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By J. E. Nesset

Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right 'strength' is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry may also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.

Jan 1, 2009

By J. E. Nesset

"Significant progress has been made over the past few years on characterizing and understanding the hydrodynamic properties of frothers and collectors and their effect on flotation performance. This new understanding of the relationship between chemistry and hydrodynamics has dramatic implications for how flotation circuits should be controlled and optimized. Previous work has shown that choosing a frother of the right ‘strength’ is critical to the optimization process, and the work and discussion presented here serve to strengthen the argument. In addition, we know that collector chemistry will also influence hydrodynamic properties and needs to be taken into consideration. To achieve the desired outcome, the overall system of reagents and operating parameters must be considered. This paper describes and discusses some of the findings from recent research on frother and collector chemistry effects (on hydrodynamics), and how this knowledge can be used to improve flotation performance. Examples from plant experience are discussed.INTRODUCTIONFrothers perform various functions in flotation but the primary ones are control of bubble size in the pulp zone and stabilization of the froth zone. Laskowski (2003) was among the first to try to capture both roles in characterizing frothers in order to provide a basis for frother selection for a given duty, as well as to explore the link between function and frother chemistry (structure). The method he used requires bubble size data and a frothing index; the procedure has been simplified by Cappuccitti and Finch (2008) using gas hold-up to substitute for bubble size, and froth height (without overflow) as the froth stability metric. The gas hold-up/froth height relationship will be referred to as ‘hydrodynamic characterization’. Essentially, the gas hold-up parameter reflects the sum of the hydrodynamic conditions in the pulp phase (water in this case), i.e. the effect of bubble size plus the apparent impact of the water surrounding the bubble due to the frother (Finch, Nesset and Acuna, 2008). Similarly, the stable froth height parameter reflects the sum of hydrodynamic conditions in the froth, i.e. the effect of bubble size undergoing coalescence plus the influence of the water in the lamellae and Plateau borders between bubbles. It could be argued that the gas hold-up/froth height relationship is a superior one to simple bubble size/froth index for discerning differences in frother behaviour"

Jan 1, 2010

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Daniel L. Cluff

The Canadian mining industry needs to find viable alternatives to the conventional cemented pastefill/hydraulic methods of backfilling open stopes for underground mines located within a permafrost zone. The harsh environment and the isolated location of a mine north of 60° impose additional challenges to standard backfill methods and opportunities to the technological and operational issues related to the use of frozen fill. Underground open stoping mining methods require the placement of fill material to enable the controlled recovery of ore from secondary and tertiary stopes. The typical design of the fill material requires the specification of inert material, water and binder. The permafrost conditions provide the additional parameter of subzero temperatures for backfill design and process control. The paper presents the results of an experimental field study, using large size samples, to determine the strength capacity of frozen backfill. The experimental work was performed utilizing rockfill and tailings material with moisture content consisting of water and ice crystals. Preliminary results indicate that the mixture of rockfill, tailings and moisture, develops strength that meet the demanded requirements for open stoping. A thermal equilibrium modelling analysis is presented in the paper.

May 1, 2008

By Daniel Cluff

Frozen backfill for mining operations in permafrost must be delivered in such a state so as not to thermally impose on the host rock surrounding the filled stope. The placement process, the material strength demand, and the freezing time delay are the parameters that control the applicability of the method. A two-year research program was carried out in the field and using a laboratory-scale apparatus, designed to simulate a pour of frozen backfill, to study the mixing, thermal properties and segregation. The frozen rock and tailings must be at a below zero temperature and get fully wetted so the surfaces cause adherence of the particles to one another and enhance the solidification of the poured backfill. The results provided a recipe and a process for mix design for open stoping operations in cold regions. The testing evaluated the sensitivity of the test parameters that included the amount of water added in the mix, the temperare of water, the rockfill/tailings ratio, and the temperature of solid constituents.The paper presents the result of this environmentally friendly, innovative technology. The distribution of the materials and the mixing process are instrumental in achieving the properties required for open stoping applications.

Oct 1, 2010

By Jacques H. Nantel, James F. Archibald

"Frozen tailings material may be required, in the future, to perform the support functions of underground backfill in mines located in zones of permafrost, notably in the high Arctic. To date, no knowledge of physical support parameters of such materials has been obtained in Canada due to the limited mining activity in permafrost regions. It is therefore judged essential that the important physical and mechanical properties relating to frozen tailings material be assessed.Innovative mining methods will be required to cope with the harsh environmental conditions that exist at mining sites in the Canadian Arctic. A preliminary laboratory study, in the absence of field trials at limited Arctic mining sites, has been completed in which the physical and mechanical properties of several types of representative mill tailings mixtures have been investigated. A variety of tests, to determine frozen slurry and pelletized tailings strength properties, moduli of compression, optimum water contents, deformation characteristics and the like, have been conducted.The results of this study will be used to establish guidelines for the suitability of tailings use in such northern mining environments. IntroductionFrozen tailings material has never been used to backfill underground openings in Canadian mines. At present only one Canadian mine, the Polaris Mine situated on Little Cornwallis Island, is investigating the use of frozen backfill. However, the Canadian North covers a large territory and potentially contains a large number of mineral deposits. The understanding of concepts related to mining activities in sub-zero frozen ground is therefore important.The implications of using frozen tailings as underground backfill material are far reaching both from the point of view of mine stability and disposal of tailings in the arctic regions.The strength of frozen materials (soil, backfill, etc.) may take on different meaning depending on the engineering situation. Both the concepts of rupture and excessive deformation need to be considered.The functions usually required to be performed by the backfill material in underground mines may be summarized asfollows:a) working floors; such as in cut-and-fill stopesb) stope wall support; for cut-and-fill and delayed fill stope~c) self-support when backfill is exposed on one face; during pillar recovery phases.For fill functions such as working floors, the short-term response of the frozen fill is the dominant concern. For the other fill functions, the long-term deformation response of the frozen fill, or creep, is of interest."

Jan 1, 1986

By Derek J. Cyr

Climate has an immense impact on the properties of Athabasca oil sands and the ease or difficulty with which it is excavated and extracted. During the winter months, exposed oil sands surfaces freeze. When hydraulic and electric shovels used in the various operations in the Fort McMurray area excavate the benches, large frozen lumps are created. These lumps are either destined for a lump dump where increased costs are incurred due to rehandle, or they are sent to the primary crushers where they can cause significant downtimes by jamming the crusher. The crusher down time can sometimes be in the order of hours of lost production. Studies on data from two consecutive winters at Syncrude Canada?s North Mine show a high correlation between climate and the generation of frozen oil sands lumps. Temperature, ground cover, traffic, bench exposure time, oil sands grade and moisture content all contribute to this problem. A 1D frost penetration model was used to predict the depth of frost expected in oil sands and the corresponding likelihood of frozen oil sands lumps. To combat the challenge of frozen lump generation, a number of proactive and reactive measures can be taken: artificial snow, shallow ponds, scheduling, blasting or ripping.

May 1, 2004

By Rafic Moubarac

FRP (Fiberglass Reinforced Polyester) equipment has been used in different and several applications during metals processing and extraction, and the hydrometallurgical process. Case histories of such equipment will be shown of major projects worldwide.

Jan 1, 2015

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By Marc Bétournay

This article examines how fuel cell technology and related power distribution system fits within mine operating requirements. Considerations for improvement of power plant architecture and functions to yield production advantages are presented. Improvements to conventional mining approaches are also discussed.

May 1, 2007

By Fred C. Delabbio

The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation. This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited, Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project.

May 1, 2003

By T. MacKinnon, M. C. Bétournay, D. Eastick, F. C. Delabbio, C. Graves

"The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation.This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory, and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project."

Jan 1, 2005

By Donald S. Cameron

By dispersing gold in high surface area form supported on metal oxides, its inert character can be transformed to make economical, effective catalysts. Gold has already been demonstrated in a number of fuel cell applications such as gas phase catalysts, electro-catalysts, and electrical connectors. In this paper, the various types of fuel cell systems are reviewed, and several opportunities for gold identified. Low temperature fuel cells, including alkaline and solid polymer electrolyte types rely on high surface area platinum group metal catalysts which are highly susceptible to poisoning by low concentrations of carbon monoxide in the fuel supply. Hydrogen is frequently obtained by steam reforming hydrocarbons, followed by the water gas shift (WGS) reaction. A promising initial use for supported gold catalysts is in catalysing this WGS reaction. Research has shown that gold supported on iron oxide (Au/a-Fe2O3 ) WGS catalysts are more active than the current commercial copper oxide / zinc oxide catalysts, and effective at temperatures as low as 120oC. Products from reformer/ water gas shift reactors can be further purified by removing traces of carbon monoxide. If a small proportion of oxygen is introduced into the fuel gas stream, carbon monoxide can be preferentially oxidized to carbon dioxide even in the presence of hydrogen. Gold nanoparticle catalysts on iron oxide support (Au/a-Fe2O3 ) have exhibited higher activity than commercially available platinum on alumina (Pt/?- Al2O3 ) preferential oxidation catalysts. The low temperature of this reaction may make it feasible to incorporate these catalysts within the fuel cell itself. Proton exchange fuel cells provide several possible applications for catalytically active gold and its alloys. Carbon supported platinum group metals would benefit greatly from improved electrical conductivity if gold replaced some or all of the carbon support material. As electrode current densities are raised, electrical resistance constitutes an increasing proportion of voltage losses within the fuel cell. Dramatic reductions in cell stack voltage losses have already been demonstrated by reducing inter-cell contact resistance using gold plating. The low temperature oxidation properties of gold catalysts have been investigated in controlling gaseous emissions from direct methanol fuel cells, and gold also provides essential catalysis in building direct borohydride oxidation fuel cells. The prospect of a range of other applications for gold in fuel cells to contribute useful improvements in corrosion resistance and conductivity is assessed. Globally, fuel cells have been developed for a wide range of applications including stationary generators, cars and buses, industrial vehicles and small portable power supplies, each of which represents a substantial market. Hence there are likely to be many and varied opportunities for gold catalysts to contribute to the performance and economics of the systems being commercialized.

Oct 1, 2003

By M. C. Bétournay

Under the requirement to define the economic advantages of using hydrogen fuel cell vehicles, a broad-scoped project was initiated to quantify the costs associated with operating fuel cell vehicles and diesel vehicles. While ventilation savings are clearly an advantage for the former, a complete and detailed analysis of this and other operational and capital cost elements was undertaken in order to provide the mining industry with factual information in considering the changeover from one technology to another. This paper outlines the results of the investigations to date defining the costs/benefits associated with capital purchases, operations (electrical/diesel, mine air heating fuel, ventilation, openings, surface and underground infrastructure, maintenance, labour, etc.), delivery of energy, regulatory obligations, and mine production. Considerations are given to the type and size of a mining operation, the depth, and location in North America. Significant ventilation power, equipment, and infrastructure savings are possible with the application of fuel cells for shallower mine applications. At depth, where heat is an issue, there is a reduction in benefit. Specific qualifiers such as minimum air velocities, dust dilution, shaft, and heating system velocity limits must be considered on an individual mine basis. While the capital cost for fuel cell mining equipment is currently higher than diesel versions, the high cost of fuel cells is anticipated to be reduced significantly in the near future with the intensification of manufacturing. In either case, the operational savings would probably be sufficient to balance the supplementary capitalization costs. Comprehensive reports have been issued.

May 1, 2005

By G. Righettini, G. Desrivières, P. Mousset-Jones, R. Lacroix, M. C. Bétournay, P. Laliberté, S. Hardcastle

"Under the requirement to define the economic advantages of using hydrogen fuel cell vehicles, a broad-scoped project was initiated to quantify the costs associated with operating fuel cell vehicles and diesel vehicles. While ventilation savings are clearly an advantage for the former, a complete and detailed analysis of this and other operational and capital cost elements was undertaken in order to provide the mining industry with factual information in considering the changeover from one technology to another.This paper outlines the results of the investigations to date defining the costs/benefits associated with capital purchases, operations (electrical/diesel, mine air heating fuel, ventilation, openings, surface and underground infrastructure, maintenance, labour, etc.), delivery of energy, regulatory obligations, and mine production. Considerations are given to the type and size of a mining operation, the depth, and location in North America.Significant ventilation power, equipment, and infrastructure savings are possible with the application of fuel cells for shallower mine applications. At depth, where heat is an issue, there is a reduction in benefit. Specific qualifiers such as minimum air velocities, dust dilution, shaft, and heating system velocity limits must be considered on an individual mine basis. While the capital cost for fuel cell mining equipment is currently higher than diesel versions the high cost of fuel cells is anticipated to be reduced significantly in the near future with the intensification of manufacturing. In either case, the operational savings would probably be sufficient to balance the supplementary capitalization costs.Comprehensive reports have been issued."

Jan 1, 2005

By W. A. Lang

RESEARCH has been defined as the link between the present and the future. Science, wonderful though its achievements may be, has but scratched the surface of the unknown. Research is directing its attention to winning new facts in order that their application to the processes of today may open up new sources of wealth for the common benefit. Two classes of research investigations are often recognized-fundamental and applied, but these classes merge into each other and it is often hard to distinguish one from the other. Fundamental research is carried out primarily to develop basic facts, but frequently these are found to have immediate economic value, while applied research, specifically aimed at economic values, often necessitates a preliminary fundamental investigation. Both are essential and both should proceed by scientific method. It is obvious in fuel technology that a knowledge of the physical and chemical constitution of the various coals is fundamental to their industrial utilization, and further, a knowledge of the way these coals react under different conditions of temperature, atmosphere, etc., is necessary in solving such problems as storage, combustion, carbonization, gasification, or con-version to liquid fuels. The wide range of coals, the complexity, of their constitution, and the many uses for coal, makes fuel research no simple subject but one with unending possibilities. The Research Council of Alberta, formerly known as the Scientific and Industrial Research Council of Alberta, was established in 1919, to promote the development and conservation of the natural resources of the Province. The work of the Council was arranged in six major divisions: Fuels; Geology; Road Materials; Soils; Natural Gas; and Forest Products. The office and laboratories are located in the University of Alberta. The Council was financed until the depression of 1933 by a separate vote of the Legislature, but since then has been continued, though on a much smaller scale, as one of the activities of the University. It might, however, be noted that although the Council is now in abeyance, a skeleton organization has been maintained so that it can be brought back to active service as soon as conditions warrant. Annual reports are still submitted to the Legislature. Funds have not been made available, however, for the publication of the last five reports.

Jan 1, 1942

By R. E. Gilmore

PREAMBLE THIS PAPER comprises material presented in two separate 'Papers at the British Commonwealth Scientific Specialist Conference on Fuel Research held in London, England, in July, 1950. These papers are now available for publication in Canada, since only essential parts of the conference discussions, in addition to the resolutions resulting therefrom, will be published in the official Proceedings of the Conference. Inasmuch as the information presented concerns Canadian organizations and training facilities for fuel research, it should be of general interest to Canadian scientists, and especially to the Coal Division of the Canadian Institute of Mining and Metallurgy. Part I, the alternate title of which is Facilities in Canada for Fuel Research and for Exchange of Information and Staff, does not include research on peat, oil shale, petroleum oils in general, and natural gas, and omits studies of the geology, constitution, and production of coal. Special reference is, however, made to research on the heavy crude oils and bitumen of the Western Prairie Provinces, and particularly to their production and treatment to produce crudes for oil refinery processing.

Jan 1, 1951

By Arnold R. Miller

Overview ? Vehicle Projects LLC (prime contractor) and the Fuelcell Propulsion Institute have developed the world?s first fuelcell locomotive. ? Principal applications are underground mining and tunneling. ? Because fuelcell vehicles solve the problem of underground emissions, mining is expected to be their first commercially viable market. ? The first year of a three-year project to develop a fuelcell mine loader is funded and underway.

May 1, 2002

By Marc C. Bétournay

Under the requirement to define the economic advantages of using hydrogen fuelcell vehicles, a broadscoped project was initiated to quantify the costs associated with operating fuelcell vehicles and diesel vehicles. While ventilation savings are clearly an advantage for the former, a complete and detailed analysis of this and other operational and capital cost elements was undertaken in order to provide the mining industry with factual information in considering the changeover from one technology to another. This article outlines the results of the investigations to date defining the costs/benefits associated with: capital purchases, operations (electrical/diesel, mine air heating fuel, ventilation, openings, surface and underground infrastructure, maintenance, labour, etc.), delivery of energy, regulatory obligations, and mine production. Considerations are given to the type and size of a mining operation, the depth, and location in North America. Significant ventilation power, equipment and infrastructure savings are possible with the application of fuelcells for shallower mine applications. At depth, where heat is an issue, there is a reduction in benefit. Specific qualifiers such as minimum air velocities, dust dilution, shaft and heating system velocity limits must be considered on an individual mine basis. While the capital cost for fuelcell mining equipment is currently higher than diesel versions, the high cost of fuelcells is anticipated to be reduced significantly in the near future with the intensification of manufacturing. In either case the operational savings would probably be sufficient to balance the supplementary capitalization costs. A comprehensive cost-benefit report will be issued in the near future.

May 1, 2003