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By Lawrence L. J

The Australian Broken Hill Consols Mine, situated some 600 yd east of the main Broken Hill line of lode, is noted for its rich ores of silver. In contrast to the vast conformable orebodies of the Broken Hill field, the Consols lode occupies a narrow fissure dipping to the south west at angles increasing from 240 through to vertical and transgressing the strike of the metamorphosed country rock at an oblique angle. This feature, together with the abundance of calcite and siderite and the virtual absence of silicate minerals in the gangue, has led to its classification as an orebody of the Thackeringa type (King, 1953). Recorded production during the period 1890 to 1903 is given as 845,000 oz of silver and 20 tons of lead.The unusually rich silver values of the Consols lode were concentrated at the intersection of the fissure with beds of amphibolite, whereas in the adjacent schists and gneisses the lode became markedly impoverished. From the surface to a depth of some 120 ft extensive surface oxidation had occurred, resulting in the breakdown of siderite and its replacement by limonite and associated manganese oxides.Silver halides, dyscrasite, acanthite and partly oxidised tetrahedrite were the main silver minerals in this zone. With increasing depth the lode material gradually reverted to minerals representative of the hypogene zone.The only previous work specifically on the mineralogy of the Consols lode is that by Smith (1922), one time manager of the mine. His zeal as a mineral collector resulted in much valuable information being available on the distribution of the minerals. More recently, Garretty (1943) noted the...

Jan 1, 1962

By Alvin J. F

Tin in ores containing 0·025 to 1·5 per cent tin can be determined polarographically by the reduction of the chlorostannite ion at the dropping mercury electrode in 2M hydrochloric acid solution containing 15 per cent ammonium chloride. The tin is separated from interfering elements by distillation as the tetrabromide and collected from the distillate by co-precipitation with aluminium hydroxide. The method can detect 0·01 per cent tin in ore.INTRODUCTIONAn iodimetric method, suitable for routine analysis of titrating tin in concentrations down to 1 per cent, has been available for some years (Low, Weinig, and Schoder, 1939).As concentrations fall below 1 per cent tin, there is increasing difficulty in obtaining a distinct end point due to large amounts of iron and silica normally present after fusion of the ore. Since concentrations of tin down to 0·02 per cent are significant in ore dressing products it was necessary to examine methods to determine such low concentrations, and to adapt these to tin ores containing a wide variety of other minerals.EXPERIMENTALDigestion and separationCassiterite, the principal tin mineral, is refractory but readily attacked by a sodium peroxide flux to yield soluble sodium stannate. In a recognized procedure, a sample of ore is mixed with up to 15 g of sodium peroxide in an iron crucible and swirled over the full heat of a Meker burner for 7 min. The fusion is leached with water and acidified.This solution then contains tin, silica, and other soluble...

Jan 1, 1962

By d&apos, Alton AJ, Rigden DT

Modern petroleum refining offers a complexity of environments, each requiring different metals for the satisfactory performance of-the various sections of the refinery, and this paper first outlines the varied enva.x¦on-ments thus met.It follows that the metal types in use will also vary to suit each particular environment, and the paper' consequently covers the use of ferrous-metals, ranging from plan carbon steels to the high alloy types and the non-ferrous metals, particularly copper and its alloys.The failures of some,of these metals and alloys are then illustrated by experiences it Kwinana. These failures are duo to (a) corrosion, (b) erosion, (c) faulty welding, and (d) mechanical defects,' of which the first is by far the most prevalent. The protective measures taken to prevent subsequent failures are then given under one or other of the following headings :(1) alterations in process conditions, (2) the use of alternative ,alloys,(3) suitable heat treatment, (4) redesign of the failed section, (5) cathodic protection, and (6) use of corrosion inhibitors.Reference is then made to the use of specialised metals and alloys.Metals, generally in the form of oxides or salts, are also used as catalysts in refining processes. Activated alumina is used, combined with silica .forScracking' of heavy oils, and as a support -for platinum, cobalt, molybdenum, nickel and similar metals, which catalyse hydro-genation and dehydrogenation-processes. .In the final formulation of petroleum products metallic compounds may be added. Reference is made to the large quantities of lead used by the petroleum industry and to the use of metallic soaps and detergents in the formulation of lubricating oils and greases.

Jan 1, 1962

Differentiation of a basaltic (?) magma occurred in an active volcanic area during the late Miocene and Pliocene, and a change in the general mode of extrusion from fissure flow for the basalt to explosion for the andesite reflects an accompanying increasing magmatic viscosity. A caldera formed after the flow phase was completed and was filled with coarse agglomerate, much of which has a fused appearance. After an erosion interval its shape was modified and it became gradually deeper as repeated explosions from growing andesitic volcanoes caused large quantities of pyroclastic material to be deposited. At the close of this phase the floor abruptly collapsed when a, large block of the underlying crust was engulfed. The incompetent pyroclastics filling the caldera steepened in dip and the ensuing fractures were filled by the rising magma as dykes and sills and a chonolith formed below the caldera at a shallow depth. The ensuing activity reveals a further stage in differentiation and biotite is an important new ferromagnesian to be observed in the new rocks.Fracturing of the surrounding basalts was most intense in the rocks forming the periphery of the caldera where steeply and flatly dipping faults resulted from increasing horizontal pressure directed towards the caldera.Further differentiation resulted in the increased crystallization of orthoclase felspar, as evidenced by the numerous intrusives of trachy andesitic composition. Magmatic freezing caused mineralizers to accumulate at the top of the chonolith. These eventually escaped and auriferous pyrites, tellurides, quartz, and calcite were deposited in the surrounding rocks.The flatly dipping fractures are the most important and can be expected at various depths in a zone about 4,000 ft wide surrounding the caldera. Latest movement along these was controlled by magmatic consolidation rather than the shape of the caldera. Some flat faults were able to remain open during mineralization and acted as a feeder for the shallower fractures, thus limiting the depths to which the steeper dipping fractures were mineralized with the possible exception of one particular Nw.-striking lode (the Crown-Crescent).INTRODUCTIONThe gold deposits of the Tavua district were discovered in 1932 and from 1935 to June, 1961, 1,985,041 fine ounces of gold were produced from 4,202,504 tons of ore. Of the original three producers, only the Emperor remains active in the...

Jan 1, 1962

Early theories of coal formation are outlined, with special emphasis on the arguments for allochthony and autochthony. Various aspects of the nature, growth, and decay of the characteristic vegetation of the brown coal peat moors, their conversion into coal, the origin of banding, and the influence of tectonics are discussed.A description of the banding in Victorian brown coals is followed by a discussion of their vitrain, fusain, and natural carbonized coal; and concludes with the nature of the coal resin and the possibilities of its extraction.The nature and derivation of inorganic matter in brown coal, based on Lessing's classification, is described. Assimilation of mineral substances in specific plants with variations due to environmental factorsare illustrated by analyses of present day trees. Consideration is then given to possible sources of salt, marcasite, and quartz in brown coal.It is shown that part of the inherent and extraneous ash may have been removed during and after coal formation. The nature and abundance of the organically combined substances in brown coal emphasizes the anomalies that may arise from estimating the total inorganic matter from ash contents.After classifying deposits on external heating surfaces of boilers, theoretical and practical aspects of slag formation, alkali matrix deposits, and the effect of sulphur and chlorine are considered.Analyses of deposits in boilers burning Victorian brown coal are tabulated.Slagging at the Yallourn power station from sand in the Yallourn open cut, and difficulties with Yallourn North Extension coal at the Maryvale paper mills are described.Tests carried out on Morwell and Yallourn coals showed that with the former, impacted deposits formed on boiler heating surfaces, and left a high percentage of chlorides on probes. Morwell briquettescompared with Yallourn briquettes also reduced the running time of a semi-industrial boiler through deposits with sodium sulphate as...

Jan 1, 1962

Extensive geophysical exploration and drilling operations have been: conducted in, South Central Queensland by Phillips Petroleum Company and Sunray DX Oil Company since late 1959. The main outlines of subsurface geology are now known, but many problems must be solved before a comprehen sine. picture can be presented of the geology and petroleum prospects e Interpretations to date suggest that -fiddle Paleozoic sedimentary rocks, probably, related to the Tasman belt of geosynclines, once extended. over. most. of the area An oro;eny 2.n late Paleozoic time, succeeded by deep pre-Pexmian erosion, removed the older sediments over large. areas, but Paleozoic sediments, were preserved from erosion in the Adavale and ancillary structur-a.l basins. Marine sediments of Devonian age are con-sidered prospective source beds for petroleum. Current work is directed toward finding favorable structure and reservoir beds to test the oil prospects of the area.

Jan 1, 1962

Air tabling of zircon-rich non-conductor products containing quartz enables most of the fine quartz present to be rejected without a markedloss of zircon. The coarser quartz in the air table feed can be separated from the zircon by screening one or more air table products, the oversize products containing most of the quartz and little of the zircon. Air tabling, with or without screening, is more efficient than wet tabling alone for the removal of fine quartz, but not for the removal of coarse quartz. Practically all of the quartz can be separated from the zircon by using wet tabling in conjunction with hydraulic classification, or by using air tabling in conjunction with dry launder treatment, in which a degree of sizing takes place that is advantageous for subsequent air tabling.INTRODUCTIONBack-dune and inland beach sand deposits usually contain fine wind-blown quartz, and neither spiral nor wet table concentration, alone or in conjunction, makes a clean separation of heavy minerals from quartz. Many rutile plants recover rutile and zircon from a low-quartz, wet-table concentrates by means of magnetic and electrostatic separation; some rutile and zircon are lost in the table tailings. Other rutile plants, and two of the ilmenite plants in Western Australia, recover rutile or ilmenite respectively, from a spiral concentrate containing several per cent of quartz, and then subject the non-conductor product to an additionalgravity concentration process to separate the zircon from the quartz. Some zircon is lost in the additional gravity process, but all of the rutile or ilmenite in the spiral concentrate is, or should be, recovered as high-grade concentrate. The higher recovery of rutile or ilmenite by this treatment method is offset by the expense of drying part of the feed twice, as a wet process is usually used to separate the quartz...

Jan 1, 1962

Statistical frequency distributions may be used to characterize the overall variation of grade in orebodies. Special types of distribution (e.g. lognormal, log-type A) are necessary to describe skewness inthe case of rare metals. Also needed (but for the most part hitherto neglected) is the serial correlation function which describes the tendency for grades near together in an orebody to be closer together than grades at points relatively far apart.The sampling problem for orebodies is interpreted in statistical terms. Different methods are reviewed, and the effect of serial correlation discussed.A discussion is given, based on experiments and observations made by the author, of biases arising in the minei:l material by such methods as chip sampling and grab sampling due to such causes as nonrepresentative selection by the sampler.INTRODUCTIONMiners have always recognized the large element of chance in their operations. Chance is the raw material of statistical theory and, provided there is some recognizable pattern or underlying regularity in a set of data arising from the operation of chance events, statisticians are able to formulate mathematical models to study them. Mining engineers, geologists, and statisticians have gone a long way between them towards finding general statistical rules which describe the distribution of minerals and metals in orebodies, and even the distribution of orebodies over the earth's surface.These rules do not have the force of physical laws, though they obviously derive from them and have been used to throw light on them. From statistical theory it is possible to find methods of estimating from sampling some of the characteristics of orebodies which are of importance to...

Jan 1, 1962

Important factors in dredge design are the estimation of total head, and the determination of flow in and around suction nozzles and in pipe lines. Total head for the dredge pump is calculated from velocity, static, and friction heads. Flow into suction nozzles depends on whether hydraulic jets or mechanical cutters are used, and on nozzle shape. Design of pipe lines depends on the transportation characteristics of the pulp, skin friction, swirl, and the avoidance of cavitation. Measurement and control of flow is important.INTRODUCTIONEconomic deposits of heavy minerals along the east coast of Australia occur in frontal dunes, which are normally unconsolidated and granular, or in hind dune areas which may contain indurated seams interspersed with loose material. In working frontal dunes, dredging depths are usually shallow since values do not persist for more than a few feet below sea level. However, the controlling factor in dredging the hind dune areas is the level of the water table and suction dredges may be designed to mine to depths of 120 ft, or even more, if necessary.In previous applications of suction dredges in the industry attention was directed primarily towards production and there was only limited research on fundamental techniques. However, with lower grade deposits now forming the major ore reserves, production levels and profit margins will fall unless more efficient dredges are developed.For satisfactory design of dredges it is essential that the total head be accurately estimated and that detailed information of the principles of flow in and around suction nozzles be determined. This paper presents information gained from field experience and laboratory investigation on these aspects.

Jan 1, 1962

Any Australian who knows of the poverty of the early settlers in the first few years following the arrival of Captain Arthur Phillip with his "first fleet" at Botany Bay must feel proud of the progress that has been made in the 174 years that have elapsed since that momentous occasionGFor all its attractive appearance as reported by Captain Cook and Sir Joseph Banks, the shores of Botany Bay and of Port Jackson proved most ,inhospitable, and the accessible country surrounding them anything but suitable for sustaining the life of the small settlement. It is well known that during the first 15 or 20 years the hardy colonists and un-tfortunate convicts were close to starvation on several occasions and were only saved by the arrival of supply ships, which were dependent on the vagaries of wind and current, and the hazards of the uncharted seas they had to -navigate-.When Australia was little more than a miserable penal settlement, Great Britain was one of the great-powers of the world, and the U,.S.A. was an independent nation with a growing degree of prosperity that even then gave promise of its mighty awakening to become, as it has, a e.olossus of industry and commerce,-and the. leader in living standards of the world to-day.Australia, from such a shaky, and comparatively recent start, has risen to a position in which its living standards rank very high in comparison with those of most of the nations of Europe and America. Exact com-parisons are hard to fix because of the wide variety of factors involved .but the Institute of Pab?Lic Affairs .(Victoria) places Australia fifthin the world, excelled only by the U.S.A., Canada, Sweden and Switzerland. The next best after Australia are the United Kingdom, West Germany and France.How we achieved such a high standard of living is a vast subject for study but some of the economic aspects of our climb from abject poverty to a position of near affluence can readily be identified.

Jan 1, 1962

By Harraway D. H, Draper N

The association of graphite with a fine grained pyrite in the Mount Isa lead-zinc ore was investigated from mineralogical and metallurgical standpoints. The pyrite has been partially or completely replaced by galena and to a less extent by sphalerite, pyrrhotiteand chalcopyrite with the retention of graphite films or inclusions. During lead flotation the graphite imparts a spontaneous flotability to all associated minerals, resulting in a low grade fraction, which we call the carbonaceous fraction, floating with and diluting the lead concentrate. In times of low metal prices this fraction seriously reduces the economic value of the lead concentrate. A flotation procedure was developed to upgrade the carbonaceous fraction separately, producing an economic concentrate and a tailing.INTRODUCTIONThe lead concentrate produced from Mount Isa ores can vary from 20 to 50 per cent lead, depending on the locality in the mine from which the ore is obtained. Variations of this order are independent of ore grade and lead recovery. The large variation is related to the presence in the ore of a variable fast floating low grade fraction known locally as the carbonaceous fraction because of its association with graphite. During conventional lead flotation with sodium ethyl xanthate the carbonaceous fraction floats rapidly and unselectively with normal Mount Isa galena.The paper discusses mainly the examination and treatment of an average carbonaceous fraction, defined here as the fast floating material in the mill feed of late 1956. The ore was drawn from the Mount Isa Black Star orebodies. The fraction represented about 5 per cent of the total ore...

Jan 1, 1961

By Mercer J. K

Shaft guide reaetions in No. 2 Ore Shaft, Mount Isa Mines Limited, have been reduced to a low order of magnitude by the use of self aligning slippers and spring loaded guide rollers. Before commissioning the new 4500 h.p. winder at No. 2 Ore Shaft in January, 1958, it was realised that the increase in hoisting speed from 1800 to 2650 ft/min. would cause high shaft guide reactions which would be increased further when the elongated 12 ton skips replaced the existing 7 ton skips.The Cambridge accelerometer was used to measure the shaft guide reactions and to confirm that progressive skip modifications were resulting in reduced reactions. The skip modifications were completed in 4 weeks.INTRODUCTIONIn 1956 an expansion programme was initiated to increase production from 5000 to 11000 tons per mining day. At No. 2 Ore Shaft the 1500 h.p. winder operated at 1800 ft./min. and hoisted a 7 ton capacity skip. The new 4500 h.p. winder operates at 2650 ft./min. and hoists a 12 ton capacity skip. No. 2 Ore shaft is equipped with two 5 ft. by 5 ft. hoisting compartments (Fig. 1) and any increase in skip capacity meant an abnormally long skip. This feature, coupled with the increase in hoisting speed, could have caused very high shaft guide reactions. Before commissioning the 4500 h.p. winder, a Cambridge accelerometer was borrowed from the University of Adelaide and was used to measure the shaft guide reactions. Rather than carry out an extensive shaft timbering programme, the skips were modified by fitting cushioned guide shoes and spring loaded guide rollers (Fig. 1). Testing commenced in February, 1958, and was completed in March, 1958.

Jan 1, 1961

Factors of importance in the ntilization of coal fines are mentioned, and the results of flotation tests on coal fines from three important coal seams in New South Wales are presented.INTRODUCTIONEconomic utilization of fine coal is an important problem in the Australian coal industry, particularly as the proportion of fines mined is increasing with progressive mechanization.While the use of uncleaned coal fines may be economic, it may be preferable to beneficiate them, but the most economic process must be selected.For beneficiating coal finer than about 28 mesh, froth flotation can be applied, but mining engineers should avoid practices that may be detrimental to flotation. Such practices include the indiscriminate use of water, particularly that containing a wetting' agent, for dust suppression. In addition, clay stemming in wet conditions may produce slimes which could adsorb on coal surfaces, while the use of oils and greases as well as the application of stone dust and chlorides in roadway consolidation may influence adversely fine coal beneficiation.This paper deals with the application of flotation to samples of fine coal from the Bulli, Greta, and Victoria Tunnel seams. In addition a discussion is given of the mineralogical constitution, size analysis, and degree of liberation of ash constituents of the various samples.COAL SAMPLESRepresentative samples of coal from the Bulli, Greta, and Victoria Tunnel seams were obtained for testing.

Jan 1, 1961

An investigation was made into the mineralogical characteristics of the upper portions of the 650 and 750 copper lodes. The investigation was based on a comprehensive suite of geological specimens representing all types of mineralization encountered during mining until the end of 1954 and the chief aims of the investigation were to determine (a) the minerals present and their textures and associations, (b) the paragenetic sequence of deposition of minerals in the orebodies, (c) significant changes, if any, which could be found in the orebodies with depth, and (d) the nature and mode of occurrence of nickel in the ore. The general structure of the orebodies is outlined and their mineral composition given. 10 textures exhibited by the ore minerals are described and a paragenetic sequence of events in the formation of the copper orebodies is outlined. No decrease in the complexity of the sulphide mineral textures with depth could be seen and no evidence was found to suggest that the tenor of the ore would decrease with depth although some factors which may eventually limit the extent of the orebodies are noted. The mode of occurrence of minor elements in the orebodies is described. Notes on the occurrence of pyrite, aikinite and berthierite in the orebodies is given and the orebodies are considered to be identified with LiIidgren's mesothermal type of sulphide ore deposit in which considerable replacement of older by younger generations of sulphide minerals occurred.INTRODUCTIONA mineragraphic study was made by Stillwell and Edwards (1945) of a suite of specimens submitted by Mount Isa Mines Limited from the Mount Isa Black Star copper orebodies with a view to determining 1. the nature, extent and association of arsenic, antimonyand bismuth minerals, 2. the mode of occurrence of silver and 3. whether galena and sphalerite occurred in minute forms and below the sizes readily observed in hand specimens.

Jan 1, 1961

By Hemingway P, Boag J

Major operating aspects of the Mary Kathleen Uranium Ltd. treatment plant are discussed with partkular reference to those which are peculiar to this operation.Problems associated with the production of a penalty free uranium oxide product are examined and the methods developed to overcome them are described in detail.INTRODUCTIONMary K,athleen Uranium Ltd. is the largest of the Australian uranium producers. The flow-sheet is based on fine grinding, standard sulphuric acid leach, ion exchange concentration, and magnesia precipitation of the final product, with certain modifications introduced as the result of pilot plant investigations at the South Australian Department of Mines Research Laboratories in Adelaide.The plant commenced operations in June, 1958, attained design tonnlige of 1,120 tons per day in September of that year and has since operated continuously with a throughput in excess of 1,000 tons per day. Pilot plant recommendations generally have been followed, and predicted results have been attained. The only exception has been the silica and rare earth content of the product produced during the early months of operation. Considerable modification of the early resin regeneration techniques resulted in the reduction of the silica content of the product to within specification limits. Research work in the ion exchange section has also resulted in the reduction of the rare earth content of the product to below specification levels. All product now being produced is completely within the agreed specification limits of impurities.

Jan 1, 1961

During the past eight years a vigorous drilling campaign resulted in large increases in the reserves of both copper and silver-lead-zinc ores.As a result the Company initiated an increased production programme.Some major capital works have been completed, others are in progress and more are needed to achieve the proposed daily throughput of 14,400 tons. The increased ore potential justified a copper refinery which has been constructed at Townsville. The increased production rate achieved to date, combined with improved techniques and greater mechanization, is assisting the Company to combat the general inflationary trends caused by increased costs for labour and materials.INTRODUCTION"Today we are armed with better weapons in our fight for lowered costs and greater efficiency, but we must not flag in our efforts to improve." Such was the resolution expressed by Mr. K. B. Gross, then General Manager of the Company, in his review lecture delivered to the First Ordinary Meeting of The Australasian Institute of Mining and Metallurgy at Mount Isa on 18th August, 1952. This present review of the period 1952 to 1960 records our efforts to fulfil this resolution. At the th:ne of Mr. Gross's statement,copper production was commencing in earnest. Although the importance of Mount Isa's copper orebodies was well recognized, the major discoveries which led to Mount Isa's emergence as Australia's premier copper mining and smelting operation were not known. These ore discoveries and their subsequent development are the major factors which warrant a further review of the Company's progress.The increased magnitude of the Company's operations is illustrated on graphs of Tons of Ore Treated (Fig. 1), Metals in Products (Fig. 2), Water Consumption (Fig. 3)...

Jan 1, 1961

This Institute, by nature of its charter, draws on various persons in the mining and metallurgical world of Australasia for its President from year to year, and consequently when the presidential address is given by one of these people the topic. which they generally select is a topic to which they are accustomed and on which they are able to speak with authority.As most of you know, my prime object in life has been concerned with steelmaking, so tonight you can steel yourself to the thought that you are going to be spoken to about steelmaking.Even if that were not the case, and were I not particularly interested in steelmaking, I think it would be appropriate to look at steelmaking in a broad sense on a basis of pure metallurgical interest, because the steel industry is going through as big a revolution today as it went through something over one hundred years ago when Bessemer made a theory become a fact.Bessemer, and as the Americans prefer to think Kelly, separately conceived the idea of blowing cold air through molten pig iron, and, contrary to the then general belief, this did not result in cooling of the metal but succeeded rather in heating it, and in burning out of the rather crude pig iron the impurities which prevented it from becoming a ductile metal.For many years before this, steel had been made in a very small painstaking way by what was known as the crucible process. Benjamin Huntsman is credited with having developed the crucible steel making process to a stage where it could make a reliable and trustworthy product, but he...

Jan 1, 1961

The coalmining industry in most countries has, at various times, suddenly been confronted with a decrease in demand for coal. Readjustments made to reduce productive capacity to match the reduced demand for coal have often resulted in hardship to mineworkers, loss of capital investment to mineowners and loss of coal reserves. The consequences of the methods of readjustment adopted in the past have contributed to the low esteem in which coalmining has come to be regarded by a large section of the gel).eral public in many countries.Four sections of the coalmining industry, representing different periods of time, different countries, and different methods of industrial organisation have been examined:Great Britain and the U.S.A. during the inter war years, the post war European Coal and Steel Community, and post war Great Britain under the National Coal Board. An assessment has been made of the methods adopted in each case to reduce productive capacity to match a reduced demand for coal. Finally the fundamentals of the problem-as it affects the coalmining industry of any country-are considered, and possible solutions put forward.During the 1950's, surplus productive capacity was a problem in many coalmining countries, including Australia and New Zealand. As a rule no techniques are developed beforehand to solve problems introduced by a sudden decrease in demand for coal. The situation is usually tackled by a series of short term decisions based on expediency, which often in the long run only aggravate the problem.

Jan 1, 1961

By Richards S. M

The abundances and abundance relationships of lead, zinc, copper and silver in the major sulphide lenses at Broken Hill are examined, and their possible geochemical significance discussed.When expressed as atoms per cent, zinc is the most abundant base metal throughout the whole .group of orebodies, the highest average lead: zinc ratio (No. 2 lens) being about 0·45, the lowest (No. 1 lensZinc Lode group) being in the 0·12-0 ·14 range. Lead and silver are clearly higher in the lower two orebodies, but the abundance of zinc shows no apparent relationship with stratigraphical position. Among the base metals copper is conspicuously low and remarkably uniform, a feature noted in other conformable orebodies.Although, as has been recognised for many years, abundances of silver and lead, and lead and zinc, are sympathetically related, correlation within the pairs is variable and generally of low degree. Silver and lead show distinctly the better correlation, particularly in No. 3 lens. On the basis of lead: zinc ratios, No. 2' and No. 3· lenses, on the one hand, and the No. 1 lenses, Rhodonitic and Siliceous Zinc Lodes on the other, constitute two groups. However on the basis of silver : lead ratios, No. 3 lens stands alone, No. 2 lens showing clear affinities with the higher layers. Ternary relationships between copper-zinc-Iead and silver-zinc-Iead emphasize the very close constitutional relationship between the No. 1 lenses and the two "zinc lodes".The possible implications of these relationships are then discussed in the light of the' two principal theories-hydrothermal replacement or chemical sedimentation-held for the formation of the Broken Hill ores. It is pointed out that the ratios of the four metals in the ores are rather different from those found in most igneous and sedimentary rocks, and in seawater. For 'example, whereas copper and zinc are present in almost equal amounts in most terrestrial materials, copper in the ores is only about one-hundredth of the amount of zinc. Lead has increased somewhat, but the ratio of silver to lead has fallen; in spite of its recognition as a source of silver, the Broken Hill lode is impoverished in silver with respect to lead as compared with most common terrestrial materials.No solutions are offered to these prob'lems of abundance. Rather it has been the aim of the work to provide data, and to demonstrate the...

Jan 1, 1961

An investigation into the causes of variable sulphur content in blast furnace metal produced at No. 4 blast furnace at the Port Kembla works of Australian Iron and Steel Pty. Ltd. was carried out. Theprogramme included an extended and detailed experimental study of a great number of the operating variables of the furnace, on a cast-bycast or four-hourly basis, over fourteen days.Possible causes of the variation were found in irregular operation due to sinter variability, and it was also clearly shown that slag conditions were most important in controlling sulphur contents of pigiron. Some decrease in sulphur variability was achieved, arising partly from this investigation, and it is hoped to try magnesia additions to modify slag conditions for better desulphurizing.INTRODUCTIONSulphur in pig iron is a problem common to many blast furnace operators throughout the world, but the direct causes and means of overcoming them are functions of the available raw materials, and are hence more particular to each plant and its operating practice. Sulphur in hot metal influences the steel-making operations, the rolling operations and the quality of the finished steel. The main problem associated with high sulphur in steel is "hot shortness", which leads to cracking of ingots and billets in rolling, to poor surface finish and to poor welding properties in the finished steel. On the other hand, sulphur is sometimes a desired additive to steel in order to promote free machining properties.Normal means of controlling sulphur A small degree of control of sulphur in steel is available to open hearth operators by alteration of slag volumes and basicity, but any large degree' of sulphur elimination is...

Jan 1, 1961