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By C. C. Harris

A critical literature review leads to a descriptive model of tumbling mill operation based upon energy partition concepts and the necessary requirements for particle fracture. As grinding proceeds into the ultra-fine region, conditions which are of little significance during normal operations gradually become controlling. These involve increasing resistance to fracture and an increasing tendency to aggregate as particles become smaller, and a growing fraction of the power input being consumed fruitlessly. The result is that fineness asymptotes to a maximum value as comminution proceeds indefinitely; thus where t is time, p and n are experimentally determined parameters, and Ø is a measure of fineness, which is presumed to be proportional to specific surface area, or proportional to the reciprocal of the size modulus (provided that the distribution modulus remains constant with time), or both. Ø, is the asymptotic value of Ø and is a measure of the grind limit. A method for its graphical determination is given. In a previous paper1 the physical and mathematical principles requisite to a study of the role of energy in comminution were reviewed. The micro-process of comminution — or the comminution event — can be investigated in terms of (a) the magnitude of the force-field localized around the individual particles which gives rise to the stresses generated in the particles, which in turn induces their fracture, and (b) the distribution of fragment sizes, should the event prove fruitful. The entire fragmentation operation can be considered to be the totality of its individual events, and in order to obtain a single independent variable of the process it is necessary to transform and sum the local stresses in terms of energy.1 This energy, however, will account for only a fraction of the energy input to the comminution process, the actual magnitude depending upon the kind of mill and several related factors. From the comminution viewpoint the primary function of a mill is that of stressing as many as possible of the individual particles of the charge to failure, with the maximum economy of energy expenditure. This is difficult indeed to achieve, for stressing a particle does not always break it, while the overwhelming portion of the energy input is involved with various internal mill processes which — almost incidentally — determine the magnitude, frequency, and manner in which the forces are applied to the particles. Essentially, these processes depend upon the mill dimensions, loading and speed, and they may be little affected whether fracture occurs or not. These processes must be delineated if a complete description of the role of energy in comminution is to be given; the energy account sheet1 (Fig. 1) in showing how the energy is partitioned for the requirements of the several functions it performs, provides a framework for the development of a model of the comminution process. Actual numerical values for the variables appearing in Fig. 1 will depend upon the mill, materials, and operating conditions. A possible general relationship between the variables will be suggested in this paper. Before proceeding further, a cautionary note must be issued. It was pointed out in an earlier paper' that while energy input is not changed by increasing the power and decreasing the time in the same proportion, and vice versa, the results of the process in terms of particle fineness may be different. Thus, although energy is chosen as the independent variable of a comminution process, it is not absolutely independent, and care must be exercised to ensure that it is used within its range of valid application. Time has the necessary independence, and it will be used in place of energy where it is appropriate. The residence time in a mill is usually of the order of minutes. Under these conditions the particles are subjected to "... a relatively constant fracture producing environment".2 However, under the more rigorous conditions of greatly extended time, which pertain in ultra-fine grinding, indications are that the fracture producing environment no longer remains constant; this is the major subject of this paper. At this extreme limit the mill is probably taxed to its utmost, and at the same time the bulk material properties are becoming closer to ideal, while the physico chemical effects associated with surfaces, edges and corners are multiplying. (The edge length per unit volume is proportional to the square of the specific

Jan 1, 1968

By A. B. Cox, L. W. Wark

In an earlier paper1 measurements of contact angles due to the effect of xanthates on mineral surfaces were reported. The solutions in which these measurements were made differed widely from those of modern flotation circuits. It is intended, however, by introducing, one at a time, the other principal reagents of flotation, to approach gradually the solution composition of flotation liquors. The work now described is an attempt to determine the effect of one of the most important of these reagents—namely, sodium cyanide—on the establishment of air-mineral contact. The work has been carried out for the following companies: Broken Hill South, North Broken Hill, Zinc Corporation, Electrolytic Zinc of Australasia, Mount Lyell Mining and Railway, and Burma Corporation. Since the effect of cyanide is inseparably connected with the alkalinity, the results cited below deal with the mutual effects of alkalis and cyanide. Alkalis alone exert a significant effect on the air-mineral contact but comparatively large amounts are required. Since the addition of a small amount of cyanide greatly decreases the degree of alkalinity necessary for the suppression of contact at surfaces of any of the minerals experimented with (except galena) and since alkalis are rarely used alone in practice, little attention has been paid to cyanide-free solutions. It was shown in the previous paper that, excluding the dixanthogen effect, whenever contact was practicable at all in an ethyl xanthate solution the angle of contact was 60". There is, therefore, less necessity to measure equilibrium contact angles; in fact, the experiments herein described have generally been conducted with a view to determining whether contact is possible and not to measuring the actual value of the contact angle. The separations which have generally to be effected in dealing with complex sulfide ores are: (1) galena from sphalerite, pyrite, etc.; (2) sphalerite from pyrite and/or gangue minerals; (3) copper minerals from pyrite and gangue minerals; (4) pyrite from gangue minerals; (5) chal-

Jan 1, 1935

By Stanley Herold

As an accompaniment to the interesting papers which discuss the practical aspects of forced drive, or flooding, in our oil fields, and to others which deal with laboratory or field tests on the same subject, a few remarks on the theoretical principles concerned may not be considered inappropriate at the present time. Without claiming to have had the field experience which some of you certainly possess I venture to present some of the results of an analytical investigation upon this method of increasing the recovery of oil from our natural reservoirs. I firmly believe that these results will accord with your experience. I shall confine the present discussion to the consideration of a perfectly ideal situation Let us assume that the productive formation lies perfectly horizontal, that it is of uniform thickness, of perfectly homogeneous texture, and that it contains oil with gas in solution, and no water, throughout a definite, although undefined, lateral extent. We shall furthermore assume that the pressure existing within the reservoir as thus specified, is such that some of the gas is in the free state, spread uniformly throughout, in the form of minute bubbles within the pores of the formation. We now have an ideal reservoir subject to the peculiar action of capillarity as described by the French physicist Jules Jamin. In all directions within the reservoir we see these bubbles of gas, separated by globules of oil which tend to remain in the capillary channels that connect the pores. The action of these bubbles and globules under the application or release of pressure has been fully described by Jamin.1 Most of our oil fields in the Mid-Continent and Eastern districts are subject to this action of capillarity: The fact that the actual reservoir is often far from being ideal in the manner specified above does not preclude the, influence of this phenomenon. The oil, existing under a pressure exerted by the compressed gas, is securely locked in place

Jan 11, 1926

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Jan 1, 1907

By Paul E. Blackburn, Joan B. Berkowitz-Mattuck, Edward J. Felten

The oxidation behavior of MOSi2 has been studied between 450° and 650°C, the temperature region where "pesling" occurs. Disintegration ("pest-ing") of MoSi2 is shown to occur in the presence of oxygen, but not nitrogen, carbon dioxide, carbon monoxide. or argon. The rate of disintegration is extremely sensitive to oxygen pressure. The crack density of polycrystalline MoSi2 increases ivith lime at temperature. All kinds of cracks are observed: THE excellent oxidation resistance of MoSi, at temperatures of 1000 to 1700°C promises to have important technological benefits. However. the ap- Ihose which are confined within a single grain, those that ci'oss grain boundaries transversely, and those that follow grain boundaries. Laue photographs verify the existence of Iranscryslalline cleavage. Single crystals of MOSi2 do not "pest". Tlrcd solrlbility of oxygen in MoSi2 is extremely low, no lattice changes being observed as a result of exposure of MoSi2 to oxygen in the "pest" temperature range. plicability of MoSi2 is somewhat restricted by the occurrence of a completely destructive oxidation of the intermetallic phase at intermediate temperatures (300" to 6003C). This phenomena was ternled to be the "MoSi2 pest" by Fitzer who first observed it.' Molybdenum disilicide is a metallic material in both physical appearance and electrical properties.

Jan 1, 1965

By F. M. Lewis, J. E. Goodman

TENNESSEE Copper Co. operates two ore concentrators, the London and Isabella mill. Copperhill, Tenn. In 1948 and 1949 the small ball mills and rake classifiers in the London concentrator were replaced by one large ball mill and one hydraulic classifier. This new ball mill was designed oversize so that it could be operated at slower than normal speed. The proper operating conditions were established and the results published.1 Later it was found that this mill operated more efficiently with a small ball charge.2 While this London grinding practice was being developed, the Isabella grinding circuit was not changed in any way. It remained a conventional two-stage rod mill-ball mill combination, the rod mill in open circuit and the ball mill in closed circuit with a rake classifier. Study of the data indicated that grinding cost could be lowered by converting to the London practice, but not enough would have been saved to warrant the expense of converting. No plan for improving this grinding operation could be developed.

Jan 11, 1957

By W. J. Taylor

IN making heating gas with anthracite coal for roasting ore during the past few years, I hare tried many forms of gas generators. So far, the most successful and satisfactory one has been what we call a fluxing producer, which is simply a small cupola or blast furnace, in which we charge with the coal, say, 30 or 40 per cent. of basic blast-furnace cinder, to unite, when melted, with the ash or earthy matter in the coal, and carry it off as cinder. The producer we have in use at Chester, N. J., has pore of the lines of a blast furnace than a cupola, the hearth being 24 inches diameter and 24 inches high. It then enlarges on an angle of about 25 degrees from a perpendicular to 4 feet, and then is drawn into 3 feet on top ; total height, 12 feet. We use one water coil-tuyere 12 inches above the bottom, and blow through a 11/2-inch nozzle. The depth of coal above the tuyere averages about 6 feet. The producer. is blown with

Jan 1, 1881

By M. C. Smith, W. V. Green, D. M. Olsen

The creep-rupture behavior of commercial powder-metallurgy molybdenum rod is reported in the temperature range 1600" to 250O°C, at stresses up to 9000 psi and times up to 1 month. The effects of temperature, stress, and grain growth are discussed. Rupture time is fitted to the Larson-Miller parameter and compared to lower-temperature and higher-stress results reported by pugh.1 BECAUSE of its high melting point, molybdenum should retain useful strength to relatively high temperatures. Combined with its ready availability in the United States, this makes it attractive for many applications in missiles, rockets, and so forth—wherever its susceptibility to oxidation can be tolerated or overcome. The mechanical properties of molybdenum rod in the temperature range —200" to 1540°C have been reported by pugh,' Bechtold,' Parke,3 and Carriker and Guard.4 Madden and chen5 have measured the tensile properties of molybdenum single crystals in vacuum up to about 2500°C. As one further step in evaluating its mechanical usefulness, the constant-load creep-rupture properties of commercial powder-metallurgy molybdenum rod have been investigated in the range 1600" to 2500°C. MATERIAL TESTED Creep specimens were machined from 1/2-in. round commercial molybdenum rod, manufactured from powder by pressing, sintering, and swaging. Spectrochemical analysis of the rod showed "traces" (less than 0.01 pct) of silicon, aluminum, chromium, iron, and zirconium, and "faint traces" (less than 0.001 pct) of manganese, magnesium, cobalt, and nickel. Carbon content was 130 to 200 ppm, nitrogen was 110 to 180 ppm, and oxygen 30 to 35 ppm. A typical microstructure of the as-received rod is shown in Fig. 1. Room temperature tensile properties for five specimens strained at about 0.015 in. per in. per min are shown in Table I. CREEP SPECIMENS USED The specimens used for creep-rupture testing are illustrated in Fig. 2. The 1/4-in.-diam gage section was 3/4 in. long, and terminated at shoulders 5 mils high. These shoulders served as fiducial marks for optical strain measurements. Surface finish on the gage section was 16pin. r.m.s. One specimen, for a "long-time" test described below, was modified by dividing the 3/4-in. gage length into three 1/4-in. long sections with individual diameters of 0.250, 0.230, and 0.210 in., each terminating in a pair of fiducial shoulders. TESTING PROCEDURE The constant-load creep-testing machine used has been described by Smith, Olson, and Brown.6 In it the specimen is held vertically on the axis of a cylindrical tantalum or tungsten heater tube by threaded molybdenum or tungsten grips. Both specimen and grips are heated by radiation from the heater-tube, which is heated by its own electrical resistance. The bottom specimen grip is held at its lower end by a clevis pin. The testing load is applied to the specimen through the upper grip by means of hanging weights, a constant force-multiplication lever system, and a pull rod sealed to the chamber lid by a bellows. The incandescent specimen is viewed by an external optical system through slots in the heater-tube and radiation shielding, and an enlarged image of it is projected on a ground-glass screen. Gage-length measurements are made on this image with a pair of cathetometers. Thorium oxide coatings were applied to the threaded ends of most specimens, to prevent diffusion-welding of specimens to grips during testing. Without such a coating welding usually occurred, and grips were often broken by subsequent efforts to remove the tested specimens.

Jan 1, 1960

By L. J. Howell, R. C. Sommer, H. H. Kellogg

WORK described herein was undertaken with the aim of determining some of the physical-chemical properties of electrolytes suitable for the electrodeposition of pure zirconium metal. In this paper the phase diagram, vapor pressure, and activities in the melt are considered. In a companion paper,' the electrolytic conductivity of some of these melts is reported. The melts studied were mixtures of NaCl and/or KC1 with ZrC1,. Chloride melts were chosen for study because 1) if the electrolyte is to be useful for industrial electrodeposition of zirconium, the chlorides will be preferred to the relatively costly bromides and iodides; 2) fluoride melts were being studied in another laboratory (Horizons Inc., Cleveland); and 3) melts containing oxygen, in any form, are unsuitable for preparation of pure zirconium, because of the great affinity of this metal for oxygen. Unlike electrodeposition from aqueous solution, the fundamental behavior of fused-salt electrolysis is poorly understood. In most cases, such basic electrochemical information as the phase diagram of the melt system, activities in the melt, conductivity, the nature of the current-carrying ions, the equilibrium electrode potentials, and the overvoltage behavior of the electrodes is unknown to the researcher who would develop a new electrodeposition process employing a fused salt. This research project was designed to supply information about some of these basic physical-chemical properties so that an intelligent choice of electrolyte for electrodeposition studies could be made. Experimental The experimental difficulties-encountered in this work result from the properties of zirconium metal and ZrC1,. ZrC1, is a solid which sublimes at 334°C. It is rapidly hydrolyzed by moist air to HC1, ZrOCl,, and ZrO,. Unusual precautions were exercised in this work to prevent hydrolysis of ZrC1, and rigidly to exclude oxygen, nitrogen, hydrogen, and carbon from the melts under study. These elements are known to react with and contaminate zirconium metal. All melts were studied in vacuum systems, i.e., in the presence of ZrC1, vapor only. Transfer of ZrC1, to or from the melts was accomplished entirely by vacuum sublimation. In this way, neither the melts nor the ingredients thereof were permitted to

Jan 1, 1958

By S. P. Kinney, G. St. J. Perrot

Consumers of metallurgical coke are agreed that the quality of their fuel plays an important part in the performance of the furnace. Less unanimous agreement is evident when the properties of a desirable coke are discussed or when consideration is made of suitable testing methods by which the worth of a coke for metallurgical purposes may be determined quantitatively. Much has been written of the importance of combustibility as a factor in determining the performance of coke in the blast furnace and it is generally believed that cokes vary widely in this respect. The usual operating data of the furnace afford little evidence as to the combustibility of the fuel. As a part of a general investigation of the properties of metallurgical coke, the Bureau of Mines has explored the hearth combustion zone in a number of blast furnaces by means of water-cooled gas sampling tubes driven into the hearth through the tuyeres. The attempt has been made to determine the difference in combustibility of cokes varying widely in physical properties. Data have also been obtained in an experimental combustion furnace at the Bureau laboratories in Pittsburgh. This paper gives the results of experiments, made at eleven blast furnaces, in which the composition of the gases was determined at various points in the hearth in the plane of the tuyeres. Further work is in progress in which the zone above the tuyeres will be explored. Factors Affecting Coke Combustibility Brassertl has defined combustibility as the rate of progression of combustion, or, in other words, the speed at which the carbon molecules

Jan 1, 1923

By R. L. Templin

In treating a cast metal by any working process such as rolling, drawing or forging, variations in the conditions present in the remelting, casting, chilling and preheating of the initial ingot will certainly have some effect on the physical properties of the final product. In considering the effects of cold working on the physical properties of metals, however, it will be assumed that these factors, being controlled according to best practice, will remain constant and therefore may be neglected. Starting with such a uniform metal ingot, the next operation in the production of wrought metal involves hot working by rolling, forging or extrusion so as to produce a slab, billet or bloom. This working must be sufficient to produce substantial grain refinement and minimize any defects occurring in the initial ingot. Even such a hot-worked product is not suitable as a starting material for determining the effects of cold working because it contains internal strains analogous to those resulting from cold working. It is necessary, therefore, to supplement the hot working with a considerable amount of cold working, followed by a proper annealing in order to obtain a material suitable for use in defining the effects of cold working on the physical properties of a metal. That is, if the effects of cold working are to be evaluated accurately it is necessary to have other effects at least constant if not absent. Such material, unfortunately, cannot always be obtained in commercial practice but the requirements just indicated certainly represent the desired goal; this goal has been attained in the treatment of some metals, one being aluminum. Factors That Must Be Considered Simultaneously with Cold Working So many other factors affect the physical properties of a metal that it is necessary to consider these factors simultaneously with cold working; their effects vary in magnitude with the amount of cold work present. The most important of these factors are: (I) chemical composition, (2) structure, (3) temperature of working, (4) character of working, (5) rate of working, and (6) methods used for measuring results. For

Jan 1, 1930

CRUSHING and concentration flow-sheets of western mills have become greatly simplified and more or less standardized of recent years with the introduction of modern grinding methods and flotation. Improvement has not stopped, however, and advancement is continually being made in crushing and milling practice. A case in point, where remarkable improvements in efficiency have resulted from comparatively minor changes in the flow-sheet, is in the New Cornelia mill of the Calumet and Arizona Mining Co. at Ajo, Ariz. This mill, completed in 1924 for the concentration ,of the sulfide ores of the New Cornelia mine, was originally designed for a 5000-ton capacity. Before recent changes and additions were made the five 1000-ton units were handling 6500 to 7000 tons per day, giving a flotation feed of approximately 14 per

Jan 1, 1930

By Reno H. Sales

Our colleagues cannot in the future earn reputations and medals for achievements in milling and smelting ore and for successful management of mining companies, if some one doesn't keep finding and mining the ore to mill and smelt and to provide the basis for the good management. Good ore seems sometimes to be quite helpful to good management, and good ore is not as easy to find as it used to be. And there are still more reasons, why—when this honor had been decided upon and named for Mr. Daniel C. Jackling—it should be initially conferred on Reno H. Sales. . The terms of reference of the award are that it should be conferred upon an individual working in the fields of mining, geology, geophysics, who has made an outstanding contribution to the progress of technology in one or more of those fields. And in this initial year (the earlier years are the easiest) just that was done. I think I could get away with it amongst the old-timers of my generation if I say that this time they made the award to the individual, who made the outstanding contribution. But, as Al Smith used to say, "Let's look at the record." Really, the record is mixed up a little with extra-lateral litigation—the old-time "apex cases" under Section 2322 of the Revised Statutes. Reno Sales doesn't like such litigation, but there is little question that the urgency, generated by conflicting claims of intra-limital and extra-lateral rights, and consequent necessity for committing to records and maps the complications of Butte structure, did advance—and by several years—the first continuous, accurate, systematic, and scientific portrayal of the geological and mineralogical details of what is, after all, the most important and the most complicated copper district—at least in North America. Prior to Sales' time, some of the most eminent of geologists often waived details. One geologist took the judge to the window to show him the Rarus fault going through a notch in the Continental Divide. The entertaining testimony in the Bluebird litigation was as perfect in literary style as it was innocent of the criteria by which faulting and lack of continuity of vein structure are now recognized. At any rate, this need for an accurate record of structure was in the background—to whatever extent it was, or was not, the etiological agent—for formation of the Geological Department of the Amalgamated Copper Co. in and about the year 1900. Charles W. Goodale was at that time the head of the Boston & Montana, and John D. Ryan succeeded William Scallon as the president of Anaconda Copper Mining Co. in 1905. Horace V. Winchell, for years a specialist in extra-lateral litigation, was perhaps the man who at that date had the vision, the persuasive weight with the management, and the willingness to defend the idea of large current expenditures (as then viewed) for a complete and sys-

Jan 1, 1955

By L. R. Ingersoll, James Fisher, Harry Vivian

The copper mines of the Keweenaw Peninsula in northern Michigan have long been of interest in connection with deep earth-temperature measurements. The extraordinary low geothermal gradient of l° F. in 223.7 ft. announced by Agassiz1 as a result of measurements dating from 1886, although later2 stated as in error, served to focus attention on this region as one offering, because of the great depth of the mines, unusual opportunity along this line. Lane,3 Van Orstrand4 and others have made valuable contributions to this study. Fresh opportunities afforded by the constant deepening of the mines, improvements in the accuracy and reliability of temperature-measuring instruments together with increasing knowledge of the heat conductivities and specific heats of the rocks, led the Michigan College of Mining and Technology in cooperation with some of the mining companies to renew work on this problem. It is planned eventually to complete a survey which will make use of the favorable opportunities for deep rock-temperature measurements presented in these mines. This survey should include the determination of a depth-temperature gradient in both conglomerate and arnygdaloid mines, and also the variations in temperature at the same depth in different geological formations. The first problem has a direct bearing on the question of providing equipment for necessary ventilation with increased depth. The second may show that a relation exists between the natural rock temperature and the mineral content of the formation. The measurements in all cases are to be guided by heat conduction considerations, to the end that they may represent as closely as possible

Jan 1, 1934

By Samuel S. Wyer

1. The following is an abridgment of a recent report made by the author, covering an investigation of: (A) The necessary use of natural-gas compressors; (B) The effect of gas compressors on natural-gas field operating conditions in Ohio, with special reference to the working pressure relations of gas wells of one company discharging by natural rock-pressure flow without compressors, and adjacent wells of other companies, discharging into intake lines to gas-compressing stations. Tests were made at 107 different places in the counties of fairfield, Licking and Knox, Ohio, which required 7,000 miles of automobile driving, and consumed 6 months' time. 2. A proper conception of the necessary use and effect of natural-gas compressors in natural-gas production necessitates a clear understanding of certain fundamental definitions and judicial doctrines, which are given herein. 3. Gas is a fluid composed of a large number of molecules which are vehicles of energy continually in motion, and havingan inherent tendency to get farther and farther apart. The range of motion of the molecules is limited only by the volume of the closed containing vessel in which they constantly move to and fro. The most distinguishing characteristic of gas is its universal property of completely filling an inclosed space. 4. Gas pressure is the result of the combined efforts of all the moving molecules in the mass trying to get farther and farther apart, that is, a mass of gas inclosed in a vessel expands and fills it, and being restrained from further expansion, it exercises a pressure against the walls of the vessel. This pressure is the same in all directions on equal areas of surface, as shown in Fig. 1. With a given mass of gas, any increase in volume of containing vessel will give the molecules more range of motion, * The public's interest in the age and magnitude of the art of gas compressing and development of the law relating to the use of grs compressors in natural gas production is discussed in the preceding paper. Development of the Law Relating to the use of Gas Compressors in Natural Gas Production; see also Is It Feasible to Make Common Carriers of Natural Gas Transmission Lines, vol. xlviii, 471 to 480 (1914). Consulting Engineer.

Jan 1, 1916

By Cyril Wells, Robert F. Mehl

The practical importance of a knowledge of the rates of diffusion of carbon and of alloying elements in steel has often been pointed out.l,13 This importance lies chiefly, though by no means only, in the study of carbufizing and in the study of reactions involved in the eutectoid inversion in steel. The present paper is one of a series in which the rates of diffusion of carbon and of alloying elements in ?-Fe and their mutual effects are measured with precision. The present paper reports the results of measurements of diffusion coefficients D of manganese in ?-Fe over wide ranges of temperature, and concentration, and of the effect of carbon and impurities and of grain size upon these diffusion coefficients.‡ Data on the rate of diffusion of manganese in ?-Fe have been reported by Fry2 and by Paschke and Hauttmann.3 Claussen4 calculated the diffusion coefficient D from Fry's data as 3 X 10-10 sq, cm. per set. at 960º, which will be shown to be incorrect by many orders of magnitude. Paschke and Hauttmann gave a rough value of 9.6 x 10-8 Sq. cm. per set. at 14000. Neither of these workers considered the variation of D with concentration and with temperature, and neither studied the effect of carbon. Method and Materials Method.—The method employed is identical with that used earlier.5 Owing to the volatility of manganese and the consequent loss of manganese from the outer surfaces of the welded diffusion bars, these surfaces were discarded. The diffusion anneals were performed in argon, except One (test 18) in which hydrogen was employed for purposes noted below. The temperatures reported are accurate to about 3" and constant within 1°C; the diffusion times are reported to the nearest half hour. The specimens were furnace-coo1ed after the diffusion ation, at about 2° per min. Layers, usually 0.004 in. thick, parallel to the welded interface, were machined from the specimens after the diffusion anneal and analyzed for manganese to 0.I Per cent Mn; the distances of these layers from the interface was measured to ±0.0002 in. The concentration-penetration curves obtained were analyzed by both the Grube and the Matano solutions.8 The D values calculated by these two methods do not differ appreci000. The Grube solution was used except in tests in which the effect of concentration upon D was greater than so per cent; in such cases the Matano method, which explicitly provides for the variation of D with concentration,' is the more reliable. In general, the number of layers machined from the zones of variable composition were large enough to permit the use of the average layer composition as that of the center of the layer. In 3 of the 3' tests, however, this is not justified, and the D values

Jan 1, 1941

By John Henry Harden

IT appears that in the earlier days of anthracite coal mining, 1824-25, the Lehigh region mined 76 per cent. of all the coal sent to market. During the same period Wyoming sent 12 and 5 per cent. respectively, whilst the Schuylkill sent 11 and 18 per cent., the number of tons marketed being in those days very small indeed. In the year 1828 the Schuylkill region mined over one-half of all the coal sent to market, and continued to do so for thirty years (with the exception of the year 1831), until 1858 ; since that date the pro¬duction has declined very steadily in comparison with the other regions, until, in 1876, it was only 34 per cent. Wyoming, in the year 1820, was mining 40 per cent., but the production of all the regions was very small ; in six years it declined to 5 per cent., increased to 34 per cent. in 1831, declined to 10 per cent. in 1838. Since which time the increase has been gradual, until 1873-75 Wyoming produced over 50 per cent. of all the anthracite coal sent to market. In 1867 the production exceeded that of Schuylkill, and has continued to do so since that time. In the year 1876, during the existence of the " coal combination," Wyoming lost 9 per cent. ; during the same time Lehigh gained 7 and Schuylkill 2 per cent. over their relative production of the preceding year, the decrease of Wyoming being two and a half million tons, the increase of the Lehigh one million, the decrease of the Schuylkill nearly three-quarters of a million. The extraordinary production of the Lehigh region at a time of decreased demand and in opposition to an agreement with the other regions to limit the supply to the supposed demand was the cause of the disagreement which ultimately broke up the combination of the great coal-producing and carrying companies. The Lehigh region produced very steadily, from 1829 to 1854, an average of about 22 per cent. of the whole production. From 1854

Jan 1, 1877

By Stuart M. Buck, J. H. Bramwell, Edward H. Williams

The Southwest Virginia Improvement Company began operations in the Bluestone Flat-Top coal-field, situated in Tazewell County, Virginia, in the fall of 1881. In May, 1883, the company had built 200 coke-ovens, and by March, 188-1, had 9000 feet of entries, exclusive of air-ways, in the Nelson or Rig coal-bed of this district (which here averages eleven feet in thickness), and had extracted 200,000 tons of coal, representing an area of about twenty acres. About this opening has grown the recently incorporated city of Pocahontas, and the completion of the New River branch of the Norfolk and Western Railroad to this point enabled the company to make large contracts for supplying coal and coke, so that it was deemed necessary, on account of the limited area developed, to work the mine day and night to fill orders. At 1.30 Thursday morning, March 13th, the inhabitants of Pocahontas were awakened by a violent shock, and within a few minutes all knew that the East mine had been the scene of an explosion of so general a nature that, of the 114 men at work, not one had escaped. The daily papers gave more or less distorted accounts of the number of victims, the scenes in and about, the mine, and the probable cause of the disaster. At the request of the company, the President of the American Institute of Mining Engineers appointed the undersigned a committee of three to investigate the matter, and the committee thus constituted presents the following report, accompanied by a copy of the testimony taken daring the investigation, for preservation in the archives of the Institute. Pocahontas was reached on Thursday, April 24th, and left on Friday, May 2d. During this interval the committee made repeated visits to the mine, especially to the points, of most importance, examining it carefully in every part; and summoned a number of witnesses, twenty-six of whom appeared and testified. The mine had been left in the same state as when the bodies were

Jan 1, 1885

By George Enos

As the coating formed affects the corrosion rate, duplicate samples of eight non-ferrous alloys were placed in flowing mine water. The alloys tested were as-cast or as-rolled and machined or polished. The paper describes the tests and gives the corrosion losses and the appearance of the samples at the end of the test. AN IMPORTANT factor affecting the rate and nature of corrosion of metals and alloys is the film, or coating, formed on the surface; and this may accelerate or retard corrosive action once started. The formation of films and coatings is intimately associated with the chemical composition and physical constitution of both the metal and the corroding medium. A film or coating may be either the corrosion product resulting from oxidation; that is, an oxide or salt, or a deposition of suspended matter from the corroding media upon the surface of the metal, or a mixture of both. The coating may adhere tightly or loosely to the surface of the corroded metal. In short, a film or coating is the reaction product of the corroding medium and the metal, which adheres to the surface of the metal and with which may be intermingled material from the attacking media not concerned in the chemical reactions. As the, terms film and coating are used by different writers for very different things, distinction is made between the two, by the present writers, on the basis of thickness. Thus, a film is defined as a corrosion product or deposition, on the surface of a corroded metal, that is of such thickness that it cannot be measured by the metallurgical microscope. A coating, on the other hand, is of such thickness that it can be measured. If the resolving power of the 2 mm. (equivalent focal length) apochromatic oil immersion objective (N.A. 1.4) is taken as the limit of the microscope, the limiting resolution is two lines that are 0.0002-0.0004 mm. apart. It is thus possible to measure coatings that are greater than 0.0002-0.0004 mm. thick. This thickness is equivalent to 200,000-

Jan 7, 1924

By Arthur E. Hall

Tax operation of "softening" in lead refining is designed, as the word implies, to separate from the bulk of the lead the elements that tend to make lead hard. These elements, which invariably are present in argentiferous lead, interfere with the desilverization, and must be almost entirely absent in refined desilverized lead. They are mainly copper, antimony, arsenic and tin. The properties utilized in accomplishing this separation are the low solubility of copper or copper sulphide in lead at its freezing-point temperature, and the greater and selective affinity for oxygen of the other elements at temperatures of the order of 700° to 900' C., or, in the prcsence of sufficient, alkali, at a temperature of about 500' C. The major problems of softening lead bullion lie in the necessary subsequent treatment of the by-products of the primary operation, which contain, either chemically or mechanically, lead or reagents that must be isolated for market or re-use. Therefore an important objective of the primary operation must be the highest practicable concentration of these elements in the by-products. Within the past three decades, during which the writer has been engaged in lead refining, the technique of softening lead bullion has had as many variations as there were lead refineries. This was the result of the variation in composition and character of lead bullion recived. The writer has received for refining shipments of lead bullion varying as widely as indicated by the following table: Sb, Per CEnt As. Per Cent Sn, Per Cent Cu. Per Cent Ag. Oz. per Ton 1.00 0.05 nil 0.05 70 0.50 2.50 2.00 0.50 200 3.50 0.50 nil 0.30 350 At times these have been received uniformly and at other times irregularly with a variation from week to week as wide as those shown. Under such conditions, establishment of a universal softening technique presented many problems. Such variations existed because refinery tolls too often were based on a ton of bullion, whatever its composition, and

Jan 1, 1937