Search Documents

By Ralph H. Espach

In the spring of 1943, when it was evident that the Tensleep sandstone in the Elk Basin field, Wyoming and Montana, held a large reserve of petroleum, Bureau of Mines engineers obtained samples of oil from the bottom of nine wells and analyzed them for such physical characteristics as the volumes of gas in solution, saturation pressures or bubble points, shrinkage in volume caused by the release of gas from solution, expansion of the oil with decrease in pressure, and other related properties. The composition of the gas in solution in the oil was studied. The pressures and temperatures existing in the reservoir and the productivity characteristics of the oil wells were determined. The data obtained indicate that the oil in the Tensleep reservoir of the Elk Basin field has unusually varying physical characteristics, such as a saturation pressure of 1,250 pounds per square inch absolute and 490 cubic feet of gas in solution in a barrel of oil at the crest of the structure, and a saturation pressure of 530 pounds per square inch absolute and 134 cubic feet of gas in solution in a barrel of oil low on the flanks. The hydrogen sulfide content of the 6a r; in solution in the oil varies from 18 percent for oil on the crest to 5 percent for oil low on the flanks of the structure. Of even greater significance is the fact that these and other variable characteristics of the reservoir oil are related to the position of oil in the structure. Many geologists and petroleum engineers have considered all the oil in a petroleum reservoir to have uniform physical characteristics and that equilibrium conditions prevailed in all underground accumulations of oil and gas. That such is not always so is borne out by the results of the study made by the writers.

Jan 1, 1951

By R. S. Warfield

The Kasna Creek copper deposit near Lake Kontrashibuna in the Lake Clark region, Alaska, was the object of an investigative project by the Bureau of Mines during the fall of 1948. Recessed because of inclement weather, it was completed in 1949. This project was a part of the Bureau of Mines program in Alaska for the development of critical and strategic minerals. The ore bodies are contact-replacement deposits in limestone. Mineralization is mainly specular and micaceous hematite associated with chalcopyrite, calcite, chlorite, quartz, and amphibole. The deposit, on the right limit of Kasna Creek approximately 2 miles from the shore of Lake Kontrashibuna, is composed of two mineralized zones that range in altitude from 2,350 to 2,650 feet. This report contains a brief history of the prospect, description of the physical setting of the property, its geology, and the factual results of the Work performed by the Bureau of Mines.

Jan 1, 1951

By James Westfield

Drilling for roof bolting has created a new dust problem for the coal-mining industry. Drilling is inherently dusty, and control of dust produced by drilling vertical or nearly vertical holes is much more difficult than control of that produced by drilling flat or down holes.4/ Also, the dust produced by roof drilling differs in composition from that produced by drill-fur, or cutting the coal face because it contains a significantly greater amount of free silica and therefore presents a greater potential hazard of silicosis. Roof bolting has been practiced successfully in the mines of the St. Joseph Lead Co. in southeastern Missouri for over 20 years, but it was not until 1947 and 1948 that large-scale roof-bolting experiments were conducted in coal mines.5/ Although the need for dust control in conjunction with roof drilling was recognized from the beginning, the development and acceptance of roof bolting progressed so rapidly during 1949 and 1950 that solution of the dust problem lagged behind other engineering phases of the technique.

Jan 1, 1951

By W. E. Robinson

A laboratory study wan made to determine whether drying and preheating Colorado oil shale with waste retort gases has any appreciable effect on its oil yield. Samples of crushed oil shale were heated at subretorting temperatures in a specially constructed electric furnace by gases similar in composition to waste gases from oil-shale retorts. The results of this study showed that preheating oil shale with nitrogen or a reducing mixture had no effect upon the oil or water yield. However, oxygen in the preheating gas caused a decrease of oil and an increase of water. In general, the oil yield decreased with (1) increase in oxygen content of the heating gases, (2) increase in temperature of the heating gas, (3) increase in heating time, and (4) decrease in the particle size of tho shale. The decrease in oil and the increase in water resulting from preheating were due to oxidation of the benzene-insoluble organic material (kerogen) rather than to oxidation of the benzene-soluble organic material (natural bitumen) in the shale, A small amount of oil was volatilized during preheating, which would constitute an additional loss if prober precautions were not taken to recover it. The results obtained in this laboratory study indicate that oil shale can be preheated without appreciable decrease in oil yield by proper selection of preheating conditions.

Jan 1, 1951

By J. H. Jacobs

In late 1946, research was begun at the Bureau of Mines Electrometallurgical Laboratory at Boulder City, Nev., to determine the possibility of electrowinning manganese from chloride electrolytes on a continuous basis. All phases of electrodeposition were investigated on a small scale it the laboratory, and the results were reported by Jacobs and Churchward. These results indicated that a chloride process had certain possible advantages over the sulfate process that made it worthwhile to continue the investigation on a semi-pilot-plant basis, and this paper reports the results of this work. Research and development work on a process for electrowinning manganese from low-grade ores has been carried on intermittently by the Bureau of Mines since 1936. A process was developed, using sulfate electrolyte, that has been extensively described in the literature.

Jan 1, 1951

By Shiro Watanabe

To determine the potentialities of nickel as a substitute for cobalt in catalysts for the synthesis of hydrocarbons from carbon monoxide and hydrogen, RESULTS The maximum oil yields obtained in bench-scale equipment were as follows: Using 100N1:20Mn:100 kaolin:200 diatomaceous earth catalyst, a maximum yield of 133.8 cm.3/m.3 of pure CO+2H2 was obtained from one pass of the feed gas, With a nickel:cobalt mixed catalyst (Ni:Co - 3:7) having the composition 100(Ni+Co):8MgO: 5Th02:200 diatomaceous earth, a maximum of 172.2 cm.3/m.3 of pure C0+2H2 was obtained.

Jan 1, 1951

By R. A. Cattell

The Bureau of Mines recently observed its fortieth anniversary, and with the close of the fiscal year 1950 it completed 36 years of close cooperation with and helpfulness to the petroleum and natural-gas industries, whose technical problems it studies. Petroleum people likewise observed the ninetieth anniversary of the start of this truly American industry when "Colonel" Drake drilled the first well at Titusville, Pa., in 1859 (see fig. 1). Throughout the period, during which there have been many changes in the fuel and related economy of the country, this work has been carried on systematically by an organized entity of the Bureau first known as the Petroleum Division and in recent years as the Petroleum and Natural Gas Branch. Changes in the industries have been brought about partly by economic forces, partly by advances in technology, and in some measure by the impact of two world wars. As the needs of industry and the Nation have changed, so have the studies of the Bureau changed to meet these needs. Consistently, Bureau technologists and scientists have tried to keep in step with progressive movements; frequently, in fact, have taken the lead. Wherever possible, they have looked far ahead in their program of research, at the same time recognizing the needs of the hour.

Jan 1, 1951

By R. L. Anderson

Mechanical cleaning of bituminous coal in the United States was begun about 1875, with plants in western Pennsylvania and Illinois. The United States Geological Survey began to record the quantity of washed bituminous coal in 1906; and the series was carried forward to 1923, except that no data were collected, for 1922. This statistical work was transferred to the Bureau of Mines in 1925, and the collection of data on mechanical cleaning was resumed in 1927. Data collected before 1927 include only the coal that was washed at the mines and do not include that cleaned by pneumatic methods at the mines and that cleaned at central washeries operated by consumers.2/ The total bituminous coal washed in 1906 was less than 10 million net tons. In 1927, the first year for which complete figures are available for all types of mechanical cleaning, 28 million net tons of bituminous coal were cleaned in the United States.

Jan 1, 1951

By K. E. Stanfield

This report presents the results of analytical studies made on two series of oil-shale samples from the Mahogany ledge of the Green River mine the character of the various grades of oil shale that are being mined and processed into shale oil and refined products at the Bureau of Mines Oil-Shale Demonstration Plant at Rifle, Colo. The analytical work was part of a synthetic liquid fuels program being conducted at the Petroleum and Oil-Shale Experiment Station, Laramie, Wyo. The 16 oil shales ranG6d in color from a gray brown ( or a sample that assayed 10.5 gallons of oil per ton to a very dark brown for a sample that assayed 75.0 gallons of oil per ton. In general, the samples were similar as to the types of organic and inorganic matter that they contained but varied widely in the amounts or these constituents. The principal constituents were calcite, dolomite, illite, and yellow organic material, while the minor constituents were quartz, feldspar and plagioclase feldspar, pyrite, marcasite, analcite, opal, black organic material, and small woody fragments. Some micro-fossils, spores and pollen grains were found also.

Jan 1, 1951

By Wiliam L. Crentz

The importance of Somerset County, Pa., as a coal producer is due in large measure to the presence reserves of low-volatile bituminous coals. Although many coal beds of minable thickness are present, the important reserves are to be found in those beds underlying the Pittsburgh bed. The Kittenning beds and Freeport beds, which are responsible for the bulk of the present coal production in Somerset County and contain the largest reserves to meet future coal requirements, are usually thin and entirely free from impurities. The Pittsburgh bed, which has been such an important coal deposit in the coal areas immediately west and south of Somerset County, is of secondary importance in this county. Although generally rather friable, Somerset County coals have enjoyed wide receptability as excellent coals and to some extent have been utilized in the metallurgical market.

Jan 1, 1951

By Gordon Bath

During the summer of 1946, the Division of Geophysical Exploration of the U.S. Bureau of Mines established several primary magnetic base stations near important iron-producing districts in Minnesota, Michigan, and Wisconsin. Stations were located in groups of four to six in six separate base-station areas, and each position was marked with a concrete monument. Differences in magnetic intensity between stations in these areas, as well as the difference between each area and a magnetic datum at the magnetic observatory of the Coast and Geologic Survey at Cheltenham, Md., were measured with a modified Askania magnetometer. Measurements also were made with a Hotchkiss superdip to study the usefulness of the stations for the calibration of instruments of this type. The work was planned and supervised by F. W. Lee, chief of the Division of Geophysical Exploration, and Edward F. Fitzhugh, Jr., chief of the Minneapolis Division of the Bureau of Mines. Special mention is due Harold B. Ewoldt, Bureau of Mines engineer, for his assistance in the field work, especially in locating and establishing monuments. Special mention also is due Clyde L. Holmberg, of the Bureau of Mines, for the magnetic measurements made with the Hotchkiss superdip. Helpful suggestions were received in the field from H. L. James, of the U. S. Geological Survey. Acknowledgment is made of the cooperation of Stephen Royce, Irving E. Beckwith, Arthur Johnson, and Josiah Royce of Pickands, Mather & Co., and A. E. Matson, of Butler Bros. The U. S. Coast and Geodetic Survey furnished daily magnetograms from the Cheltenham Magnetic Observatory as well as calibration equipment and values of absolute magnetic intensity. Short-term forecasts of ionospheric conditions were obtained from the National Bureau of Standards.

Jan 1, 1951

By Irving Hartman

The results of the first experimental study by the Bureau of Mines on the explosive properties of metal powders were published in 1945. Since that time the explosibility of numerous other industrial dusts and powders has been investigated. Part of this information has been published, but most of the data has not been released to date. This paper summarizes the results of experiments on 22 samples of titanium, zirconium, thorium, uranium, and hydrides of these metals. The major part of the investigation was made under cooperative agreement with the Atomic Energy Commission.

Jan 1, 1951

By James J. Dowd

The investigation to evaluate the reserves of coking coal is being made by the Bureau of Mines in three parts: (1) To estimate known (measured plus indicated) recoverable reserves of all coking coal; (2) to upgrade marginal coals through effective preparation; and, (3) to study the carbonizing properties of coal and coal blends not now widely used for metallurgical coke. This is the third of a series of reports giving results of studies by counties under part (1) of the investigation. This report covers Pike County, Ky., which comprises parts of the Harold, Williamson, Matewan, Gilbert, Pikeville, Regina, Hurley, Pound, and Clintwood quadrangles. (See fig. 1.) A base map for each bed in each quadrangle was made to the scale of 1 inch equals 1,200 feet. Maps of mines, locations of drill holes, bed and total coal thicknesses, and the outcrop of the bed were plotted on the maps. With all available data plotted, isopach lines were drawn to limit areas of known unmined reserves in beds 0 to 14 inches thick, 14 to 28 inches thick, 28 to 42 inches thick, and over 42 inches thick. These areas of coal reserves also were divided into "measured" and "indicated" categories. All areas in each thickness range and in each category, mined-out areas, areas excluded from the estimate but which may contain reserves based only on geologic inference, and areas outside of the outcrop were measured by planimeter on the base maps. Estimates of total reserves 14 inches and more thick and maps for individual beds were prepared from these data.

Jan 1, 1951

By R. L. Bolmer

Rapid depletion of our known mineral resources has stimulated exploration for new mineral deposit. Abandoned mines or prospects may prove to be commercial in today's economy. Often it is necessary to revaluate such properties. Some of these may be inaccessible because of caving of flooding. Many, however, remain in good condition, except that over the years the air in the workings has become depleted of oxygen. Each year the Bureau of Mines receives numerous requests for aid in entering old mines, the air in which is incapable of supporting life. Requests of many individuals who wish to examine or explore-such places with the help, of the Bureau's self-contained oxygen breathing apparatus have been denied because of the hazards involved in the use of this equipment for such purposes. The distance to be traveled in irrespirable gases may be too great for safety; under favorable conditions, a round trip of 2,000 feet from fresh air is the maximum distance that may be traveled.3/ The use of such equipment is hazardous unless a team of at least 5 men thoroughly experienced in its use is provided; and when extensive traveling from. a fresh-air base is required, a reserve team should be provided.3/ Usually, the apparatus is requested for use in exploring workings having only one surface connection, as mines having more than one opening usually are more easily ventilated;,and in some natural ventilation is sufficient or can be made so by cleaning out obstructed openings.

Jan 1, 1951

By John Soule

The Torpedo copper mine in the Organ Mining, District, Dona Ana County, N. Mex., was discovered in 1899, and production of copper from oxidized-ore deposits was begun in 1900. Production continued through 1907, but operations were only intermittent frown 1907 through 1921. The production of copper during these periods amounted to about 3,500,000 pounds. Reserves primary sulfide copper ore were believed to occur below the old workings, and after a detailed examination of accessible workings and a study of drilling records of several private companies by an engineer of the Bureau of Mines, a development program of diamond core drilling was initiated. This investigation was started October 3, 1949; and completed April 30, 1950. Four holes totaling 2,122.3 feet wore diamond-drilled, and 70 samples were analyzed. All drilling was done with a Government-owned hydraulic-feet drill having special rods and core barrels to increase the recovery of core in critical zones. This report describes the location, history, ore deposits, and factual data obtained by the Bureau of Mines from the drilling.

Jan 1, 1951

By A. L. Engel

Simple treatment methods, employing the least possible equipment, can sometimes be established for marginal ores and economical results achieved. In continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno Station of the Bureau of Mines, typical ores from newly discovered or recently explored mining districts have been investigated. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores, as well as the conservation and recovery of values in products from former operations that were discarded because of past inability to treat them economically. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas some involved samples of old dumps or tailings piles. The test, work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials; and because, inasmuch as the samples were representative of the districts from which they were obtained, this in-formation should be helpful in the future development of these districts. The present report is a compilation of results of brief preliminary tests on oxide ores only, which contained gold and silver and in some cases base metals. The methods of treatment used include gravity concentration, amalgamation, flotation, and cyanidation. For the most part, only standard laboratory procedures were employed. No attempts were made to develop new methods for the low-grade refractory ores in this group of samples if simple treatment was not successful, as the stage of development of the properties did not warrant extensive experimentation on the samples submitted.

Jan 1, 1951

By Stanley M. Walker

Safety consciousness is not a constant for which a specific value can be assigned, but is a variable, which is frequently intangible. Its evaluation is not simple. We all know that safety consciousness is the most potent factor in the prevention of accidents. Safety consciousness may be defined as awareness of hazard and alertness to danger, which controls every action of an individual through his desire to remain alive and uninjured.

Jan 1, 1951

By J. D. Davis

THE CARBONIZING properties of Chilton-bed coal from Lorado No. 5 mine, HE Logan County, W. Va., were determined by Bureau of Mines-American Gas Association tests at 600°, 700°, 800°, 900°, and 1,000° C. and by expansion tests. Chemical analyses, agglutinating and plasticity tests, and low- and high-temperature assays also were included in the investigation. Blends with low-volatile Pocahontas No. 3 coal were carbonized at. 900° C. The Chilton coal bed lies in the Kanawha, or Upper Pottsville formation of the Pennsylvanian system; the estimated original reserves are nearly 3.2 billion tons. The bed was 39/1 to 57 inches thick in the Lorado No. 5 mine, and the coal was 38 to 57 inches thick. The carbonization sample contained 62.6 percent fixed carbon on the dry, mineral-matter-free, basis, and the heating value on the moist, mineral-matter-free basis was 15,190 B. t. u. per pound; it therefore ranks as high-volatile A bituminous. It contained 1.8 percent moisture, 35.2 percent volatile matter, 57.9 percent fixed carbon, 5.1 percent ash, and 0.7 percent sulfur, as carbonized. The sulfur was largely organic, and the ash softened at 2,630° F. The agglutinating value determined on a silicon carbide-coal mixture of 15:1 was 6.8. In the Gieseler test the coal softened at 327° C., fused at 407° C., attained a maximum fluidity of 5,730 dial divisions per minute at 435° C., and solidified at 487° C. Maximum resistance in the Davis plastometer was 45.5 pound-inches.

Jan 1, 1951

By M. J. Ankeny

Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the prevention of such accidents will materially improve progress in safety in the coal-mining industry. Beginning March 1950, Federal coal-mine inspectors were made responsible for completely investigating all fatal accidents in and around coal mines. During these 10 months, Federal coal-mine inspectors investigated 447 fatal accidents. This is a study of 121 of the fatal haulage accidents investigated, which constituted 27 percent of fatalities from all causes. Haulage employees represent only 12 to 15 percent of mine personnel, but, on the basis of accident frequency, their work is the most hazardous in coal mines. Fatal haulage accidents occurred in 53 bituminous coal-producing counties representing 14 States and Alaska. The physical conditions represent a cross section of' producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of modern mechanized mines.

Jan 1, 1951

The United States has not begun commercial operations to tap its largest poten-tial sources of oil supply - oil shale and coal. The reason is that domestic petrol-eum has been plentiful in the past and liquid products probably could be produced from it at the lowest cost. In view of the ever-increasing need for petroleum in the United States, the critical international situation threatening foreign supplies, the growing demands for steel, and the heavy costs to industry of constantly discovering and developing new oil fields, it is believed that the prompt development of a synthetic fuel industry based on oil shale and coal is not only requisite to safeguard our oil supply but is an economically sound course for the foreseeable future, To neglect its development is to close our eyes and minds to our own resources at a time when they are needed critically. It also is apparent now that neither the Government nor industry would be taking any considerable economic risk in starting the initial plants, especially as measured against their potential value in meeting critical oil and chemical demands and in building a new industry in the West.

Jan 1, 1951