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By Venugopal Tammishetti

One of the important technological challenges facing the iron ore industry in India is to find commercially viable technologies to process alumina rich iron ore fines and slimes. The key to solving this problem lies in developing selective reagents for the separation of iron oxide minerals from associated gangue minerals like quartz, gibbsite, kaolinite and montmorillonite. We present in this paper our successful results on the dispersion-flocculation of three different natural iron ore slime samples from mines in India using the reagent combination of PVP dispersant and corn starch flocculent. All the three samples contained hematite, goethite, kaolinite and gibbsite minerals as confirmed by X-Ray Diffraction (XRD) analysis. The effect of various process parameters such as pH, dosage of reagents, settling time and pulp density was studied. We were able to produce a concentrate assaying 66.2% Fe and <2% Al with a yield of 67.4% by weight (with a recovery of 77% of iron values) using PVP (1 ppm dosage) and corn starch (20 ppm) for one of the slime sample (Sample I) assaying 58.2% iron (Fe) and 3.8% aluminium (Al). The XRD analysis of settled and dispersed fractions revealed that alumina-containing minerals like clay and gibbsite mostly remain in the dispersed phase while iron-bearing minerals tend to concentrate in the flocculated fraction. Keywords: iron ore, slime, flocculation, dispersion, beneficiation, starch, polyvinylpyrrolidone

Sep 1, 2012

By N. R. Mandre

In the present work an attempt has been made to study beneficiation of low-grade iron ore associated with manganese clay by selective flocculation. The representative samples obtained for this purpose were initially subjected to chemical and mineralogical studies. The chemical analyses indicated 42.56 % Fe, 6.25% Mn, 8.72 % SiO2 and 13.60 % Al2O3 in the representative sample. The mineralogical analyses carried out under optical microscope showed that the ore mineral predominantly comprised of iron oxides and hydroxides along with manganese and silicate as gangue minerals. Prior to the beneficiation studies, the samples were subjected to settling tests. These tests were carried out by using poly acrylic acid (paa), poly acryl amide (pam) and guar gum (gg) as the flocculants. From these studies it was observed that settling rate of particles increases with increase in pH and a maximum settling rate of 0.23 cm/secwas obtained at pH 9 in presence of poly acryl amide. Further, the samples were subjected to selective flocculation studies using above-mentioned reagents. From these studies better results were obtained in the experiments carried out with poly acryl amide as the flocculant. Thus, it was possible to upgrade the iron content from 42.5 to 53%, with a recovery of 92%. However, 51% Fe with recovery of 87% and 50% Fe with recovery of 94 % was obtained using poly acrylic acid and guar gum respectively.

Sep 1, 2012

Poor floatability of fine particles is known to be the main cause of the low recovery of ilmenite in Panzhihua, which is the largest titanium mine of China. To get an optimum ilmenite recovery, selective flocculation, and flotation of fine ilmenite was investigated through flotation tests, particle size analysis, zeta potential tests and scanning electron microscopy. The results indicate that carboxymethyl cellulose (CMC) shows flocculation effect for both ilmenite and titanaugite without selectivity, while selective flocculation could be realized by the combination of water glass and CMC. It is because that competitive adsorption would take place on these two kinds of mineral when water glass and CMC are used together. On the surface of ilmenite, the adsorption ability of CMC is stronger than that of water glass, so that CMC can absorb to the same extent irrespective of the presence of a pre-adsorbed layer of water glass and ilmenite particles is flocculated by CMC. The same cannot be said of the titanaugite phase as water glass strongly adsorbs onto the titanaugite, and the adsorption of CMC is hindered. Therefore, the titanaugite particles keep dispersion. Furthermore, the flotation of fine ilmenite particles is feasible as the ilmenite floccules could react with sodium oleate. In the flotation separation of Panzhihua ilmenite ore, the recovery of TiO2 increased from 52.63% to 68.28% by selective flotation. Keywords: ilmenite, flotation, selective flocculation, adsorption

Sep 1, 2012

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By T. N. Matveeva, L. B. Lantsova, N. K. Gromova

"Multimetal gold-antimony ores are complexed processing products, since they are characterized by veindisseminatedsulfide mineralization with fine-dispersed submicroscopic gold, low content and uneven distribution ofAu, which is concentrated together with iron sulfides (pyrite, arsenopyrite, pyrrhotite). Such ores are classified asrefractory ones and characterized by low gold recovery rates during cyanation. A particular feature of gold-antimonydeposits is the presence of antimony in industrial concentrations therein, along with gold that significantly increasesthe value of these deposits. The main antimony mineral is antimony sulfide - antimonite (stibnite). Gold-antimonyores undergo flotation concentration with producing collective gold-containing concentrates or gold sulfide andantimony concentrates. The purpose of the work is an experimental study of the flotation separation mechanism ofsulfide minerals of copper, antimony and arsenic using tannin-containing modifiers during processing of multimetalgold-bearing ores. During the research it was established that for the selective separation of antimony and arsenicsulfide minerals into concentrates of different kinds, it is possible to use vegetable reagents capable to be selectivelyadsorbed on the arsenopyrite surface. Using the laser KEYENCE VK-9700 and electronic LEO-1420 VP INCA-350microscopy methods, it has been established that the film of a vegetable modifier was not washed off with water andfixed firmly enough on the surface of the polished sections of arsenopyrite. In the X-ray spectrum there are C and Obands related to the reagent structure. The vegetative reagent is fixed both on the pre-adsorbed phase of the collectorand on the areas free from the collector. On the polished sections of antimonite before and after a contact with thetannin solution, only partial adsorbed tannin phases are detected, which disappear as a result of subsequent washingwith water.The reported study was funded by RFBR according to the research project ? 16-05-00646 ?."

Jan 1, 2018

The flotation of nickel sulphide minerals is normally difficult in the presence of serpentine minerals due to the coating of serpentine particles on the nickel mineral surface. To improve the flotation, dispersants such as polyphosphate and carboxy methyl cellulose are normally used to remove the slime coating. However, in the flotation using high ionic strength process water, these dispersants are invalid due to their ionic nature. In this study, a new type of non-ionic dispersants, Pluronic triblock copolymers were examined with an objective of improving the flotation of ultrafine pentlandite (a nickel sulphide mineral) in the presence of lizardite (a serpentine mineral) in saline water. Three Pluronic triblock copolymers varying in solubility and hydrophile-lipophile balance (HLB) values were studied by flotation tests, settling tests and froth measurement. It was found that two of the copolymers improved pentlandite flotation against lizardite, and one copolymer deteriorated the flotation. The effect of Pluronic triblock copolymers on the flotation was actually linked to their dispersibility and foamability, which were governed by their physical properties. The two copolymers with a higher solubility or HLB value produced more stable mineral suspensions and more stable froth in the flotation resulting in better nickel grade and recovery in both rougher and cleaner flotation. Keywords: ultrafine particle, flotation, slime coating, dispersion, saline water, triblock copolymers

Sep 1, 2012

By Hossein Zarei, Masoud Kashani, Mehdi Safari

The feed of flotation unit in Angouran mine, as a part of Iranian Lead and Zinc National Corporation, contains about 34.26% zinc (about 12% Zn sulphide) and 10.14% lead (about 2% Pb sulphide). The grade of Pb and Zn in the final concentrate (rougher+scavenger), under optimal conditions (200 g/ton PEX, 500 g/ton zinc sulfate, 30 g/ton MIBC and pH = 7.5), was 63.18% and 13.01%, respectively, and the total Pb (sulphide-oxide) recovery was about 19% which included 95% Pb sulphide. The grade of Pb and Zn in rougher concentrate step was about 71.86% and 5.97%, respectively, when PEX (Potassium Ethyl Xanthate) was used as collector. While in the presence of PAX (Potassium Amyl Xanthate), the grade of Pb and Zn in rougher concentrate step was 66.8% and 10%, respectively. Tailing of the galena flotation (with 8.48% Pb grade and 34.92% Zn grade under the optimal conditions) was used as a feed for sphalerite and oxide section flotation.

Jan 1, 2014

By V. K. Kuppusamy, M. Holuszko

"Lamps and lighting products are the most commonly used electrical products around the globe. With the improvement in lamp technologies, lighting products have grown complex and hence require an improved recycling process. The LED lamps consist of various valuable metals such as iron, copper, aluminum, chromium, silver, and gold, as well as non-metals such as glass, plastics, and fibers. In addition, there are also traces of hazardous substances such as lead, arsenic, and mercury. A major step in the recovery process is size reduction, and researchers have suggested that up to 40% of the total valuable material is lost during the shredding and grinding processes. SELFRAG is a high voltage selective fragmentation comminution technology that uses high voltage pulses in a water medium to efficiently separate the metals at a coarser size without generating many fine particles. It has been proposed that during the fragmentation process of electronic waste (e-waste), the metals can be separated without fine grinding. This research considers the applicability of high voltage pulse fragmentation for LED lamps. Eight different types of LED lamps were processed through the SELFRAG unit at varying pulses to study metal liberation. The product obtained was characterized for metal liberation, metal grades, and liberation analysis. The specific energy consumption for this size reduction process was also monitored. INTRODUCTION Lamps and bulbs are the most commonly used electrical products in homes, offices, industrial operations, and streets. According to Energy Star research (2006), an average US household has more than 40 sockets for light bulbs and consumes approximately 2100kWh every year for lighting. The development in lamp technology has pushed the boundary for newer products. The LED lamps have been taking over the market from the incandescent bulbs and compact fluorescent lamps (CFL). According to the US Department of Energy (2012) and myLEDlight.com (2007), LED lamps have several benefits over other lamps. LEDs produce light hemi-spherically, which increases their efficiency in directional light emission. It has higher breakage resistance from vibration or transportation. LED lamps use up to 90% less power than incandescent bulbs thus making them highly energy efficient; They have a longer lifespan, lasting 10 times longer than a CFL and 133 times longer than the traditional incandescent bulb. Because of all the benefits, Smallwood (2014) suggested that the market of LED lamps will grow to $12.2 billion by 2018."

Jan 1, 2018

By W. H. Cheung

Nickel and cobalt production relies heavily on the processing of nickel laterite ores; these ores contain the majority of known Ni and Co reserves, 80% and 90% ~ 95%, respectively. The Caron process is used to extract Ni and Co metals from low-grade nickel laterite ores (1% Ni and 0.1% Co). It involves selective reduction of NiO and CoO minerals followed by ammoniacal leaching. Despite low metal recoveries, this process continues to be technically and economically reliable and thus commercially important globally. However, keeping the Caron process cost-effective has been a challenge for industries because of increasing economic and environmental pressures. Although studies of the Caron process have been extensive, significant improvements in recoveries of industrial processes have not been forthcoming. Reported industrial metal recovery from high iron content ore is only 80% ~ 85% for Ni and only 40% ~ 45% for Co; recovery is even lower for ores rich in magnesium. The real difficulty here is that there is no complete understanding of and control over the complex series of reactions in the ore and in the leaching solution during processing. Achieving effective metal recoveries from the Caron will require control of the mineral transformations, which affect the activation of minerals by reduction. In this study, the effect of over-reduction was investigated, which superseded the effect of activation by lowering the activity of the minerals and thus metal dissolution. Reduction was carried out in a batch reduction apparatus with 1:1 and 1:2.5 CO/CO2 gas mixtures from temperatures of 500 ~ 700°C and residence times up to 60 minutes. The pre-reduced ores were leached using a standard ammoniacal leaching test. Thermodynamic analysis and possible effects of stable phase field on leaching was examined. The results suggest that control of over reduction effects are directly related to the mineral transformation and reduction conditions.

Jan 1, 2014

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014

By Renato S. Costa, Afonso H. Martins, Flávia D. Mendes

"This paper presents some important aspects regarding the ion exchange treatment of an Ni and Co sulphate acidic liquor using chelating resins. Chelating resins possessing iminodiacetic or bis-picolylamine functional groups were compared in terms of nickel and cobalt recovery. The experimental resin with bispicolylamine functionalities (Dowex M4195) was evaluated with respect to Ni and Co uptake, and compared with Rohm &Haas commercial chelating iminodiacetate acid resin.The use of selective ion exchange to recover metals from sulphuric acid liquors has been studied for a long time. Companhia Vale do Rio Doce (CVRD) has been actively involved in hydrometallurgical applications of IX and has researched in selecting the optimum resin for nickel and cobalt selective removal and the design of a suitable IX circuit. When an IX operation is contemplated for a specific application, it is followed a screening process which generally involves consideration of the solution composition and pH, speciation of the metals in the liquor to be treated and other possible techniques that can be applied to achieve the desired specifications or recoveries. Once a decision has been made to use IX for a specific application, relevant testwork should be done to select the most cost-effective resin and design the IX circuit to achieve the desired criteria. The experimental part dealt with the working conditions, resin characteristics and the influence upon the resin maximum exchange capacity of the following factors: nickel concentration, temperature, pH and resin-to-solution ratio. Based on the experimental data obtained, it has been proposed a innovative technological treatment"

Jan 1, 2003

By Renato S. Costa, Afonso H. Martins, Flávia D. Mendes

"This paper presents some important aspects regarding the ion exchange treatment of an Ni and Co sulphate acidic liquor using chelating resins. Chelating resins possessing iminodiacetic or bis-picolylamine functional groups were compared in terms of nickel and cobalt recovery. The experimental resin with bispicolylamine functionalities (Dowex M4195) was evaluated with respect to Ni and Co uptake, and compared with Rohm &Haas commercial chelating iminodiacetate acid resin. The Rohm & Haas chelating resin, Amberlite IRC 748, with its weakly acidic groups, did not work in acidic solution but exhibited good results at pH 4 and above. The resin that efficiently removed metals from high acidic solutions was the bis-picolylamine resin. Maximum nickel uptake values ranged between 85 g and 112 g Ni per Kg of resin.The experimental part dealt with the working conditions, resin characteristics and the influence upon the resin maximum exchange capacity of the following factors: nickel concentration, temperature, pH and resin-to- solution ratio. Based on the experimental data obtained, it has been proposed a innovative technological treatment."

Jan 1, 2003

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By Jin Duan, Qi Zheng, Bo Yan, Li-cheng Ma, Xiao-kui Che

"The aim of this study was to develop an approach for the selectively removal of Zn(II) from heavy metal-bearing-wastewaters produced by gold chemical industry using magnetic chitosan based adsorbents. Chitosan beads were prepared by cross-linked modification of Fe3O4-chitosan bead using epichlorohydrin as the cross-linker. Both Zn(II) inprinted magnetic chitosan hydrogel bead (Zn-MCHB) and unprinted magnetic chitosan hydrogel bead (MCHB) were prepared and batch adsorption experiments were used to evaluate their adsorption capacities and selectivities. Single adsorption of Cu2+, Pb2+, Zn2+ and Ni2+ showed that both MCHB and Zn-MCHB adsorbs all the four metals and had an affinity in the order of Cu2+ > Pb2+ > Zn2+ > Ni2+. The binary adsorption revealed that the two adsorbents preferentially adsorb Cu2+/Pb2+ from Zn2+-Cu2+/ Zn2+-Pb2+ binary systems. However, MCHB does not show any selectivity in Zn2+-Ni2+ system. In contrast, Zn- MCHB preferentially adsorbs Zn2+ from Zn2+-Ni2+ binary system. Furthermore, the adsorption selectivity is predictable from stability constants of the metals with the amino group of chitosan. The information revealed in this work can be used for further applications in the treatment of wastewater containing a range of heavy metals from the gold chemical industry."

Jan 1, 2014

By Thomas Mütze, Michael Klichowicz, Mathis Reichert, Holger Lieberwirth

"Self-similarity is proofed to be a common feature when brittle material is comminuted, either in particle bed or single particle mode. Appropriate test work is well documented for particle sizes less than 7 mm in several publications. In contrast, almost no research has been done for coarser particles. The aim of this paper is to show that the fracture pattern of coarser material also tends to be self-similar. Hence, single particles of quartzite, granodiorite and dolomite were comminuted under compressive load. The focus was set on three different size fractions -3.15 +2.5 mm, -31.5 +25 mm and lumps -300 mm. According to the wide range of particle sizes, three different piston-die presses were used with a maximum compressive force ranging from 5 kN to 4000 kN. The force-displacement curves were recorded in order to calculate the specific comminution energy. Additionally, the -31.5 +25 mm size fraction was crushed in a laboratory scale jaw crusher and a roll crusher. Some authors report that the energy-size-reduction relationship of self-similar materials can be approximated by a linear function, which is independent of the comminution equipment. In their charts the slope can be seen as a product-size-independent grindability measure. Our tests show a self-similar breakage behavior when particles in a range of -300 +3 mm are comminuted in single particle mode. Furthermore, the products of the piston-die-presses and the roll crusher are similar to each other in a self-similar representation of the particle size distribution. The jaw crusher product, however, is not self-similar compared to the piston-die-press products. Finally, the linear energy-size-reduction relationships are confirmed for each fraction, but show size dependent slopes."

Jan 1, 2014

By T. Mütze

The progress in comminution is often described by the specific surface area and the energy utilization or the brakeage ratio and breakage function. The principal mechanisms of size reduction are therefore, well known. All four parameters share a common disadvantage: They are limited in describing the behavior of a feed material with fine particles and a wide particle size distribution. An alternative is to describe the progress in comminution with ? The particle size distributions Q(x) before and after the stress or ? The particle concentration ratio pcr(x), which combines these two states. In the case of a self-similar fracture behavior, (in short: self-similarity) the progress in comminution can be simplistically described by the relationship between a reference particle size and the stress intensity. Self-similarity means self-similar breakage functions of geometrically similar particles of the same strength, a certain stress situation and stresses up to the breakage point. Self-similar breakage functions show the same curve at different stress intensities when the fragment size x is normalized with a reference particle size xNorm. This behavior was demonstrated for single particle comminution repeatedly and unequivocally. In the field of particle bed comminution, these results differ in literature. Therefore, the self-similarity in particle bed comminution was systematically investigated at the Institute of Mechanical Process Engineering and Mineral Processing of the TU Bergakademie Freiberg as part of a research project. Limestone, quartz, silicon carbide and glass beads, were examined with a hydraulic press. The particle sizes covered monodisperse fractions in the range of 1-1000 µm, bimodal mixtures of these fractions and polydisperse fractions. The results obviously show that there is no self-similar fracture behavior in the case of glass beads, quartz and silicon carbide. Statements on the self-similarity of limestone are much more difficult: Only some of the investigated limestone fractions show a similar clear, non-self-similar behavior. Self-similar curves appear particularly for fine monodisperse fractions as well as bimodal mixtures, which stressed with pressures above 200 MPa. Considering the measurement accuracy of particle size analysis the coincidence of the curves can be explained by the fact that progress in comminution almost ends above 200 MPa. At this point, a hydrostatic stress state is reached in the particle bed which is known from the literature. This stress state inhibits further fractures. Overall, it has been verified for the investigated materials that there?s no self-similar fracture behavior in particle bed comminution. One reason for the diverse opinions in literature is that there are three types of particles after the comminution in the particle bed: ? Particles which are stressed below their breaking point, ? Particles which are stressed right up to the break point, and ? Particles which are stressed beyond their breaking point.

Sep 1, 2012

By Jacek Kolacz

A new sensor based sorting system has been developed, based on complex image analysis, where an image texture and a shape pattern is considered for identifying particles for separation. The sorting system employs different images generated by visual light and X-ray to provide maximal information about processed particles. Application of X-ray makes it possible to analyse the internal structure of the particles, which provides a 2D image with complicated texture, however, which contains valuable information. The advanced system for the texture and the pattern recognition is applied to analyse these images simultaneously, to provide the required identification of the particles for efficient separation. The mathematical models applied during identification and separation, are assisted by high speed calculations being specially optimised for this kind of process. This allows sorting with high capacity and high accuracy, which is critical for practical applications in mineral processing. The paper describes a number of tests during sorting of iron ore and coal with high separation efficiency.

Jan 1, 2014

By M. R. Robben

Carbonates have gained significant economic importance for the human kind. On one hand over a hundred uses are listed for carbonates. On the other hand, carbonates host base metal deposits. Although the carbonates play a significant part in the development of those deposits, in the mineral processing they consume acid and cause selectivity problems during flotation and leaching. Carbonates also accompany other industrial minerals as waste rock. For all those cases it necessary to find a technique to separate carbonate as early as possible in the processing chain. In this paper, the applicability of near-infrared spectroscopy (NIRS) sorting for the separation of carbonates is discussed. NIRS sorting is a sensor-based sorting technique, in which particles are singularly detected by a sensor and then rejected by an amplified mechanical, hydraulic or pneumatic process. This technique can for example be implemented in the process as a pre-concentration step for coarse particle sizes up to 300 mm. NIRS sorting discriminates among materials based on the difference that exist between their spectral properties in the near-infrared (NIR). Vibrations of molecular bonds in carbonates cause characteristic spectral properties in the NIR, which makes carbonates detectable, possible to identify, distinguish and separate from other rock materials. The spectral properties can also be used to distinguish between different carbonate minerals and mixtures. If the spectral variations are large enough for detection, sorting based on NIRS is possible. Feasibility studies on sensor-based separation of carbonates in the processing of talc, borate, fluorite, marble, zinc-oxides, copper sulphide and iron ore as well as the discrimination of calcite and dolomite mixtures are conducted and indicate the high potential of NIRS sorting in the minerals industry. Keywords: carbonate separation, sensor-based sorting, near infrared spectroscopy, NIRS sorting

Sep 1, 2012

By X. M. Wang

Magnetic floatation column (MFC) is a new equipment used for increasing content of iron, in which magnetite is separated in open gradient magnetic field. Simulation study was performed to investigate the separation characteristics of the separation method by analyzing the dynamic motion of magnetic particles. In this paper we compare two magnetic fields created by different magnets. The obtained simulation results give perspective in industrial design of MFC as the basis stage.

Jan 1, 2014

By Kauko T. Ingerttilä, Jouko O. Kallioinen, Jaakko O. Leppinen, Alexander V. Lashkul, Vladimir E. Nenno

"Separation in Froth (SIF) is a process for the separation of mineral particles during their descent downwards through a moving froth layer, generated on the surface of water or some other liquid media by means of a bubble generator and frother. Due to the special operation principles of SIF it is possible to separate mineral particles that are about 10 times coarser than the optimal particle size for conventional flotation. In this paper the performance of the SIF technique is presented in the separation of apatite, calcite and silicate minerals from various industrial sources, based on tests with laboratory and pilot plant-scale SIF machines. Basic laboratory test results of the flotation of pure diamonds are also presented.It was shown that calcite, apatite and diamonds with particle size up to about 3 mm can be successfully floated with SIF at high recovery and grade, provided that the degree of liberation is sufficiently high. Coarse calcite (+0.25-2.8 mm) was concentrated with reverse SIF in one flotation step at 87% recovery with better than 99% grade. Apatite particles coarser than 0.2 mm are not well floated in the conventional flotation circuit leading to high P2O5 content in the coarse size fractions of flotation tailings. On the contrary, SIF is capable of recovering such coarse particles at high recovery. However, P2O5 content of the SIF tailings starts to increase at about 0.7 mm due to insufficient liberation of apatite. At higher particle size the lack of hydrophobicity of apatite particles is also likely to lower the recovery.The pilot plant testwork showed that SIF can be successfully used at operating plants not only for preliminary upgrading of the feed of conventional flotation, but also for producing final grade calcite concentrate (>99.5%) from the screen overflow or from the cyclone underflow in a particle size range up to 1 mm. It was particularly promising that the separation took place in one SIF flotation step, instead of several stages of the conventional flotation circuit, with over 90% calcite recovery. The specific capacity determined with the 1 m2 pilot plant unit was approximately 30 t/m2h. Simultaneously the consumption of chemicals was significantly lower than for conventional flotation."

Jan 1, 2003