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By U. F. Kocks

SINGLE slip and a single parallel array of edge dislocations have been obtained in silicon single crystals by homogeneously bending them in a four-point dead-loading device at 1000°C around the [211] axis with [253.] as the tensile axis which encloses an angle of 40° with the glide plane. Other orientations or lower temperatures proved unsuitable. The homogeneity of the bending was checked by the method shown in Fig. 1. The chemically polished specimen was exposed to parallel light from a microscope-stage lamp. The sharpness of the focus of the reflected light is an approximate measure of the circularity of the sample. This method permitted the determination of the actual radius of bent specimens within 10 pct accuracy. The etching solution developed to show up dislocations consisted of the following volume parts: 2 HF, 1 HNO,, 2 CH,COOH, 1 a solution of 5 wt pct of CuNO, in water (Rosi'). The acetic-acid content was adjusted to produce fine well-defined etch-pits in about 2 min at room temperature. The effectiveness of the etch did not depend on the crystal-lographic orientation of the face etched. The number of etch pits produced after a given deformation was checked in the usual way against the Cahn formula' and showed good agreement. As it is to be expected from the orientation of the primary system there are slip steps on the top and bottom faces but not on the side faces (perpendicular to the bending axis), whereas etch pits appear on the side faces but not on the top and bottom faces. This is different only for occasional dislocations of a secondary glide system. All the micrographs included have been taken in places where the most of secondary glide could be seen. From this it is evident that in the homegeneously deformed region the number of secondary dislocations was less than 1 in 1000 of the primary type. Dislocation Distribution—A series of tests with varying amounts of deformation is shown in Figs. 2(a-c). An observation that can readily be made from these pictures is that the linear density of dislocations within slip lines is relatively constant and independent of the amount of deformation. "Slip line" in this context is understood to mean a line that is a straight connection of individual etch pits. The heavily pitted bands which can be seen in each of these three pictures may be resolved fairly definitely, at higher magnifications, into many "slip lines" the distance between them being of the order of 0.5p The distance between dislocations in slip lines is of the order of 2p and it is also fairly constant in going from the neutral zone outward. The higher over-all dislocation density in the outer regions of any sample and the higher total number in a more heavily deformed sample, are effected by a larger number of "slip lines." The relative constancy of the dislocation distance within an individual slip line is surprising. The absence of pile-ups" may imply, if there is no rear- rangement on unloading," that there are no substantial obstacles to slip in this case. It seems that the equilibrium distribution of the dislocations in each active slip plane under the higher external stress on

Jan 1, 1959

By R. H. King

This paper describes the results of an underground coal mine trial installation of a shielded trailing cable. The cable was a three conductor, round, type SHC-GC and was installed on a shuttle car in a conventional room-and-pillar mining section. The purpose of the study was to evaluate proposed legislation that would require shielding on low-voltage trailing cables. Such legislation would require machine modifications to cable reels, packing glands, and couplers; increase cable splicing complexity; and necessitate additional splicing materials and training. Furthermore, fault location might be more difficult. Even though shielding will cause some problems for the mine operator, it can reduce electrical shock hazard to mine workers. This paper presents information that mine operators can use to solve most of the problems encountered if they are required to install shielded cables. The in-mine evaluation was funded by the US Bureau of Mines; however, the views and conclusions in this paper are those of the author and should not be interpreted as necessarily representing official policies of the US government.

Jan 1, 1982

By Robert L. Taylor, Richard E. Goodman

A complete rational analysis for design of excavation slopes and loaded rock masses is a desirable but perhaps unattainable goal. Irregular external and internal boundary conditions, poor understanding of failure criteria for large masses of rock, capricious material properties, and the importance of indeterminate forces and inaccessible and virtually unsampleable rock defects emphasize the importance of experience in this aspect of rock engineering. The experience must be correlated with geological factors. In certain regions the accumulation of such experience through the observation of existing rock slopes in various formations constitutes an important aspect of studies for design of rock excavations. In former times an accepted method of rock construction consisted of trials and adjustments. This approach is not often compatible with present methods of contract management. With the development of improved instruments and warning devices such as inclinometers, piezometers, relays, stress meters, and rock noise detectors, modified trial procedures of rock construction may reappear in specific applications. In spite of the great advances made, development of methods to predict the performance of rock slopes, abutments, and foundations deserves vigorous effort. Two distinct approaches may be taken. The rock mass in question may be considered a continuum and the stresses and strains throughout the region of influence of the work may be calculated. Or, the rock mass may be described as a discontinuum whose stability calculation involves the statics and kinematics of accumulations of rigid blocks. The prototype must lie in the range between these contrasting models. As yet, however, there is little reconciliation between the two methods

Jan 1, 1967

[ARIZONA Established July 10, 1915 ROBERT W. HUGHES, Chairman CHARLES R. KUZELL, First Vice-Chairman GILBERT C. DAVIS, Second Vice-Chairman W. CLARK MASON, Secretary-Treasurer Inspiration Cons. Copper Co., Inspiration, Ariz. LYLE BARKER ROBERT HIGH T. G. CHAPMAN P. D. I. HONEYMAN GEORGE M. COLVOCORESSES WALTER C. LAWSON EDWIN H. CRABTREE, JR. W. H. LOERPABEL WALTER I. GARMS ALBERT MENDELSOHN WESLEY P. Goss CARL E. MILLS H. C. HENRIE JOSEPH A. WILLCOX C. F. WILLIS]

Jan 1, 1946

By S. K. Kawatra, R. A. Seitz

Various mathematical models and expressions to describe the behavior of a hydrocyclone have been presented in the literature (Lynch and Rao, 1977; Plitt, 1976; Plitt and Kawatra, 1977). Two of these models, by Lynch (1977) and by Plitt (1976), have been extensively used for process control studies (Kawatra and Thayer, 1879; Seitz and Kawatra, 1984). However, neither of these models relates the fineness of grind in a hydrocyclone overflow to the corrected efficiency curve of a hydrocyclone. If such a relationship were available, then one could relate fineness of grind to the operating variables using equation (1) or (2). A plant metallurgist is interested in knowing the fineness of grind rather than the dso(c) of a hydro- cyclone. As a consequence, several empirical relation- ships between fineness of grind and hydrocyclone operating variables are available. These relationships (Fewings, Wickham, and Wiseman, 1979; Manning, 1978; Watson, Cropton, and Brookes, 1970; Watts, Thompson, and White, 1978; Wiegal, 1973) have only a limited relationship with each other and have met with varying degrees of success. The object of this paper is to develop a fundamental relationship between fineness of grind and the efficiency curve of a hydro- cyclone

Jan 1, 1986

By Herbert H. Kellogg

In 1930, Taggart, Taylor and Knoll1 found that addition of various electrolytes to suspensions of ground minerals resulted in the stopping or starting of Brownian movement of the suspended particles. On the basis of the many new facts found, they rejected the " classical"† theory of Brownian movement and proposed an "ioniza-tion " theory. This new theory was further supported in later publications by Taggart.3,4 The acceptance of the ionization theory by men in the field of flotation may be judged by the mention given this theory in Gaudin's "Principles of Mineral Dressing,'16 Wark's "Principles of Flotation,"8 as well as in a recent paper by Fitt, Thomas and Taggart.7 The proponents of the ionization theory have gone further than the mere statement of the new theory. A parallelism between the Brownian movement of mineral particles and their behavior in flotation was reported.1,3,4 Likewise, the correlation between flocculation-dispersion of mineral particles and the Brownian movement of these particles has been investigated.' Bankoffl5 has suggested that "slime-coating" can also be directly correlated with the Brownian movement of the slime particles. In each of the instances mentioned it is the ionization theory of Brownian movement that has been used to "explain" the correlations that were found. The essential conflict between the kinetic theory and the ionization theory can be understood best by a brief description of each. The kinetic theory* proposes that Brownian movement is caused by the impacts of liquid molecules against the solid particles. At any instant of time, the molecular impacts on all sides of the solid particle will not balance, and the particle will receive a push in some direction. According to this theory, dl particles suspended in a liquid are in Brownian movement. However, if the particle is very large, the impacts on all sides will very nearly balance and the motion will not be noticeable. Another factor, besides the size of the particle, that affects the magnitude of the Brownian movement is the viscosity of the liquid—the greater the viscosity, the less the displacement of particles by Brownian movement. This theory has been verified experimentally by measurement of the velocity of Brownian movement, and by measurement of the compacting of suspensoid particles under the influence of gravity.2 The originators of the ionization theory found that he addition of various electrolytes to slime pulps caused cessation or commencement of Brownian movement, depending upon the chemical nature of the particle and the electrolyte. The Brownian movement of quartz particles was observed to stop upon the addition of Certain electrolytes, where the conditions of the experiment prevented flocculation

Jan 1, 1947

By George Otis Smith

In the utilization of natural resources owner, operator, and consumer* should share the attendant benefits. Development needs to be planned under terms recognizing fully the interests of all concerned, for ally undue advantage given to any one of these participants is apt to involve even greater and disproportionate injury to one or both of the others. For this reason it is well to preface any consideration of needed reforms in legislation affecting the disposition of public land with a survey of certain fundamental principles that determine the general conditions of a11 land transfers preliminary to development, utilization, and production. The disposition of any undeveloped natural resource, whether timber, oil, coal, or water power, as a transaction to which land owner and prospective developer are parties, must be based in theory upon a division of expected returns.' Whatever the terms of such disposition, neither party can reasonably ask for anything other than an equitable division of the returns. Under this analysis three and only three questions need to be discussed; namely, what are those profits, how is this division to be accomplished, and what is the equitable basis of division ? The answer to the third question should probably be found by applying to the problem the principles of theoretical sociology, and the question need not be mentioned further at this time, inasmuch as it does not involve the practical considerations to be kept in mind in connection with the other questions, which are concerned with only the measure of returns and their division. That is to say, whether the land owner's equity is to be stated as 95 per cent, ox as 6 per cent, of the profits attending the development of the particular resource, no change would be necessary in the method to be adopted of arriving at the closest approximation of the prospective total profit. If on this basis we now compare the two methods of disposing of

Jan 1, 1915

NEW MEMBERS The following list comprises the names of those persons who became members during the period Oct. 10 to Nov. 10, 1914: Members ADDAMS, CHARLES EDWARD, Asst. Supt.. . Ray Consolidated Copper Co., Ray, Ariz. ALEXANDER, HARRY H., Asst. Mgr. and Mgr., American Smelting & Refining Co., Maurer, N. J. ALLING, MARK,N., Min Engr Downieville, Sierra Co., Cal. ANDERSON, LESLIE DOUGLASS, Supt U. S. Smelting Co., Midvale, Utah. ATKINS, WILLIAM, JR., Sec'y Kingwood Coal Co., Howesville, W. Va. BLAKE, TRUE WALTER, Min. Engr Rombauer Coal Co., Novinger, Mo. BRACKETT, GEORGE SYLVESTER, Supt... Pittsvein Coal Co., Flemington, W. Va. BRAINERD, HOWARD STANFORD, Met Ingersoll-Rand Co., Phillipsburg, N. J. BROWN, THOMAS J., Genl. Supt., Nova Scotia Steel & Coal Co., Sydney Mines, N. S., Canada.

Jan 12, 1914

By G. K. Dumbauld, B. E. Morgan

A satisfactory well-cementing composition must retain its fluidity long enough to be pumped into Place; then it must develop within a reasonable length of time sufficient strength and impermeability to anchor the casing in position and to form an effective seal between the casing and the formations. These properties may be evaluated by pumpability, strength (compressive or tensile), and permeability tests. Laboratory test procedures for the determination of pumpability time and strength development have been outlined previously and are readily available,1 but a satisfactory and convenient laboratory procedure for the measurement of the permeability of set cement has not been developed heretofore. some permeability data have been obtained previously by passing air through dried cement specimens.2 such a procedure is unsatisfactory because the drying of set cement alters it physical and chemical properties and subjects it to conditions dissimilar to well conditions. A more realistic method would be one wherein the cement remains water-saturated durin

Jan 1, 1952

By R. A. Swalin, L. A. Neimark

The research work presented in this paper had initially a two-fold goal. First, further data concerning the low-temperature recovery of cold work was desired. Recovery phenomena have been extensively studied in face-centered-cubic metals but at the time of initiation of this research, no investigation concerning the low-temperature recovery in body-centered-cubic metals had been made. During the course of the investigation a paper by Martin on the recovery of point defects in molybdenum appeared.&apos; Comparison of our results on tungsten with Martin&apos;s results on molybdenum will be made. Secondly, knowledge concerning the influence of a particular type of impurity addition on the recovery kinetics was desired. It has been known for a long time that extremely small amounts of certain impurity additions exert a profound influence on the recrystallization behavior and the resulting microstructure of tungsten. Small amounts of potassium silicate and aluminum chloride added prior to the reduction of tungsten oxide to the metal have been found by Smithells to raise the recrystallization temperature markedly,2 and yield an ultimate microstructure in which grains several millimeters long are produced in fine wires of say 10 mil diam. If the impurities are added singly, ordinary secondary recrystallization results with none of the spectacular properties of the wire to which special additions were made. Swalin and Geisler3 and Rieck4 have studied the recrystallization behavior of such doped wire in some detail. The former workers found that small amounts of these impurities raised the recrystallization temperature over 400°C and electron microscopic examination revealed no obvious inclusions in the microstructures. In fact. chemical analysis showed that there was <0.001 pct K, <0.002 pct Al, trace of Si, and <0.0003 pct 0 in the wire studied. The possibility that the role of the special impurities is to keep the structure open by void formation and that submicroscopic porosity acts as the inhibiting agent has been discussed.2&apos;3 Meijering and Rieck5 have suggested that the impurities are strung out as second-phase particles in a direction parallel to the drawing direction. It was thought that a kinetic study of recovery could perhaps elucidate the role of the impurities to some extent. When a metal is deformed by cold work three basic types of defects are thought to be introduced into the crystal lattice, namely, interstitials, vacancies, and dislocations. Van Bueren6 has proposed that recovery of cold-worked metal is a four-stage process, each step being the result of the annealing of a primary defect or a combination of defects and having a unique activation energy. The steps in order of increasing activation energy are attributed to a) the diffusion of interstitials recombining with vacancies, b) diffusion of vacancy pairs, c) the diffusion of single vacancies, and d) climb of dislocations. In metals with relatively low- or medium-range melting points the temperatures for recovery are low enough so that the first three steps may occur during room-temperature deformation. For tungsten, because of the high melting point and subsequently high recovery temperature, it was calculated, using Nowick&apos;s approach7 that this recovery would occur in the temperature range 200" to 600°C. It is also known that recovery of X-ray line broadening, presumably due to dislocation climb, occurs at about 600°C.8 EXPERIMENTAL METHOD Two types of cold-rolled 10-mil-diam tungsten wire were used in the investigation; a) pure tungsten, (called undoped) and b) G. E. No. 218 wire (called

Jan 1, 1961

By Hsun Hu

Based on Kurdjumoiv-Sachs orientation relationship for the fee bee transformation in metals, the jirzal crystal orientation resulting from successive transformations of bee-fee-bee has been analyzed mathematically. There are 528 different variants; many of ther are crystallograpyically equirvalent. Specific examples show that, for equal probability of all the variants, the principal crystallographic axes [100 ], [110], and [111] of the initial bcc crystal can be transformed into vairous axes in the fina1 crystal However, fur each of these principal crystallographic axes, a continuous range of orientation within certain regions of the unit triangle is completely avoided by the finctl Crystals. For uses of higher indices, the final orientations are more uniformly distributed throughout the unit triangle. Results from the PI-esent analysis are in good agreement with preferred Oientations Observed in a zone-meltecl iron bar. THE allotropic forms of iron are characterized by the unusual fact that at both high and low temperatures a bcc structure is stable, whereas at intermediate temperatures (1400" to 910°C) the metal is fcc. Hence, during cooling from its melting temperature, iron undergoes successive phase transformations ofd—? —a with corresponding changes in the crystal structure of bcc — fcc -bcc. while numerous studies have been made in the past of the 1 — a transformation in iron and in various iron-base alloys, no information is available in the literature as to the mechanism of 6 — l transformation and the lattice orientation relationship between these two phases. Experimental difficulties have apparently prevented researchers from undertaking these studies. The laltice orientation relationship between the parent and the new phases of iron resulting from

Jan 1, 1965

By L. W. Pommier, F. B. Brien

The Rheological properties of pulps are non-Newtonian in character and more than one viscosity parameter is necessary to describe their behavior, therefore, the single term &apos;apparent viscosity&apos; which has been used in the past may be misleading. The study reported in this paper uses a dimensional analysis based on the Ostwald-de Waele shear stress-rate of shear model for non-Newtonian liquids to develop velocity and resistance equations for falling spheres. An electronic monitoring apparatus was assembled for determining the velocity of metallic bodies as they fall through opaque liquids and suspensions. By means of this apparatus the behavior of the viscosity parameters of the Ostwald-de Waele model and the applicability of the proposed equations were examined for a number of non-Newtonian liquids. The validity of the equations for these liquids was confirmed. Preliminary data collected using solid-liquid suspensions established the validity of the form of the basic equations for these systems. The differential movement of solid particles through solid-liquid pulps and suspensions is very important LO many branches of engineering, such as minerals processing, soil mechanics, ceramic slip processing, oil well drilling-mud technology, materials-handling in pipelines, and many others. There is a dearth of fundamental knowledge on the flow resistance encountered by immersed bodies moving through solid-liquid suspensions. The resistance offered by Newtonian liquids to the movement of free settling spheres is well described for laminar and turbulent conditions by Stokes&apos; and Newton&apos;s Laws, respectively. However, problems are encountered when attempts are made to extrapolate these simple relationships into solid liquid suspensions. The rheological properties of pulps are such that they are non-Newtonian in character;&apos;" that is, the applied shearing stress and resulting rate-of-shear are related by non-linear functions, and thus, in the simplest case two viscosity parameters are necessary to describe their rheological properties. For this reason the single term &apos;apparent viscosity&apos; which has been commonly used to explain the flow resistance of suspensions and non-Newtonian liquids may be misleading. It is realized that a rigorous analysis of the rnechanisms of momentum transport of liquid-solid systems is complex indeed. There are many variables that affect the rheological properties of the systems such as density, size, shape, and surface energy of the suspended solid and density and viscosity of suspending liquid, as well as the solid to liquid ratio. However, it was felt that a useful contribution to the knowledge of the behavior of suspensions could be made by examining the systems in terms of the basic fundamentals of nowNewtonian flow. This has led to the development, by means of dimensional analysis, of velocity and resistance equations, using two viscosity parameters to describe the velocity of penetrating bodies and the flow resistance encountered by these bodies, as they pass through non-Newtonian systems. THEORY In order to examine the effects of the rheological properties of solid-liquid suspensions on the movement of immersed bodies it is appropriate to start with non-Newtonian liquids and develop equations, analogous to those of Stokes and Newton, for laminar and turbulent flow respectively, from which quantitative information may be obtained. Further investigation would then be directed at the complex suspension systems, and the effects of the many variables on the velocity and resistance equations. Liquids are classified on a basis of viscosity which may be defined as the relationship between applied shear stress and resulting rate of shear?-&apos;* Pure single phase liquids composed of small light molecules behave as Newtonian liquids, having a single viscosity parameter since the shearing stress and rate-of-shear are related by a linear function. Bingham plastics are similar but have a yield stress. Of particular importance in our investigation are dilatant (shear thickening) and pseudoplastic (shear thinning) non-Newtonian liquids, with and without yield values.

Jan 1, 1968

By J. Parke Channing

THE caving system of mining is that method of removing the ore from an underground body in which the top is first attacked and mined out and the capping, or roof, as the case may be, is allowed to fall in or "cave" and fill the space formerly occupied by the mined ore. It is applicable, generally, to large orebodies where the ore is relatively soft. We may say, within moderate limits, that when ore is removed the surrounding ground either caves in or remains open. For example, in mines like the Lake Superior amygda-loid copper mines, when the lode is removed there is left a void which remains open for many years; on the con-trary, mining a Lake Superior soft hematite ore, however carefully it may be done, always produces a caving of the surrounding rocks. We may say, with propriety, therefore, that the caving system is applicable to that type of ore deposit in which the surrounding rock readily caves. Another factor which governs the use of the caving system is the value of the ore itself. Admittedly, any form of caving will not extract 100 per cent. of the ore, and in the case of a very rich orebody it is often desirable to get out every pound of the ore with as little dilution as possible. Under these conditions, some other method of mining, such as that by square sets and filling, is indicated and should be followed. We may say, however, that, looking at it broadly, in the United States the caving system of mining is generally used for the removal of soft hematite and for the so-called "porphyry" coppers. In both cases this method is used where open-pit mining is not possible.

Jan 1, 1922

By C. D. Stahl, S. M. Farouq Ali

This investigation attempts to describe and simulate the alcohol displacement process by means of a cell model, as employed in chemical engineering practice. The proposed model is more simple than previously proposed models. and utilizes parameters chosen on a theoretical basis. The model successfully reproduced the formation of the stabilized bank and the breakthrough of alcohol, the latter depending on one of the model parameters, which may be correlated with the length of the porous medium. Moreover, the effects of the phase behavior of the liquid system involved, as observed in experimental studies, were reproduced. Several variations of the basic model were devised and tested on a digital computer. These included the cases in which: (1) the actual value of fractional flow was used in cell-to-cell computations; (2) the number of cells was varied within the same run; and (3) incomplete rather than complete phase equilibrium was assumed within each cell. The proposed cell model clarifies the basic mechanism of the process. Detailed concentration profiles obtained for each cell, for instance, showed the mechanism of bank formation in relation to the phase behavior characteristics. The results obtained indicated a varying degree of phase equilibrium concommitant with changes in the velocities of the phases in an actual alcohol displacement. This condition was approximated by changing the number of cells during the simulation. Interesting information was obtained on the influence of path length on the efficiency of alcohol displacement, which has been the subject of some controversy. Certain limitations preclude the use of the proposed model as a substitute for experimental studies. The results obtained were, nevertheless, of value in interpreting the experimental results. INTRODUCTION During recent years considerable effort has been directed toward an understanding of alcohol displacement, the process whereby oil and water are recovered from a porous medium by the continuous injection of a solvent. The complex nature of the physical process involved has so far defied a complete mathematical treatment. Other methods of approach, amounting to an overall material balance, have been proposed, yielding useful information on certain aspects of the process.1-3 Taber et al, in particular, defined the displacement mechanism in terms of the phase behavior of the alcohol-oil-brine system invoIved.2 Wachmann reported a mathematical treatment of alcohol displacement subject to certain simplifying assumptions? Donohue proposed the use of a "cell model" for simulating alcohol disPlacement.5 The nature of the assumptions involved limited the utility of the model. The present work attempts to examine the variables involved in the simulation of alcohol displacement and discusses several possible versions of the basic cell model. Under certain conditions the model results are similar to the experimental results. In particular, the spontaneous formation of of the stabilized bank and the effects of the system phase behavior were successfully reproduced. PREVIOUS WORK ON CELL MODELS Cell models and the theoretical plate concept are often used in solving chemical engineering problems in which an explicit mathematical solution may be difficult or impossible to obtain. Examples of such applications occur in distillation, gas-liquid chroma tography,6 reactor technology, absorption, etc. In petroleum engineering, such a model was used by Attra7 to describe non-equilibrium gas drive, and by Higgins and Leigh ton8 to calculate sweep efficiency in water flooding. Aris and Amundsen pointed out the equivalence between the diffusion model and perfectly mixed cells connected in series.9 Deans proposed a three-parameter cell model to simulate two-component

Jan 1, 1966

By P. V. Martin

Shortly after the middle of the nineteenth century, the invention of the regenerative open-hearth furnace and the development of the Bessemer process stimulated a rate of steel production whose magnitude created an unprecedented demand for pig iron. Revolutionary improvements in furnace design, auxiliary equipment, and operating technique enabled the blast furnace to keep abreast of the constantly increasing requirements of the steel mill. The development of improved blowing equipment, more adequate facilities for material handling, and particularly the general use of anthracitc and coke to replace the physically weaker charcoal, led to a rapid expansion in both the height and volume of furnaces. Beyond a doubt, however, the greatest single factor in blast-furnace improvement at this time was the use of the higher blast temperatures made available by the replacement of the recuperative iron pipe stoves by the regenerative Cowper brick stove. The increased blast temperature not only resulted in greater output but also reduced fuel consumption . far more than could be explained by the additional heat content of the blast. The progress of iron manufacturing was thus largely mechanical and thermal. Little attention was given the chemistry of the process until the publication of the investigations of Sir Lowthian Bell.1 Bell&apos;s painstaking experiments and investigations gave to the blast-furnace man his first real scientific conception of blast-furnace chemistry. Bell&apos;s recognition of the dual function of the carbon, the technical importance of reversible reactions and chemical equilibria, and his conception of the degree of oxidation of the carbon as shown by the analysis of the outgoing gases as a criterion of furnace efficiency, laid the foundation upon which has since been erected the structure of blast-furnace theory. Prominent among those availing themselves of Bell&apos;s data as .a basis of further study was M. L. Gruner,2 professor of the French School of Mines. His "Blast Furnace Phenomena," published in 1870, presented

Jan 1, 1940

THE primary interest in the subject of this chapter lies in the fact that various heats of steel made to the same chemical specification do not always have the same properties. The properties considered here, of course, are those inherent in the ingot immediately after solidification and not qualities imparted by variations in subsequent mechanical or thermal treatment. The expression "made to the same chemical specification" is used because some of the variations in properties are due to variations in chemical analysis within the specified ranges of those elements commonly specified and determined. Other variations in properties are due to variations in those constituents of steel (elements or compounds) that are not ordinarily included among the elements specified, thus not a part of the specified "composition." The term "constitution" is used to include not only the specified composition but also the nature and distribution of every element or compound contained in the steel entering the ingot mold ; also included are items such as aluminum oxides and nitrides, presence of soluble gases, and dispersion of nonmetallic particles. When it is considered that the constitution of steel is determined by the addition or absorption into the bath of all such constituents from whatever source, it follows that constitution is of necessity the final result of steelmaking practice. It is the agency through which steelmaking practice operates to control the properties of the steel. The term steelmaking practice is here used in the broad sense, meaning the control of all the materials entering the steel and of the conditions under which the process is carried out. Steelmaking practice, thus defined, establishes the chemical system within which the reactions between components must proceed in obedience to the laws of chemistry. Thus the chemical constitution of the steel is established and, through constitution, the properties of the metal are established. In the preceding chapters it has been shown how the constitu-

Jan 1, 1964

By A. J. Mortlock

Cobalt and nickel have been diffused at tracer concentrations in gold at several temperatures in the range from approximately 700° to 950°C. The diffusion penetration profiles were determined by a serial sectioning technique in which the gold is first anodized and then the anodic layer is dissolved in acid. In this ulay sections as thin as 250A could be removed reproduci-bly. In all cases, the region close to the specimen surface was characterized by irregular behavior in the sense that the logarithm of concentration was not linear in the square of the penetration distance. In sotne cases, there zuas an indication of the operation of very slow dijfusion in this region, while in others the apparent diffusion coejj&apos;icient was negative. Possible reasons for this anomalous behavior are briefly discussed. In recent years it has been found that the region close to the surface of a metal can sometimes exhibit anomalously slow diffusion characteristics relative to the interior of the metal. One of the best examples of this fact is the work of Styris and omizuka,&apos; who showed that the apparent diffusion coefficient for zinc in the region withi: about 1 p of the free surface of copper was about ,,,, that at deeper penetrations. This result is particularly interesting, because it is free from the possibly complicating effects of low solubility of the diffusing tracer in the solvent metal. In the case of diffusion under conditions of low solubilitjr, interpretaticn of the results in terms of lattice diffusion is difficult because of the enhanced short-circuiting produced by segregation to dislocations.2&apos;3 Measurements by Duhl et 1. suggest that cobalt diffusing in gold may also show a near-surface effect of this type. Once again the solubility is high, so that this result could be of great interest. However, the technique used for analyzing the diffusion penetration zones by Duhl, viz. the counting of residual gamma activity in the specimen following sectioning, appears to have indicated a near-surface effect in a parallel experiment on the self-diffusion of gold reported at the same time. The latter result is known to be spurious, since Kidson5 has demonstrated that self-diffusion in gold does not show this effect. Duhl et 01. also reported some measurements on the diffusion of nickel in gold, but failed to give any data for the near-surface region. As the solubility of nickel in gold is high, such data would also be of special interest. We, therefore, decided to conduct another set of experiments on the diffusion of nickel and cobalt in gold, using a sectioning technique that allows the individual sections to be assayed for solute content and thus gives direct determinations of penetration profiles. Also, by sectioning with an anodizing/stripping tech- nique, very thin layers can be removed and the region close to the surface studied in detail. MATERIALS The gold specimens were supplied as single crystal disks $ in. in diam by a in. high by Monocrystals Co. of Cleveland, Ohio. The gold itself was of spectro-scopic purity, i.e., better than 99.99 pct pure. METHOD Specimen Preparation. One flat end face of each gold crystal was spark planed with a Servomet spark erosion machine set for minimum spark energy. Following this treatment the crystals were preannealed for 2 to 4 days at temperatures of either 400" or 700°C. The three crystals preannealed at 700°C showed signs of recrystallization. The spark-planed end face of each crystal was then coated with the appropriate amount of 63i or 60 radioactive tracer. This deposit was laid down in a simple plating bath containing the as-supplied solution of the radioactive isotope as well as sufficient ammonium oxalate to saturate the solution. Some ammonium oxalate remained undissolved on the floor of the bath for this purpose. During plating further additions of ammonium oxalate were sometimes required to allow the plating to continue satisfactorily, perhaps due to passivation of the undissolved oxalate already present. The thickness of the deposited layer was determined by comparison of the apparent surface activity of the plated specimen with that of a similar specimen having a weighable deposit of the isotope on its end face. Correction for self-absorption of the radiation was made in this calculation. Annealing. The deposited crystals were annealed in a hydrogen atmosphere in sealed silica tubes. During this heat treatment they were supported, active face down, on optically flat silica plates. The temperature was measured with calibrated Pt vs Pt-10 pct Rh thermocouples, and the tabulated values can be taken to be correct to Z°C. All the crystals showed evidence of recrystallization following these heat treatments, suggesting that initially they may not have been good single crystals or had suffered strain during delivery. Concentration Profile Analysis. After annealing, the crystals were sectioned by the anodizing-stripping technique.6 The anodizing involved suspension of the specimen with its cylindrical axis horiz6ntal by a gold wire in a 200-ml beaker containing 1 M Hg304. A cathode in the form of a strip of gold sheet, 2 in. wide and positioned to be in contact with the curved side of the beaker, completely encircled the specimen. An anodizing current of 30 ma, corresponding to a current density of 5 ma per sq cm on the surface of the specimen, was passed for times ranging from 5 to 150 min depending on the thickness of gold to be removed; the solution was stirred continuously during this process. Following this treatment, the specimen

Jan 1, 1969

By John Birkinbine

Among the notable deposits of iron-ore, the Iron Mountain at Durango, Mexico, is prominent. But, although it has been noticed in records of travel and official reports for three centuries, the statements made concerning it have been so largely alloyed with improbabilities that general credence has not been given to data relating to the Cerro & Mercado, that being the name by which this remarkable mountain of ore is known. Location. Geographically, the mountain is centrally located, being situated immediately at the City of Durango, which is distant in direct lines (as the crow flies) as follows: From the Rio Grande River at El Paso, Texas, in the north, 510 miles; from the same stream at Laredo, Texas, in the northeast, 410 miles; from Tampico, in the east, 475 miles; from the City of Mexico in the southeast, 520 miles; from Mazatlan in the west, 110 miles. At El Paso, the standard-gauge Mexican Central Railroad, and at Laredo, the narrow-gauge Mexican National Railroad, enter Mexico. Tampico is a prominent Mexican port on the Gulf of Mexico, and Mazatlan occupies a similar position on the Gulf of California. To reach Durango from Laredo or Tampico, spurs of the Sierra Madre Mountains must be crossed, and between Mazatlan

Jan 1, 1885

By R. H. King

The Automatic Extraction System (AES) was designed and built under a US Department of Energy Contract by the National Mine Service Co. in cooperation with the Lee Engineering Division of Consolidation Coal Co. The Pennsylvania State University, Mining Engineering Section, was contracted as an independent auditor of the AES performance. The AES had a rotating cutter drum like a continuous mining machine. But two hydraulically powered roof supports, four roof-bolting drills, a dust scrubber, a ventilation fan and ducting in the roof supports, semi-automatic control, an extensible chain conveyor, and other innovations led to the distinction "extraction system" as opposed to "miner-bolter" or continuous mining" machine. After design and assembly, the AES was field tested experimentally in an underground coal mine. The in-mine performance audit was preceded by a computer simulation of the potential production for a later comparison with the actual tonnage mined by the AES. This paper describes the results of an in-mine trial and assesses the production potential of the AES.

Jan 1, 1983

By Fred N. Kissell, Natesa I. Jayaraman

Introduction This paper describes a recent Bureau of Mines research project that resulted in a simple procedure for reducing the dust exposure of longwall shearer operators. This project involved the development and testing of a water spray and passive shield system to hold dust against the face and away from the shearer operators. This system is known as the Shearer- Clearer.

Jan 1, 1981