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By I Ametov, S Harmer, R Alford

A process that allows selective flotation separation of low Cu/S ratio minerals (chalcopyrite and pyrite) from high Cu/S ratio minerals (bornite and chalcocite) from a mixed copper mineral concentrate under controlled oxidative-reductive potential conditions has been developed. The process has been extensively tested on samples with varying mineralogy using laboratory batch flotation tests and mini pilot plant trials.In this process, the mixed final copper mineral concentrate is purged with nitrogen, and then treated with sodium dithionite to achieve a slurry Eh in the -200 to -100 mV standard hydrogen electrode (SHE) range. Flotation was then carried out using nitrogen gas. As a result, a low Cu/S ratio concentrate (<1.3) and a high Cu/S ratio (>1.6) tailing stream were produced. QEMSCAN analysis of the flotation products showed that more than 85 per cent of the chalcopyrite and 95 per cent of the pyrite reported to the froth concentrate. Chalcocite and bornite were almost evenly distributed between the concentrate and tailing streams.Surface analysis studies, focused on the mechanism of separation, showed that at a negative redox potential xanthate and possibly dixanthogen are the dominant hydrophobic species on the surface of chalcopyrite and pyrite. As a result, the flotation of these minerals remained unaffected. In contrast, a much lower concentration of xanthate species on the surface of chalcocite and bornite particles was observed. Therefore, it is likely that at low Eh the copper xanthate complex desorbs from the chalcocite and bornite surfaces, causing a decrease in surface hydrophobicity and the diminished floatability of chalcocite and bornite.CITATION:Ametov, I, Harmer, S, Grano, S and Alford, R, 2014. Selective flotation of chalcopyrite and pyrite from a mixed copper mineral concentrate under controlled redox potential conditions, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 131–140 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By M S. El Salmawy

In order to develop the HF-free flotation reagent system, the main objective of this investigation was to study the possibility of separation of quartz from feldspar using non-ionic surfactants as the collector. The non-ionic surfactants used were polyoxyethyl cethyl ether (PECE) and polyethylene glycol monocethyl ether (PGME). The flotation behaviour of quartz and microcline with PECE and PGME was investigated. Each surfactant was a good selective collector for quartz with its recovery being influenced by pH and surfactant concentration. Quartz is floated favourably by both types of polyoxyethylene non-ionic surfactant whereas microcline was not so much. The floatability of quartz increases as the oxyethylene length of surfactants increases. Zeta potential measurements in the system of PGME/mineral were also carried out. It was determined that in the absence of PGME the points of zero charge for quartz and microcline should be approximately at pH 2.5 and 1.8, respectively. The addition of PGME to the system causes both minerals to become less negatively charged. Differences in the zeta potential value between quartz and microcline, in the presence of PGME, were detected. It can be suggested that the interaction of the oxyethylene group to the microcline surface should not be as strong as that to the quartz surface. In the mixed surfactant system of PGME and dodecylamine acetate (DAA), a small addition of DAA causes drastic enhancement of quartz flotation in the wide pH range of 1 ~ 10. In the mixed surfactant system selective flotation of quartz from microcline would be anticipated at pH

Jan 1, 2005

By Bisshop J. P W

Maximum recovery of sulphide minerals by flotation is achieved over a limited size range. Valuable particles above and below this range have a smaller probability of being recovered. In the normal grinding-flotation operation, not all valuables are reduced to the optimum size range, and therefore sub- stantial losses occur. A significant improve- ment in the size distribution is not usually possible within the conventional circuit, and a more complex arrangement may be necessary to obtain optimum recovery of the valuable mineral. This problem is considered with refer- ence to the Mt. LyeZl concentrator. The performance of the existing circuit is dis- cussed, and it is shown that losses in recovery occur in both coarse and fine sizes. Laboratory tests indicate that regrinding the coarse particles results in an increase in recovery of up to 4%. Redistribution of plant grinding capacity to reduce initial grinding power by 6% and use this capacity to regrind coarse particles was considered. It is con- cluded that overall plant efficiency would be increased by 2% provided that overloading of the regrind mill could be avoided.

Jan 1, 1977

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991

By Komosa T, Muir D. M

Mixtures of ammonia and cyanide at low concentrations leach gold selectively from copper-gold ores. The effects of various reagent compositions on three different ore types containing between 0.3 - 1.5 per cent Cu are reported. It is shown that the results and optimum compositions vary according to the ore, which is attributed in part to the mineralogy and adsorption of solution species on the mineral surfaces. The solution chemistry of the Cu-NH3-CN system indicates that Cu(CN)a - and Cu(CN)3 species are involved in the leaching mechanism. Rotating disc studies on pure gold and copper are reported which show that the Cu(CN)32- species leach gold at about half the rate of CN but leach copper at the same rate. The presence of ammonia retards the leaching rate further. Mixtures of Cu(CN)a3- and NH3 effectively leach gold from Telfer tailing without leaching copper. The role of ammonia appears to be to control the precipitation of copper rather than the kinetics of leaching.

Jan 1, 1991

By Manlapig EV, Lawson F, Clarkson CJ

A low grade middling sample from Mount Isa, Australia, assaying 31.7 per cent zinc, 12.9 per cent lead and 14.5 per cent iron was leached under atmospheric pressure in sulphate and sulphate-chloride solutions with ferric ions as oxidants. About 96 per cent of the contained zinc was dissolved into a 0.5 M H2SO4 - 0.5 M Fe2(SO4)3 solution at 90¦C within three hours from a five per cent by weight slurry density mixture. The leaching process is very temperature-dependent, suggesting a surface chemical control. In the latter stage, the leaching rates levelled off and the leaching was most probably controlled by both surface chemical reaction and diffusion processes. The addition of chloride ions in the leach solution resulted in an increase in the leaching rate. About 95 per cent of the lead sulphide contained was converted to lead sulphate which precipitated and remained in the residue. Essentially no lead remained in solution and the low chloride concentration did not affect the precipitation of lead sulphate. Half of the iron orginally present remained in the residue as pyrite although essentially all the cadmium and 90 per cent of the copper initially present were dissolved. Some three per cent of sulphide sulphur was oxidised through to sulphate, about 67 per cent was converted to elemental sulphur which can be recovered by solvent extraction, the rest remained in the residue mainly as pyrite. Ferric sulphate and sulphate-chloride solutions can be used to effectively leach finely ground lead-zinc middlings and other bulk sulphide concentrates. A complete separation of zinc from lead and silver has been demonstrated.

Jan 1, 1993

Selective open pit mining for gold has been in progress at Harbour Lights since the onset of mining in March 1985. Selective mining techniques used are similar to those in other recently opened gold mines in Western Australia. However certain practices have been introduced to accommodate the irregular distribution of mineralisation and comparatively high mill tonnage throughput. These include selective mining with large bucket excavators, sequential waste stripping - ore mining normal to the strike of the orebody and sample line preparation and ripping on bench floors. Application of these selective mining practices at Harbour Lights enables the operation to maintain delivery of approximately forty by 50-tonne truck loads of ore to the mill crusher everyday, with limited rehandling of material through ore stockpiles.

Jan 1, 1986

By W A. van der Westhuizen

Selective mining played a major role in saving a mine and a communityÆs existence as well as creating a working culture that is the model for all KumbaÆs mines. The successes that resulted from selective mining led to receiving KumbaÆs highest award (it was the Gold Medal Breakthrough project of 2003) as well as the productivity award at the National Productivity Institute award ceremony in 2004. Kumba was established in November 2001 (previously Iscor Mining). The new company identified Mineral Resource Management (MRM) as one of its key drivers and an initiative was launched to define MRM in the Kumba way. Best MRM practices at the Kumba mines were included in the definition. Selective mining was born out of this initiative. One of the key principles of good MRM practice was identified as: æThere must be a balance in the operational processÆ. This principle was applied with great success at Thabazimbi Iron Ore mine in the Limpopo province, South Africa. The emphasis of this paper will be to show how value can be unlocked throughout the whole mining value chain. In the past (up to 2001) the mine went through a number of crisis situations: planned production performances were not reached, the stripping ratio was extremely high with two new pits, the product beds were not of constant quality, slope failures were big risks, flooding could and did cut off half of the ore supply, and restructuring demoralised staff.This paper focuses on: selective mining throughput drivers, and selective mining and its role in achieving this balance.The results were dramatic, with huge improvements in production results, stockpiles, plant yields and product bed specifications. The mine was brought into balance and a self feeding loop was created with positive spin-offs up to this day.

Jan 1, 2005

The Ok Tedi Project has been planned as a selective mining operation since the Feasibility Study. The nature of the orebody, and the need to 'stage' the infrastructure buildup meant that initially the mill would process gol ore using a leach-CIP process, followed by parallel leaching of gold ore and flotation of copper ore, and finally all flotation of copper ore. Cutoff grades were applied to gold and copper ore of 1.0-1.3 g/t Au and 0.4-0.3% Tot. Cu. Since startup, unpredicted occurrences of sulphide copper and, to a Lesser extent, carbonaceous material, has necessitated significant additional short term drilling (other than at grade boundaries), and shift grade control in the pit to control contaminant levels. Remodelling of the orebody based on the most up to date variography and geological interpretation has had a significant impact on the reserves, and thus the whole project development strategy; necessitating the earlier processing of copper ores, and preflotation of the gold ore.This paper discusses some of these points in detail, and in particular highlights how unforseen geological occurrences coupled with processing restrictions can have significant impacts on ore reserves and the mine development schedule.

Jan 1, 1986

Gold mining commenced at Telfer in Western Australia in 1977. Ore mining was carried out by owner equipment and personnel with waste stripping by a contractor. Initial ore reserves were in predominantly high grade, geologically simple reef structures. A mining method was developed using dozers to selectively mine the ore bearing horizons with a minimum of dilution. As the mine has developed the simple, high grade ore reserves have been progressively replaced by more geologically complex, lower grade reserves. In turn, mining methods have evolved to extract this ore by the most appropriate methods. On-going attention to ore mining practices will ensure that project profitability and viable mine life are optimised.

Jan 1, 1986

By Kandemir H, Stafford G

The Croydon Gold Mine is located in northwest Queensland and is a joint venture between Central Coast Exploration N.L. and Pancontinental Mining Ltd. The mining operation commenced in 1987 and consists of satellite open pit mines feeding a central Carbon-In-Pulp gold Treatment Plant. The gold mineralisation is hosted by quartz veins within the Croydon Volcanic Group and the Esmeralda Granite, a cogenetic igneous suite of Middle Proterozoic age. The mineralisation comprises gold and silver with associated basemetals. The gold and silver electrum occurs as extremely fine free grains. The gold distribution is heterogenous occuring across the full vein width, or restricted to the footwall or hangingwall. The average mineral resource grade is 3.5 g/t. The deposits are all hard rock and mining is carried out by drill and blast technique. All mining activity is carried out by a mining contractor. Mining is by a selective mining method which entails the drilling, blasting and extraction of the hangingwall waste prior to orebody extraction.

Jan 1, 1989

Selective Recovery of Platinum from Cobalt-Rich Crust

Sep 13, 2010

The processes most likely to be adopted for beneficiating ores or concentrator streams containing a large proportion of particles finer than 10 um are froth flotation, selective flocculation, wet magnetic separation and selective leaching. Flotation will be made more efficient for very fine particles if ways can be found to selectively flocculate the valuable mineral beforehand (floc-flotation), to produce smaller bubbles and to reduce entrainment of ultrafine gangue. Schemes for selective flocculation have proved difficult to implement because of the delicate balance between surface forces (electrostatic, dispersion, hydrophobic) and hydrodynamic forces, that determines flocculation, and the changes which occur to particle surfaces through hydrolysis, oxidation-reduction and cross-contamination between minerals in aqueous suspensions. The search for a better understanding of selective adsorption of flotation collectors and flocculants continues and will be particularly important for the practical success of selective flocculation and selective magnetic coating.

Jan 1, 1986

Selective Removal of Arsenic from Acid Mine Drainage Containing Ferrous Ion Using Sulfide Precipitation Method

Sep 13, 2010

By E Forbes, G V. Franks

"This study investigates the dual function of a temperature responsive anionic co-polymer of poly (N-isopropyl acrylamide) (PNIPAM) as a selective flocculant/flotation collector. PNIPAM is used for separating hematite from 50:50 mixtures of hematite and quartz, at a variety of particle sizes. The performance of PNIPAM in this system is compared to that of conventional flotation collectors: sodium oleate and sodium dodecyl sulfate. The results of the study demonstrate that anionic PNIPAM used at 50¦C (above the lower critical solution temperature (LCST)) is the most effective flotation collector for hematite particles in the size range between 10 and 20 ¦m. This is attributed to the increased probability of both particle/bubble collision and particle/bubble attachment through the formation of hydrophobic hematite aggregates. Anionic PNIPAM used at 50¦C also produced the highest hematite recoveries for very fine hematite particles (circa 1 ¦m). However this recovery was completely unselective. This lack of selectivity is partially attributed to the activation of quartz particles by PNIPAM, but is thought to mainly occur as a result of entrapment of quartz particles within the matrix of hematite aggregates.CITATION:Forbes, E and Franks, G V, 2013. Selective separation of hematite from quartz by flotation using a temperature responsive polymer, in Proceedings Iron Ore 2013, pp 381-390 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By J-P Franzidis

A technique for determining the recovery of attached particles across the froth phase in flotation that relies on measuring the rate at which bubble-particle aggregates enter the froth is used to investigate the selectivity of attached particles across the froth phase. Combining these measurements with those of other techniques for determining the froth recovery of attached particles provides an insight into the different subprocesses of particle rejection in the froth phase. The results of experiments conducted in a 3 m3 Outokumpu tank cell show that the detachment of particles from aggregates in the froth phase occurs largely at the pulp-froth interface. In particular it is shown that the pulp-froth interface selectively detaches particles from aggregates according to their physical attributes.

Jan 1, 2005

By M L. Muller, A R. O’Donnell

The Mount Isa Mines (MIM) Copper Concentrator has an extensive history of reagent trials, with different reagents coming in and out of favour over the years. The research and use of carbon depressants is particularly prevalent, as carbonaceous pyrite is a major source of concentrate dilution. Years of research led to the use of naphthalene sulphonate due to its excellent carbon depression properties. However, due to rising reagent costs carbon depression ceased in the late 1990s. This led to the loss of knowledge about the use and value of naphthalene sulphonate. Cyanide is used at the Copper Concentrator for the sole purpose of pyrite depression and over the years multiple projects have been devoted to finding alternatives to it. In 2012 the neighbouring MIM Lead-Zinc Concentrator replaced cyanide with naphthalene sulphonate which resulted in cost savings and the elimination of a hazardous reagent. In 2013, plant trials were conducted at the Copper Concentrator in hopes to replicate the outcomes obtained at the Lead-Zinc Concentrator. The results of the trials conducted at the Copper Concentrator showed that naphthalene sulphonate could not replace cyanide and this work was set aside to pursue more promising projects. Further research conducted in 2014 found that mineralogy and a better understanding of the depressing mechanism of naphthalene sulphonate held the key to improved pyrite depression at the Copper Concentrator. The findings showed that Mount Isa copper ore contains two forms of pyrite; euhedral pyrite (cubic pyrite) and framboidal pyrite (carbon rimmed spheres of pyrite), both of which require different reagents to sufficiently depress them. Naphthalene sulphonate was found to be an excellent carbon depressant, suitable for depressing graphite and framboidal pyrite, whilst cyanide specifically targets euhedral pyrite.In 2015 laboratory test work was conducted to examine the use of naphthalene sulphonate in conjunction with cyanide to selectively target both forms of pyrite. This work led to a full plant trial, the results of which showed a significant increase in plant performance, with higher copper concentrate grades and recoveries being achieved. This paper aims to focus on the benefits and importance of understanding past work and linking a detailed knowledge of feed mineralogy to reagent selection for improved plant outcomes.CITATION:O’Donnell, A R and Muller, M L, 2018. Selectively targeting hydrophobic gangue minerals at the Mount Isa Mines Copper Concentrator, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 413–421 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

Self Advancing or "Poweredtt supports are a successful means of supporting roof and designs have reached the stage where adequate support capa- bility is available for all conditions. Some designs have resulted in equipment being too difficult to transport underground and too complex to maintain. Current trends are reducing those problems and simplicity in hydraulic systems is now the keynote of both supplier and user. There is a good possibility that the "Shield-Chock" support will be the universal design of the future. So-called t'shortwall supports" have been developed to the point where they can be applied with a high degree of confidence to conditions of great variety. Develop- ments by manufacturers and practices of users related to maintenance should result in consistent achievement of designed performance.

Jan 1, 1974

By Sheer T. J, Van Rensburg J P

The primary objective of this research was to address the demands imposed on self- contained self-rescuer (SCSR) performance dur- ing simulated escapes. The results clearly indicate that SCSR performance, apart from the inherent technological features, is a function primarily of the physical and anthro- pometric features of the wearer, and of the particular nature of the escape route. These factors consequently play a major role in the planning of any escape strategy, which may vary from mine to mine. It is therefore concluded that each mine would have to formulate its own escape strategy which in turn would depend on the choice of SCSR, and the particular escape Route.

Jan 1, 1988

In 1984/85 financial year Australia produced 529 thousand barrels per day (kbd) of crude oil. By far the major contribution (453 kbd) was light waxy oil from offshore Gippsland, Victoria. When these discoveries were made in the latter 1960s, imported oil was available in abundant supply and at low prices. Because of this, the Gippsland producers persuaded Government to control the marketing and pricing of their crude, and thus provide the required security of offtake. Political events in the middle East created supply shortages during the 1970s, and dragged up government selling prices for OPEC crude oil. Thus Arab Light crude that sold for less than US$2/barrel (bl) in 1970 reached $34/bl in 1981. Following the consequent decline in world oil demand, in 1982, Australian refiners sought to evade their obligation to lift Gippsland crude. Hence, in 1983, the Government was forced to introduce a floor quota of 385 kbd of Gippsland crude liftings and to allow producers to export any additional production refiners did not require. On expiry of the old arrangements, Government introduced a partial free market from January 1985, whereby the balance in excess of 350 kbd may be sold to Australian refiners at negotiated prices, or exported as before. In 1984/85 exports were some 90 kbd and will be higher in the current year. About half this total has been exported by BHP, providing valuable experience and lessons which are described in the paper.

Jan 1, 1986