Search Documents

By Vernon R. Miller

The Bureau of Mines developed and evaluated a detector-sorting device to separate the copper-bearing portion from the barren portion of native copper ores. Small-scale sorting tests were run on minus 1-inch plus 1/2-inch size materials from the following Michigan samples: Winona, Kingston, and Centennial ores, and "poor" rock from the Champion mine dump. Results showed that 60 to 85 pct of the copper was recovered in 9 to 19 wt-pct of the sorted fraction. About 90 pct of the copper recovered was obtained in the first pass through the sorter. For the Kingston and Centennial ores, combinations of sorter concentrates and fines generated during crushing, resulted in recoveries of 93 and 94 pct, respectively, of the total copper in the samples. The combined products constituted about 66 wt-pct of the total sample and allowed the balance to be discarded with only a 6 to 7 pct copper loss.

Jan 1, 1974

By John C. Edwards

Chapman-Jouguet detonation calculations were carried out for pentaerythri-tol tetranitrate (PETN), TNT, and ammonium nitrate-fuel oil (AN-FO) explosives using the compressibility form of an equation of state of hard spheres based upon Percus-Yevick (PY) theory, and a chemical equilibrium detonation code called TIGER. Similar calculations were also carried out with the Becker-Kistiakowsky-Wilson (BKW) equation of state. For PETN, the BKW equation gives somewhat better agreement with experimental values of detonation velocity and pressure. However, in terms of experimental temperatures and concentrations of the minor product species (NO), the predictions of the PY equation are shown to be more satisfactory. Similar comparisons of experimental and theoretical results for TNT and AN-FO indicate that the PY equation has general utility in predicting the detonation properties of condensed explosives at moderate loading densities (Po < 1.3 g/cm3).

Jan 1, 1974

By L. E. Schultze

[The Bureau of Mines conducted bench-scale studies to develop techniques for stripping tetravalent cerium from tri-n-butyl phosphate solutions. Experiments were conducted in a constant-temperature bath using beakers and mechanical stirring. Ninety-five pct of the cerium was stripped from a 50-pct tri-n-butyl phosphate 50-pct kerosene solution containing 0.18 M cerium in 15 minutes at 50° C using 0.11 M aqueous formaldehyde.]

Jan 1, 1974

By R. V. Subramanian

This project financed by the Bureau of Mines investigated the use of polymers to achieve rock bonding and reinforce coal mine structures for better or permanent ground support. Support was achieved by pumping the polymers into the rock interstices to bond the mass together for increased structural competence. Holes were drilled in the mine roof, after which the polymers were injected at about 100 psi to permeate the cracks. Initial laboratory work indicated that of all the resin systems tested, the epoxy resins could most likely be modified to be suitable for rock injection. This was confirmed when several potentially suitable resin systems underwent intensive evaluation. In a series of three field tests, two conducted in a copper mine with coal mine-type shale and the third in a coal mine, it was shown that the polymers penetrated cracks less than 0.005 inch wide. The fast-setting epoxy systems, cured out in thin films under mine conditions, produced a bond exceeding the strength of the uncracked virgin rock.

Jan 1, 1974

By Donald N. H. Chi

The unsteady, one-dimensional, compressible-flow equations have been solved numerically for a deflagration propagating through a gallery of finite length closed at the ignition end and open at the opposite end. These equations were solved for two situations wherein (1) the propagating flame was extinguished after 0.1 sec or before the return of aerodynamic disturbances reflected from the open end, and (2) the flame was allowed to propagate a full 0.8 sec until it was extinguished. It was found that the process of sudden flame extinguishment creates rarefaction waves that, upon entering the burned zone, produce resonance within the burned cavity. For the relatively small value of the product of the expansion ratio (8.5) and the effective burning velocities of 7.4 m sec-1 for the first experiment and 4.9 m sec-1 for the second experiment, it was found that the acoustic approximation provides an adequate estimate of the pressures developed ahead of the flame during the system&apos;s early history.

Jan 1, 1974

By George E. Fasching

The Bureau of Mines has developed a pulse counting system with improved energy resolution and having dual channels to process pulses at different rates and a pulse pileup detector for channel selection. Pulse input is delayed until the detector determines if any pulse is so closely followed by a second pulse as to constitute pulse pileup. If no pulse pileup is detected, the slower channel is selected; this clips the pulse to a wide pulse width to retain good energy resolution. If pulse pileup is predicted, the fast channel, with correspondingly shorter pulse width, is selected to improve resolution with respect to time. Output of the two channels is transmitted to a pulse height analyzer for interpretation. The pulse processing system can process count rates above 300,000 counts per second with little loss in energy resolution.

Jan 1, 1974

By P. W. Jeran, C. M. McCulloch, Maurice Deul

The natural vertical fracture sys tem in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north- western West Virginia to N 57° W in southwestern Pennsylvania ; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures . Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974

By C. M. McCulloch

The natural vertical fracture system in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north-western West Virginia to N 57° W in southwestern Pennsylvania; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures. Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974

By Carlon S. Land

The Bureau of Mines investigated the influence of a free gas saturation on oil recovery by water drive. A digital computer was used to calculate the combined oil recovery from solution-gas drive to various states of depletion. Results of these calculations are compared and optimum conditions for the maximum oil recovery are found for various fluid-rock systems. For most of the fluid-rock systems, the calculations show an optimum gas saturation other than zero. Using fluid and rock properties as parameters, graphs are plotted showing the optimum gas saturation and increase in oil recovery brought about by the gas saturation. The effects of fluid properties and relative permeability on the optimum gas saturation are seen in these graphs. The graphs can be used as guides in connection with other considerations in determining the optimum time to start a waterflood. They should also be helpful in determining the MER of a water-drive reservoir. The effects of compressibility and solubility of the trapped gas saturation are investigated for select cases using a backward difference scheme to solve the partial differential equation of three-phase flow. From these calculations, it is observed that some benefit of a gas saturation remains for injection pressures up to 1.5 times the original bubble-point pressure.

Jan 1, 1974

By James R. McVey

A new method for measuring deformations of rock surfaces in underground excavations has been suggested by Dr. James Powell of Brookhaven National Laboratories (BNL) and subsequently developed and successfully demonstrated in a mining environment by the Federal Bureau of Mines, Spokane Mining Research Center (SMRC) and Brookhaven National Laboratories. The system uses 35-mm photography of targets strategically located on surfaces of interest, such as across the roof and on the sides of a mine drift or tunnel. The optimum tar-get, as determined in this investigation, consists of a white ?X? made with 1/8-inch-wide reflective tape on a black 6-inch square. Photographs, taken in pairs from two separated camera positions and at regular time intervals, were analyzed at the Bureau by hand and at Brookhaven National Laboratories using techniques and equipment similar to those used in cloud chamber film analysis. Test results show that deformation-measurement accuracies of better than ±0.020 inch in a drift that is 20 feet wide can be expected. This degree of accuracy, plus providing displacement data in the X, Y, and Z directions (rather than the one direction formerly possible), makes this a noteworthy and useful tool for industry as well as for mining research.

Jan 1, 1974

By J. E. Murphy

A method is being developed by the Federal Bureau of Mines for recovering lead metal from galena without the generation of SO2. Lead chloride is obtained by leaching lead concentrate at a temperature of approximately 100° C with FeCl3 solution: PbS + 2FeCl. " PbC1 2 + 2FeC1 2 + S. Electrolysis of the PbCI 2 product in a fused-salt bath results in deposition of molten lead metal at the cathode and evolution of chlorine at the anode. The chlorine can then be absorbed in the spent leach solution to regenerate FeCl3 for recycling. Optimum electrolyte composition was a PbC12-LiCl eutectic containing 7.6 wt-pct LiCl. The PbCl2-NaCl eutectic also proved satisfactory. Electrolysis in the PbCl2-LiCl bath at 450° C yielded 99 pct current efficiency at a current density of 5 amp/in2 with an energy requirement of only 0.24 kW-hr/lb metal produced. This compares with 98 pct current effi¬ciency and 0.26 kW-hr/lb metal produced for the PbCI2-NaCI bath. A typical lead deposit contained less than 100 ppm total detectable metallic impurities. At the low temperature employed for electrolysis, there was essentially no vaporization of Pb or FbC12.

Jan 1, 1974

By H. V. Makar

The Bureau of Mines successfully demonstrated, on a pilot plant scale, a sodium sulfate (Na2S04) refining process for removal of copper from molten ferrous scrap. Previous tests established technical feasibility on a bench scale for achieving low copper concentrations and determining the principal factors controlling process efficiency. The pilot plant study involved a 1-ton arc furnace for melting ferrous scrap and a 1-1/2-ton treatment ladle. Results of these tests showed that copper removals obtained in laboratory tests (approximately 40 relative percent copper removal with 10 weight-percent surface addition of sodium sulfate) could be achieved on the pilot plant scale when excess carbon was added with the sodium sulfate compacts. Data were obtained on temperature losses and carbon consumption related to Na2SO4 treatment.

Jan 1, 1974

By Russell E. Griffin

Dielectric constants and dissipation factors were measured by the Bureau of Mines for 13 simulated lunar rocks over the 20-to 100-megahertz frequency range by means of the susceptance-variation method. Measurements were made at room temperature and normal atmospheric pressure. Results are presented and some comparison is made with data reported by others. The rocks used include a broad range of physical characteristics and chemical compositions from the large areas of volcanism in Oregon and northern California, and two nonvolcanic types. These rocks make up a suite of rock standards used by a group of laboratories engaged in lunar research. The data presented will add to the basic scientific and engineering knowledge needed to utilize extra-terrestrial mineral resources for support of future space missions.

Jan 1, 1974

By F. N. Kissell, R. J. Bielicki

The Bureau of Mines found sulfur hexafluoride (SF6), released from a lecture bottle, to be an ideal gaseous tracer for studying mine ventilation systems. Air samples were collected in glass syringes and analyzed by electron-capture gas chromatography. In these studies, the lower limit of detection was about 1 part per billion by volume (ppb) of SF6 per part of air. Experiments conducted in a Pennsylvania limestone mine showed this technique useful in evaluating the effectiveness of auxiliary fans, measuring low flow velocities, probing the air circulating near a working face region where ventilation appeared to be poor, and estimating volumetric flow rates in airways of large cross-sectional area and having low flow velocities. This technique was also used in a western vein-type metal mine to measure the amount of return air being recirculated into the intake air due to leakage through old stoped areas.

Jan 1, 1974

The Bureau of Mines found sulfur hexafluoride (SF6), released from a lecture bottle, to be an ideal gaseous tracer for studying mine ventilation systems. Air samples were collected in glass syringes and analyzed by electron-capture gas chromatography. In these studies, the lower limit of detection was about I part per billion by volume (ppb) of SF6 per part of air. Experiments conducted in a Pennsylvania limestone mine showed this technique useful in evaluating the effectiveness of auxiliary fans, measuring low flow velocities, probing the air circulating near a working face region where ventilation appeared to be poor, and estimating volumetric flow rates in airways of large cross-sectional area and having low flow velocities. This technique was also used in a western vein-type metal mine to measure the amount of return air being recirculated into the intake air due to leakage through old stoped areas.

Jan 1, 1974

By F. N. Kissell

The Bureau of Mines has successfully used sulfur hexafluoride (SF6) as a tracer gas to measure mine air flows under conditions where conventional methods have failed. SF6 was employed experimentally to measure accurately recirculation of return into intake air caused by leakage through an old stoped area, to check for potential leakage from an adjacent mine, to trace 10,000 cfm of “lost” air from an intake airway, and to measure transit air time through uranium mines. It proved useful as a means of accurately measuring airflow volumes in airways of large cross section and very low flow velocity, and in determining the recirculation resulting from underground cooling plants.

Jan 1, 1974

The Bureau of Mines has successfully used sulfur hexafluoride (SF6) as a tracer gas to measure mine air flows under conditions where conventional methods have failed. SF6 was employed experimentally to measure accurately recirculation of return into intake air caused by leakage through an old stoped area, to check for potential leakage from an adjacent mine, to trace 10,000 cfm of "lost" air from an intake airway, and to measure transit air time through uranium mines. It proved useful as a means of accurately measuring airflow volumes in airways of large cross section and very low flow velocity, and in determining the recirculation resulting from underground cooling plants.

Jan 1, 1974

By F. R. McDonald

The compound ?-valerolactone has been identified in an acid fraction isolated from waste water collected from an in situ oil-shale retort. Infrared, nuclear magnetic resonance, and mass spectrometry were used by the Bureau of Mines to confirm the identification of a subfraction collected from a gas chromatograph.

Jan 1, 1974

By D. J. MacDonald

Wettability measurements and laboratory waterflood tests were compared under a wide variety of conditions. Experiments were conducted with synthetic and natural crude oils, treated and untreated outcrop and oilfield sandstone cores, and synthetic brines with and without caustic, detergent, or phosphate additives. Measurements were made on equilibrated and unequilibrated systems at 77° and 150° F. Wettability was evaluated by the Bureau of Mines method from capillary pressure curves determined with a centrifuge. The waterflood data were fitted by empirical curves; the parameters of the curves characterize primary and subordinate production and also give the ultimate oil recovery. Results showed that wettability measurements at 77° F were useful predictors of recovery efficiency in waterflood tests run at both temperatures. Oil recovery in the early stages of waterflooding increased with increasing water wettability; however, the ultimate recovery was highest at a slightly oil-wet condition. The oil displaced at highest speed in the centrifuge was correlated with ultimate recovery in waterflood tests. Chemical additives to the brine sometimes lowered wettability and also sometimes improved waterflood recovery, but wettability and recovery were not correlated with additives present. The effect of additives on recovery in waterflooding was best seen in water-oil ratio curves.

Jan 1, 1974

By A. W. Hall

Cylindrical plastic scintillators were investigated for efficiency in detecting neutron-induced prompt gamma rays. Scintillator performance was compared on the basis of half-resolution and peak-to-trough ratios for gamma spectra obtained from Co-60 (1.17 and 1.33 MeV), Th-228 (2.62 MeV), and PuBe (4.43 MeV). Various sizes of Pilot Chemical scintillators (types B, F, M, and Y) were tested. The best half-resolution, 7.7 percent for PuBe, was achieved with a 5-by 5-inch Pilot Y?scintillator and dual photomultipliers. Comparison with sodium iodide (NaI) scintillators and the use of plastic scintillators for on-stream analysis of sulfur in coal is discussed. Plastics were found to be unsuitable for on-stream analysis of materials having complex prompt gamma ray spectra; however, they could conceivably be used for those yielding Simpler spectra.

Jan 1, 1974