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S. A. Tomich (Consulting Geologist, Perth) : I would like to commend Mr. Haycraft on his presentation on the economic geology of the North End of Kalgoorlie. This is an intriguing area which is in the Kalgoorlie field but not of it, inasmuch as it is separated spatially from the main Golden Mile by the Golden Pike Fault. Mr. Haycraft has stressed the differences-the mineralogical and structural differences of economic significance between the two areas.I would like to ask whether he is satisfied that the lithological sequence in the North End is the duplicate of that in the main Golden Mile area irrespective of the postulated effects of erosion, and more specifically whether there is any chance that the quartz-dolerite-greenstone of the North End may be in any way dissimilar from the quartz-dolerite-greenstoneof the Golden Mile which is tellurude bearing.J. A. Haycraft: In relating the quartz-dolerite in the Hannan's North-Mount Charlotte area back to the Golden Mile, we find some quite close similarities. Although the rocks are similar they are not necessarily one and the same.At Mount Charlotte we have three varieties of dolerite- a coarse-grained gabbroic dolerite on the eastern side of the orebody, the host rock medium grained and on the western side, a fine grained dolerite. Further west we have an amphibolitic variety of quartz dolerite.Recent drilling south of the Golden Pike fault on the Enterprise No. 20 level had indicated a remarkably similar sequence of rocks. We drilled west through a wide section of medium grained rocks into a fine grained rock and then into amphibolitic quartz dolerite before intersecting the Golden Pike fault. Williamstown dolerite was located west...

Jan 1, 1965

Orebodies in the Mt. Charlotte - Hannans North Area N. & B. of the town of Kalgoorlie provide a marked'dontrast to the pyrite - telluride lodes of the Golden Mile, although both groups of orebodies appear to be fundamentally related. These highly siliceous telluride free orebodies N. of the Golden Mile are closely related to strong oblique faulting. The Golden Mile. lodes, while possessing an apparent over-all relationship to the oblique faults also have a close relationship to E.-dipping strike faults.

Jan 1, 1964

At Great Boulder Gold Mines Ltd. a number of attempts were made to remove water soluble copper and iron salts from calcined pyritic concentrates but variou~ problems arose and the methods were abandoned.A method of rapid washing has been developed and although some problems still exist a workable process was established which resulted in substantial savings of reagents used for the cyanidation of calcine.INTRODUCTIONIn the Great Boulder flowsheet crude ore is ground in cyanide solution, then thickened, agitated and subjected to two stage filtering. Secondary filter discharge is pulped with flotation circuit water, gassed with sulphur dioxide to precipitate soluble gold and activate pyrite, and after the addition of copper sulphate and xanthate, the pyrite and tellurides are recovered by flotation. Flotation tailings are thickened and pumped to the disposal area and concentrates are calcined in Edwards roasters. Calcine is washed to remove water soluble copper and iron salts and the washings pumped to the flotation section where the copper is used as an activator. The washed calcine is cyanided and returned to the crude ore circuit via the thickeners. Solution for precipitation in the Merrill Crowe is drawn from the crude ore thickeners.Prior to the introduction of calcine washing the calcine contained 7 lb/ton copper of which approximately 60 per cent was water soluble. It also contained approximately 90 lb/tol'l of water soluble iron salts. Both the copper and...

Jan 1, 1964

Gold was determined directly in eight different mill cyanide solutions, by atomic absorption spectroscopy in an acetylene-air flame. Some of the mill solutions were diluted with water to bring them into the most sensitive absorption region (5-50 p.p.m. Au) whereas those solutions with very low gold content «2 p.p.m.) were concentrated by evaporation.Calcium was complexed with ethylene diamine tetra-acetic acid (EDTA) to avoid the undesirable effect of a precipitate on atomization.When added to standard gold solutions, EDTA had no effect on absorption, nor did any of the impurities common in mill cyanide solutions.Known amounts of gold, ranging from 2 to 30 p.p.m., were added to mill solution'aliquots and recovered to within 100 ± 2·5 per cent. For duplicate determinations under normal worKing conditions, standard deviation was 1·32 p.p.m.Excellent agreement was found between atomic absorption gold values and accurate fire assay values.INTRODUCTIONAtomic absorption spectroscopy has been shown to offer a rapid and accurate method for the determination of trace amounts of a number of metal ions. In the field of primary metallurgy atomic adsorption has been used for routine determinations of lead, copper, silver, zinc, cadmium and iron in a variety of raw materials and intermediate products.The scope of atomic absorption spectroscopy was reviewed recently by Willis (1963).The noble metals silver, gold, platinum, rhodium and palladium were determined by atomic absorption from chloride solutions by Lockyer ·and Hames (1959). In their determination of gold down to 1 p.p.m., they found no interference from the noble metals, nor from considerable excess...

Jan 1, 1964

Although the 'exi'stence of bauxite in Australia has been known for many years it is only recently that exploitation has commenced.. of the two most' important` deposits, strangely at almost diagonally opposite tips of the continent. Recognition of the importance. of the bauxite in the South/West corner came about initially through the efforts of a well-known Australian mining company which,` with some outside financial help, tackled the early exploration with commendable foresight and courage.

Jan 1, 1964

To enable AN-FO .tòo' be used on an equal .weight basis wish Nitro Gl reerin.e expl3oòsives r smaller diameter bore holes became necessary With consequent modifications to drill steel and burden on holes, De't'onation of AN-FO "in small diameter holes proved successful' both with 'and without primer charges but some altorat-ions were required to. adopt Anolodeòr.s to the smaller -holes, Important factors in training all operators In the new charging method were the retention of imp-,cved, fragmentat'ion, avoidance of excel ive ove:break and keeping wall rock dilution 'to an absoluato mi. iArurle ò The ò successful storage of Ammonium 14t-rate in c"!ime.tic conditions 'with daily'.-' temperature fluctuationc above and below the critical' 90¦F, has. been "achieved,

Jan 1, 1964

The widely accepted kinetic model for the gaseous reduction of hematite is critically examined. The formation of the wustite layer during internal reduction cannot be explained in terms of solid-state diffusion. Present evidence indicates the existence of a micropore system in the wustite adjacent to the magnetite with the gas/solid type of reaction occurring not only at the iron/wustite interface but also at the wustite/magnetite interface. During the partial reduction of dense hematite pellets, in a controlled atmosphere, porous magnetite and wustite are formed as products. The mean pore size, as measured by mercury injection, increases with time at constant temperature and with temperature increase over the range 6500C to 950°C. The sizes of the pores indicate that Knudsen diffusion is the principal gaseous transport mechanism across thick layers of magnetite or wustite.The kinetics of the gaseous reduction to iron are consistent with a mixed control mechanism involving the interaction of gaseous diffusion effects with a first order reversible chemical reaction at the iron/wustite interface. Because of the larger pore sizes in the iron layers, ordinary molecular gaseous diffusion must be the principal transport mechanism. The usual experimental methods used for establishing the validity of chemical rate ~ontrol are incapable of differentiating between the mixed control- mechanism and exclusive chemical control.Some implications of mixed control kinetics are developed, including a predicted independence of rate on reducing gas pressure at higher pressures.INTRODUCTIONAn extensive literature review of the reduction of iron oxides has been compiled recently by Themelis and Gauvin (1962). From the large number of papers published and the widely divergent opinions of workers in this field, it appears that a simple unified quantitative analysis of reduction kinetics is not possible. The aim of the present paper is to show that a major cause of confusion is due to the attempts of many workers to interpret experimentally observed reaction rates in terms of a single rate controlling mechanism without due regard to other rate processes which must occur simultaneously.Some of the differences in behaviour reported for particles...

Jan 1, 1964

Cut and fillstoping using hydraulically placed mill tailings has become an essential feature of stoping operations in Kalgoorlie. ' Approximately 30 per cent of the total production is currently mined by this method. Fill is prepared by thickening or cycloning and is gravitated or pumped underground. The average pulp density is 70 per cent solids by weight, Recent cost reducing innovations are the use of steel passes, corrugated iron manways, polythene film sealing, and the replacing of vertical cement lined pipes with boreholes. TTTTTI rvr T Trim r l1TT

Jan 1, 1964

The corrosion of aluminosilicate refractories by soda from three different sources has been studied by microscopic methods. Sodium sulphate from oil ash, sodium chloride used in glazing structural clay products, and sodium borate from borax-impregnated wood ash have fundamentally the same effect on the refractories. The soda is the chief medium of reaction and fluxing, the sulphur, chlorine, and boron being volatized as sulphuric, hydrochloric, and boric acids.INTRODUCTIONBecause of their strong fluxing action, alkalis are one of the main causes of corrosion and slagging of refractories.The action of potash and soda on refractories follows somewhat similar lines, although it is common for one alkali to be greatly in excess of the other. The course of the reaction in a number of cases of alkali attack has been studied by microscopic and chemical methods. For example, the action of potash on blast furnace refractories was studied by Kraner (1942) and Rigby and Richardson (1947), who described the occurrence of various potassium aluminium silicates. Its action on cement kiln refractories was described by Brisbane, Segnit, and Weymouth (1957). The action of soda on glass tank refractories has been studied by many people, for example Bisby (1956) and Resch (1954). Clews, Hugill, and Green (1940) made a microscopic examination of the attack by soda on silica bricks from a gas retort.Some recent cases of corrosion of aluminosilicate refractories which were brought to the attention of the Division of Building Research, C.S.I.R.O., illustrate phenomena which occur under conditions different from those...

Jan 1, 1964

The, Mount Charlotte orebody contains' 5,000 tons per vertical foot-Of'quartz gold ore at an estimated ore reserve grade of )just 'over' 3 'dwt. per ton, Production from it i.s plan ned at a rate of 1,000 tons per working day during 1964.

Jan 1, 1964

By Canning RG, Uusna S, Goodheart BA

The paper outlines the development of"a process for removal of iron oxides from ilmenite, thereby upgrading the TiO2 content of Western Australian ilmenites, from 55 to approximately 90 per cent. In the first stage, the iron oxides are reduced with solid carbon (coal) to metallic iron. Experimental reduc- tions were carried out in crucibles,, a fluidised bed and a small pilot plant rotary kiln. The reduced'ilmenite is,then agitated in aerated water, in the presence of catalysts, so that the iron "rusts" away from the ilmenite'grains and the precipitated iron oxide is easily separable by decantation. The influence of variables on the rates. of reduction and oxidation are discussed, The oxidation rate was exam- ined for both - the' physical oxygen-transfer characteristics and electrochemically by reference to Peurbaix diagrams, which plot redox potential against solution 'PH, The upgraded ilmenite is expected to be an attractive material. for pigment -manufacture,, and the iron oxide has prospects of being a marketable by-product. The process may possibly be. applied, to .other..ores.

Jan 1, 1964

The comparison of belt drives with other types of power transmission involves the consideration of many factors before a final choice is made. Where other forms of power transmission might also be suitable, the selection of the correct type of belt has first to be made, in order to obtain a true comparison. The paper first deals with the types of belting available, followed by a description of most other forms of transmission equipment. An example is then given of the selection of suitable belts, which are then compared with other types of transmission. Comparative costs are also given. Reference charts provided show drives found suitable in general practice...

Jan 1, 1964

To date Iron Monarch is the most important Australian source of iron ore and since HH5 has produced about 84 million tons of direct shipping ore containing 62 per cent iron and 3 per cent manganese.Previous geological work, mainly by Rudd, Edwards and Miles is reviewed and the results of later exploration by quarrying and drilling are discussed and modified interpretations of both stratigraphy and structure are advanced. Renewed study of the mineralogy of the iron ores is advocated.The Iron Monarch orebody lies on the up-thrown side of a major transcurrent fault that truncates it on its northern boundary. The nearby Iron Knob orebody is believed to occupy a horizon that is some thousand feet stratigraphically above Iron Monarch.The origin of the ore cannot be explained by any simple theory; development probably took place over a long period of time from Lower Palaeozoic to Tertiary.INTRODUCTIONIron Monarch orebody has supplied the Australian iron and steel industry with the greater part of its ironstone requirements since the establishment of the Newcastle steelworks in 1915. Annual production of direct-shipping ore has exceeded three million tons but declined slightly after 1956 when Iron Prince was brought into production. Total production of ore from Iron Monarch to the end of 1962 is about 84,000,000 long tons containing some 55,000,000 tons of metal.The deposit (Lat. 32°44'30"S : Long. 137°08'30"E) is 34 miles north-west of Whyalla, on the western shore of Spencer Gulf. A 42 in. gauge railway connects Iron Monarch and its associated small town of Iron Knob with Whyalla (Fig. 1).For the purpose of this paper Iron Monarch includes Iron Knob and the intervening jaspilite hill known as Substation Ridge, and the description of the general geology necessarily 'Assistant Chief Geologist, The Broken Hill Proprietary Co. Ltd.This paper was presented at the Annual Conference of The Institute, 14-24th August 1968.

Jan 1, 1964

An intensely sheared and mineralisedIzone occurs in the Quartz Dolerite Greenstone (or Younger Greenstone) mass on, the western limb of the Kalgoorlie Syncline. This zone comprises the western part of the Golden Mile and has produced the greater part of the 33,000,000 ounces of gold produced to date from the main mining belts. A study of.th e general geological and structural features gives rise to the expectation that the lode shear system,will continue southward on a pitch similar to that of the maln syncline whose axial plane may be referred to as the "Boulder Dyke". Although payable ore has recently been found further south than previously, the expectation of large quantities extending southward from the present mining areas is Problematical.'

Jan 1, 1964

In the- past, at Great Boulder Gold Mines Ltd,, ,' s.. number of attempts ' ha'tre been made to remove water ' `solublo copper and' iron sa'lt's from calcined pyritic concentrates, but various problems have arisen and the methodsi ve been abandoned. A method of rapid washing has now been developed,, and although some problems still. exist,, a workable `process has boreh established .which. has; resulted in 'substantial savings of 'reagents used for. the. cyanidation of calcine

Jan 1, 1964

Updraft sintering of lead concentrates was introduced at Port Pirie in 1955 and since that time a considerable amount of investigational work has been carried out in the laboratory and on the plant with the objective of improving both the understanding of the process and its practical application.From this work it is now possible to predict trends in design and operation, which should result in capital savings and increased efficiency of future updraught plants.INTRODUCTIONOver the last 70 years a remarkable advance has been made in the method of preparing lead concentrates for smelting in the Port Pide blast furnaces of The Broken Hill Associated Smelters Pty. Ltd. (RH.A.S.). Beginning in 1889 with heap roasting, the process progressed to Ropp roasters and Huntington-Heberlein pots in various combinations, then to multiple small Dwight Lloyd (D.L.) downdraught machines. In 1940 two large 10 ft by 50 ft D.L. downdraught machines were installed, and finally in 1955 updraught sintering was ,introduced with the installation of the present 10 ft by 99 ft sinter machine.At the time this last machine was built it was the first unit of its type and thus, of necessity, an experimental machine. During the eight years it has been operating a considerable amount of investigational work on sintering has been carried out both on the plant and in the laboratory.It is now felt that sufficient information is on hand to predict at least tentatively, some of the future developments in lead sintering, whereby both the quality of the sinter and the rate of production may be improved. This will result in a considerable reduction in smelting costs.

Jan 1, 1964

By Hindmarsh J. W, McCoy A. E R

Instantaneous outbursts of coal and gas have occurred at various times in several working districts of Metropolitan Colliery, N.S.W.They have occurred in headings only, under both hand and mechanised conditions, and with seam gas ranging from mainly methane to nearly pure carbon dioxide. A modification of inducer shotfiring using a shear cut was introduced in 1955, and in 1961 full face firing both to a machine cut shear and off the solid was introduced. The current series of outbursts -1961 to 1963 - has been induced under these systems with full control of the time of outburst, but without prediction, and with some disappointing production features.Various aspects of current conditions and practices at Metropolitan are considered singular, such as the coarse granulometry of outburst coal, the prevalence of floor heave, the absence of strong structures at outburst sites, the possibility of outburst at any stage in pillar formation up to the last few yards, the effect of rate of advance on outburst occurrence, and the mildness of many outbursts experienced.It is concluded that inducer shotfiring is a reliable control but it suffers by comparison with outburst-free conditions, and that control by preyention would be preferable.INTRODUCTIONThe phenomenon of instantaneous outbursts of coal and gas has been described in detail previously (Hargraves, 1958). Briefly, it is a combined gas and stress hazard of deep coal mining, usually occurring in virgin work and during active face advance, when coal and seam gas burst from the face into the workings.Instantaneous outbursts have occurred sporadically at Metropolitan Colliery, N.S.W., since 1895. Early outbursts were recorded as firedamp and recent outbursts are of blackdamp.Mining methods used have been conventional hand work, with progressive and relatively complete mechanisation over the past 25 years to substantially conventional...

Jan 1, 1964

The treatment of beach sands in'' the Bunbury/Capel' area for the extraction of ilmenite is a very recent development in the mining industry in'J7estern Australia. Nevertheless since the commencement of production in 1956, ilmenite has become the sixth most important mineral produced. The increasing world recognition of W.A. as a major' Iiroducer of ilmenite is due primarily ' to its low chromic oxide. ; (Cr203 content,, 0,03% to 0.04%, combined with a medium to high grade TiO2 content, 54% - 6 , supported by large reserves, a'. stable government with close access to good shipping facilities.. Ilmenite is produced from-these deposits at low-costs, enabling the industry to compete on world markets despite high rates for sea freights because of the distance from.major markets.

Jan 1, 1964

The addition of a thallous salt to the cyanide leach of a calcined pyritic concentrate causes a marked increase in the rate of extraction of gold. This is due probably to the activation of passive gold by the thallous ions. Lead, bismuth, and mercury salts, which should produce a similar effect, fail to do so. It is postulated that this latter result, together with the reprecipitation of silver at low cyanide levels, is due to the presence of soluble sulphide.INTRODUCTIONThe work of Fink and Putnam (1950) showed that the rate of solution of gold in cyanide can be increased by the addition of small amounts of lead, bismuth, mercury, and thallium salts. Mills (1951), during a study of the electrochemistry of gold, with particular reference to cyanidation, was able to show that gold may become passive towards cyanide solution. The addition of lead or thallium salts prevented this passivity, although the action of lead was limited to the pH range 10 to 12. In a recent paper Cathro (1963) confirmed the findings of Mills, and presented results which showed that the addition of thallium to a cyanide leach of a calcine from Lake View and Star mine, Kalgoorlie, increased the rate of extraction of gold appreciably. In, this paper the use of thallium to prevent the gold becoming passive, and hence to decrease leaching time and cyanide consumption, is examined.EXPERIMENTALA series of leaching tests was carried out on a sample of Lake View and Star calcine, comprising calcined pyrite (about 70 per cent.) and siliceous gangue (about 30 per cent.) and containing 165 p.p.m. gold, 45 p.p.m. silver, 0·1...

Jan 1, 1964

The southern portion of the Swan Coastal Plain, a geomorphological element formed since late Tertiary times, contains commercially exploitable accumulations of ilmenite, zircon, rutile and monazite associated with a series of raised shorelines. The location of the deposits is controlled by a locally outcropping Archaen granite/ granulite complex and a sea current pattern determined by local geography and a prevailing wind direction. A progression from medium to high titanium ilmenite is evident parallelled by progressive leucoxenisation as the age of the deposits increases. Variations in trace element content accompany this process. Circulating groundwater has caused vertical mineralogical variations within individual deposits and by precipitation of iron has formed layers of hardpan.The Geographe Bay deposits are of important economic significance.INTRODUCTIONObservations made during the course of a brief survey of the southern portion of the Swan Coastal Plain provide an outline of the geology and mineralogy of the mineral sand deposits of the area. This preliminary study will require considerable modification in the light of more detailed work in the future.REGIONAL GEOLOGYThe Geographe Bay area is situated in the south-west corner of Western Australia between longitudes 115° O'W. and 116° O'W. and latitudes 33° 15'S. and 33° 45'S.The general geology of the area is shown in Fig. 1 where the control of the physiography exercised by the Cape Leeuwin-Cape Naturaliste basement ridge is readily apparent. Between this ridge and the Precambrian east of the Darling fault lies the southern part of the Perth basin which contains outcropping Jurassic to Recent sediments and lavas (McWhae, et al., 1958).The Leeuwin-Naturaliste ridge is the exposed portion of L Assistant Production Managcr. Laporte Titanium (Aust.) Ltd.

Jan 1, 1964