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By S F. Simmons

The Ohaaki Rhyolite and the Rautiwiri Breccia are two volcanic units occurring in the shallow and deep parts of the Broadlands-Ohaaki geothermal system. Alteration of these units by chloride waters results in distinct mineral assemblages that also have distinct whole rock compositions. The Ohaaki rhyolite is altered to an assemblage dominated by quartz, adularia, illite and pyrite as a consequence of silica, potassium and sulfur metasomatism. Locally, these rocks contain up to 0.5 ppm Au. The Rautiwiri Breccia by contrast is altered to an assemblage dominated by albite, adularia, quartz, illite, chlorite and pyrite in association with modest sodium metasomatism. Whole rock oxygen isotope compositions of altered rocks range between 3.3 and 7.5 ë, and are generally lower compared to their fresh rock equivalents having values of 9.5 to 10.6 ë; the result is broad pattern of lower values with increasing alteration intensity.

Jan 1, 2002

Key incompatible element ratios for metabasalts from the Early Permian Croisilles and Patuki Volcanics, South Island, New Zealand, provide constraints on the tectonic environment in which their precursor ophiolitic protolith formed. Two geochemically distinct metabasalt suites are recognised among both the Croisilles and Patuki rocks. Metabasalts from one suite exhibit the geochemical signatures of depleted tholeiites from oceanic spreading ridges (N-type MORB) or spreading centres in evolved back-arc basins. These N-type tholeiites show high Zr/Nb ratios (Zr/Nb = 37-62) and are depleted in light rare earth elements (LREE)((La/Y)N

Jan 1, 1987

The relative contents of Au in a series of groundwaters from water bores and exploration drillholes, located near Au mineralisation at Stawell, Ararat, Clunes and Ballarat in central Victoria, were found to be clear indicators of relative proximity to mineralisation in each region. In the same series, waters with anomalous concentrations of As distinguished Au mineralisation in bedrock from secondary palaeochannel or deep lead Au. In some groundwaters, acid pH values, high sulphate relative to other anions and detectable concentrations of reduced Fe reflected sulphide minerals associated with bedrock Au deposits. Close to some ore zones, locally anomalous groundwater concentrations of Mn reflected the Fe carbonates that accompany Au in these zones. In addition, elevated concentrations of other elements provided geochemical signatures for the aquifer lithologies associated with Au mineralisation. Of the lithological indicators Co and Ni, U and F, Rb and Cs, Mo and Li respectively reflected the mafic, felsic, potassic rich and quartz zones, principally in the Stawell mine area and to a lesser extent those at Clunes and Ballarat. Mineral stability diagrams, based on groundwater activities of K', Mgt and H`, demonstrated that a series of ore-zone groundwaters follow a trend that conforms with a biotite to sericite to kaolinite alteration sequence in aquifer mineralogy. This is a good illustration of how present day groundwaters under surface conditions can reflect the underlying mineral sequences that accompany these Au deposits. These observations around mine areas suggested that groundwater chemistry could provide a rapid and cost effective method of assessing prospectivity for An of extensive areas in central Victoria. To test this, regional sampling and analysis of 355 bore waters was carried out in a region where potential An bearing rocks are covered by Mesozoic and Cainozoic sediments and volcanics. Contoured elemental abundances and distribution from this program indicated five zones in which groundwaters had elevated Au and despite the cover, appeared to reflect variations in the underlying Palaeozoic rocks. Three of the Au zones could be in terrain affected by extensions or intersections of faults, a feature in common with the established Au deposits in central Victoria. Reflections of concealed Palaeozoic rocks included a possible zone of concealed Cambrian greenstones that coincides with three of the Au zones. It was concluded that each of the An zones represents a groundwater Au focus that warrants follow-up exploration.

Jan 1, 1997

By S D. C Rabone

An elongate belt containing granodiorite stocks with associated stockwork molybdenum mineralisation in west Nelson is correlated with the I-type Separation Point Suite of mid Cretaceous age. Trace element characteristics of the 'Mo-granites', and the Separation Point Batholith strongly suggest a primitive, subcrustal origin for these granitoids, by partial melting of oceanic basaltic crust or upper mantle material in a subduction zone. They were emplaced in the upper crust without undergoing significant differentiation or contamination by sialic crust. Molybdenum, which is at levels of approximately 5 ppm in unaltered granite, is not significantly reduced in altered (but unmineralised) granite. This suggests the metallisation has a magmatic, subcrustal source and is not derived by hydrothermal leaching of upper crustal rocks or the granitic host rocks. Geochemistry of the 'Mo-granite' belt, in particular low K2O, calc-alkali to calcic Peacock Index, high Sr and TiO2, and low Rb, Nb and F, suggest classification as calcic granitoids similar to those which host porphyry copper deposits, indicating grades of mineralisation are likely to be low.

Jan 1, 1987

By T Baumgartl, D Bradshaw, B Forsyth, M Edraki

In a tailings storage facility, the chemistry of pore water is a function of oxidation and dissolution of sulfide minerals, containing metals and metalloids, the neutralising effect of gangue minerals and the geochemical processes controlling solute equilibria such as pH, redox potential, precipitation, ion exchange and adsorption. On the other hand, the changes in geochemical composition of tailings feed over time is a function of spatial variability within the orebody and modifications in processing method. Tailings properties such as pyrite content, pH, concentration of deleterious elements, surface chemistry, pore water chemistry and particle size are already shaped in the dynamic environment of a process plant.To engineer desired environmental outcomes, a new research framework is needed. The new approach should follow the physical and geochemical processes of tailings feed and construct models that can be used for the prediction of seepage water quality and dust propagation and evaluate the potential re-processing of tailings or production of tailings with desirable surface chemistry, particle size and internal structure. The challenge of developing tailings engineering model is not in laboratory techniques, but more of the overall communication of results and establishing the link between disciplines. It requires investigating geochemistry across mining and processing for improved environmental outcomes at tailings storage facilities.The paper reviews the current tailings management practices by comparing the geochemistry and mineralogy of tailings and the chemistry of seepage water from three Australian case studies in the context of geology, mineral processing and climate. Some alternative methods of tailings management are also reviewed and it is concluded that a proactive multi-disciplinary approach is needed with respect to tailings management, based on a novel integrated research framework.CITATION:Edraki, M, Forsyth, B, Baumgartl, T and Bradshaw, D, 2012. Geochemistry of tailings and seepage from three tailings storage facilities in Australia - Uncapped, capped and active tailings, in Proceedings Life-of-Mine 2012 , pp 269-278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By D N. Castendyk, J L. Mauk

The world-class Waihi (>6.6 Moz Au, >41.8 Moz Ag) and adjacent Favona (>0.5 Moz Au) deposits are within a single volcanic-hosted epithermal Au-Ag district located in the southern Coromandel Peninsula, New Zealand. Gold and silver mineralised quartz veins at both deposits are hosted in porphyritic andesite flows of the Waipupu Formation. Both deposits have veins surrounded by intense widespread hydrothermal alteration that is characterised by the assemblage of quartz, pyrite, adularia, illite or interstratified illite-smectite, plus less common chlorite and albite, which is locally overprinted by minor calcite or rare kaolinite. Quantitative mass transfer calculations using Gresen's general metasomatic equation indicate that hydrothermally altered andesite at both deposits is enriched in silicon, potassium, rubidium, barium, sulphur, gold, arsenic and antimony, whereas sodium, strontium and calcium are mostly lost. Iron and magnesium show mixed gain and loss. Element gain or loss can be directly related to the prevailing alteration mineralogy. Addition of potassium, rubidium and barium coupled with the concomitant loss of sodium, strontium and calcium in intensely altered wall rocks corresponds to the replacement of plagioclase by adularia or illite. Partial retention of sodium and calcium reflects the presence of hydrothermal albite and calcite, respectively. Mass balance calculations show distinct element gain and loss that can be related to the intensity and type of alteration mineralogy. However, because most rocks are intensely altered and the progression into less altered peripheral rocks is not observed in this study, the lateral extent of elements gain or loss is unconstrained with anomalies extending at least 200 to 300 m away from major veins.

Jan 1, 2003

By J L. Mauk

Golden Cross is a volcanic-hosted, low-sulfidation, epithermal Au-Ag deposit in the Hauraki Goldfield. Irrespective of the rock type (andesite versus dacite), hydrothermally altered wallrocks are enriched in K, Rb, As and Sb around Au-Ag mineralised veins of the Empire vein system and stockwork. Sodium and Sr are strongly depleted around these veins, whereas Mg and Fe are locally depleted. Calcium and Si display mixed behaviour, varying from unchanged to depleted to enriched. Other elements including Al, Ti, Mn, Zr, Y, and Nb show little change or are immobile during hydrothermal alteration. Element enrichment and depletion trends are directly related to the degree of alteration and the alteration mineralogy. Addition of K and Rb and converse loss of Na and Sr in intensely altered wallrock surrounding veins corresponds to the replacement of igneous plagioclase by hydrothermal adularia. Sodium and Sr occur in moderately altered rocks on the margins or in æhard barsÆ that contain plagioclase. Locally, elevated Si concentrations and depletion of Mg adjacent to the Empire vein system reflects intense silicification of the wallrocks and the replacement of mafic minerals by quartz rather than by chlorite. The geochemical zonation patterns at Golden Cross are very similar to those at the McLaughlin deposit California, and shallow levels of the active Broadlands Ohaaki geothermal system. Therefore, determination of K, Na, Rb, Sr, and Ca enrichment and depletion patterns provides insight into alteration intensity and mineralogy that is complimentary to traditional trace element analysis of As, Sb, Hg, Au, Ag, Zn, and Pb used in the exploration of shallow level (< 500 m) epithermal Au-Ag deposits.

Jan 1, 2000

The Fiji islands are the world's most ac- cessible Cenozoic remnant arc. They provide occasional subaerial exposures of an arc frag- ment some 750 km long and 80 km wide, or about the size of the NE Japan volcanic arc. The fragment is one part of the former Vitiaz Arc which once connected Fiji to Vanuatu and Tonga. The Fijian portion has the most completely stu- died Tertiary section which contains a history of arc volcanism from the late Eocene to late Miocene (the Early and Mature Arc stages), a rich diversity of subsequent magmatic responses to the most recent episode of arc rifting (Ear- ly Rifting stage), and an example of transition from arc to intraplate volcanism as this rift- ing proceeded (Late Rifting stage). The arc fragment is surrounded by younger backarc ba- sins. The chemical composition of magmas in both the arc and backarc changed with time, but in opposite directions. In the arc, magmas be- came enriched in sialic components from the Early Arc to Early Rifting stages, whereas in the basins the magmas became more similar to mid-ocean ridge basalts (MORBs) with time. In southwest Fiji, the oldest backarc basin has subducted obliquely beneath the remnant arc du- ring the last 3 Ma, resulting in chemically ex- otic calcalkaline volcanism. During the last decade over 150 radiome- tric age measurements and 650 rock analyses, many with trace element and isotopic measure- ments, have been obtained for samples from Fi- ji, Tonga, and the surrounding seafloor (Figs. 1 and 2). These data are summarized, drawing from the publications of Colley and Hindle (1984), Gill et al. (1984), Hawkins and Melchi- or (1985), Kroencke (1984), Malahoff et al. (1984), Scholl et al. (1985) and Whelan et al. (1985), from the specific research papers refe- renced therein, and from the half dozen or so manuscripts currently in preparation by these people and others.

Jan 1, 1987

By Y Zha, J L. Walshe, A Ord, N J. Archibald

The purpose of this paper is to discuss the concept of Geodynamic Modelling as an exploration tool and to provide a specific example, namely, the Century Zinc deposit in Northern Queensland. Geodynamic Modelling is an attempt to become more quantitative in the way we develop exploration models. It is a systems approach to ore genesis which examines the complete four-dimensional mineralising system of interest, rather than individual site specific ore deposits. The goal is to establish a predictive capability that enables the explorer to predict grade, tonnage, mineralogy, alteration patterns and precise location of a potential orebody given a particular exploration model. The process consists of two well-defined stages: firstly, a æsoftÆ modelling stage where all available data on lithospheric architecture, geodynamic history, fluid chemistries, fluid flow mechanisms and mechanisms of metal transport and deposition are collected; and secondly, a æhardÆ modelling stage where the system is modelled using fully coupled deformationûfluid flow-thermal transport-chemical reaction computer codes. In the case of the Century Zinc Deposit we point to its existence on the boundary between two fundamental blocks of Proterozoic mantle lithosphere. This boundary has controlled Pb/Zn mineralisation in Northern Australia from the Proterozoic through into the Paleozoic. Detailed thermal, chemical, fluid flow, deformation modelling of the Century System points to an origin involving mixing of crustal oxidised fluids bearing zinc, with reduced fluids bearing H2S and CO2 from the lower crust or mantle. We use this modelling to define critical exploration criteria for another Century type of deposit.

Jan 1, 2000

By D Giles

We present plate tectonic reconstructions, showing that porphyry-type ore deposits are spatially and temporally linked to ridge subduction. A reconstruction of the Peruvian subduction system reveals an immediate metallogenic response to the arrival of the Nazca Ridge at the subduction trench, followed by southward migration of the zone of metallogenic activity due to the lateral migration of the zone of ridge subduction. A similar pattern is recognised in central Chile , where the spatio-temporal distribution of giant ore deposits coincides with the arrival of the Juan Fernandez hotspot chain at the subduction zone. We conclude that there is a spatial and temporal link between ridge subduction and ore deposit formation, with high metal fluxes concentrated in zones of ridge subduction. Thus, the recognition of tectonic patterns associated with ridge subduction can provide insights into predictive mineral discovery by enhancing our ability to predict the position of large mineral deposits in other modern and ancient orogens. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Haslam C. O, Los V. L, Abramson G. J

The technology applied by lonex Pty Ltd provides an important breakthrough in geochemical exploration, enabling the discovery of concealed mineral deposits to great depths below surface. Most mineral discoveries have been made in areas of outcrop or relatively shallow cover; deposits at greater depth have been beyond the range of conventional geophysical and geochemical methods. Quite apart from the need to explore to greater depths in regions of major current or past production, most continents have vast areas where prospective host rocks are concealed by more recent material. There are numerous case studies where Ionex methods have located deeply-buried metal deposits, up to 500 m below surface, beneath thick younger sedimentary, volcanic, or transported cover. Research leading to the development of this technology was initiated by Dr I S Goldberg at the Rudgeofizika Institute in St Petersburg (CIS), and the methods have been employed there - and in other countries - for many years. Ionex technology became available in Australia in 1993. It comprises: ò geochemical and geoelectrochemical sampling and ultra-high-sensitivity analysis for mobile and weakly-bonded elements (I S Goldberg); ò the delineation and interpretation of regional zones of enrichment and depletion of the prime elements within geoelectrochemical systems (GES) (I S Goldberg); ò the investigation and interpretation of the three-dimensional geochemical zoning within geochemical anomalies (G J Abramson); and ò multi-variate computer modelling of the geochemical fields and systems (V L Los). lonex technology has been adapted to the environmental conditions in Australia with the participation of C 0 Haslam.

Jan 1, 1997

By A B. Bell

The health and in some cases survival of mineral exploration and mining companies is, in today's markets, more dependant than ever on the effective use of information technology. The need for speedy collection, organisation, maintenance and distribution of corporate and project information is a phenomenon that will continue to strengthen with market thirst.Geographic Information Systems (GIS) provide a medium for storage, maintenance and retrieval of data, and Internet Mapping adds a technology for effective distribution of that data. Combining these technologies can return benefits both fiscally and technically by reducing costs of ownership in IT infrastructure and increasing the efficiency and effectiveness of both internal and external information delivery.GIS and Internet Mapping technologies have reached a practical stanza in their evolution and will continue to develop as a key business tool in the natural resources sector.

Jan 1, 2002

We often read and hear, especially in the United States, that we are running out of critical metals. These are vague forebodings of stagna- tion or winding down of our civilization. Our technological progress has been rapid in the last 50 years and is still advancing at an accelerated rate, and predictions of its long-term impact on consumption and production of metals are more hazardous than ever in the light of the great economic and political shifts that are bound to continue. There are many factors that will have a hardly predictable but profound effect on pro- duction and consumption of metals over a time span of, say, 25 years. Among such factors are recycling, substitution, availability of capital, direct involvement of governments in financing and production, and the capability of producing much lower grade ores at possibly much higher prices relative to costs in the event of scarcity. I must state at the outset that my discussion of this topic does not take into account the role that deep-sea nodules containing copper, nickel, cobalt, and manganese may play, because I don't believe production from these deposits will be of much significance within the 25 year span I will be discussing.

Jan 1, 1978

By S Talu, E Savage, S Howe

Major falls of ground, strainbursts, airblast and mudrush events are the major hazards in block caving environments, resulting in both safety and financial consequences and losses. Rio Tinto mines have developed strategies to reduce the likelihood of these events occurring. However, until recently, there have been no tools available to monitor and manage these hazards in real time.Mira Geoscience and Rio Tinto have collaborated to develop real-time geohazmaps to monitor and manage major cave hazards. These geohazmaps are used by mine planners to integrate multiple hazard parameters that contribute to form a combined hazard rating.The benefits of implementing geohazmaps include safety and cost improvements through the early identification of potential locations for major events. These cost savings are realised in the design phase, where development and critical infrastructure is located in areas of lower hazard rating. Additional improvements can be achieved by taking the hazard level into consideration when planning the production and development schedules and ground support design.CITATION:Talu, S, Savage, E and Howe, S, 2016. Geohazmap implementation in block cave mines, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 817–822 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Buisman C. J N, Koch R. O

Soil and groundwater beneath the Budelco zinc production plant at Budel-Dorplein (The Netherlands) are contaminated with metals and sulphate. To avoid contamination of nearby drinking water aquifers in the very distant future, a geohydrological containment system (GCS) and a microbial treatment plant for extracted contaminated groundwater have been developed. As a first step in the design of the system groundwater data from over 150 wells and geological profiles were used to model geohydrological conditions beneath the site. Several configurations of water-extraction wells were deduced from the model. Data gathered during additional fieldwork were then used to improve the model. Finally results that were calculated for the various configurations were used to select an optimal groundwater containment system. Currently some 5000 m3/day groundwater are extracted from a combination of 12 shallow and deep wells. Heavy metals and sulphate have to be removed from the extracted water before it can be discharged into the river system or used as process water. Several water treatment methods have been studied and pilot-tested at the site. The preferred and selected process is based on the activity of sulphate reducing bacteria (SRB) and combines sulphate removal and heavy metal removal in one single step. The anaerobic bacteria reduce the sulphate to sulphide resulting in the precipitation of metal sulphides. A pilot plant gave promising results and a commercial-scale plant has been designed. The proposed design has been tested in a demonstration plant which included all main process units. Test results for all process units are presented. The collected information was then used to optimise the design of the commercial-scale plant. Special attention was paid to automation and safety items. Construction of the plant was finished in May 1992. Start-up, commissioning and operational experience are reported. The concentrations of metals and sulphate in the effluent of the SRB water treatment plant are well within the limits set by the authorities for discharge to public waters.

Jan 1, 1993

Carbonate replacement tin deposits in the areas studiedhere are genetically related to biotite granites. Biotite in the granites is distinguished by distinctive compositional features. High MgO content is found in biotite in the Renison Bell granite; high MnO and A1203 contents in the Gejiu granite; and high FeO content in the Xinlu granite. The compositional features of biotite in the granites are reflected in skarn minerals formed around the granites.Granites associated with these tin deposits are characterized by different accessory minerals. Magnetite-bearing granite in the Xinlu deposit is related to the andraditic garnet (andradite 40-45 mole%)-hedenbergite skarn, with tin mineralization occurring in the contact skarn only. The sphene-bearing granite in the Gejiu deposit is related to the grossular garnet (grossular 50-60 mole%, almandine 20-30 mole%) -salite skarn, with tin mineralization occurring in the contact skarn, as well as stratabound replacement orebodies in the distal skarn. The ilmenite-bearing granite in the Dachang deposit and the Renison Bell deposit is related to the grossular-diopside skam, with tin mineralization occurring 500-1500 metres vertically and 1.5-3 km horizontally away from the granite contact.

Jan 1, 1990

By E U. Petersen, D R. Cooke

Hydrogen and oxygen isotopic constraints on hydrothermal fluid composition from the Pliocene Boyongan and Bayugo porphyry copper-gold deposits (southern Philippines ) reveal mixing of magmatic and sea water reservoirs as the hydrothermal system evolved. Magmatic-equilibrated fluids (d18O: +8.3ë to +9.1ë; dD: -61ë to -51ë) are represented by hypersaline brines implicated in copper-gold transport and deposition. These dominate the fluid inclusion assemblage in early comb-quartz (unidirectional solidification textures), miarolitic quartz, and in K-silicate-stage quartz-K-feldspar ¦ biotite veins. Fluids responsible for post-K-silicate alteration assemblages of pyrite-clay (illite, pyrophyllite and kaolinite), alunite and smectite are represented by low-moderate salinity two-phase inclusions in co-existing quartz. These are interpreted as mixtures of evolved magmatic fluids (d18O dD: -42ë to -20ë) with evolved Pliocene sea water (d18O: + 4.0ë; dD: +4ë). The isotopic evidence for sea water involvement in the hydrothermal system suggests that porphyry emplacement and associated diatreme formation could have occurred in a submarine setting. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Campbell D. L, Nutt C. J

The Delta two-degree quadrangle is located in west-central Utah, in the eastern Basin and Range physiographic province but near the intersection of the Basin and Range, Rocky Mountain, and Colorado Plateau provinces (Fig. 1). The quadrangle lies in the region of interior drainage that includes western Utah and most of Nevada, and, like the rest of that province, it has an arid climate. This work is part of the United States Geological Survey's ongoing CUSMAP (Conterminous United States Mineral Assessment Program) project in the Delta quadrangle. Trace-element geochemical data presented here includes information from approximately 600 heavy- mineral-concentrate and 2500 rock sample sites from throughout the Delta quadrangle.

Jan 1, 1988

By Large RR

Underlying the 15 million tonne, high grade Hellyer volcanogenic massive sulphide deposit of western Tasmania is an extensive, well developed, and well preserved stringer system. Pervasive alteration of the footwall mafic volcanics occurred as the hydrothermal system initiated. Mineralogical zoning exists within the footwall alteration pipe, with a central siliceous core giving way to zones of chlorite, chlorite-carbonate, sericite-chlorite, and finally sericite-quartz on the margins (stringer envelope zone). However, the alteration morphology and zonation is not symmetrical around the central siliceous core; eastward the alteration zones are steeply dipping and terminate abruptly under the massive sulphide, while westward they extend out under the ore body in a blanket fashion. Geologic evidence indicates that the pervasive alteration started with the development of sericite-quartz which was subsequently overprinted by chlorite and finally quartz-sericite as the hydrothermal system became focused towards the centre of the stringer system.

Jan 1, 1990

Geological modelling is a crucial preparatory stage to most facets of the mine planning of an orebody. The process of modelling involves skilled geological interpretation. Recent innovations in computer software and graphics hardware provide many tools which can be used to dramatically improve on manual methods of interpreting orebody data. Geological interpretation can be carried out quickly to produce accurate block models for many orebody attributes, such as grades, and these models can be easily updated locally as exploration and mine development data become available. The speed of the modelling process coupled with the mass storage capabilities of the computer now allows geologists to optimise the geological model or carry more than one model through to the mine planning phase.

Jan 1, 1987