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By Michael G. Zabetakis

Investigation of gas explosions usually reveals that the combustible gases have come from transmission and storage facilities or from natural gas or oil wells. However, combustible gases such as methane and hydrogen can derive from biological processes. Hazardous situations have been created in the past by the use of abandoned mines for the disposal of sewage and rainwater, by the interconnection of storm and sanitary sewers, by sealing the openings in manhole covers when repaving the roadway over a sanitary sewer, and by the construction of buildings over or near garbage fill areas without adequately providing for the release of combustible gases.

Jan 1, 1962

By John Fitzpatrick

In this Bureau of Mines investigation a device was developed that permits the determination of the modulus of elasticity of the stress-relief cores obtained in the process of making in situ stress measurements. This determination is made by hydraulically loading the external surface of the stress-relief cores and by measuring the corresponding borehole deformation. The theoretical relationship between the borehole deformation, the applied pressure, and the modulus of elasticity is presented. Also, experimental results obtained from measurements on a simulated stress-relief core made of aluminum and on a limestone stress-relief core are given. Because of the symmetrical loading obtained with this device, the isotropy of the core material can be evaluated. With this device it is also possible to study the effect of eccentricity, that is, the effect within cores in which the inner hole is not coincident with the long axis of the specimen.

Jan 1, 1962

By James A. Whelan

The Bureau of Mines sponsored research studies of variables in rotary drilling, done in the Department of Mineral Engineering, University of Minnesota. By studying carefully controlled drilling with good instrumentation, it was hoped to obtain a better understanding of rock failure during drilling and of the stresses in drill bits during drilling. Experimental procedures and equipment are described. From these studies it was concluded that 1. Thrust requirements, other things being equal, are proportional to the total length of cutting edge in the bit. 2. Data from penetrating a wedge into rock under thrust only are not directly applicable to rotary drilling. 3, In rotary drilling the initial wear on a bit greatly decreases penetration rate under any given set of conditions; however, after initial wear the effect of wear on penetration rate is reduced. 4. An increase in rotary speed increases the overall penetration rate but decreases the penetration per revolution. 5. An increase in thrust increases the overall penetration rate and the penetration per revolution. 6, Torque on a drill bit is proportional to both penetration rate and bit diameter. 7. For small-diameter holes full-hole drilling will save both drilling time and energy compared with pilot drilling followed by reaming; for large-diameter holes pilot drilling-reaming is advantageous in both respects,

Jan 1, 1962

By W. W. Weller

This report provides low-temperature heat-capacity data and entropies at 298.15° K. for magnesium metavanadate (MgV206) and magnesium pyrovanadate (Mg2V207). The work completes low-temperature measurements planned for alkaline-earth vanadates; an earlier report dealt with calcium vanadates.4 No similar data for these compounds have been published previously. Free energy of formation values at 298.15° K. were derived by combination of the present entropy values with heat of formation data. MATERIALS The materials used in the measurements were portions of the samples described in a previous Bureau of Mines publication by King, Koehler and Adami.5 Methods of preparation, chemical analyses, and X-ray examinations are covered in this paper. The indicated purity of the samples was 99.9 pct.

Jan 1, 1962

By R. E. Lindstrom

Effective separation of rare-earth mixtures is obtained using hydrogen as a retaining ion at 200° F with ethylenediaminetetraacetic acid (EDTA) eluant. Results obtained in Bureau of Mines bench-scale apparatus and large columns with hydrogen as a retaining ion closely parallel those obtained with copper as a retaining ion. The use of hydrogen as a retaining ion permits EDTA and water, collected before rare-earth breakthrough, to be recovered in a form that allows the material to be recycled without extensive processing. With the exception of yttrium and dysprosium, separation of rare-earth mixtures is improved and throughput is increased by elevated temperatures. Separation with 1,2-diaminocyclohexanetetraacetic acid (DCTA) eluant increases markedly on increasing temperature from ambient to 250° F; however, on the basis of separation efficiency, DCTA does not compare favorably with EDTA.

Jan 1, 1962

Spectrochemical methods were developed to determine beryllium in the concentration range 0.0015 to 4.0 percent in siliceous mineral beneficiation products. Two methods are described. They are (1) a fusion-pellet-spark procedure (spark method) and (2) a sustaining alternating-current arc procedure (arc method). In the spark method the sample is fused with lithium tetra-borate and vanadium pentoxide. The resulting bead is crushed, mixed with powdered graphite, and briquetted. This is analyzed spectrographically using controlled high-voltage spark excitation. In the arc method the sample is diluted with germanium metal, graphite, and vanadium pentoxide. Weighed charges are packed into cupped graphite electrodes and subjected to excitation with a sustaining alternating-current arc. Vanadium serves as internal standard for both methods. Effects due to matrix variations in samples and standards are eliminated either by fusion with lithium tetraborate in the spark method or by dilution with germanium and graphite in the arc method. Beryllium determinations show deviations from accepted chemical values of approximately 5 and 8 percent for the spark and arc methods, respectively. Analyses can be made more rapidly by the arc procedure with a sacrifice in precision and accuracy. Either method can be applied to the determination of beryllium in silicate rocks.

Jan 1, 1962

By Frank A. Peters

This Bureau of Mines report is the second of a series of process evaluations planned to determine the relative processing costs of producing metallurgical-grade alumina from low-grade aluminous materials. Included in these evaluations are recommendations for additional research and development to improve the processes and to lower their costs. The design for each process is based on published work. The processes considered in this report are designed to extract alumina as aluminum chloride from calcined clay with 20 percent hydrochloric acid and to remove the silica residue by filtration. Iron is removed by one of the following processes: Isopropyl ether extraction, in which iron chloride is extracted before decomposing the aluminum chloride; gas precipitation, in which the aluminum chloride is precipitated with hydrogen chloride while leaving the iron chloride in solution; gas precipitation-isopropyl ether extraction, in which the aluminum chloride from precipitation is extracted with isopropyl ether, if necessary; caustic purification, in which a crude alumina is produced and then purified by a modified Bayer operation; or sinter purification, in which a crude alumina is produced and then purified by a lime-soda sinter operation. For plants producing 1,000 tons of alumina a day the estimated operating costs per ton of alumina are: [Isopropyl ether extraction process $ 65.09 Gas precipitation process 89.04 Gas precipitation-isopropyl ether extraction process 119.65 Caustic purification process 73.79 Sinter purification process 80.47] The estimated fixed capital costs per annual ton for these plants on a Marshall and Stevens chemical equipment basis of 240.0 are: [Isopropyl ether extraction process $229.03 Gas precipitation process 287.16 Gas precipitation-isopropyl ether extraction process 356.59 Caustic purification process 266.48 Sinter purification process 279.13]

Jan 1, 1962

By C. H. Riggs

This report describes the development, oil recovery, and potentialities of productive formations in the Hall-Gurney field, Russell County, Kans. It is presented as part of a general program to aid and promote increased recovery from petroleum reservoirs. The report is based on studies of well logs, drill cuttings, and oil-and water-production histories of individual wells and leases. The geological interpretations follow closely those in published literature with only slight local modifications. Oil and water analyses, made at a Bureau of Mines research center, were supplemented by many analyses obtained from oil-producing and service companies. The Hall-Gurney field, in south central Russell County, Kans., (fig. 1) was discovered in 1931 but was not developed extensively until 1941. By 1960 the rate of oil production from the field had declined to the extent that many wells were abandoned. In some areas natural productive forces have effected good recovery. However, in other areas inefficient waterflooding, both natural and accidental, has adversely affected recovery potentialities.

Jan 1, 1963

By J. T. Schimmel

The purpose of this investigation was to obtain complete information on some of the uses of a 24-inch-diameter auger in the underground mining of pitching anthracite beds. The auger was placed in operation early in 1958 to drive ventilation connections between coal gangways driven by a continuous miner. Although designed to drill rise holes only, it was used also to drill dip holes. The latter holes were drill id from an adjacent gangway to avoid interference between the auger and the continuous miner. These holes established immediate ventilation returns when intersected by the continuous miner. Bureau participation in the project covered 361 working days. The auger was used on 288 shifts, usually one 7-hour shift per day, and drilled 3,246 feet, of which 493 feet were reamed. The longest hole was 87 feet; hence the maximum drilling depth of the machine (rated at 100 feet) was not required. Holes drilled normal to the strike of the bed ranged from 30 to 66 feet deep, averaging 45 feet. The continuous miner drove gangways on 575 shifts. Thus, the auger worked one shift for each two worked by the continuous miner and was used on less than 80 percent of the workdays. The auger drove 24-inch holes 10 times faster than the larger, conventional openings could have been driven by usual mining methods and exceeded the workload for which it was purchased. Augering eliminates exposure to the hazards encountered in driving chute-work by conventional methods and provides adequate circular ventilation openings, which are strong in self support and are adaptable to reaming when required. With alterations, the auger may have limited use as a production machine in thin-bed pitch mining but cannot compete with established methods of thick-bed pitch mining.

Jan 1, 1962

By T. E. Gray

This report describes the preparation characteristics of the significant coalbeds in Nicholas County, W. Va. It is one in a series describing coals suitable for producing metallurgical coke, either as mined or after beneficiation. Almost 5 million tons of coal were produced in Nicholas County, W. Va., in 1960, of which over 2.6 million tons were cleaned in eight preparation plants. It has been estimated that over 6 billion tons remained in the county as of December 31, 1960, in beds 12 inches and more thick.

Jan 1, 1962

By Stephen Utter

This report summarizes the procedure and results of an investigation to determine the stresses in the rock around an underground opening in the Climax molybdenum mine, Climax, Colo. This study is part of an overall investigation conducted by the Bureau of Mines to determine the stresses induced by block-caving mining. The purpose of this study is to obtain estimates of the magnitudes and directions of the principal stresses, the location of the maximum stress concentrations, and the effect of topography on the stresses.

Jan 1, 1962

By Louis A. Panek

Tests of mine-roof models in a centrifuge show that the suspension effect due to bolting a horizontally bedded mine roof with frictionless surfaces of contact between beds depends principally on the number of bolted beds and their relative flexural rigidities, provided that sufficient bolt tension is exerted to prevent strata separations at the bolt locations. Strata separations tend to occur in the unbolted roof mainly because the beds have unequal thicknesses. "Suspension effect" refers to the transfer of part of the weight of weaker or thinner beds to the flexurally more rigid beds by roof bolts or by any other means. The factors investigated were number of beds in the bolted unit, bed thickness, modulus of elasticity of beds, length of bolts, spacing of bolts across and along the opening, bolt load, and intensity of roof load. The general principles of behavior of the bolted roof beds are explained by an approximate theory. Model test data are used to validate the theory and to obtain an expression for the "suspension efficiency". As the suspension effect actually observed in the models is smaller than that predicted by the approximate theory, the suspension efficiency in general is less than unity. Mathematical expressions are obtained for (1) the change in roof bending stress due to the suspension effect, which is needed for design of a roof-bolting system, (2) the change of roof deflection due to the suspension effect, which may be useful for evaluating the effectiveness of a roof-bolting system, and (3) the bolt load or pre-load that is required to achieve the desired reinforcing effect.

Jan 1, 1962

By Louis A. Panek

This report deals with the combined friction and suspension effects in the reinforcement of horizontally bedded mine roof by bolting. Other reports have treated these two effects separately. Friction effect refers to the reduction of bending in a laminated roof due to the clamping action of tensioned bolts. If the beds tend to have unequal deflections, the bolts oppose this tendency, thus creating a suspension effect, which consists of a transfer of part of the weight of weaker or thinner beds to the flexurally more rigid beds within the bolted unit. The combined effects of friction and suspension on the bending of the beds, whether an increase or a decrease, are difficult to generalize because they depend on the bedding sequence and the bolt pre-tension. Some analysis of the bedding sequence usually is required to determine the critical bed within a set of bolted beds. However, if the suspension effect is substantial and if the bolts are pre-tensioned, then the greatest bending stress is likely to occur in the thickest bed. Findings are based partly on theory and partly on tests of mine-roof models in a centrifuge, which were found to verify the theory. Mathematical formulas are obtained for the change in maximum roof bending stress and for the change of roof deflection due to the combined friction and suspension effects. The maximum bending stress is needed for designing a roof-bolting system and the deflection for evaluating its effectiveness.

Jan 1, 1962

By Webster S. Anderson

Two series of tests were run with planer model 'BB": one at the Arickaree mine of the San Francisco Chemical Co., Rich County, Utah, and one at the Roslyn No. 9 mine of the Northern Pacific Railway Co., Roslyn, Wash. The tests at the Arickaree mine were started on June 25, 1958, and continued until September 30, 1958. Prior to these tests, an electrically activated remote-control system was installed, and other modifications were made on the planer. The tests showed that the planer in general and the remote-control system worked very well; however, the various cutting tools used would not consistently penetrate and cut the phosphate rock. This indicated that the cutterhead design had to be changed before the planer would operate efficiently in phosphate beds similar to the "A" bed in the Arickaree mine.

Jan 1, 1962

By Raymond P. Maloney

The Rhyolite mercury prospect is on the south flank of Juninggulra Mountain--a large rhyolite intrusive in the Kuskokwim River region about 36 airline miles northwest of Red Devil, Alaska. Bulldozer trenching by the Bureau of Mines exposed bedrock at intervals in a 2,000-by 3,000-foot area where previous prospecting by the owners had disclosed abundant float and several in-place stringers containing cinnabar in widely varying amounts. The additional trenching indicated that the mercury mineralization in the limited area investigated was confined to erratically distributed short stringers and to small lenses, occurring in discontinuous zones in numerous silica-carbonate dikes and sills or along their altered contacts with sedimentary rocks. The geologic relationship of the mercury-bearing silica-carbonate dikes and the nearby rhyolite intrusive is similar to that existing at several other mercury mines and prospects in the. Kuskokwim region. The depth of over-burden and the presence of permafrost were serious obstacles to bulldozer trenching, and only a comparatively small part of the mineralized area was thus investigated.

Jan 1, 1962

By H. E. Powell

Because of increasing consumption of high-and super-duty refractories, the Bureau is studying the feasibility of beneficiating submarginal and marginal clays. Diverse mineral dressing tests were used to beneficiate samples from the east-central Missouri fire clay district. Standard ASTM tests were used to determine refractory properties of both crude and beneficiated clay samples. Marginal and submarginal clays containing impurities were effectively beneficiated by both wet-cyclone and wet-table treatment, but the wet-cyclone treatment was cheaper. Ion-exchange resins in the hydrogen form will probably prove more effective in removing potassium, the only alkali in Missouri fire clays to be a problem. Resins with greater cross linkage are more effective than resins with less. Roasting the crude clays before removing alkalis by chemical leaching was ineffective. By applying ultrasonic energy at a frequency of 10 to 25 kilocycles to aqueous suspensions of the clays, subsequent ion-exchange extraction of potassium was slightly improved. Higher frequency ranges did not help.

Jan 1, 1963

By R. Barany

The heats of formation at 298.15° K of calcium tungstate, calcium molybdate, and magnesium molybdate were determined by solution calorimetry. For the heats of formation from the elements, the values obtained were calcium tungstate, -402.4 ± 0.5 kcal/mole, calcium molybdate, -369.5 ± 0.3 kcal/mole, -334.8 ± 0.2 kcal/mole. For the heats of formation from the oxides J the values obtained were calcium tungstate, -49.2 ± 0.4 kcal/mole, calcium molybdate, -39.6 ± 0.1 kcal/mole, and magnesium molybdate, -12.9 [ ] 0.1 kcal/mole.

Jan 1, 1962

By R. F. Tenney

No detailed information has been published heretofore on the performance of small industrial-type anthracite stokers in building-heating service, apparently because of the difficulty of comparing the performance of one unit with that of another over an entire season's operation. Studies of competitive heating fuels have been similarly handicapped, and attempts to compare fuels are seldom technically sound in this investigation, the performance of a 60-in. Losch4 stoker burning rice-size anthracite in a standard commercial boiler was observed during a 4-month winter-spring season. It was used to heat two buildings at the Bureau of Mines' Anthracite Research Center at Schuylkill Haven, Pa., with the customary type of automatic pressure-range control. Attendance was limited to inspecting, fuel weighing, data recording, and ash removal. Results were computed daily and grouped by weekly periods to minimize daily irregularities. The same stoker-boiler unit had already been tested in a series of American Society of Mechanical Engineers (ASME) test code runs, with the stoker running continuously and with other conditions well stabilized A comparison of results from the code test and the building-heating tests provided information not available in the past for a single stoker unit, assisted in analyzing heat losses not computable in a cyclic operation, and established a basis for evaluating stoker performance in heating service.

Jan 1, 1963

By Lowell Stroud

This report is the third in a series presenting equilibrium vapor-liquid data for helium-bearing natural gases. The first two reports contained phase data for the gases processed for helium at the Bureau of Mines Amarillo and Exell, Tex., helium plants. The present report offers similar information for a lower-helium-content (0.75 mole-percent) natural gas to be processed in the Department of the Interior's long-range helium-conservation program. A windowed-cell apparatus was used to obtain 218 samples of equilibrium vapor and liquid phases at 73 experimental conditions ranging in temperature from -100° F to -275° F and in pressure from 100 to 500 psi. From the phase data, the condensation characteristics, helium solubility, and equilibrium-vaporization-coefficient data for helium, nitrogen, and methane were evaluated. The effect of using a. preliminary hydrocarbon trap upon the subsequent vapor-liquid compositions is reported. A brief comment regarding the composition effect of passing the gas through a gasoline-removal unit is also included.

Jan 1, 1963

By R. L. Montgomery

Heats of solution of cerium metal and cerium (III) chloride in hydrochloric acid were measured. The standard heat of formation of the aqueous cerium (III) ion at 25° C is -166.1 ± 0.3 kcal/mole. Heats of solution of cerium (III) chloride in hydrochloric acid are consistent with the existence of a complex CeC1++ having a stability constant of 1 and a heat of complexing of 5.4 kcal/mole.

Jan 1, 1962