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A method is proposed for the determination of antimony in ores. Antimony is volatilized as antimony iodide by heating with ammonium iodide at a controlled temperature.The fusion mixture is extracted with hydrochloric acid and the antimony content is measured by atomic absorption spectrophotometry using an air/ acetylene flame. The time taken for analysis when comparedwith existing fusion and separation procedures is considerably reduced. Cations and anions likely to be present in antimony ores were also studied for possible interference effects but were not found to interfere.

Jan 1, 1972

The economic significance of a fundamental understanding of the mineral pyrrhotite is dis- cussed. Particular emphasis is placed on the relationship of other sulphide minerals to the pyrrhotite when it is the major sulphide mineral present in an ore body. Studies of the Kambalda nickel deposit are used to give a better under- standing of (a) the genesis and other character- istics of a particular ore body (b) the textural relationships between pyrrhotite and other sul- phide minerals (c) magnetic properties of natural pyrrhotite, and (e) the oxidation and supergene processes that take place in a sulphide ore body.

Jan 1, 1972

The passage of chloroform vapour in a carrier of oxygen through two nickel sulphide ores heated to 380°C converted the nickel to the water soluble chloride form. In one ore the nickel (2·75 per cent) was presentas violarite ((Ni, Fe)3S4) whereas in the second it was present as pentlandite, ((Fe, Ni)9S8) (4·9 per cent Ni).A similar technique was utilized to convert nickel in nickeliferous laterites (1·6 per cent Ni) into a soluble chloride using town gas instead of oxygen as a carrier.With both techniques greater than 90 per cent extraction was achieved.

Jan 1, 1972

By Fitchett K

Refractory application in the major iron and steelmaking units are discussed. Mechanis- ms of refractory consumption as revealed by pre- vious studies are reviewed and current practice is evaluated. Deficiencies in refractories now in use are noted and some lines of development are indicated. The iron and steelmaking units discussed are generally restricted to those subject to slagging, structural change or erosion at steel or iron making temperatures, and include the Blast Furnace, Hot Blast Stoves, Hot Metal Ladles, Basic Oxygen Furnaces, Continuous Cast- ing Units and Steel Teeming Ladles.

Jan 1, 1972

By Wilson GR

Pellets were produced from carefully sized iron ore and silica sand fractions, under controlled moisture conditions, using a sealed balling drum. The strength of these pellets was measured as a function of moisture content and particle size. The results showed that the strength of the pellets could be adequately described by a model which equates the strength of the pellets with the negative pressure developed within the porous mass, provided that the particle size distribution was narrow and the mean particle size relatively large. However this model failed to account for the observed strengths of pellets produced from systems containing even small quantities of ultrafine particles (

Jan 1, 1972

The maximum current density at which conventional copper electrowinning plants will result in satisfactory, adherent, and dendrite·free cathodes is determined by the thickness of the diffusion boundary layer. A decrease in the value of that thickness will permit an increase in the current density. This fact is utilized to develop a high current density cell in which the reduction of the boundary layer thickness is accomplished by means of a specially designed electrolyte circulation system. The high current density cell is used to determine the effect of current density on such process parameters as current efficiency, cell voltage, power consumption, and cathode purity. A number of empirical equations are developed for the purpose of estimating the magnitude of these effects.

Jan 1, 1972

By Blackham M

West Wallsend No. 2 Colliery is a new mine that is presently being developed in the New- castle Coalfield by J. & A. Brown & Abermain Seaham Collieries Ltd., a subsidiary of Coal & Allied Industries Ltd. It is situated near Barnsley and is some 15 miles by rail from the port of Newcastle. The mine will produce coal from both Bore- hole and Young Wallsend seams. The Borehole seam has a working seam thickness varying from 7 ft to 5 ft while the Young Wallsend seam presents a choice of two distinct working thick- nesses, i.e. 5 ft. or 8 ft, the upper 3 ft containing much high ash material. The inter- seam interval varies from 10 ft on the western edge of the area to more than 70 ft in the central portion. The Borehole seam lies at a depth varying from 550 ft to 750 ft and the overlying surface terrain is gently undulating bushland with limited surface development.

Jan 1, 1972

Basic Oxygen Steelmaking (B.O.S.) commenced in Australia in December, 1962. Two 200-ton furnaces were installed initially at Newcastle with a 50-ton furnace coupled to a continuous casting machine added in 1967. In 1965, two 100-ton furnaces were installed at Whyalla plant and two 225-ton furnaces are nearing com- pletion at Port Kembla to commence oper- ations in 1972. Plant layouts in each centre differ due to changing circumstance and increasing knowledge of the B.O.S. process since 1962. Raw materials are a most important factor for good operation of the process. Most materials come from within Australia but some are imported. General operating practices are similar in each plant, although treatment of fume at Port Kembla will be by the OG (Oxygen Converter Gas Recovery) Process as against electrostatic precipitators in Newcastle and Whyalla. Special alloy steels as well as plain carbon steels can be made by the B.O.S. process. Production potential of the process in Australia has yet to be fully utilised with 45 per cent of steel production coming from B.O.S. In 1971.

Jan 1, 1972

By Thomas CG, Armstrong GJ, Lynch KS

A small glass walled pot grate has been used to simulate drying of iron ore pellets in a travelling grate plant. This equipment has enabled the effect of decreasing grind and de- creasing pellet bulk density on plant production to be quantitatively predicted. These predic- tions are compared with plant experience. The use of the laboratory simulator in comparing the effect of various additives on plant production is also described and substantial improvements in both the goethite and free-water drying periods are predicted.

Jan 1, 1972

In November, 1967, a four strand curved mould continuous casting machine coupled with a 50 ton basic oxygen furnace began producing billets for the rod mill and new merchant mill at the Newcastle Steelworks. To date over 500,000 tons of carbon and alloy steels have been cast at the rate of 20,000 tons per month, the major part for the wire industry. Many alterations have been made to the plant to simplify the process, improve quality and increase production. Casting parameters have been developed for each different type of steel. The quality of the final product has been influenced most by casting temperature, secondary cooling and casting speed. All these factors have been controlled and good results are reproduced. More exacting requirements of liquid steel quality have brought about the use of higher lime/silica ratio slags during steelmaking to control phosphorus revers- ions and standard ladle additions of manganese suicide and ferro aluminium for more effective deoxidation.

Jan 1, 1972

By Bowmaker MD

Zinc and lead sulphide flotation con centrates containing from 0.02 to 0.20% Cd are roasted on an updraught sinter machine at the Cockle Creek Works of Sulphide Corp- oration Pty. Limited to provide sinter for simultaneous smelting of zinc and lead in an Imperial Smelting Furnace (I.S.F.). The major portion (about 85%) of cad- mium in concentrate feed to the Sinter Plant is eliminated with sinter fume and is rec- overed by weak acid leaching in the Cadmium Plant'followed by counter-current decantat- ion, ion exchange concentration, precipitat- ion of cadmium sponge and partial refining to caustic refined cadmium metal. Cadmium not eliminated during sintering is volatilised in the I.S.F. and subsequently recovered as zinc alloy by distillation in the zinc ref- ining columns of the Zinc Refluxer. The partially refined cadmium metal and cadmium- zinc alloy are blended as feed to the cadm- ium refining column where separation and recovery of cadmium is effected. Condensate from the column is further refined under caustic soda flux and cast into anode shapes. Production is 200 t.p.a. at 85% recovery of cadmium in concentrates. Emphasis is placed on changes from the practice described by Baker and Munro (1965) and upon operation

Jan 1, 1972

The stratigraphic sequence west of Mount Isa contains the Judenan Beds, Eastern Creek Volcanics, and May Downs gneiss. It is an incomplete sequence as major north-south faults divide the area into four separatezones containing portions of these different units. The first three zones, which occur directly to the west of the Mount Isa Fault, consist of quartzites and quartz-mica schists which are uncorrelatable between zones but have been grouped together as the Judenan Beds. The most western zone contains an incomplete section of Eastern Creek Volcanics which rests conformably on a unit believed to be equivalent to the Mount Guide Quartzite; this is again underlain by the May Downs gneiss. A detailed description of the rock types is presented, but only a broad stratigraphic correlation is possible with the very much thicker sequence to the east of Mount Isa.The age of sedimentation is believed to be Lower Proterozoic and it may not occur in the type of geosynclinal basin envisaged by previous authors.This sequence is intruded by many small basic intrusions and also the Sybella Granite with its associated microgranite and pegmatites. The Sybella Granite consists of both a massive and a foliated phase; the latteris generally restricted to the margin of the main granite mass.Four regional metamorphic zones have been identified on the basis of their pelitic mineral assemblages; these are a chlorite, biotite, biotite-cordierite, and a sillimanite zone; separating each are prominent north-south faults.This metamorphism is a regional metamorphism which accompanies the first generation folding of the area and is not associated with the emplacement of the Sybella Granite. A very localized retrogressive metamorphism is also found in some areas of second generation folding.

Jan 1, 1972

The McArthur lead-zinc-silver deposit is of the stratiform type. It consists essentially of a mineralized bituminous shale sequence that incorporates tuffites, numerous graded beds, and isolated but massive slump breccia horizons.The principal sulphides are' pyrite, sphalerite, and galena. These occur mostly in the shales. The accompanying turbidites contain only minor mineralization.The geochemistry of the deposit has been investigated in relation to the stratigraphic column and mineralogy of the sediments.A sedimentary origin is proposed for the deposit. Volcanism, thermal spring activity, salinity, regional faulting, and climate are examined as possible factors that may have contributed to sulphide formation and which could be used as criteria for mineral exploration.The metallurgy 'of the McArthur deposit is discussed in terms of its geological history.

Jan 1, 1972

Silica reacts with cryolite at 1010°C in two stages. The first stage is the formation of a sodium aluminosilicate of composition consistent with the mineral jadeite (Na20.AI20s.4Si02). The formation proceeds by atleast two different reactions. Formation of alumina or an aluminosilicate proceeds to its limiting value in the first 30 min while the formation of jadeite proceeds at a steady rate until quantitative conversion is achieved after 150 min. The net overall reaction can be expressed by the equation 6 Si02+2 Na3AlF6? (Na20.AI20s.4Si02) +2 SiF4 +4NaF.The second stage involves a slow reaction that proceeds with the evolution of a little SiF4, The net result is the formation of sodium aluminosilicates that are soluble in 30 per cent AlCIs-HCI solutions. While this could be explained by disproportionation of jadeite to form albite (Na20.Al203.6Si02) and nepheline (Na20. AI203.2Si02), it is more likely that it is due to further but limited reaction between the oxides and fiuoroaluminates.

Jan 1, 1972

By Fraser RJ

A Robbins Raise Drill Model 61R was used to provide one 7' diameter shaft 1050' deep in Clutha Development's exploratory mine at Blackwater in Central Queensland and two 7' diameter shafts 1450' deep at their South Clifton mine on the Illawarra Coast of New South Wales.

Jan 1, 1972

The kinetic and practical aspects of the extraction of copper from copper-rich solutions by cementation on iron was investigated. Tests were made on the effect of stirring speed, cupric sulphate concentration, acid concentration, temperature, and ferric sulphate concentration on the reaction rate and excess iron consumption.Most kinetic investigations were conducted under a nitrogen atmosphere to prevent any oxidation of the iron or copper metals. The stirring mechanism for all tests incorporated the use of a rotating impeller above a static disc in the solution. The activation energy for cementation on the steel disc at high stirring speed was 8·6 kcal/mole, indicating a predominant chemical control.Increasing the pH first decreased, then above pH 3, increased the reaction rate. Additions of sodium sulphate also significantly increased the reaction rate.The use of high temperature and high pH under an inert atmosphere has been suggested for increasing the reaction rate and producing a high purity sponge copper product.

Jan 1, 1972

Mackenzie (1968, p. 167) inferred that amphibolitelayers grade into and may be correlated with footwall Potosi gneiss where it is thin under the thickest development of the "lead lode" in the New Broken Hill Consolidated mine, Broken Hill. This gradation from amphibolite to Potosi gneiss is tacitly assumed in many of the constructed crosssections of the southern end of the orebody, where amphibolite and Potosi gneiss, defined in hand specimen, are correlated in adjacent drill holes. The basis for such correlations is the observation that some amphibolites in drill core lighten in colour from black to grey along the core and grade into an unlayered rock containing conspicuous pink garnets, which resembles Potosi gneiss (for descriptions of Potosi gneiss see Andrews, 1922; Gustafson, BurreIl and Garretty, 1950; Carruthers and Pratten, 1961;\Ternon, 1969).Average chemical compositions of "footwall" Potosi gneiss and "upper" amphibolite (Hawkins...

Jan 1, 1972

Developments in furnace construction and design have been very rapid in recent years. Larger furnaces operating at high top pressures with much improved burdens are giving extremely high production rates. Modern scientific techniques and the use of computer control are contributing to these Rates.

Jan 1, 1972

By Henderson J, Ward RG

Dissolved oxygen has been measured directly using a rugged, reliable, accurate electrochemical probe system developed for steelworks application by B.H.P. Central Research Laboratories. Furnace measurements show that the steel is generally supersaturated with oxygen and that oxygen contents vary considerably from heat. to heat. Ladle measurements also show considerable heat-to-heat variations. Analysis in terms of ladle deoxidation chemistry differentiates between carbon monoxide controlled and manganese silicate controlled oxygen levels. Deviations from these levels are sometimes due to aluminium present in other added ladle alloys but in some cases the plant applicability of laboratory derived equilibria is questionable.

Jan 1, 1972

By Fitzgerald DE, Taverner MG

The principles, fields of application and equipment design concepts of several new approaches to continuous vacuum treatments of molten metals and alloys are discussed. Partic- ular attention is paid to the results of pilot plant tests evaluating a launder-in-tube method of 1. continuous production of refined zinc from a zinc-bearing lead produced in the lead splash condenser of the Imperial Smelting Furnace (ISF), and 2. continuous refining of crude cadmium. The former trials were not sufficiently encouraging to justify consideration of the process for commercial development. The applic- ation to cadmium upgrading gave very promising results; metal of 99.99 per cent purity was produced continuously at pilot scale (120 lb per hour) from crude metal containing 5.0 per cent Pb.

Jan 1, 1972