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By Muhammad Zaka Emad

Cemented rockfill (CRF) is a mixture of rock aggregate and binder slurry. It is a stiff backfill, it is fast curing, its operation is simple, placement rate is reasonably high and no drainage is required. The main demerit of CRF is failure of exposed faces causing ore dilution, which can be associated with the fill placement method. This paper discusses the effects of two placement methods being practiced by mines and numerical modelling is used as a tool to evaluate stability of the backfill column. In the first method, practiced in longitudinal retreat mining of a narrow vein deposit, the rockfill is hauled and dumped into the stope with a LHD scooptram. Once dumped, cement slurry is sprayed into the stope. In the second method, a raise situated centrally above the mined stope is used to convey already mixed CRF into the stope. Stopes are mined out transversely in primary and secondary blocks in a sublevel stoping system. Problems of poor mixing in combination with both placement methods are discussed. The two backfill placement methods are analyzed for blast induced vibration damage using the dynamic Flac3D modelling technique accounting for rock mass and fill damping characteristics, and a pressure wave is used to simulate the blast vibrations. Fill heterogeneity has also been considered for the two cases and results are compared.

Jun 1, 2012

By S. Banisi, M. Poorkani, M. Farzaneh, M. Askari

"At the Sarcheshmeh copper mine 40,000 t of ore per day with an average grade of 0.9 % Cu is ground to 70% passing 75 microns. Grinding is effected in 8 parallel lines of 8 x 5 m ball mills in a closed circuit with cyclones. The make-up balls are 80-mm forged alloy steel balls and the average ball consumption is 750 gh of ore ground. In order to optimize ball size distribution inside the mill, based on the previous investigation instead of using only 80 mm make-up balls a combination of 80 and 60 mm (75% to 25% by weight) ball charge was used in one of the mills. To evaluate the performance of three ball types namely forged alloy steel balls (A), ductile cast iron (C), high chromium cast iron (D) and also a combined (80 and 60 mm) charge of forged alloy steel balls (B), four identical parallel mills were charged accordingly. These four mills were sampled during a period of six months. The amount of material finer than 75 microns of cyclone overflows was selected as a criterion for the performance evaluation. It was observed that in a mill with the combined make-up balls the amount of fine produced was 4% higher than the other mills. The consumption of ball types A, C and D were 730, 710 and 534 g/t, respectively. The results of laboratory flotation tests showed that due to an improvement in the production of fines an increase of 1.4% in the overall copper recovery is obtainable. Due to the promising results, the new make-up ball regime was implemented in all mills in the plant.INTRODUCTIONThe Sarcheshmeh copper ore body which may rank as third or fourth largest in the world contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybednite concentrate per year. After three stages of crushing, the ore with a F80 of 12.7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70% finer than 75 microns. The concentrate of the first stage of flotation is reground and the tailing constitutes the main component of the plant final tailings. A concentrate with an average grade of 31% Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type."

Jan 1, 2002

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By B. MohammadSadeghi, S. Bakhshivash, M. Haghshenas, F. Rahimi

"Spring-Back/Forward in sheet metals is defined as recovery of elastic strain upon unloading in a deformed sheet specimen. Since this phenomenon can cause alternation in the dimensions of a part, leading to irrecoverable compensations, the operative parameters need to be investigated, thoroughly. To assess spring-forward and effective bending parameters, V-shaped bending dies are the most commonly used experimental approach. In the present research, the effect of bending angle and punch tip radius on the spring-forward behavior of an Al-Mg-Si alloy sheet specimen is studied. To this end, a V-shaped die with four bending angles (i.e. 30°, 45°, 60°, and 90°) was designed and fabricated. Specimens with thickness of 2 mm were cut with dimensions of 50 mm×10 mm. Results show that by increasing the bending angle, the spring-forward angle decreases. In addition, smaller punch tip radiuses lead to further spring-forward. The effect of these parameters on the amount of spring-forward angle, strain distribution and homogeneity along sheet thickness was assessed using finite element analysis (FEA). Simulation results show that as the bending angle increases, the strain is developed more homogenously. Finally, micro-hardness test was used to study the effect of strain hardening caused by bending operation on strength evolution. Results show higher hardness trends for the zones in which the maximum plastic strain occurs.INTRODUCTIONPrecise production plays a significant role in the durability of a part. When it comes to sheet metal forming, this issue should be taken into account as an important factor. In order to predict the alternations, bending dies with special geometric parameters (i.e. V-shaped, U-shaped and L-shaped dies) are commonly used (Wagoner, Lim, & Lee, 2013)."

Jan 1, 2016

By C. Guo

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd oil sands plant. Over the past years (since 1997), there has been a marked change in the consolidation behaviour of MFT in the MLSB, which is attributed to microbial activity. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. In certain regions within the MLSB, gas bubbles are released to the water surface of the tailings pond. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings). This phenomenon contradicts the consolidation models for MFT developed over the past 20 years. The above phenomenon has also been reported at the oil sands tailings ponds operated by Suncor Energy Ltd. in Fort McMurray. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. The rapid densification of the MFT may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program is underway to study the mechanism leading to the rapid densification phenomenon. Systematic field investigations were performed to determine the distribution and characteristics of the rapidly densified MFT. Gas bubble distribution on the water surface was mapped to determine the zones of different biological activities in the pond. These field investigations provided solid ground for further experimental and theoretical research. A number of small-scale column tests were carried out to observe the gas evolution and to measure the changes of some geotechnical parameters under different microbial activity. Also, a series of gassy MFT densification tests are being conducted to study the mechanism of the rapid densification of the MFT under microbiological activity. A review and discussion of the research program is given and some preliminary research results are presented in the paper.

Apr 1, 2005

By C. Guo, R. J. Chalaturnyk, M. MacKinnon, J. D. Scott

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd. oil sands plant. Over the past years (since 1996), there has been a marked change in the densification behaviour of MFT in the MLSB. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings) at the area with intense microbial activity. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. It may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program was carried out to study the mechanism leading to the rapid densification phenomenon. A review and discussion of the research program is given and some results from the field investigations and small-scale column tests are presented in this paper.

Jan 1, 2007

By G. Titichoca

Modification of the blasting process considers that any increase in the energy consumption generates greater benefits if done in the later stages (associated with a larger decrease in energy consumption). Therefore, although the blasting cost is doubled, generating a greater proportion of fines in addition to a weaker ore (because with greater loads and appropriate distribution of explosives a greater number of internal cracks is generated), the reduction of the unit cost that occurs in the grinding stages (SAG and ball mills) generates a positive balance in the overall size reduction process. Codelco Chile, Division Andina, has developed an extensive experimental plan to evaluate the concept of blasting modification applying greater energy. This was implemented in two stages, each including a specific mine sector: La Union and Don Luis. This paper reviews the experience of implementing such blasting modifications at the La Union mine and its impact on the design concepts and the operation of the SAG mill plant

Jan 1, 2007

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By H. Henao, E. Kohnenkamp, L. Rojas

The slags generated in the copper conversion process are mainly composed of Cu2O-Fe2O3-SiO2 with the compounds CaO and Al2O3 in concentrations up to 10 wt%. The present work contributes to the knowledge of the conversion process, generating experimental data for the diagrams of phases Cu2O-Fe2O3- SiO2-Al2O3 and Cu2O-Fe2O3-SiO2-CaO. The experiments were carried out in a tubular furnace at temperatures of 1150°C and 1200°C under a condition of saturation with tridymite. Once the equilibrium was reached, the samples were fast quenched in water. The phases in the samples were observed in a Scanning Electron Microscope (SEM) and the elemental composition of the phases analyzed by means of Energy-dispersive X-ray spectroscopy (EDS) detectors. The addition of Al2O3 and CaO into the Cu2O-Fe2O3- SiO2 system resulted in an appreciable displacement of the liquidus lines, corresponding to an expansion of the liquid in the tridymite primary phase field. INTRODUCTION The conversion process of copper consists of oxidizing Fe and S present in mattes with 60 to 65wt% Cu (up to 16wt% Fe). This process is separated into two stages: 1- Slag blowing: Fe is oxidized, the addition of a flux such as SiO2 (silica) forms a second liquid phase called slag, this phase is removed from the furnace; 2-Copper blowing: in this stage, the matte with low concentration of Fe (<1% w/w) is again oxidized to remove S as SO2 in the exhaust gases. The product of these two processes is the formation of Copper Blister (> 98wt% Cu) (Schlesinger et al., 2011). Unlike the aforementioned conventional processes, in most Chilean smelters, conversion Peirce- Smith Furnaces are loaded with high copper matte (70–75wt% Cu) (Henao & Moyano, 2016). Due to the low concentration of iron in these matte (up to 5wt%), it is considered that separating the conversion process in two stages is neither operational nor environmentally convenient. Therefore, the process is carried out in a single stage (Pradena et al., 2006), generating a slag phase with a high percentage of Cu2O (wt%Cu>40).

Jan 1, 2019

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, David Grimsey, Denis Shishin

"An integrated nickel flash smelter is operated with Peirce-Smith converters at the Kalgoorlie Nickel Smelter. To improve the partitioning of arsenic between slag waste and matte product, an option to modify the slag–matte chemistry by addition of CaO was analysed. A combination of plant sample analysis, high-temperature laboratory experiments and thermodynamic modeling was carried out to evaluate the process options. The high-temperature experiments involved the re-equilibration of industrial matte-slag samples at 1225 °C and P(SO2) = 0.12 atm, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LAICPMS). A private thermodynamic database for nickel sulfide smelting and converting was used together with the FactSage thermochemical software package to assist in the analysis of the distribution of elements between slag and matte as a function of CaO addition. The thermodynamic predictions combined with experimental data obtained in this study can be used to characterise the effect of CaO fluxing on the slag–matte thermochemistry during the nickel sulfide converting.INTRODUCTION At the Kalgoorlie Nickel Smelter (KNS), nickel sulfide concentrate is processed in an Outotec-type flash furnace to produce nickel matte containing +47 wt% Ni. Separation of nickel matte and waste slag from the flash smelting is enhanced through settling in the electric arc -heated zone attached to the flash furnace. The flash furnace matte is further processed in a Peirce-Smith converter to produce Ni-rich matte containing +66 wt% Ni (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011). Iron silicate-based slag is used in the converting process at KNS. Most of the arsenic is contained in the final matte and very little of the arsenic partitions into the slag. Previous work by Font et al (Font, Hino, & Itagaki, 2003) shows that the distribution ratio of arsenic between calcium ferrite slag and nickel-matte (LAsslag/matte) is significantly higher than that between iron silicate slag and nickel-matte, where LAsslag/matte = (wt pct As in slag)/{wt pct As in matte} (1)"

Jan 1, 2017

"In the present study, the reduction behavior of composite pellets comprising of iron oxide, synthetic graphite and slags were investigated in a laboratory-scale horizontal tube furnace. Two different types of slags indicating silicate base and aluminate base slags were chosen to examine the effect of slag chemistry on the reduction behavior of pellets. Slag composition of binding materials has influences on the reactions occurring in composite pellets during direct reduction. In-situ high temperature visualization approach was used to observe the slag / iron / carbon interactions at 1773K (1500°C). The off-gases were measured by means of infrared analyzer to determine the reaction rates of the pellets. Different physical appearances during the in situ reaction inferred a strong correlation between the slag composition and internal reactions. In addition, compression tests were conducted to examine physical strength of the pellets. This investigation was carried out to establish feasibility of physical property control of pellets by selecting optimum slag compositions of binding materials INTRODUCTIONCurrently, most of the iron ore mines have facilities that make an ore more usable for the blast furnace operation by improving its physical properties (e.g. pelletizing and sintering). However, during the process, a large amount of fuel is supplied to indurate materials which consequently deteriorate energy efficiency and produce more CO2 emission. Along with increased interests, direct reduced iron (DRI) making process; simply without coke oven or sintering process, has opened the era of clean and environmental friendly iron making process. While some of the established DRI technologies such as Midrex and HYL were restricted to certain locations where natural gas is abundant, coal based technologies using Rotary Hearth Furnace (RHF) such as FASMET and ITmk3 have been developed with regardless of expensive fuel deposit. In addition to the direct use of pulverized non coking coal and fine iron ore, RHF process also has advantages of utilizing waste materials such as EAF dust, biomass and recycled plastics. Nevertheless, there are still many challenges in the coal utilizing technologies as the unprocessed coal and the waste materials contain huge volatiles and ashes. Although recent investigations on volatiles in a RHF process (Sohn and Fruehan, 2005, 2006) have indicated the benefits of coal in terms of iron oxide reduction and have shown feasibility of multi-layer process, carbon composite pellets still have disadvantages because of its weak mechanical bonding strength. As the mixed system with carbon and oxides generates intermediate gases (e.g. CO and CO2) between solid particles, it is difficult to keep its physical state without the help of binding materials. In this reason, industries have been tried to use various binding materials such as bentonite, kaolinite and Portland cement. However, they are still struggling to find out new materials that provide not only sufficient mechanical strength but also metallurgical properties, such as porosity, reducibility and swelling throughout the reduction reaction. Recently, Canadian researchers (Aota et al, 2006) observed enhanced mechanical strength of pellets by using high alumina cement as a binder and concluded that the method could be used to recycle EAF dust as well, but in depth mechanism of reinforced strength has not been concerned. Most of the ashes coming from binders formulate certain type of slag during the reduction process due to its incombustibility. Thus, observation and regulation of slag property is an essential for the control of carbon composite pellet. Yet, only a little thermodynamic consideration from the perspective of slag chemistry has been adapted in the iron and steel making industries as ash has been easily ignored for its tiny proportion. In this study, effect of CaO-SiO2- Al2O3 slag system on the reduction of iron oxide was investigated in terms of"

Jan 1, 2012

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By Z. -E. Nakagawa, O. Yamamoto

After the formation of a concentration gradient of SiC within C-C composite, either zircon or mullite thin films were coated on the surface by sol-gel process. Oxidation resistance tests of as-prepared composites with a couple consisting of a ceramic thin film and a SiC-gradient were then carried out in air at the temperature range from 600 to 1600°C. By the coating of zircon with a thickness of 1.5 µm, a pronounced oxidation resistance was observed; the mass loss by oxidation was almost negligible at 1000°C and one hundredth of original composite at 1400°C. In the case of the coating of mullite with a thickness of 1.0 pm, the marked improvement in oxidation resistance over the whole temperature range examined, from 600 to 1600°C, was found with the combination of a SiC-gradient and a mullite thin film

Jan 1, 2004

By L. Sun

A numerical model has been developed to study the air flow in the flow plate and gas diffusion layer assembly on the cathode side of a PEM fuel cell. The flow plate in this type of fuel cell often has serpentine channels and the porous layer is adjacent to the flow plate to diffuse the air to the catalyst layer. Flow cross-over of air through the porous diffusion layer from one part of the channel to another can occur. This flow cross¬over is a result of the pressure differences between different parts of the channel, and it causes the flow rate through the channel to vary with the distance along the channel. A numerical study of pressure distribution and flow cross-over through the gas diffusion layer (GDL) in PEMFC flow field using a serpentine channel system has therefore been undertaken to compare the cases of a single channel and two parallel channels, with the channels having a trapezoidal cross-sectional shape. The purpose of the present work was to study the effect of the flow plate geometry on the basic fluid flow through the plate. The flow here has been assumed to be three-dimensional, steady, incompressible, isothermal and single-phase. The flow through the porous diffusion layer has been described using the Darcy model. The dimensionless governing equations have been solved by using the commercial CFD solver, FIDAP. From the results obtained, it can be found that the single channel systems have greater maximum flow rate difference than the parallel channel systems under the conditions considered in the present study. Also, the size ratio R of trapezoidal cross-sectional shape has a significant effect on the flow cross-over and pressure variation in the flow field.

Jan 1, 2005

By Mohammad Reza Khalesi, Ruhollah Rezazadeh, Mohsen Izadi Yazdan Abadi, Mahmoud Abdollahy

"The rotary vacuum drum filter (RVDF) is widely used for dewatering in mining industrial. In general, different parameters have influence in the solid-liquid separation such as: solid percent, level of vacuum, particle size distribution, filter cloth and chemical additives. These parameters can influence on some variables such as cake moisture, throughput and filter cloth life time. The aim of this study is to propose some chemical additives to improve the rate of filtration and decrease cake moisture of Gol-E Gohar iron ore concentrate by using laboratory scale bottom feed vacuum filter and suggest a filter cloth with long life time (more than 400 hours). Effect of particle size distribution on filtration investigated in large scale by measuring the thickness of cake and cake moisture.Increasing molecular weight of anionic flocculant lead to increases throughput but cake moisture increases too; While the filter aid increases throughput and decreases cake moisture simultaneously; the combination of them show different behavior. TSS and filter cloth life time have directly relation with material and type of filter cloth weave. Depending to type of feed, two polyester and polypropylene filter cloth are suggested. More over twill and satin weave have the best results. To prove the laboratory results some industrial tests performed in Gol-E Gohar hematite iron ore concentrate plant.INTRODUCTION“The process of grinding and classification involves the use of large quantities of water. The separation of solids from liquids is usually achieved by gravity sedimentation in thickeners. For fine particles this is a slow process. In general, 75–80% of the water can be separated and removed by thickeners. For further water removal, filters are used where in excess of 90% of the water can be removed” (Gupta, 2006).“Many types of filters are available, which are broadly classified here as vacuum, pressure, precoat and depth filters. Each classification contains a number of sub-processes. A category of filter that uses vacuum induced driving forces and semipermeable media to facilitate the separation of solids from suspension. While pressure differences across the filter are limited to less than 85 KPa (usually 75 KPa), most units are capable of processing a wide range of feed materials in a continuous manner” (Rushton, 2008)."

Jan 1, 2016

By A. Danaei, A. McLean, M. Barati, C. Ravindran

"The aluminum industry generates about 90 million tonnes of red mud each year. Previous research shows it could be utilized as a refining flux with a high capacity to absorb phosphorus and sulphur from hot metal in the steel industry. The present study was undertaken to evaluate the melting properties of such fluxes, as it affects the effectiveness of the flux. The results show that the melting behavior of red mud is strongly affected by lime addition and the characteristic melting/softening temperatures reach minimum VALUES (at 32.7 wt% CaO. From these findings, a correlation was established between melting behavior and optical basicity. This allows one to adjust the composition of the flux based on the process requirements. INTRODUCTIONThe aluminum industry generates about 90 million tonnes of bauxite residues each year. This residue is usually red in color because it contains a substantial amount of iron oxide. The red mud, as it is called, is a solid waste with a high concentration of sodium oxide, high pH (10 to 13), and high alkalinity, and thus is harmful to many forms of life. Traditionally, the material is stored in large tailings ponds within the plant’s vicinity (Power, Grafe, & Klauber, 2009). Development of solutions for safe disposal or preferably using this residue for other industrial processes or applications could help restore polluted locations and eliminate a negative impact on the environment (Haake, 1988; Power et al., 2009; Yan & Xuegong, 2010).The mineralogy and chemical composition of red mud depends on the quality of the bauxite and refining process parameters. In general, it consists of iron oxide (Fe2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), sodium oxide (Na2O), silicon oxide (SiO2), and calcium oxide (CaO) (Power et al., 2009). Like most ores and soils, bauxite can contain trace quantities of metals such as arsenic, beryllium, cadmium, chromium, lead, manganese, mercury, nickel, and naturally-occurring radioactive materials, such as thorium and uranium. Most of these trace elements stay in the residue (Power et al., 2009)."

Jan 1, 2012

By E. Burdukova

Rheological measurements have found a wide array of applications in mineral processing research. Rheological properties of mineral suspensions are highly dependent on the mineral surface properties as described by DLVO theory, and the relationship between these properties and inter-particle interactions is well established. In this paper, rheological properties of mineral suspensions are used to study the differences in behaviour of isotropic talc and anisotropic zirconia minerals as a function of varying properties of the suspension medium, such as pH and polymer dosage, specifically carboxymethyl cellulose (CMC). It was found that the rheological tests when carried out in parallel with electrophoretic or point of zero charge measurements, clearly reveal differences between behaviour of the suspensions of isotropic and anisotropic minerals. These differences are further accentuated with the addition of carboxymethyl cellulose (CMC).

Jan 1, 2006

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By H. Huang, H. M. Chen, W. B. Xie

Cu-0.8Cr-0.1Zr alloy were prepared by atmospheric melting. the microstructure and properties of the CuCrZr alloy after first cold rolled, solid solution, second cold rolled and aging treatment were analyzed by using optical microscope, electrical conductivity analysis and Vickers hardness tester. The results show that with the increase of the first cold rolled deformation, the grain breakage becomes more serious, and the cold hardening becomes more obvious and the hardness increases. The conductivity and peak hardness of the first cold rolled (reduction of 30% and 60%) alloys after solution, secondary cold rolled and aging treatment reaches 81 %IACS and 187 HV, respectively. However, the conductivity in the CuCrZr alloy with a higher rolling degree (reduction of 90%) after solution, secondary cold rolling and aging treatment is significantly higher, and the conductivity and peak hardness is 85.8 %IACS and 178 HV, respectively. INTRODUCTION CuCrZr alloy has been widely used in domestic industry for its excellent comprehensive properties such as high strength and high conductivity, especially in the contact wire and lead frame of high-speed railway (Sun, Tao, & Lu, 2015; Mishnev, Shakhova, Belyakov, & Kaibyshev, 2015; Zhang et al., 2016; Fu et al., 2017). In recent years, a lot of research has been done on how to improve the strength and conductivity of CuCrZr alloy. However, the high strength and high conductivity of copper alloys are contradictory characteristics. On the one hand, the addition of alloying elements is conducive to solution strengthening and aging strengthening; on the other hand, too much alloying elements in copper alloys cause defects in the lattice of copper matrix, resulting in a serious decline in the conductivity of copper alloys (Martienssen & Walirmont, 2005). How to obtain high strength and high conductivity at the same time is the main problem. At present, the main research methods are adding microalloying elements, thermomechanical treatment and severe plastic deformation to study the electrical conductivity and mechanical properties of CuCrZr alloys. For example, Xie et al. (2011) added trace Ag to the Cu-0.26 wt%Cr-0.08 wt%Zr alloy, and the size of precipitated phase Cr and Cu4Zr became smaller and the mechanical properties of the alloy were improved. Su, Dong, Liu, Li, & Kang (2004) found that the addition of trace Mg in CuCrZr alloy inhibits the growth of precipitated phase and reduces the internal stress around the precipitated phase. At the same time, the size of precipitated phase becomes smaller and the peak aging strength of the alloy is improved. Pang et al. (2013) found that adding trace Ni and Si to the CuCrZr alloy could improve the peak hardness, softening resistance and precipitation morphology of the alloy. Experiments shows that the grain size was significantly refined by equal channel angular extrusion combined with aging treatment, while the strength of the alloy was increased, and the electrical conductivity of the alloy did not decrease (Vinogradov, Patlan, Suzuki, Kitagawa, & Kopylov, 2002; Saray, 2016); Kermajani, Raygan, Hanayi, & Ghaffari (2013) showed that the strength of CuCrZr alloy can be improved by rolling at 500 °C. After 150 minutes of aging treatment, the strength and conductivity of the material increased to 431 MPa and 81 %IACS, respectively. Takata, Ohtake, Kita, Kitagawa, and Tsuji (2009) noted that the strain hardening, uniform elongation and tensile strength of the nano-precipitates produced by the mechanical heat treatment process can be notable enhanced. The mechanical and electrical properties of CuCrZr alloy can be improved by combining large plastic deformation with aging treatment in the test process (Gao, Huttunen-Saarivirta, Tiainen, & Hemmila, 2003; Huang et al., 2003; Xia et al., 2012; Zel’dovich et al., 2014).

Jan 1, 2019