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Thermodynamics of Non-Cyanide Gold Solvents The present status of the raw material base in the gold industry requires specific ways to recover gold and silver from ores. Most gold is closely associated with sulfides which require flotation followed by pressure or bacterial oxidation. The next stages of processing usually require using expensive operations for the preparation of leaching. A lot of researchers want to find a new alternative solvent for the extraction of precious metals from these products. According to the authors, one of the best ways is to use sulfur-based solvents (thiosulfate, sulfite, and their various mixtures). Thermodynamics of gold and silver thiosulfate dilution are calculated for conditions: the concentration of Au - 200 mg/L, oxygen - 3.2 mg/L, thiosulfate - 79 mg/L, OH- - 170 mg/L. the general result is the possibility of process remains under standard conditions. (erAu = = 0.035 V, ?G298 = - 29.18 kJ/g-atom ??). Silver with thiosulfate forms two strong complexes: [AgS203]- and [Ag(S203)2]3-. ?G0 = -1027 kJ/mol. The complex [AgS203]- is less stable: ?G0 = 486 kJ/mol. It should be noted that despite the high stability of gold complexes, the sodium thiosulfate may decompose to sulfite and elemental sulfur during the process, especially when heating. Gold is slightly soluble in the sodium sulfite solution, however it forms the strong complex [Au(SO3)2]3-. Depending on the concentration of free S2O32-ions, silver with sodium sulfite forms three complexes: [AgSO3]-, [Ag(SO3)2]3- and [Ag(SO3)3]5-. The dissolution speed of gold in sodium sulfite solution may be in the same range as it is during cyanidation. In this case, a practical application of sulfite process can be also used, especially for the products containing free elemental sulfur. In conclusion, sulfite-thiosulfate gold lixiviants can be used for concentrates after pressure oxidation of the cakes.

Sep 13, 2010

By Kobayashi M

Particulate chalcopyrite samples (78 ~ 98 mole per cent chalcopyrite, screen size fraction from 710 to 250 µm) were prepared by crushing and sieving lump ore samples from 12 locations in the Mt Isa Mine. Measurements of thennoelectric power (which does not involve the passage of a current) were made using a packed bed that was compressed by loading with a weight and placed in a temperature gradienL Details of the apparatus are described.The effect of particle size was investigated by preparing 12 fractions, with mean particle sizes ranging from 605 to 2.2 µm, from one of the ore samples. Values of thennoelectric power decreased with both increasing particle size and loading pressure; however it remained fairly constant for particle sizes above 80 µm, when loading pressure exceeded 3.3 MPa.Measurements of the chalcopyrite samples gave an average value of -260 JlV/K (-248 ~ -268 µV/K) for nine samples and about -290 µV/K for three samples, showing that these samples were all n-type semi-eonductors.

Jan 1, 1990

By Ypma PJM

The Westmoreland uranium deposits occur on the northern flank of the Murphy Tectonic Ridge in the upper member of the Westmoreland Conglom- erate. Uranium mineralization is spatially associated with the contact of the overlying basaltic Siegal Volcanics and the margins of in- trusive dolerite dykes which are geochemically similar to the Siegal Volcanics. Thermoluminescence (TL) measurements on 800 samples from within the orebodies and surr- ounding host rock (up to 8 kilometres away from the deposits) have indicated that all of the Westmoreland Conglomerate has suffered major radiation damagg attributable to at least 10 ppm uranium over 10 years. The underlying rhyolitic Mid Proterozoic Cliffdale Volcanics have distinctive TL glow curves indicative of radiation sensitization caused by high uranium contents. These vol- canics are part of the Mid Proterozoic volcanic event known to be enriched in uranium. The Westmoreland Conglomerate has been derived by erosion of the uranium-rich Cliffdale Volcanics and associated Nicholson Granite Complex which makes it likely that the Westmoreland Conglom- erate had a high inherent uranium content.

Jan 1, 1984

By D R. L Vedoy, L Botha, S P. Gumfekar, J B. P Soares

Most of the known in-place reserves of oil sands are found in Canada. These oil sands ores are mined using various processes to extract bitumen. The by-product slurry resulting from the extraction process, known as tailings, is discharged into tailings ponds. Fine kaolin clays are an important ingredient of the tailings because they remain suspended in water for many years. Current polymeric flocculation/dewatering technologies use acrylamide-based polymers such as polyacrylamide (PAM), but sediments produced using PAM-based flocculants hold considerable amounts of water due to the formation of loosely-packed flocs. Anionic polymers are better flocculants due to bridging and the charge-neutralisation mechanism. In this paper, we will compare the synthesis of two flocculants: thermosensitive, anionic flocculants and thermosensitive, hydrophobically modified anionic flocculants. The first flocculant is a copolymer of acrylic acid (AA) and N-isopropyl acrylamide (NIPAM), in which AA is the anionic monomer. The second flocculant is a copolymer of NIPAM, AA and the hydrophobic monomer N-tert-butyl acrylamide. We evaluated the dewatering efficiency of 2 wt per cent kaolin using both flocculants by comparing settling rates at different flocculant dosages, charge neutralisation ability and supernatant clarity. To better understand floc formation, we measured the floc size formed by both flocculants at different flocculant dosages. We propose that the hydrophobic monomer in the terpolymer flocculant helps expel water out of flocs, ultimately decreasing the water content in the sediments.CITATION:Gumfekar, S P, Vedoy, D R L, Botha, L and Soares, J B P, 2015. Thermosensitive, hydrophobically modified anionic flocculants for dewatering kaolin clays, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 45–50 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

ABSTRACTFor the binary system copper-lead two relationsEquation 1andEquation 2have been derived for the activities of copper and lead at compositions and absolute temperatures within the liquid region of the phase diagram.These relations give, with greater accuracy than is given by previously published relations, the activity-composition temperature variations for all regions of the phase diagram of interest to metallurgists.These relations are essentially simple forms of the Margules equations but with linear temperature dependence applied to their coefficients. This has been done in such a manner that a phase diagram obtained from these relations agrees well with the data available for this system. The methods of obtaining the relations and constructing a phase diagram from them are both given in detail. The enthalpies and entropies of mixing are compared with those derived by other methods.

Jan 1, 1971

This paper describes thick seam mining as practised at Westfalen Colliery, Redbank via Ipswich,in South Queensland. The author describes the develop- ment of the mine from conception to the time of successful operation and compares the two systems of mining adopted at the colliery.

Jan 1, 1976

The author describes 1. The classification and characteristics of various thick seam mining techniques in various Japanese coal mines. 2. Practices of thick seam mining methods experienced in Taiheiyo Coal Mine. Currently, thick single lift, simultaneous multi lift and non simul- taneous multi lift mining methods are adopted as underground flat thick seam excavations in Japan. These are now reliable and effective in increasing the extraction ratio. At Kushiro Colliery of Taiheiyo Coal Mining Co., these three thick seam mining methods have been used. According to the results, if solidification of the top lift goaf is essential, the non simul- taneous multi lift mining method is the most effective in increasing the extraction ratio without minimising productivity of each lift and it points out that further development of this method is necessary.

Jan 1, 1976

An approach to underground mining of shallow dipping, thick seam coal is proposed in broad outline. The method is based upon overhand slice and fill, with hydraulically emplaced washery refuse as the filling material. Likely fill behaviour and character- istics are discussed and likely problem/investigational/ research areas defined.

Jan 1, 1976

Thickener Modelling - Incorporating Shear Effects

Sep 13, 2010

By G Hart

As the iron ore/magnetite boom gains momentum, it is particularly important to question established past trends and explore the potential of alternative design options. Traditionally, ‘rule of thumb’ methods have been used to size dewatering equipment. Greater consideration needs to be given to technological advancements and specific throughput testing of each ore body type based on innovative developments.This paper will describe how an innovative approach resulted not only in significant savings in capital cost and site work hours but also delivered a truly optimised design for the thickener duty at Karara. Test work also played a crucial role and a comprehensive test work program on the ore samples showed the scale-up benefi ts of new technology in thickener designs. Working closely with the Karara team during the laboratory testing proved the old sizing theories for iron ore/magnetite processing have been superseded with the knowledge and results of the industry’s newest feedwell technology. Increased solids flux and rise rates in the testing process proved very successful, resulting in signifi cantly reduced thickener sizes and lower capital expense.Mechanical design considerations such as removal of underflow and pump access led to a preference for an above-ground thickener confi guration, and the economics of a completefabrication and installation package favoured steel construction for the thickener units.The ultimate choice of the bolted/fl anged tank methodology provides both economic and timely solutions for the site installation including reduced man power and quick and safe site-work. A benefits comparison between this design and other fabrication and installation procedures will also be analysed in the paper.

Jul 11, 2011

By B Roache

Ground support installation into the face of development headings has become an accepted practice at many Australian hard rock mines. Ground support is installed in the development face to reduce personnel exposure to rockfall while conducting work tasks such as marking up, installing lifter tubes, charging, and face sampling. The ground support system installed in the face is typically friction bolts and mesh. This support system can be effective at reducing rockfall occurrence, but it also increases the cost of development per metre, in terms of capital for the ground support, jumbo and operator capital allocation and the installation time slowing each drill and blast cycle. Other issues associated with meshing and bolting the development face include management of rock bolts and mesh sheets in the fired dirt of every cut, damage to services such as vent duct, geometry issues when installing ground support onto irregular development profiles and operator error. Fibrecrete installation onto the development face for support is an option considered by many mines, but it can be difficult to manage due to the removal of visual indications of misfires and slowing the mining cycle due to the wait time for fibrecrete curing. The use of Thin Spray Liner (TSL) products in underground hard rock mines has been relatively infrequent in the past, mainly due to issues with cost, health and safety, and liner strength. Kanmantoo Mine investigated the use of TSLs for the purpose of development face support, while collecting data on the costs and practicalities associated with their use. Several TSL products were trialled and a preferred TSL product was selected for use as face support. Cost savings, drill and blast cycle timing improvements and other benefits were achieved while meeting the requirement to reduce rockfall risk.

Mar 29, 2023

TSL Concepts and Practical Examples of the Non-Reactive System - Meyco TSL 865 Thin Spray-on Liners (TSLs) have been intensively investigated by mining and chemical industries within the last decade. Apart from the basic concept of spraying thin liners, expectations of the product's performance vary, eg immediate active strata support is seen as a key to control the ground permanently. For many coal mines this is an important factor to reduce maintenance in their roadways and enable permanent production from the long wall. In opposition to a passive mesh system this technology offers immediate active support to the strata. But not only coal mines are interested in TSL technology, there are potential applications in hard rock mines, during shaft sinking, pillar support and as an anti-weathering sealant. This paper will explain the advantages and disadvantages of TSL concepts; it will give examples of successfully applied TSLs with a main focus on the non-reactive and flexible system MEYCO TSL 865 by BASF. Furthermore, it will indicate the limitations and discuss briefly the bearing capacity and reasonable lab testing of such systems.

Nov 25, 2010

By Z Li, D Chalmers, J M. Tenney

This paper presents the findings and analysis of the investigation of effectiveness of thin spray-on liners (TSLs) as a gas management tool in underground coalmines. The project involves spraying TSL on the area surrounding gas drainage holes whereby the TSL acts as a thin membrane decreasing the permeability of the coal. This restricts air migrating through the coal seam and diluting gas from the drainage holes. There are a number of potential benefits from this technique but key points are that gas drainage holes produce gas with higher concentrations of methane. The design and execution of a field trial to investigate the effectiveness of a TSL on purity of in situ methane from gas drainage holes is presented in this report. For eight drainage holes, the results show an average increase in methane purity by 9.14 per cent and a reduction in air contamination by an average 7.93 per cent. Overall methane flow rate decreased by 27.6 L/s; however, flow rates were unreliable due to poor measuring equipment. For most holes, methane purity was not changed significantly; however, certain boreholes were responsible for most of the variation in methane purity. The boreholes showing a dramatic improvement in methane purity were likely those with intersecting cleats covered by the TSL. If the TSL was sprayed over more area, specifically in areas where the cleats are intersecting with holes, it is likely that purity of methane in the drainage holes will increase.CITATION:Tenney, J M, Chalmers, D and Li, Z, 2015. Thin spray-on liners potential in reducing dilution of in situ gas in underground coalmines, in Proceedings The Australian Mine Ventilation Conference, pp 323–328 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

In the last 30 years, human appropriation of global renewable resources has accelerated to the point where 35 per cent of the earthÆs land surface is now in managed agro-ecosystems, consumptive water use consumes between 50 per cent and 85 per cent of freshwater supply and 60 per cent of ecosystem services are utilised in an unsustainable manner. There are virtually no landscapes in which renewable resources are not already fully allocated among different economic and environmental uses. Furthermore, it is increasingly recognised that water availability issues do not exist in isolation but are linked with the related environmental issues of biodiversity preservation, the carbon cycle, soil degradation, and energy use and supply. It is against this background that the sustainable management of water in mining is increasingly developing a strategic viewpoint where water is viewed as a resource within an interconnected landscape, having economic, environmental and social value and providing a range of environmental services in the provision of public and private goods. This paper explores the issues associated with sustainable management of water in mining from a strategic viewpoint. The cumulative impacts of multiple water users, both within and outside the mining sector, is increasingly threatening the security of supply for all users. To quantitatively assess the ætrueÆ value of water it is necessary to: Better understand the science of ecosystem functioning and how human actions impact on environmental processes. Develop appropriate policy, finance and governance structures to support innovative programs that preserve ecosystem function and services (including market based instruments). Apply knowledge as interventions across landscapes in ways that maximise benefits and minimise unintended consequences taking into account differences in the value of water among sectors. A strategic viewpoint of water management relies on knowledge to guide decision making that has been acquired at a range of scales from mine site to mining region. This knowledge must be based on rigorous science, sound data and syntheses of different types of information. Strategic management of water resources will better position the industry in terms of understanding the risks posed by complex, interlinked environmental issues that are increasingly impacting on future access to land and renewable resources, including water, thereby ensuring miningÆs future social licence to operate.

Jan 1, 2009

It has become increasingly clear in recent years that human kind has developed the capacity to alter the environment of the Earth on a global scale. The changes are often subtle. This is particularly true in the case of stratospheric ozone. Ozone is produced primarily in the stratosphere, at altitudes in excess of 20 km, initially through the action of ultraviolet sunlight dissociating molecular oxygen. According to theory as it existed up to a few years ago, ozone is removed mainly by reaction with atomic oxygen. In the unperturbed environment, this reaction proceeds both directly, and by paths catalyzed by trace quantities of nitrogen radicals. Molina and Rowland [Nature, 249, 810, 1974] pointed out that decomposition of industrial chloroflurocarbons could in-troduce an additional source of radicals to the strato-sphere. Chlorine radicals are even more efficient than nitrogen in catalyzing recombination of oxygen atoms with ozone; models suggested that we might expect reductions in the vertical column density of ozone of as much as a few per cent over the next several decades. A reduction in ozone of x¦/a, by increasing the flux of ultraviolet sunlight reaching the surface, was predicted to result in an increase of about 2x% in the number of cases of skin cancer, with other less well defined impacts on the non-human environment for life.

Jan 1, 1990

By Ciminelli VST

Thiourea leaching has been applied to a refractory gold concentrate previously treated by bacterial oxidation. Following the bio-oxidation, gold has been leached in acidic thiourea solutions, under different pH(1 - 2.4), thiourea concentrations (2 - 15 g/1), ferric ion concentrations (0.04 - 3 g/1) and temperatures (298 - 333 K). Through this procedure, it was possible to increase gold extraction from 40 to 77 per cent. The increase in temperature raised gold extraction and reduced reagent consumption. Sodium sulphite addition was also very effective in lowering thiourea consumption. Staged leaching operations with interstage acid washing and carbon-in-leach experiments were tested, in an attempt to increase gold extraction. The results of thiourea leaching were compared with those obtained with cyanidation.

Jan 1, 1993

By P Breuer, X Dai, A Bergamin, D Hewitt

"Copper-ammonia-thiosulfate?leaching of gold has been researched for several decades as a potential alternative to cyanidation. However, this technology has not yet been applied commercially due to many challenges such as complex solution chemistry, reagent degradation and losses, system instability with losses of precious metals and difficulties in gold recovery from the leachate. Progress has been made at CSIRO in tackling some of these challenges including:better understanding and control of the leach conditions to minimise reagent losses whilst maximising gold recovery use of strong base ion exchange resins to recover the gold strategies to deal with polythionates that adsorb competitively with gold on ion exchange resins development and evaluation of process flow sheets.As a result there has been increased interest from the gold industry and renewed activities to develop thiosulfate based processes for gold recovery. One application area, which has been developed to the point of piloting, is the treatment of gravity gold concentrates using a copper-ammonia-thiosulfate leach with ion exchange recovery of the gold thiosulfate. This paper describes some of the advancements in the development of a potential process flow sheet for this application.CITATION:Dai, X, Breuer, P, Hewitt, D and Bergamin, A, 2013. Thiosulfate process for treating gold concentrates, in Proceedings World Gold 2013, pp 61-70 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By J Langhans, Y Choi, Q Wang, J Y. Baron, P Kondos

Barrick has successfully developed the thiosulfate leaching process to treat sulfidic high preg-robbing ores. The process was developed through rigorous bench test programs and proved in pilot campaigns and demo plant operations. The process uses calcium thiosulfate as a leaching reagent, resin for gold recovery with sulfite/trithionate elution and reverse osmosis as a mean of reagent recovery. The thiosulfate leaching plant is under construction as a brownfield project and the start-up is planned in 2014 at Goldstrike, Nevada, USA, one of BarrickÆs operations.CITATION:Choi, Y, Baron, J Y, Wang, Q, Langhans, J and Kondos, P, 2013. Thiosulfate processing - from lab curiosity to commercial application, in Proceedings World Gold 2013 , pp 45-50 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By M G. Aylmore

Thiosulphate is an attractive alternative reagent to cyanide for processing gold ores. It is relatively cheap and non-toxic, forms relatively strong gold and silver complexes, and readily leaches gold ores in ammoniacal solutions, catalysed by Cu(II). It is particularly suited to carbonaceous ores where the recovery of gold by cyanide is poor. However research over the past 20 years has identified a number of issues and impediments that must be understood or overcome before an overall process can be demonstrated as practical and economic for typical oxidised gold ores. This paper reviews our current understanding of thiosulphate chemistry and mechanism of gold dissolution, and discusses the stability of thiosulphate and polythionates. It then reviews the results of leaching various gold ores that have been reported in the literature, discusses gold recovery options, and considers environmental and toxicity issues. Some of the issues that require further research include decreasing the oxidation of thiosulphate by Cu(II) or other oxidants, increasing the extraction of gold compared to cyanide, and understanding the variation in gold recovery between ores. More work is also required to minimise the effect of polythionates on gold recovery using resins or alternative absorbents, to improve the elution of copper and gold from resins, and to recycle or minimise the concentration of reagents.

Jan 1, 2002

In the humid, subtropical climatic conditions, typical of Papua New Guinean high-lands, auriferous carbonate-quartz lodes and stockwork veins of the Upper Ridges mine at Wau, have weathered in situ forming manganese dioxide-quartz wad flatmakes and veins. Vein assemblages and sulphidized host breccia have been chemically weathered to 20-25m depth, and microscopic grains of electrum (550-600 fine) formerly enclosed in carbonate, sulphide and quartz have dissolved in the oxidizing alkaline fluid. Coarse secondary electrum, crystalline and dendritic, is concentrated by manganese dioxide and at the base of chemical weathering. Fineness is unchanged, eliminating the possibility of gold and silver migration as a chloride complex. Experimental tests on the stability of thiosulphate, and its ability to dissolve gold and silver from colloid, crystal and synthetic alloy confirm that secondary electrum at Upper Ridges is most compatible with precipitation from (Au,Ag)(S203)23-; a complex readily destabilized in the presence of MnO., or with decreasing Eh.

Jan 1, 1984