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By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By Jeff R. Reinson

The Diavik Diamond Mine is producing diamonds from two orebodies, the A154 South and A154 North kimberlite pipes, discovered beneath the waters of Lac de Gras. Innovative dike technology with appropriate water collection and treatment systems allowed Diavik to start open pit mining of the ore bodies in 2002. To allow planning, engineering, and implementation of sufficient water handling infrastructure, reasonably accurate estimates of groundwater inflow quality and quantity over the life of mine are required. Prior to mining, a numerical model using the continuum approach was developed for regional and site wide water management. After approximately two years of mining, groundwater inflows to the pit were found to exceed those predicted by the base case hydrogeologic model. The most likely explanation was flow through Dewey?s Fault zone. As this fault was not explicitly accounted for in the model, a detailed hydrogeologic investigation was conducted to evaluate its geometry and hydraulic properties. A multi-disciplined approach was used and involved core logging, fluid logging, geophysical logging, packer testing, a pumping test, and water quality sample collection. The results of the field investigation were used to update the conceptual and numerical models and to develop a Discrete Fracture Network (DFN) model to address small scale problems such as flow into future underground drifts. The updated numerical hydrogeologic models predict that up to 70 per cent of the groundwater inflow to the A154 N/S open pit is through the relatively narrow fractured rock zone associated with Dewey?s Fault. Consistent with the continuum model, the DFN model predicts that inflow to a drift excavated in Dewey?s Fault will be approximately 10 times the inflow to a drift excavated in competent rock. The DFN model provides a better understanding of the distribution of these inflows on a local scale over the length of the drift.

May 1, 2006

By C. M. Davidson, D. J. Drexler

"Sulphuric acid treated with hydrogen peroxide to destroy organic contaminants could conceivably show increased corrosivity toward carbon steel shipping and storage vessels, caused by the persistence of a peroxide residual. This paper describes work performed to determine the effect of 0-200ppm hydrogen peroxide on the corrosion of carbon steel by 93% and 98% sulphuric acid at room temperature (23ºC) and 50ºC.Steel electrodes were exposed to acid containing several peroxide levels (0. 45, iOO and 200 ppm) for up to two weeks. Specimens were removed at intervals and weight loss, open circuit potential, depth of metal loss and residual peroxide concentration recorded.Hydrogen peroxide decomposes considerably over two weeks in iron-contaminated sulphuric acid. initial peroxide concentrations > l00 ppm suppress corrosion, but the effect is lost when concentration decays below about 60 ppm. Sustained peroxide levels in the range below 60 ppm may increase corrosion rates. These phenomena are interpreted by analogy with anodic passivation."

Jan 1, 1987

By K. Esmaieli

The Synthetic Rock Mass (SRM) approach has the potential to capture the mechanical behavior of large rock samples. In order for the method to be used with confidence it is necessary to gain a good understanding of the factors that influences its analysis. This paper reports on a series of numerical experiments, based on field data from a large underground mine, to investigate the influence of intact rock mass strength of a constructed (SRM). A jointed rock mass defined by three fracture sets was simulated by a Discrete Fracture Network (DFN) model. The generated fracture network was subsequently embedded into six different intact rock samples, simulated by a bonded particle model in PFC3D, generating six SRM samples. Each intact rock sample was 7 m × 7 m × 14 m and assigned different mechanical properties. The first intact rock sample was assigned a uniaxial compressive strength of 205 MPa and an elastic modulus of 104 GPa with the UCS and elastic modulus values of the other samples downgraded by 10% until the weakest sample had a UCS value of 121 MPa and an elastic modulus value of 61 GPa. All SRM samples were loaded under uniaxial compression to obtain the complete stress strain curve. It was observed that the compressive strength of the rock mass samples decreased by 10% following the same trend as the rock material strength. However, the elastic modulus of the rock mass samples decreased non-linearly with reduction of the elastic modulus of the rock material. The Poisson's ratio of rock mass samples does not change with decrease of rock material properties. For the post-peak behaviour the results show that both the brittleness index and the residual strength of rock mass samples decreased as the rock material properties degrades.

Aug 1, 2013

By L. Tong

"The oxidation of Quebracho was evaluated by acid-butanol assay, which indicates depolymerization of Quebracho. Anthocyanidin, an oxidation product of Quebracho, is stable at 95?C for up to 2 h. The ionization, complexation, and oxidation properties of Quebracho were discussed. Complexation of metal-Quebracho occurs at ambient temperature. The formation of complex precipitates is influenced by the acidity of the solution. Temperature is another important parameter that influences the oxidation and the complexation of Quebracho. Quebracho-ferric complex precipitate forms at 90?C, 0.1 mol/L H2SO4. The formation of Quebracho-metal complex in the leach solution is a possible reason for the consumption of Quebracho. Quebracho molecules adsorption on the mineral surface is reduced by consumption of Quebracho, resulting in poor sulfur dispersing effect in the leaching process. INTRODUCTIONQuebracho is used as a sulfur dispersing agent (SDA) in the pressure leaching of zinc concentrate as stated in U.S. Patent No. 3,867,268 (1975). It prevents the zinc sulfide particles from being coated with molten sulfur, thus preventing the inhibition of the zinc leaching reaction. Recently, the sulfur dispersing effect of Quebracho was investigated in the oxygen pressure leaching of nickel concentrate. The oxygen pressure leaching of pentlandite can be represented by reactions 1-3."

Jan 1, 2012

By B. R. Neufeld, M. G. Heximer, S. J. Roach, W. G. Van Luven, D. G. Reynolds

"Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. In the zinc plant, zinc concentrates are roasted to produce calcine, which is then processed in the leaching circuit for zinc recovery. Calcine is first dissolved at pH <2.0. This is followed by a precipitation stage using additional calcine that removes iron as a ferric hydroxide precipitate which is recycled to the lead operations. It is during this pH adjustment that impurities, notably arsenic, antimony and germanium, are co-precipitated with ferric hydroxide which is the primary removal phase for these elements. Recent processing conditions have resulted in lower iron inputs to the leaching circuit and this has resulted in insufficient co-precipitation of key impurities. This paper summarizes the influence of iron concentrations on impurity removal using laboratory and plant scale surveys, and emphasizes key specification limits for the primary iron removal circuit.INTRODUCTIONThe Sulphide Leach Plant (SLP) at Teck Metals Ltd., Trail Operations produces a zinc sulphate electrolyte from three different zinc bearing streams:1. Calcine, primarily containing zinc oxide, from the roasters2. Zinc electrolyte from the Oxide Leach Plant (OLP) is produced by leaching zinc oxide fume from the pyrometallurgical lead smelting operations3. Zinc slurry from the Zinc Pressure Leach (ZPL) autoclaveThe feed sources are blended and introduced to the iron removal process to precipitate iron in the form of a hydrolyzed iron precipitate which is recycled to the lead smelting operation. Along with iron, impurities, namely arsenic, antimony, germanium and silica, also co-precipitate; this process acts as the primary removal step for these elements. Following iron removal, the electrolyte is further processed in the zinc dust purification circuits. Cadmium and copper are removed in the cold stage circuit via zinc dust cementation, followed by cobalt cementation in the hot stage circuit."

Jan 1, 2016

By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By G. Lafont

Aug 1, 2013

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011

By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

By S. M. Chentouf, M. Jahazi, N. Bombardier, T. Belhadj

The main limiting factor in the commercial expansion of superplastic forming (SPF) of thin sheet aluminum alloys is the extent of cavitation phenomenon that takes place during the processing. The severity of the cavitation process is mainly dependent on the uniformity of deformation (i.e. level of local thinning) during processing. In the present paper, correlations are made between thickness variations in several formed sheets and the characteristics of the cavities observed in the material. The 1.4 mm thick 5083 aluminum alloy sheets were hot pre-formed at around 450°C for 4 min and then air-cooled. Opto-digital and Scanning Electron Microscopy were used to examine the microstructure and analyse the cavities. Also, grain size measurements were carried out for different location in the SPF formed piece. The surface and volume fractions of the cavities were measured with the aid of metallography image processing (MIPTM) on as-polished samples prior to etching. The results are analyzed in terms of the influence of applied strain and microstructure conditions on the propensity to cavitation of the alloy.

Jan 1, 2015

Stress induced, gravity-assisted failure processes typically dominate long before stress levels approach the strength of the intact rock (at approximately smax > 0.4UCS where smax = 3s1 ? s3 and UCS is the Unconfined Compressive Strength of the intact rock (Martin et al. 1999)). Under these conditions, discontinuities typically become clamped and the failure process becomes brittle. This brittle failure process is dominated by new stress induced fractures growing subparallel to the excavation boundary. While it is possible to identify areas with the potential for brittle failure, for example, using the general assumption that brittle failure will occur in areas at right angles to the major principal stress (Hoek et al., 1995), when the threshold smax > 0.4UCS is reached in areas around the tunnel boundary, or elastic modelling and the Hoek-Brown brittle parameters proposed by Martin et al., (1999) (i.e. m? 0 and s ? 0.11), amongst others, recent observations discussed by Everitt & Lajtai (2004), and Kaiser (2005; 2006) suggest that brittle failure processes are enhanced when structural features such as joints, weakness zones, bedding planes or foliations are preferentially orientated around the excavation boundary creating stress raisers which in turn facilitate the stress-driven rock mass disintegration process (e.g., as illustrated by Everitt & Lajtai (2004) on Figure 1b). Such weaknesses induce stress heterogeneities that thus promote tensile-spalling failure processes (Diederichs 2000). The observations suggest that stress induced damage can occur ?prematurely? depending on the orientation of micro and macro structures in situations where the known stress conditions should not yet initiate brittle failure processes. In general, when structural features (micro and/or macro), especially foliations, are present in a rock mass, the strength is effectively reduced, largely due to tensile strength heterogeneity in areas depending on the orientation of the structural features with respect to the excavation boundary. As a result, stress induced damage could occur in areas not normally considered due to the influence of anisotropy (Figure 1).

May 1, 2009

By Kamran Esmaieli

This paper investigates the behavior of ore pass walls under impact loads caused by material transiting through an ore pass. In particular it considers the influence of foliation in the rock mass surrounding an ore pass as both a triggering and accentuating cause of degradation. Based on empirical observations in several underground mines a numerical experiment was designed to understand the influence of rock mass foliation on impact-induced damage on ore pass walls. The distinct element method, and in particular the Particle Flow Code (PFC2D) was used to simulate three different rock masses surrounding an ore pass. Each simulated rock mass has similar properties but was defined by distinct dominant foliation (70o, 80o, 90o) along the foot wall. The numerical experiments investigated different scenarios whereby the walls were loaded by a projected rock fragment striking the foliated walls at a constant impact angle and velocity. The damage inflicted by the projectile rock fragment, on the foliated rock mass, was quantified using the number of impact-induced micro-cracks initiated on the ore pass wall. The results of the numerical analysis indicated that the presence of foliation resulted in greater damage zones in the surrounding rock mass. In addition, the extent of impact-induced damage to the ore pass wall increased as the angle of interception between the ore pass wall and the rock mass foliations decreases. This is in agreement with qualitative field observations.

Jun 1, 2012

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

A pre-flotation process of the Kupferschiefer ore with only frothers produces a concentrate enriched in carbonaceous matter and tailings for further upgrading steps. A partial removal of easy-to-float components of the feed before the main enrichments steps by flotation (rougher, scavenger) improves overall efficiency of separation of valuable elements from the ore. Since the types and doses of frother used for pre-flotation effect the process, the aim of this study was to determine the influence of selected frothers on the efficiency and selectivity of the Kupferschiefer ore processed by KGHM Polska Miedz S.A. A series of pre-flotation tests in the presence of different poly(propylene glycols) ethers, poly(ethylene glycols) ethers and aliphatic alcohols were conducted. The obtained results indicated that the types and doses of frother determine the flotation selectivity of copper and total organic carbon. The evaluation of the pre-flotation process was based on the analysis of selectivity parameters calculated from the recoveryrecovery Fuerstenau upgrading curves as well as the values of copper and organic carbon grades in the flotation products. It was shown that pre-flotation performed in the laboratory scale using a suitable frother provides higher overall flotation selectivity of organic carbon with lower overall flotation recovery of copper in comparison to flotation without the pre-flotation step. Thus, the pre-flotation process improves the quality and quantity of the final concentrates produced from the Kupferschiefer ore.

Jan 1, 2016

By Alexandre Desbarats, Michel David

"All optimum pit design studies start from the geological are reserves inventory, the estimated grades of all blocks of potential are within the interpreted limits of the deposit. The actual optimization procedure is then carried out on block valuations based on these estimated grades. Thus, the relevance of any pit design can be seen to depend directly on the ore reserve estimation . To insure a proper pit design, a first step would be to use a geostatistical reserve estimation technique such as kriging, however, this is not enough. A frequently neglected fact is that the blocks of ore estimated during the planning stage of the mine are usually considerably larger than those on which the ore-waste selection will be made at the time of mining. Experience in the exploitation of large low-grade deposits has shown that large blocks, estimated to be are, when mined selectively in smaller blocks, often yield significant amounts of waste material. This phenomenon, known as internal waste, is a function of the variability of the grades, the size of mining unit and the amount of sampling information on which ore-waste decisions are made.In this study, it was proposed to consider the effect of internal waste caused by selective mining, on. pit design, using geostatistical methods to predict the tonnage and grade of recoverable reserves within large blocks.Optimum pits obtained using a block valuation formula taking into account the recoverable reserves within large blocks were compared with optimum pits obtained using a conventional block valuation formula. It was found that the optimum pits obtained by the proposed method had the highest total valuations and thus were, in fact, ""more optimum”. These pits were characterized by greater are tonnages at a lower average grade, the additional ore more than compensating for the drop in grade. It was also found that the consideration of internal waste in pit design could considerably alter pit limits in marginal areas of the deposit.It was concluded that selective mining had a significant, potentially critical, impact on the design of optimum pits especially in the case of large low-grade deposits."

Jan 1, 1984

By K. S. Kalenchuk

Massive landslides display complex deformation processes. For instance, slope movements of the Downie Slide, monitored using borehole inclinometers, extensometers, and survey monuments, show considerable spatial and temporal inconsistencies in the displacement rates. This study assesses the influence that inferred shear surface geometry, as a key factor contributing to variable slope movements, has on resolving spatially discriminated slope deformations in three-dimensions. Borehole data defines the shear surface location at discrete points within the slide and therefore, the shear surface geometry for the extent of the slide must be largely inferred. A series of three-dimensional numerical simulations have been run to assess the effect of different interpretations of the shear surface geometry. This investigation illustrates the importance of rigorous geospatial definition of slip surface geometry and the value of three dimensional modelling.

May 1, 2009

By O. -J. Siljan

"Refractory materials are an integral part of aluminium production. One special feature of aluminium making is the prominent role of sodium in all parts of the production process. This presence of sodium inflicts stresses on the refractory materials through reactions and may cause severe damages to the refractory linings. The present paper address possible reactions between sodium and refractories in anode bake furnaces, electrolytic pots and casting furnaces. The discussions presented in the paper points to the importance of selecting materials with excellent alkali resistance in all parts of the aluminium making process, although alkali resistance is not the sole parameter to determine refractory life-time. ""Acid"", i.e. silica-rich alumino-silicate refractories are shown to be the best materials for aluminium electrolysis cell potlinings, whereas high- alumina refractories based on minerals like andalusite seems to be the preferred choice for anode bake furnaces as well as cast house furnaces."

Jan 1, 2004

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005