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By J. E. Burke, C. W. Mason

IN attempting to study precipitation from a tetragonal lattice using solid solutions of bismuth in tin, it was found that although a Widnmanstatten pattern is observed 1 only a qualitative analysis of the orientation relationships is possible, because of the unusual structural changes that accompany the precipitation process MICROSCOPICAL STUDIES Alloys were made from Chempur tin (Standard samples 42b and 42c, National Bureau of Standards), and bismuth (Kahlbaum C P ) by melting neighed quantities together under palm oil, stirring well, and casting in a heated graphite mold The polishing and etching techniques employed largely govern the visibility of the structural changes The preliminary surfacing operations were similar to those recommended by Villela and Bergekoff,5 through BehrManning 3/o abrasive papers, lubricated by a solution of paraffin in kerosene A rough metallographic polish was next given, using a thin cotton cloth charged with relevigated alumina (maximum particle size of about 4µ) and soap solution, repeated etching and polishing served to remove disturbed metal For high-power examination better preparation was necessary It was found that on such soft metals the threads of the fabric, rather than the abrasive, cause most of the scratching Cotton outing flannel, which had been brushed so that the nap lay down, was fairly satisfactory, but a Heavy grade of silk velvet (not the noncrushable kind) was found to be better, especially after some use A better procedure was as follows The metal lap was warmed slightly, and a 4-in circle of woolen broadcloth was cemented to its center by a thin film of melted paraffin The broadcloth was then moistened with water, and a 30 to 40 per cent solution of sodium hydroxide heated to about 50°C was poured over it, allowed to stand for 1 to 2 min and then washed off It was neither necessary nor desirable to remove all the sodium hydroxide from the cloth, since its etching action aided in the removal of the flowed layer from the sample The cloth was then charged with a paste of the relevigated alumina in water Since this lap did not remove deep scratches, it was necessary previously to polish the specimen on some material such as the silk velvet The sodium hydroxide softens and partly gelatinizes the woolen lap covering, permitting a scratch-free polish, but its action continues, and the cloth deteriorates after about 24 hr This is not serious, because a new lap can be prepared in about 5 min, and only small pieces of cloth are used Etching with a strongly acid solution of ferric chloride was found satisfactory for removing the flowed layer For the final etching, the most satisfactory reagent was that of Taffs,7 the formula for which is FeC13 6H20, 2 grams, HC1, 5 c c , H2O, 30 c c , C2H5OH (95 per cent), 60 c c This etchant reveals differences in com-

Jan 1, 1941

[E. O'C. Acker '86 Jinzoc Adachi ‘88 *Truman H. Aldrich '78 Walter H. Aldridge '89 Anson W. Allen ‘87 *John H. Allen '84 William R. Appleby '90 *W. Lawrence Austin '82 *W. SAyres ‘73 David Baker '86 *John Henry Banks .83 Henry C.Banon '90 Alonzo F.. Bardwell '89 Walter A. Barrows ‘90]

Jan 1, 1940

By John Ziats

This chapter covers the drawing requirements for the design of a comminution plant.

Jan 1, 1982

By D. H. Polonis, M. B. Kasen

AN unusual thermal etching phenomenon has been observed on the surface of a Cu-Si alloy. The observations were made during studies of vacancy condensation pit formation which were reported in previous papers.1,2 Figs. 1 and 2 are photomicrographs of the surface of a Cu-4.8 pct Si alloy after heating in vacuo (3 x X mm Hg) to 525°C and subsequently holding at that temperature for 16 hr in an impure (air-contaminated) argon atmosphere. Under these conditions preferential removal of silicon from the matrix by oxidation results in a surface which is entirely a phase overlying an a plus y structure. The light areas of Fig. 1 are regions in which very little thermal etching has occurred, while the majority of the surface has experienced severe etching. Similar regions in Fig. 2 are seen as plateaus above contours produced by net transfer of material from the specimen surface. Twin boundaries are also visible in Fig. 2. The difference in matrix mi-crostructure between Figs. l and 2 reflects the par- ticular orientation of low-index planes with respect to the surface of observation. Thermal etching contours of this type have been studied in detail by Hondros and Moore Both of the photomicrographs show that one or more dark spots are located approximately at the center of every protected area; where two spots are in close proximity, the protected areas have merged. The microstructures indicate that the anomalous resistance to thermal etching is related to the presence of these spots. Williams and Hayfield have shown that local regions of unusually high oxidation resistance can be caused by a surface monolayer of atoms with a work function higher than that of the base material. The result is an inhibition of the rate of electron removal from the base material and a decrease in the oxidation rate. The source of the protected layer may be either surface diffusion from contaminants on the specimen surface or pipe diffusion of solute atoms followed by migration across the surface. In the latter case the driving force is a difference in chemical potential resulting in a Gibbs adsorption phenomenon. In the present case, chemical polishing of the specimen surface precluded contaminants of a strictly surface nature. Consequently, diffusion of impurity atoms from within the lattice appears to be the most tenable explanation of the observed phenomena. The authors propose that the structures of Figs. 1 and 2 reflect the diffusion of impurity atoms along extended dislocations within the individual a phase grains prior to surface oxidation. The central spots within the protected regions are seen as sites of dislocation emergence which have become locally decorated with oxide in the manner discussed in Ref. 1. Williams and Hayfield observed protected regions adjacent to the grain boundaries of iron-contaminated copper which they attributed to the segregation of iron to the grain boundaries coupled with high dif-fusivity along the complex dislocation array at such boundaries. No evidence of such grain boundary protection was observed in the Cu-Si alloy; this

Jan 1, 1964

PRESIDENT ROBERT E. TALLY, JEROME, ARIZ. PAST PRESIDENTS FREDERICK W. BRADLEY, SAN FRANCISCO, CAL. WILLIAM H. BASSETT, WATERBURY, CONN. TREASURER KARL EILERS, NEW YORK, N. Y.

Jan 1, 1923

THE subcommittee on Coal Mining, since its appointment, has been engaged in collecting data about subsidences in coal mines in this country, and it now feels that almost all of the available data about occurrences of this sort in bituminous mines has been collected. As most of the bituminous seams are nearly level, the records obtained give the problem in its simplest form, without complications due to the pitch of the seam. Similar data is being compiled for the anthracite regions and it is hoped that this will be ready for the 1927 meeting. Copies of the questionnaire, Appendix A, were mailed to all of the coal operators' associations, to most of the large operating companies and to many engineers, with the request that any data on the subject be returned to the committee, or that advice of any subsidences known be given. The replies to most of the questionnaires were general only, although some specific cases were given. Many of the companies were unable to reply to all questions, as they lacked the necessary data, but in nearly every case where accurate data was available, it was cheerfully furnished, and any additional information requested was secured. All specific cases of subsidence were followed up by correspondence, and in several cases by personal inspection. Figs. 1 to 31 were made from the information furnished. Table 1 gives measurements of elevations taken in one case at intervals from October, 1913, to May, 1918. With one exception, where the evidence cannot yet be released on account of a lawsuit, it is believed that the cases submitted with this report include practically all that have happened in bituminous coal mining in this country of which actual measurements were secured. Some of these have already been published in the excellent report by Young and Stoek,1 and some instances have been secured from other publications. In collecting these data, the subcommittee had the Engineering Societies Library extend the bibliography given in the bulletin mentioned above to date. This list is given in Appendix B.

Jan 2, 1926

By Robert E. Palmer

The Hawkesworth detachable drill steel shank and bit were invented by A. L. Hawkesworth, while he was a mechanical foreman for the Anaconda Copper Mining Co., at Butte, Mont. Mr. Hawkesworth died on June 16, 1925, at the time that his invention was practically a proved success. The first application for patents was made by him in November, 1918, and the bit is now being manufactured under patents issued in 1922 and 1923. The credit for its development in the early stages belongs to A. L. Hawkesworth, Roy S. Alley, Harry A. Gallwey, E. J. Bowman and various officials of the Anaconda Copper Mining Co. Later improvements, manufacturing problems and the direct usage in the mines were originated and perfected by the mechanical department under C. D. Woodward, E. R. Borcherdt, head of the Rock Drill Equipment Department, Robert E. Kelly of the Mechanical Department, and various operating department heads of the Anaconda Copper Mining Co. The author wishes to acknowledge the assistance of these officials in the preparation of this paper. Comparison of Costs Using Regular Drill Steel and Detachable Drill Steel In 1922 production was satisfactory and sufficient enough to warrant a complete installation in an operating mine. The study and tests were made at the Badger State mine, the production of which averaged 1200 tons of ore per day. E. R. Borcherdt, head of the rock drill equipment department, was in direct charge of the trials, installation, operating problems and records during the entire .period, arid still continues in that position. This mine is a typical Butte mine, operated through a standard four-compartment shaft, served by a double drum hoist and an auxiliary hoist. The texture of the ground and ore has all the variations from soft to very hard granite and sulfide ore with production from levels between the

Jan 1, 1930

History of Reverberatory Smelting in Montana, 1879-1933. By FREDERICK LAIST (Trans, vol 106 31,800 words ) The development of the art of reverbera¬tory smelting from 1879, when smelting first started in Butte, up to the present time is described. The paper traces the development of the reverberatory furnace, as regards both constructing and operating, from the initial 10-ton furnaces to the present-day 600-ton furnaces and the changes in operating practice which accom¬panied the gradual enlargement of the furnaces and the reasons therefor are described and explained The results obtained from an investigation (made in the course of the Carson litigation) into the various methods of charging reverberatory furnaces are given These investigations proved that the method of charging a reverberatory had very little to do with its performance It was also found, at the same time, that the depth and extent of the bath maintained in the furnace had very little to do with its performance Numerous operating results are included and the article is illustrated Development of Copper Converting at Butte and Anaconda. BY WILLIAM KELLY AND FREDERICK LAIST (Trans , vol 106 4400 words.) This paper is based on recollections of one of the authors, W M Kelly, who has been identified with the development of smelting and converting at Butte and Anaconda since early times The article starts with a description of the circumstances surrounding the first intro¬duction of copper converting at the Parrot Works in Butte under the Manhes patents It briefly recounts the difficulties which were encountered and the steps taken to overcome them Among these were the absence of means for punching tuyeres in the original converter This difficulty was overcome crudely by drilling holes in the windbox opposite the tuyeres, said holes being closed by wooden plugs Later these plugs were replaced by steel slides and still later by the Dibblie ball valve, which has remained standard ever since The development of the converter from both struc¬tural and operating standpoints is traced from the early beginning to the present day Developments in Lead and Copper Converting at Tooele. BY B L SACKETT (Trans, vol 106. 3900 words) This paper shows the development at this Utah lead and copper smelter from separate converting of the two kinds of matte produced to a more efficient and economical treatment of the combined mattes This was accompanied by the use of relatively large amounts of silicious ore in the converting of lead matte as well as copper matte, which greatly improved the quality of converter slag produced, both from the standpoint of its copper content and its desirability for

Jan 1, 1935

ALABAMA Altoona -Cain, J Anniston -Cowie, L K Heimrod, A A White, H E Bessemer-Abbott, C C Ball, E M Mitchell, F R Thompson, N E Birmingham -Adler, T E Aldrich T H Aldrich, T H, Jr Blackburn, A R Bush, 117 W Clark, G H Cowin, P G Crane, W R Crawford, G G Crockard, F H Darnelspn, G E Davis, C B

Jan 1, 1923

By H. Rush Spedden, A. M. Gaudin

IN the belief that a critical study of its operating problems might be a sound investment, the Cuban American Manganese Corporation initiated an ore-treatment research in cooperation with the Massachusetts Institute of Technology One of the early objectives of this research naturally became the relationship of the microscopy of the Cuban ores of the Corporation to their flotation treatment The operations in Cuba have already been described by F S Norcross, Jr 7 and the laboratory study of manganese oxide flotation goes back a number of years 4 Broadly speaking, the difficulties encountered in the flotation of manganese ores are that the consumption of reagents is extremely high, the concentrate contains more silica than is desirable and the tailing losses are relatively high An appreciable betterment on any of these scores would achieve a definite betterment in costs, quantity of minable ores, and quality of product The microscope study discussed in this paper was made on samples from the Quinto mine, from the Ponupo mine, and from mill products at various stages of passage of the ore through the mill The writers have had access to Company records and in particular to the petrographic studies made on thin sections of ore by the late Professors R J Colony and Philip Krieger, of Columbia University They acknowledge their debt to both of these men for the help derived from the reports Manganese oxides are black, friable, smudging It is therefore, very difficult to judge operations by inspection The mineralogy of manganese compounds seems to be confused, and the authors believe that many more minerals have been described than actually exist Much of this difficulty is due to the prevalence of the structural conditions that will be discussed further in this paper, namely, the porosity and the friability of the ores, and the extremely intimate association of minute manganifeous mineral crystals with impurities of various sorts By all odds the most important manganese mineral in Cuba is the one that in this paper is called "psilomelane " The name "psilomelane" has been used in so many different ways that the choice of it for this ore may not be approved by all However, it seems to be the best under the circumstances This mineral accounts for about 97 per cent of the manganese in the ores of the Quinto and Ponupo mines and in the mill feed The remaining odd 3 per cent consists mostly of pyrolusite together with minor amounts of other manganese oxide minerals DESCRIPTION OF PSILOMELANE Aggregate Structure In grains or lumps, psilomelane has a characteristic fibrous appearance and seems

Jan 1, 1942

By D. N. Witman

ONE of the special uses to which the electric furnace has been put recently is the melting of an alloy of nickel and cast iron for the production of electrical-resistance grids. The metal sections of these grids, Fig. 1, are quite uniform for each pattern, but there is, among the various patterns, a variety of thicknesses. The cross sections vary from 1/2 by 3/16 in. to as small as 1/8 by 1/8 in. The electrical resistance f a perfect casting lies within 10 per cent. above or below the fixed listed resistance for each pattern. Good molding is essential to success in the making of these grids, for with absolutely correct metal, a variation of 0.01 in. in width and thickness of section on some of the patterns may mean as much as 12 or 14 per cent. variation in resistance. The service for which these castings are intended demands that the metal, even in the smallest castings, be very soft, showing an open, gray, highly graphitic structure in order that they may be resistant to shock, and stand up well under rough usage. The metal used for this purpose is a gray iron alloyed with 4 to 5 per cent. of nickel, which element, when the composition of the alloy is correct, imparts toughness and pliability to the metal and helps to overcome the tendency of metal to run white and become brittle because of the rapid cooling action of the sand mold. When cold, these castings can be twisted into various shapes, taking a permanent set without breaking. The alloy has approximately double the electrical resistance of ordinary cast iron. The metal specification is as follows: PER CENT. Silicon 2.40 to 2.60 Sulfur Under 0.05 Phosphorus Under 0.08 Manganese Under 0.40 Total carbon 3.60 to 4.00 Nickel 4.00 to 5.00 Copper 0.50 to 0.70

Jan 8, 1921

DAVID THOMAS 1871 R. W. RAYMOND 1872-1874 A. L. HOLLEY 1875 ABRAM S. HEWITT 1876 T. STERRY HUNT 1877 ECKLEY B. COXE 1878-1879 WILLIAM P. SHINN 1880 WILLIAM METCALF 1881 RICHARD P. ROTHWELL 1852 ROBERT W. HUNT 1883 JAMES C. BAYLES 1884-1855 ROBERT H. RICHARDS 1886 THOMAS EGLESTON 1887 WILLIAM B. POTTER 1888 RICHARD PEARCE 1889 ABRAM S. HEWITT 1890 JOHN BIRKINBINE 1891-1892 H. D4. HOWE 1893 JOHN FRITZ 1894 J. D. WEEKS 1895 E. O. SPILSBURY 1896 THOMAS M. DROWN 1897 CHARLES KIRCHHOFF 1898

Jan 1, 1941

1 Healthy and active Local Section organizations are vital factors in promoting the vigor and growth of the Institute 2 Activity on the part of Local Sections should be recognized and stimulated by appropriation of funds from the Institute's treasury, and these appropriations should be as large as is consistent with the relative needs for other activities 3 As between different Sections, the amount of such appropriations should be based primarily on the extent of activities as reflected in the number and character of meetings held and the attendance of the members at such meetings 4 In making a request for funds for any year, the officers of a Local Section should submit a report on the printed form approved by the Directors at their meeting on November 19, 1937 5 A standing Committee on Local See-

Jan 1, 1952

not weaken. I saw him shortly before he was killed; his conduct under fire was splendid and an inspiration to his men. His loss is felt deeply by all ranks. Thanks to him and to others, who like him, paid the full measure of devotion to their country, our line was held until the critical situation in that vicinity was at an end. He died the true death of a soldier, with his face to the enemy. As we now look back, it is easy to believe that this holding of the line of defense intact by General Carey and his men was a determining factor in the outcome of the war. To have played so important and noble a part in this vital effort as that taken by Perry is assuredly the privilege of few. Our lives, it seems, are like capital entrusted to us to be expended as wisely and effectively as we may. With them we purchase whatever of accomplishment the stuff that is in us permits. It is impossible to escape profound regret that a career so full of the highest promise, and a personality so overflowing with all that is fine and lovable, should have been cut short at the age of thirty-one. Yet who can doubt that in a few months Perry bought with his life the fullest achievement of a life-time—a glorious part in the salvation of Liberty and Justice and Decency, indeed of Civilization itself! L. C. Graton.

Jan 1, 1920

By N. A. Ziegler

A certain amount of interest has been indicated recently in the resistance to oxidation at high temperatures of iron-aluminum alloys (rich in iron). Hautmanl published a paper in which some interesting results are given. According to his paper, only alloys containing at least 8 per cent aluminum indicate a marked improvement in their resistance to oxidation. At about this aluminum content, however, alloys become brittle, which considerably reduces their commercial value. About two years ago the author performed a series of experiments, the results of which are presented here. A series of iron-aluminum-carbon alloys was prepared by melting electrolytic iron, aluminum and high-carbon iron alloy in an induction vacuum furnace.2 The list of these alloys is given in Table I. Each alloy was forged in the ordinary way to All carbon determinations were performed by " Yensen " method. [N. A. Ziegler: Recent Developments in Analysis of Carbon in Iron and Iron Alloys. Trans. Amer. Electrochem. Soc. (1929) 56, 231.1

Jan 1, 1932

By Campbell Hunter

PETROLEUM is found in almost every province in Persia. On the northern frontier, along the southern shore of the Caspian Sea, it is found near Anzelli and Shakhtesar and gas at Khoremabad. Oil is also found at Gumush Tepe, northwest of Astrabad, on the southeastern shore of the Caspian Sea. Further inland, to the south of Astrabad, oil is found at Schahkuh-i-balae, also on the margin of the Khorasan desert at Semnan, 115 mi. (35 m.) east of Teheran. Along the western frontier, from northwest to southeast, oil is encountered at Ouschachi, north of Lake Urumieh; in the province of Azerbaijan, at Zohab, Khanikin, and other places in the district of Kormanshah in the province, of Ardelan. Further south, in the province of Luristan, oil is found east of Mendeli and in the Pusht-i-kuh districts. Considerable quantities of oil are also obtained from Schuster, Maidan-i-Naphtun, Ram-Hormuz, Beheban, which are almost on a straight line, running northwest and southeast along the foothills of the Bakhtiari Mountains. At Ahwaz, in the province of Arabistan, oil has been found along another range of hills whose axis also lies in a northwest-southeast direction. In the Fars province, boring for oil has taken place at Daliki, and indications of oil are found at Kheri, Fasa, Darab, and other places. A gas show is also recorded at Kuhi-Sung-Atush in this province, 30 mi. (48 km.) east of Darab. In the south of Persia, oil is encountered on. Qishm Island, also at Ahmedi and other places north of Bunder Abbas. On the southeastern frontier, oil is found on the Sarhad range of hills. Thus, oil indications have been noted over a distance of approximately 1100 mi. along the western and 700 mi. along the northern frontiers of Persia.

Jan 2, 1920

By Garry M. Hughes

Sherritt's new, 3000 tpd, copper- zinc Fox mine is situated 30 miles southwest of Lynn Lake. The copper-zinc orebody is part of a large body of massive and semi-massive sulfides consisting chiefly of pyrite; with chalcopyrite, sphalerite (containing 7-9s Fe) and pyrrhotite in varying proportions which occur within a series of volcanic and sedimentary rocks. The average sulfide content is 67%. Higher zinc zones are masses of pyrite grains cemented by sphalerite with lower than average copper content. Zones higher in copper and lower in zinc are slightly more quartzose. Gold and silver are present in small amounts roughly proportional to the copper content. Surface diamond drilling indicated an orebody containing 12,269,000 tons grading 1.74% Cu and 2.35% Zn to the 2000 ft level. Underground drilling established the tonnage at 11,- 300,000 tons containing 1.96% Cu and 2.74% Zn.

Jan 4, 1972

Organization Place Date 1918 American Society of Mechanical Engineers...:.. Worcester, Mass. June 4-7 American Institute of Chemical Engineers Berlin, N. H. June 19-22 American Concrete Institute Atlantic City, N. J. June 24-26 American Society for Testing Materials Atlantic City, N. J. June 25 28 American Institute of Electrical Engineers Atlantic City, N. J. June 26-28 New York Electrical Society, Annual Meeting... New York, N. Y. June American Institute of Mining Engineers Colorado Sept. 2-7 National Association of Stationary Engineers.... Cincinnati, 0. Sept. 9-13 British Iron and Steel Institute, Autumn Meeting London, Eng. Sept. 12-13 National Exposition of Chemical Industries New York, N. Y. Sept. 23-28 American Chemical Society Cleveland, 0. Sept. National Petroleum Association.: Atlantic City, N. J. Sept.

Jan 6, 1918

CLARENCE N. FENNER.-Mr. Gelstharp, chief chemist of the Pitts-burgh Plate Glass Co., has directed my attention to the fact that that company was using optical pyrometers obtained from the Leeds & Northrup Co. several months before the members of the Geophysical Laboratory arrived at Charleroi. I am glad to make this correction. The chief object of my paper was to emphasize the necessity of careful temperature control in the making of optical glass and to describe the kind of tests to which an optical pyrometer should be subjected at a glass plant in order to obtain information regarding the closeness with which its readings correspond with true temperatures under the condi-tions which prevail in each particular case.

Jan 12, 1919

By Kenneth K. Humphreys

INTRODUCTION What is automation? Why automate? Webster's New Collegiate Dictionary defines automation as "the automatically controlled operation of an apparatus, process or system by mechanical or electronic devices that take the place of human organs of observation, effort, and decision." This definition gives an implied answer to the second question, )"Why automate?" Automation, automatic control devices and process control equipment receive their justification in supplementing or replacing manpower, which results in decreased operating costs. In the past, processes were operated with a minimum of instruments for the purpose of merely guiding the operators. Processes were manually controlled by the operator on the basis of simple temperature, pressure, flow and level indications on a panel. Today the tendency is to design a new plant to operate in a fully automatic manner according to a preset pro- gram utilizing a minimum of manpower. In addition to this direct cost reduction savings in manual labor, increased equipment capacity results from uniformity of flow and uniform control of process variables. This control eliminates or minimizes surges and permits equipment to be operated at or near its ultimate capacity and, for a given material through- put, permits the use of smaller process equipment. Automatic control, therefore, be it in the field of coal processing or in any industrial field, is simply a problem of economics. Control equipment is justified in terms of its contribution toward increasing productivity, increasing profit margins or producing a new and saleable product at a profit. Instruments and control devices can be divided into two general groups: (1) units which measure, and (2) units which both measure and control a process variable. In coal processing, the first class of instruments, those which measure only, include analytical devices such as automatic ash, moisture and sulfur measuring units and the simple pressure, temperature, flow and level indicating devices mentioned previously. The second group of instruments, those which both measure and control, include a wide variety of units such as continuous weighing devices on conveyor belts and photoelectric cells which gauge the position of railroad cars on the track and insure that the cars are in the proper location for loading (see Chapter 15). The latter types of units as used in the coal industry differ from those used in other industries in one significant point. In coal processing these instruments need not be as highly sophisticated and accurate as in other industries; hence their cost is proportionately lower than in other industries. Because of the economic fact that coal sells for only a fraction of a cent per pound compared to dollars per pound for many chemical products, and

Jan 1, 1968