scale model may there¬fore be performed at a comparatively small expenditure of time and money, instead of on a full scale in the mine, where the cost, time, and danger elements are necessarily great. The experiments described in this paper are to be considered as part of a progress report and a continuation of Technical Paper 425. One object of the research program is to make each experiment point the way for further research on that particular phase of the general problem. The results and conclusions presented here are therefore not to be considered as final, but are to be interpreted as

Jan 1, 1933

By K. S. Seljesater

SINCE the development of dispersion-hardenable lead-antimony alloys1 in the laboratories of the Western Electric Co., Inc., studies have been made of the effect of various third constituents on these alloys.2 This paper covers a study of the effect of small amounts of arsenic. This element is important since it occurs as an impurity in many commercial antimonial leads and the results obtained are particularly interesting as indicating a class of addition agents which exert a stabilizing effect on dispersion-hardened alloys. EXPERIMENTAL In order to-study the effect ,of increasing amounts of arsenic, a series of alloys were made up containing 1 per cent. antimony, and arsenic varying from 0. to 0.10 per cent., the balance Doe Run lead (99.997 per FIG. 1..-CHANGE OF MICRO-BRINELL HARDNESS WITH TIME OF 1 PER CENT. LEAD-ANTIMONY ALLOY. cent. lead). The alloys were cast into bars 1 ½ in. wide by ¾ in. thick and cold-rolled to about 1/8 in. thickness. Three samples of each composition were annealed 1 hr. at 225° C. and quenched in water. One set was aged at room temperature, one at 50° C., and the third at 100° C., the

Jan 1, 1929

By R. A. Cummings, N. N. Moebs, M. M. Singh

Disintegration of the immediate shale roof in coal mines interferes with ventilation, production, and safety. The effect is seasonal and correlates with high levels of moisture in the intake ventilation air. Disintegration, though not completely understood, is caused by shale dilation and weakening upon exposure to atmospheric moisture. Fluctuating moisture conditions are particularly deleterious, but may be at least partially controlled by tempering the air before it is brought to the working places. Disintegration of shale roof is progressive loosening of chunks or slabs or roof shale, which fall to the floor. Bolts are left dangling or are connected to the roof by a column of loose rock. Posts are rendered ineffective. Passage of ventilation air and personnel is restricted by piles of fallen material on the floor. Shale disintegration as it occurs in mine roofs does not appear to have much in common with slaking, such as is measured in slake-durability tests, which results in the failure of certain shales when exposed in embankments or foundations. A two-year program was conducted on behalf of the US Bureau of Mines, incorporating field and laboratory analysis of deterioration. During this study, a. survey was conducted of underground mining operations in the Illinois Basin and Appalachia. In all, 47 mines in six different coal seams were identified as possibly having roof deterioration problems pertinent to the study. Of these, the No. 1 Mine of the Valley Camp Coal Co. near Triadelphia, WV was selected for detailed study. This mine uses conditioning entries, workings where raw intake air is routed before reaching the key haulageways. Deterioration is to be confined to the conditioning chambers. The approach adopted to study the deterioration problem was to measure atmospheric moisture in the mine, determine shale behavior in the laboratory under various moisture conditions, and measure mine roof behavior that could be correlated with atmospheric moisture observations. The following tasks were performed: • Atmospheric baseline data were collected, consisting of airflow measurements, continuous monitoring of the mine and surface atmospheric conditions using a sling psychrometer. • Roof deterioration was documented through measurement of roof convergence (sag), mapping of roof conditions, collection of fallen and rashed material and measurement of roof height increase and photographic logging. An infrared scanner was also tried, but not found useful. • The behavior of shale under various moisture conditions was determined in the lab through tests of shale expansion, natural moisture content, moisture uptake capacity at various humidities, and static (immersion) slaking.

Jan 1, 1984

By K. J. Reid, H. A. Lex, I. Iwasaki, K. A. Smith

The effects of autogenous grinding and conventional grinding on the floatabilities of copper-nickel sulfides from Duluth gabbro were investigated. At the same mesh-of-grind copper, nickel, and cobalt recoveries were higher and residual sulfur in the flotation tailings was lower with the autogenously ground pulps. With the ball-mill ground pulps the residual sulfur in the tailings could not be lowered to the level attained by the autogenously ground pulps even at increased levels of the collector addition. From mineralogical examinations of concentrate and tailings samples, an electrochemical interaction between grinding media and sulfide minerals was thought to have a greater effect on sulfide mineral flotation behavior than the breakage characteristics of the ore samples in these two types of mills.

Jan 1, 1984

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of quartz with oleic acid as collector and barium, calcium, aluminum, iron, and tin as activators were studied using a simple vacuum-flotation technique in glass-stoppered graduates. The detailed study of barium activation led to an interpretation based on ideal Langmuirian chemisorption.

Jan 1, 1950

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of quartz with oleic acid as collector and barium, calcium, aluminum, iron, and tin as activators were studied using a simple vacuum-flotation technique in glass-stoppered graduates. The detailed study of barium activation led to an interpretation based on ideal Langmuirian chemisorption.

Jan 5, 1950

By J. M. Lovejoy

Tests are described that show that back pressure on flowing wells is a waste rather than a conservation of natural forces. Stop-cocking, however, gives encouraging results. VARIOUS estimates have been made as to the percentage of oil left in a field after the wells have become so small that it is no longer practical to produce them. Engineers have given the matter much study and can substantiate their figures by data taken from fields from the Appalachians to California. The average oil sand has a porosity of about 20 per cent., which gives a capacity per acre-foot of approximately 1500 bbl. The sand thickness in Oklahoma pools averages 20 ft. With 20 per cent. porosity and a 20-ft. sand thickness, the capacity per acre is 30,000 bbl., yet these pools will seldom yield more than 5000 bbl. to the acre. These figures support the theory that at least 50 per cent. of the oil remains in a sand after all known methods to recover it have been used. Certainly we can never recover all the oil, unless in years to come oil becomes so rare and yet so necessary that the price will justify sinking shafts into the abandoned fields and regular mining methods of drifting and stoping. However, with improved methods of production and conservation of the natural agencies of expulsion, we should be able to increase recovery. It is with this in mind that this paper, relating to the effect of back pressure on wells, is presented. Except in the fields where production is caused by hydrostatic pressure, the chief agency for getting, oil out of the sand into the hole is the gas that occurs with the oil. After the pressure has declined, probably gravity also is a factor, but not an important one. With a given amount of oil in a sand and a given amount of gas occurring with the oil, the ratio of gas volume per barrel of oil is the key to the ultimate recovery from that sand. Our efforts should be along lines that will, lower this ratio and make the gas, the agency given us by nature, do its work better and yield more of the oil, of which it is a part.

Jan 1, 1924

By F. B. Eiseman

IT is desired -to determine the effect of the extent of bank repairs on the final slag volume in acid electric steel-melting practice. It is understood that the repairs stud- TABLE I-Summary of Effect of Bank Repairs on Slag Volume [ ] ied here are necessary and the amount of sand added is that needed to maintain hearth and banks in a satisfactory condition. In this way the effect of repair materials on the amount of slag tapped would be found with a reasonable degree of accuracy. Ten heats were made for this study with careful attention to a uniform charge. The steel was the usual grade B and melting was carried out in a 3 1/2-ton top-charge Lectromelt furnace. Melting practice in all cases was the same-complete oxidation, with recarbonization by means of low-silicon pig iron.

Jan 1, 1947

By W. M. Duncan, F. S. Kendorski, C. V. Jude

After shotcrete had been in use for a short time al the Climax Mine of the Climax Molybdenum Co., Climax, Colo., it was noted that regular longhole undercutting blasts would severely damage or detach slusher drift shotcrete linings. If this were to be a usual occurrence, the widespread application of shotcrete would have to be reexamined or abandoned. Concrete drift linings are affected less by blasting because of occasional significant gaps between the placed concrete and rock and the greater thickness of poured-in-place linings. Research Project Organized A research project was organized to determine: 1) the seriousness of the problem, 2) more complete in-use shotcrete strength data, and 3) possible solutions.

Jan 12, 1973

By J. A. Bowers

THIS investigation of the effect of bottom shape and life on slag volume was carried out in two Lectromelt top-charge furnaces whose rated capacity is 1000 lb per hour. Unfortunately, just as the work [ ] was started, our steel tonnage was reduced approximately one half, therefore we did not accumulate enough data from which to draw any definite conclusions. Furthermore, the life of the linings in these furnaces was greatly decreased by intermittent operation, which was a further handicap in making a study of this kind. The weight of the heats from which the data were taken varied 1200 lb but all the information was corrected to the standard weight charge for these furnaces of 4500 lb. Almost all the heats were plain carbon; a few contained a small percentage of added copper.

Jan 1, 1947

By H. Sato, R. J. Lipp, I. Iwasaki, K. A. Smith

Selective desliming holds much promise for upgrading low-grade, finely disseminated iron ores that are not readily amenable to conventional flotation. The process is extremely sensitive to the presence of calcium and magnesium ions that are in process water or are released by constituent minerals. The effects of these two alkaline earth ions on quartz were compared through streaming potential measurements, flocculation and cationic flotation tests, abstraction tests and scanning electron microscope studies. Calcium ion, adsorbed as CaOH+, and magnesium ion, attached by heterocoagulation as Mg(OH)2 precipitate, were responsible for the flocculation of quartz suspension and for the depression in cationic flotation of silica in alkaline pulp solutions. Magnesium hydroxide coating could be removed, similarly to adsorbed calcium ion, by complexation with EDTA and polyphosphates.

Jan 1, 1980

By Donald E. Freshcorn

The minimum sulphur level which can be attained during fluid bed roasting of zinc sulfide concentrates is largely determined by the residual sulfates of calcium, magnesium, and zinc. The fractional conversion of these elements to their respective sulfates is derived from semi- empirical relationships, and multiple regression analysis is used to fit the relationships to experimental data from a commercial fluidized bed roaster. The resulting equation shows that the calcine leaving the roaster contains almost no zinc sulfate, nearly all of the calcium is present as calcium sulfate, and the amount of magnesium sulfate formed is primarily dependent upon the roaster temperatures.

Jan 1, 1976