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By Valérie Tremblay

Plan de la presentation ?Laboratoire d?analyse des fluids ?Gestion des contaminants ?Condition Monitoring Avantages reliés aux analyses ?En savoir plus!! ?pour minimiser les coûts d?opération; ?pour prévenir les défaillances catastrophiques; ?pour maximiser le rendement des équipements; ?pour maximiser la longévitédes équipements; ?pour permettre des périodes d?entretien planifié.

Feb 1, 2008

By B. Tiryaki, M. Ayhan, O. Z. Hekimoglu

"This paper discusses the aspects of tracking cutters related to the computer-aided design of shearer drums. A comprehensive computer analysis of drum dynamic parameters for multi-tracking tool arrangement is not presently available, as the current computer programs mainly consider the aspects of single tracking. Despite the fact that the single-tracking arrangement is recommended for efficient cutting, some major drum manufacturers have been seen to persistently adhere to multi-tracking, probably due to a lack of information. Further studies in this field are believed to contribute greatly to the current understanding of the computer-aided design of shearer drums.A number of laboratory simulation trials and long-term underground investigations were carried out in detail on tracking cutter arrangement, and an equation required for a computer program was derived. The results obtained from computer assessment of dynamic parameters for drums with multi-tracking arrangement were found to be in accordance with those of the underground trials, indicating the validity of the equations. The procedure adopted for the computer appraisal of the shearer drums designed with a multi-tracking concept, as described in this study, is therefore recommended to be considered in the currently employed computer programs."

Jan 1, 2003

Inco Limited has been evaluating options for streamlining the overall flowsheet at its Sudbury, Ontario operations to improve productivity and to minimize the cost of at¬mospheric emissions reduction. Some of the flowsheets being considered include vari¬ous levels of copper/nickel separation at the Clarabelle Mill where all Inco's Sudbury Basin ores are processed. This paper reports on the laboratory and miniplant studies car¬ried out during the flowsheet development for a commercial Cu/Ni separation plant. There are two potential feed streams for Cu/Ni separation. It was determined that Cu/Ni separation from the rougher concentrate requires no regrind, and a very clean copper concentrate is produced, but the recovery of copper is limited to about 70% from ore. Cu/Ni separation is more difficult from the bulk concentrate because of the presence of excess flotation reagents in the slurry and due to locked particles. By replacing the slurry water with clean process water, and by addition of some hydrogen peroxide, entrainment is minimized and excess reagents are removed from the surface, providing a satisfactory separation of copper from nickel. Fine regrinding is required to increase liberation of the locked particles and to obtain 85% copper recovery with minimal nickel contamination of the concentrate.

Jan 1, 2005

By P. R. A. Andrews, I. Jackman

"A mineral processing investigation to recover chromite was performed at Lakefield Research, under the guidance of CANMET personnel, on a 70 tonne ore sample from the Bird River deposit in Manitoba. In the laboratory phase a flowsheet was developed which involved grinding, gravity separation and flotation. The gravity concentrates were upgraded by magnetic separation and the flotation concentrates by gravity concentration. Pre-concentration by electronic ore sorting, magnetic separation and heavy media separation also was examined.The developed flowsheet was applied on a pilot-plant scale in the second phase of the testwork to the ore as received, and to ore pre-concentrated by electronic ore sorting and magnetic separation. Ore pre-concentrated by heavy-media separation was treated on a laboratory scale based on the pilot-plant flowsheet.Processing the are as received resulted in 77% recovery of chromite in a concentrate analyzing 30% Cr20 J; processing are pre-concentrated by electronic are sorting resulted in 64% recovery of chromite in a concentrate analyzing 30.5% Cr20J.IntroductionA five-year mineral development sub-agreement was signed between the federal government and the province of Manitoba in 1984. The purpose of the agreement was to establish a work program which would strengthen and diversify the mineral resource industry of Manitoba. Basically, the agreement covers three sectors: Sector A, geoscience; Sector B, mining and minerals technology research; and Sector C, development studies.Project selection involved input from industry, federal and provincial representatives. In the case of industrial mineral s, the selection was initiated at a meeting held at the offices of the Department of Mines and Energy, Winnipeg, Manitoba, in October 1985. One such project was the evaluation of the chromite ore deposits at Bird River, Manitoba."

Jan 1, 1988

By P. R. A. Andrews, I. Jackman

"A mineral processing investigation to recover chromite was performed at Lakefield Research, under the guidance of CANMET personnel, on a 70 tonne ore sample from the Bird River deposit in Manitoba. In the laboratory phase a flowsheet was developed which involved grinding, gravity separation and flotation. The gravity concentrates were upgraded by magnetic separation and the flotation concentrates by gravity concentration . Pre-concentration by electronic ore sorting, magnetic separation and heavy media separation also was examined.The developed flowsheet was applied on a pilot-plant scale in the second phase of the testwork to the ore as received, and to ore pre-concentrated by electronic ore sorting and magnetic separation. Ore pre-concentrated by heavy-media separation was treated on a laboratory scale based on the pilot-plant flowsheet ,Processing the are as received resulted I n 77% recovery of chromite in a concentrate analyzing 30% Cr20 J; processing are pre-concentrated by electronic are sorting resulted in 64% recovery of chromite in a concentrate analyzing 30.5% Cr20J."

Jan 1, 1988

By S. M. Bulatovic, D. M. Wyslouzil, K. R. Rawlings

"The suitability of a new organic reagent DS20 as a depressant for oxidized and carbonaceous pyritic lead-zinc ore from Nanisivik Mines Ltd. has been evaluated in the laboratory and in the plant.The depressant DS20 is a mixture of Lignosulphonate-Dextrin-Quebracho and was developed specifically for depression of highly oxidized and carbonaceous pyrite.The laboratory test work indicated that the poor metallurgy resulting from the oxidized ore could be improved to normal plant performance by the addition of the DS20 depressant with the existing plant reagents. The laboratory data suggested that lime consumption could be reduced when using DS20.In this paper, the development work and the plant trials with DS20 are described.INTRODUCTIONNanisivik Mines Ltd. treats approximately 2000 tonnes per day of lead-zinc massive sulphide ore, containing currently 1% Pb and 9% Zn. The concentrator operations have been described previously (1,2) and typical metallurgical performance is detailed in Table I.The concentrator flowsheet (Figure No. 1) and the standard reagent scheme (Table No. 2) demonstrate the relative simplicity of treatment of this coarse grained ore.A recently discovered satellite orebody - Area 14 - containing 2% Pb and 12% Zn was brought into production in October 1983. This ore had been oxidized to varying degrees by ground water; the pyrite mineralization was found to be very fast floating and a carbonaceous constituent present in higher than normal proportion also affected flotation. The simple high lime addition could not control the pyrite, and very low grade lead concentrates resulted; zinc metallurgy was also affected by this oxidized condition (Table 3)."

Jan 1, 1986

By F. Q. Su

Underground Coal Gasification (UCG) is a promising environmentally acceptable clean-coal technology. A typical UCG system has two wells drilled from the surface into a coal seam with some separation of injection from production. The wells are connected underground by various linking techniques. After creating a combustion reactor in an underground coal seam, air and oxygen flow through the injection well. Heat energy and gases are collected from the production well. As gasification progresses, the combustion reactor is moved along the linking hole. Using this process, the fracturing activity inside the coal seam serves an important role for enlargement of the gasification zone because the surface area oxidization increases continuously by coal cracking. For effective coal gasification, fracturing activity must be controlled. Moreover, excess fractures inside the coal seam and surrounding rock can induce gas leakage, underground water contamination, subsidence, etc. Therefore, monitoring and control of fracturing activity in underground areas constitute key technologies for efficient and safe UCG. To monitor fracturing activity, we conducted laboratory and small-scale field experiments of UCG using acoustic emission (AE) measurements. UCG model tests were conducted for linking and coaxial types UCG models. Coaxial UCG systems are compact and are anticipated for application in underground coal seams having a complex geological structure. The UCG model consists of a coal block molded in a steel canister (20 liter capacity) with heat-resistant mortar, with a linking hole or a coaxial-hole passing through the coal block. During coal combustion, coal temperatures, production gas contents, and AE activity were monitored under the control of injection-air and oxygen flow rates. Results show that the combustion propagated inside the specimen along the linking hole. Many AE events were generated during coal combustion. The AE activity was related closely to temperature changes inside the coal block. This AE generation apparently results from crack initiation and extension around the coal combustion area under the influence of thermal stress. However, comparing the results from UCG models of linking and coaxial types, the gasification of the linking type model showed an average calorific value as high as 11.3 MJ/m3. The coaxial type yielded an average calorific value of produced gas as only 5.79 MJ/m3. In the coaxial type of UCG model, the combustion region was limited to the area around the coaxial hole. The AE activity was lower than in the linking type model. For small-scale UCG field experiments, linking and coaxial types were tested at an open pit coal mine in Hokkaido, Japan. Using a linking type UCG, 58.2 kg coal was processed in 39 h, with the calorific value estimated as 11 MJ/m3. However, the coaxial type UCG processed 7.0 kg coal in 9 h, yielding an estimated calorific value of 6.0 MJ/m3. These tendencies resemble those of results of laboratory UCG experiments. Results of these experiments demonstrate that AE monitoring is a useful tool to evaluate combustion reactors for efficient and safe UCG systems. To develop a coaxial UCG system, results show that fracture control around combustion reactors is indispensable.

Aug 1, 2013

By M. P. Brameld, G. Archambault, R. H. McCorkell

"The rates. J. at which materials emit radon are of interest in studies of the sources of radon in mines. buildings. soils overburden and other places where it may indicate the location of ore or be a health hazard. Here J values were determined by measuring the radon concentrations by means of scintillation counters or alpha-particle track detectors in chambers in which specimens were sealed. Errors in the measurements due to leakage from the chambers. lack of secular equilibrium in the decay series of the radon measured, or the limited rate of diffusion of radon from powders or within the chambers were shown to be insignificant or could be corrected. Scintillation counter measurements are highly reproducible; track detector measurements also appear useable and may be made on many small samples using small, simple chambers. J measurements were made for uranium ores, drill cores, standard CANMET pulps. concrete and gypsum board. Powdering of ores had little effect on their J values.IntroductionIn the mining and mineral sciences, radon (222Rn) is of interest chiefly for two reasons: in geochemical exploration for mineral deposits its presence in soil. overburden and water in more than background concentrations may indicate the existence and locations of uranium deposits and, if present in sufficient concentrations, it is a possible health hazard in mines, mills and other places where people live and work. The latter aspect of radon's role has received considerable attention recently(1,2,3,4,5), and surveys of soil-gas radon concentrations have been used for some time in searches for uranium deposits(6,7,8,9,)."

Jan 1, 1981

By J. M. Goris

"Researchers at the U.S. Bureau of Mines are conducting research on cable-type ground supports to assess their material and support properties and to provide design criteria for implementing cable supports as a workable roof control system under various underground mining conditions. Much of this work involves laboratory assessment of the material and support properties of cable supports using both conventional and birdcage steel cables. Included in this assessment are single and double cables, effects of changes in embedment length on support strengths, water-cement ratios, use of breather tubes, and pumpability and water-bleeding properties of grouts.IntroductionSince cable supports were introduced in the early 1970s, considerable research has been conducted in laboratories and at mine sites to understand their behaviour. The U.S. Bureau of Mines began a laboratory evaluation project in 1985 at the Spokane Research Center (SRC) to study the behaviour of cables supports under uniaxial loads so that the effects of various cable support components, such as grout and breather tubes, could be identified. Other objectives were to compare the behaviour of various types of cables and grouts and to collect meaningful data for numerical analyses. Pull tests were conducted to determine how cables supports reacted under uniaxial loads and how they failed when ultimate loads were exceeded. Such data are essential for the development of numerical models for analyzing rock mass behaviour when the rock is supported with cables.Test ProgramBecause each cable support can be composed of either single or double cables as well as a breather tube, pull tests were designed to include a variety of samples containing these components. A series of samples containing a single conventional cable, a neat cement grout having a water-cement ratio of 0.45, and no chemical additives was selected as a standard (Table I). Then one component in the system, such as the presence of a breather tube, was changed, and results of tests compared to results obtained for the standard samples to determine what influence that component might have on the behaviour of the support system. If significant changes in test data occurred, they could be attributed to that one component. To control the quality of the samples, the physical condition of the cables and tubes were monitored closely, and compressive and tensile strengths as well as flow properties were determined for the grout used in each test series."

Jan 1, 1991

By I. Demers

The abandoned Manitou mine site covers an area of approximately 190 ha near Val d?Or, Quebec. This old site has been generating acid mine drainage for several decades. In 2006, a partnership was established between the Quebec Ministry of Ressources Naturelles (MRN) and Agnico-Eagle Mines to reclaim the Manitou site using tailings from the nearby Goldex mine. These neutral tailings were to be deposited on top of the Manitou site. An extensive study was performed to evaluate specific reclamation scenarios to control acid mine drainage using Goldex tailings as cover material. The article first describes the global approach used for this evaluation, which includes in-situ hydrogeological monitoring, tailings characterization, laboratory column tests, and numerical modelling. Of the thirteen column tests, three were conducted to evaluate the parameters affecting the performance of covers made of Goldex tailings placed over the spillage area of the Manitou site. Geochemical and hydrogeological parameters were assessed during the leaching column tests for almost two years. The tests aimed at evaluating the effect of water table level and monolayer cover thickness on the overall performance. The testing procedure involved monthly leaching and measurement of geochemical parameters. Results indicate that water table position is the most important factor affecting the monolayer cover performance to control AMD. Based on these results, it was established that the water table must be located near the interface between the Goldex and Manitou tailings to effectively reduce AMD generation. Cover thickness also has an impact on cover performance, which is however less significant than the water table position. The testing scenario with a water table located at the interface with a one-meter Goldex tailings cover showed progressive improvement in effluent quality.

Aug 1, 2013

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By Jarret Thomson

An understanding of groundwater flow is essential for many aspects of mining. This is especially true for the process of shaft sinking through the sandstones of the Manitou Falls Group in the Athabasca Basin of northern Saskatchewan. Experience has shown that the hydraulic conductivities of these sandstones can be relatively high, especially in zones containing natural fractures. To develop a better understanding of the inflow potential into a shaft, a laboratory testing program was undertaken to investigate the hydraulic conductivity of fracture core samples from the Manitou Falls Group. This program involved the measurement of hydraulic conductivities under steady-state flow conditions, while cycling the effective confining pressure across a span that is representative of in-situ conditions. The change in fracture aperture was simultaneously recorded at each confining stress level. It was found that existing relationships relating aperture and flow did not accurately capture the behavior of the samples tested. The effects of fracture staining and infilling were also investigated, and were found to have a notable impact on the hydraulic conductivity.

Jun 1, 2012

By James Kear, Romain Prioul, Robert G. Jeffrey, Andrew P. Bunger, Dimitry Chuprakov

"Unconventional gas and geothermal reservoirs are typically naturally fractured and therefore the challenging problem of hydraulic fracture (HF) growth through naturally fractured rocks is an important issue especially for the development of accurate predictive HF models. This paper presents results from laboratory experiments in which HFs have been created in both sandstone and crystalline (gabbronorite) rock specimens such that they impinge either orthogonally or at an oblique angle on an unbonded, machined frictional interface. Depending on the conditions of each experiment, the fractures either cross or are blunted at the interface. The growth behavior was ascertained for these experiments based on a synthesis of the injection pressure record, active ultrasound monitoring, and direct post-experiment inspection of fractured specimens. From these experiments we observe: 1) A contrast between direct crossing and crossing with an offset for orthogonal and oblique intersection, respectively, 2) Apparent independence of crossing/blunting behavior on the friction coefficient for orthogonal intersection, 3) Dependence of the stresses required to promote crossing on the intersection angle between the HF and NF, 4) Existence of cases in which the hydraulic fracture crosses but then essentially ceases propagation such that all fluid is diverted to the interface. INTRODUCTIONHydraulic fracturing is a vital technology used to increase the productivity of oil, gas, and geothermal wells. Predicting hydraulic fracture (HF) growth is, in turn, critical to design of hydraulic fractures that grow to the desired length, accept the desired amount of proppant, and remain contained in the reservoir without unwanted height growth into surrounding layers (e.g. Economides and Nolte, 2000). The importance of HF modeling has prompted 6 decades of research during which simulators have become more efficient, more accurate, and have addressed a growing range of complexities (see review of e.g. Adachi et al., 2007).One of these complexities is the interaction between HFs and mechanical discontinuities such as natural fractures (NFs). Efforts in this area have been mainly driven by development of unconventional (i.e. low permeability) oil and gas resources because essentially all viable low permeability reservoirs, including shale gas/oil reservoirs, are naturally fractured to some degree (King, 2010). One of the most important questions for developing effective HF stimulation strategies in these reservoirs is whether the hydraulic fracture(s) is/are expected to be single-stranded or whether interaction with the NFs will lead to network-like growth. The basic building block for numerical simulators that can address this question (such as Kresse et al., 2013 and Weng et al., 2014) is whether an HF that intersects an NF will cross the NF or whether its growth will be captured by the NF so that additional fluid injection pressurizes the NF but does not generate ongoing growth of a new HF. These scenarios, including subcategories such as crossing with an offset, have been recognized for several decades (Daneshy, 1974; Warpinski and Teufel, 1987, and as recently reviewed and expanded by Chuprakov et al., 2013)."

Jan 1, 2015

By J. C. Hampton, L. A. Matzar, C. R. Gamwell

In geomechanics, conducting uniaxial or triaxial compression tests require samples to be prepared to a certain length-to-diameter ratio. This ratio is typically defined as 2:1 (length to diameter) and is accepted as a common standard for all materials on which mechanical properties testing is performed. Variations in sample length can cause changes in measured strength properties across multiple material types, such as cement, rock, or soil. Within the oil and gas industry, it is not uncommon to receive samples for technical services work that are slightly under or exactly the length requirement before surface grinding and sample preparation. Many of these samples are discarded from uniaxial and triaxial compression tests and used in another manner; therefore, it is necessary to study the length-to-diameter ratio in efforts to understand the limits and validity of testing samples that are slightly out of the 2:1 ratio. This paper discusses uniaxial compression tests performed using Berea sandstone and a standard cement mixture of 2.54-cm diameter to study changes in rock strength and properties. Compressive strength for each lengthto- diameter ratio over a range of 0.5:1 to 2.2:1 was measured. The investigation was extended to study near-end effects, where the sample length is near, but not exactly twice the diameter. It was discovered that the cement samples conformed reasonably well to the suggested ASTM correction factors. The sandstone did not conform to the correction factors and further analysis is required to develop a correction factor unique to the material. Near end effects, in both the cement and Berea, were found to increase compressive strengths, especially when the L/D of the samples was increased slightly over a 2:1 L/D.

Jan 1, 2015

By L. Jacobsson, J. E. Lindqvist

A series of laboratory tests were conducted to study stress-induced spalling on medium to coarse-grained granite specimens. The specimens made from cylinders had two manufactured notches on opposite sides aimed to represent the tangential loading around a circular opening. Specimens of three different sizes were tested with notch radii, 98.5, 225 and 375 mm, representing 197, 450 and 750 mm diameter holes, to study the effect of notch radius on the spalling initiation stress. The cracking was monitored by acoustic emission sampling. The fracture patterns were investigated visually on polished slabs and by microscopy on thin sections. The crack analysis describes how the cracks propagate in relation to the grain structure in the rock and to the macroscopic stress field.

Jan 1, 2015

By Gautier Njiekak

The current study provides an experimental approach that aims at documenting the effects of different phases of CO2 (gas, liquid, supercritical fluid) on rock seismic responses. This has implications on obtaining quantitative estimates of fluid saturations for geological storage. The ultrasonic pulse transmission technique is the underlying methodology used in this work. Unlike previous rock physics studies involving CO2 as pore fluid, care is taken to fully saturate the studied samples and also to separate pore fluid effects from pore pressure build-up effects during the experiments. This allows to record seismic effects that are solely reflective of changes in the pore fluid properties. Measurements were done on a CO2 saturated Berea sandstone. Laboratory results show P- and S- waveform variations (velocity, amplitude) in response to CO2's varying phase state. Overall, CO2 phase changes (gas to liquid and gas to supercritical fluid) are marked by a drop in velocities, with the drop being smaller and less immediate over the gas-supercritical fluid transition than over the gas-liquid transition.

Jun 1, 2012

By D. A. Wheeler, Rémi Tremblay

"INTRODUCTIONDuring the last few years, through Column Flotation Company of Canada ltd, the Centre de Recherches minérales has worked on the column flotation of coal, phosphate, feldspar, talc, graphite, copper, lead-zinc and diamond ores. The operating companies and prospective deposits were located in Canada and in other countries. Since these projects were financed by the concerned mining companies, all results remain confidential unless we obtain permission to publish. Three companies have graciously allowed us to use their information which I will describe in this text. These are the Polkowice copper mine in Poland, the North Coast Industries ltd graphite deposit and a talc company which preferred to remain anonymous. I will also describe our 2 inch column which was used for all tests. Data is also given on how to scale-up the 2 inch column to industrial size.Figure 1 presents a schematic of a flotation column. Feed, at a controlled rate and pulp density, enters at about 1/4 of the height of the column from the top. A controlled rate of air is bubbled into the bottom of column through a fine-holed sparger. The column volume between the feed point and the top of the sparger is called the recovery zone. Tailings, at a controlled rate, always slightly greater than the feed rate, discharges from the bottom of the column. This difference in feed and tailings flowrates is called the bias. The floated mineral is carried through the recovery zone on air bubbles which rise into the cleaning zone which is that column volume between the feed point and the overflow at the top. As the bubbles rise in this zone they are washed of gangue material by wash water which enters over the top of the froth layer. The froth layer is maintained at a given depth during flotation but this depth will depend on the froth cleanliness, for quite a bit of cleaning by wash water is accomplished in this layer."

Jan 1, 1988

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By D. J. Sapsford

This paper details results from laboratory simulation of an innovative underground bioleaching process. The underground reactors are periodic flushed with recycled leachate to remove uranium that accumulates within the reactor water. This leaching cycle has been recreated within the laboratory. This study examines the influence of varying cycle protocol on uranium leaching. Protocol variants examined include variation of flushing frequency, flush volume, leachate recycle, nutrient solution (NPK) addition to reactors and Fe(III) sulphate addition to reactors. The presented data highlight the dramatic improvements in uranium recovery that might be achievable by varying the operating protocol for the actual underground reactors.

Aug 1, 2010