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By R. V. Lundquist

Past reports by the Bureau of Mines have described the extraction of alumina from numerous aluminum silicate materials by the lime-soda sinter process. The results from pilot-plant investigations of six materials, with alumina-to-silica mole ratios from 0.3 to 8.7, indicated a relationship between the alumina-silica ratios and the processing characteristics of the sinter. A series of laboratory tests was conducted to define this relationship. Sinter and leach tests determined that an alumina-to-silica mole ratio of 0.90 or greater resulted in the best alumina and soda recoveries while leaving the leach slurries practically free from any tendency toward gelation. The widely different chemical and mineralogic properties of the various aluminous materials used in compounding the mixes had no perceptible effect on the leaching characteristics of the sinter. The blending of low-cost, high-alumina materials with aluminum silicate materials to give an alumina-to-silica mole ratio of 0.90 or greater would improve alumina and soda extraction and minimize operating problems in the lime-soda sinter process.

Jan 1, 1970

By Laurance L. Oden

The Bureau of Mines is developing melting data for binary combinations of the alkaline earth fluorides and yttria to facilitate the formulation of slag composition. Liquidus and solidus temperatures and solid solubilities were determined for the BaF2-Y203 system, and the information is presented as the phase diagram. The phase diagram was constructed from data obtained by ceramography, X-ray diffraction, and thermal analysis of specimens encapsulated in small molybdenum ampoules. The data indicate a simple eutectic system with maximum terminal solid solubilities of less than 1 mole pct. The eutectic temperature is 1,343° C, and the composition of the eutectic is less than 1 mole pct Y203.

Jan 1, 1970

By Fun-Den Wang

A two-dimensional plane strain analysis by the stiffness matrix method was used to analyze two basic pit slope configurations. The magnitudes and the directions of stresses are given for a V-shape and for a flat-bottom pit with the slope angle varying from 30° to 90° at 10° intervals, Stress effects due to irregular pit configuration or to in-situ forces are discussed. Equations of similitude for gravity loading are given. Expressions are also given for the stresses at the toe as a function of slope angle. Procedures are given for finding the stresses in any geometrically similar pit slope of different dimensions and material properties from the stresses and equations presented in this report. Numerical results show that the V-shape pit slopes have lower stresses than the flat-bottom pit slopes; hence, they are inferred to be more stable.

Jan 1, 1970

By A. Aly Selim

This report describes the feasibility of predicting percussive drilling rates by equations derived from statistical regression analysis. The least squares statistical method was used and the analysis was performed both by direct and by stepwise linear regression analysis. The predicted penetration rate is a function of the drill power and the physical properties of the rocks penetrated. The results show promise that the technique may be of value in providing a mathematical model by which percussive drill manufacturers and users can predict the performance of a given drill. Experimental work involved two mining type percussive drills. Penetration data for these drills were determined from nine rocks drilled in the laboratory. Drill work rates (power) were determined in a separate series of experiments. Rock physical properties were measured from diamond-drill core samples taken from the same blocks used for percussive drilling.

Jan 1, 1970

Ever since the problem of mine pollutant waters has been under consideration, different mining methods have been investigated to abate the pollution problem. Two such methods which have been reported are inert gas operation and revised mining methods.

Jan 1, 1970

By G. H. Keith

A vanadium-base alloy consisting of the following elements in weight-percent--molybdenum, 20; titanium, 10; carbon, 0.1; silicon, 0.5; and yttrium, 0.5--had exceptionally high strength at temperatures up to 1,200° C. This alloy was capable of fabrication to sheet of ~ 1 mm thickness by a combination of hot swaging and hot and warm rolling. In the warm-rolled condition at ambient temperature, its ultimate tensile strength was 1,205 MN/m2. The strength at 1,200° C was 150 MN/m2. Within the temperature range of 25° to 1,200° C, the ductility of the alloy as measured by elongation increased from 4 to >90 percent. Strengthening was achieved by both solid-solution and dispersed-phase mechanisms. Alloys of 20 percent molybdenum and 10 percent titanium were stronger than the other molybdenum-titanium alloy compositions tested. Strength was increased 15 percent in the temperature range of 25° to 800° C, with no accompanying loss in ductility, by the addition of 0.5 percent silicon. Workability was improved by additions of 0.25 and 0.5 percent yttrium.

Jan 1, 1970

By R. R. French

The industrial minerals industry in the Atlanta, Ga., area was studied in order to better understand problems associated with exploiting mineral resources in and near metropolitan areas. A method for delineating the Atlanta urban area and its component parts was developed so that the factors affecting the location of the minerals industry could be viewed mere objectively in the urban context. Major attention is focused on the area's dominant crushed stone subindustry Demographic and socioeconomic analysis of the Atlanta, Ga., area shows that expansion of the metropolis and its environs will probably eliminate potential mineral resources from the mineral resource base in the area, and that the expanding metropolis will be the primary determinant of future mining sites. Competition for land is accentuated to varying degrees by the incompatibility of wining operations with residential and other environmental requirements. Areas of consideration are suggested to provide maximum development of land and resources for greatest economic benefits it minimum social cost. Further research is recommended to determine market locations in urban areas, optimum operating levels for industrial minerals plants, and alternatives to surface mining.

Jan 1, 1970

By Gary A. Kingston

Chromium resources in the United States are estimated at 1.8 million tons of recoverable chromium contained in 22.5 million tons of chromite-bearing material. Additional resource is presumed existent in large, but as yet undetermined, quantities of material containing less than 10 percent Cr203. No domestic resources are being mined presently (1969). Excluding transportation charges to domestic consuming areas, the total 1.8 million tons of chromim is estimated to be available, in ore or concentrate, at costs up to $0.64 per pound; 63 percent of the total is available under $0.11 per pound; and 38 percent under $0.08 per pound. It is judged that transportation from the resource areas to the existing market centers would add nearly $0.05 to the cost of a pound of chromium contained in ore or concentrate. Technically effective beneficiation methods have been developed for much of the known domestic resource, and further development might reduce costs of processing these materials. However, at present, domestic chromium resources are noncompetitive with foreign sources.

Jan 1, 1970

By B. I. Ferber

Sodium chloride aerosol was employed to determine respirator filter penetration in a manner suitable for use in Bureau of Mines approval and certification procedures. The aerosol was produced by an ultrasonic generator and treated to yield the proper conditions of relative humidity, particle size, and concentration. Respirator filters were exposed to the aerosol; filter penetration (down to 0.02 percent) was determined with a flame photometer. Results are comparable with those obtained in another laboratory using different equipment.

Jan 1, 1970

By Bruce D. Sartwell

A program was written which utilizes a remote teletype input to a time- sharing computer to plot charged particle or X-ray energy spectra which are stored in the memory of multichannel analyzers. The program, written in FORTRAN V, accepts the data printed out by the pulse height analyzer on paper tape and then, after reading these data tapes into the computer, plots on the teletype the desired energy spectra on a scale automatically adjusted for the maximum number occurring in the data. The program is flexible enough so that the researcher can subsequently expand or contract the vertical (intensity) or horizontal (energy) scales. With a slight modification, the program will accept data printouts from scalers or analog to digital converters. The program also includes a feature for integrating the energy peaks obtained by pulse height analysis.

Jan 1, 1970

By Albert J. Forney

A process for the manufacture of high-Btu gas from coal has been developed by the Bureau of Mines. The process consists of fluid-bed gasification of the coal, followed by the gas treatment steps of gas purification and methanation. Advantages of the system are that caking coals can be used directly, and more than half of the ultimate methane is made in the gasifier.

Jan 1, 1970

By K. Thirumalai

This study forms a part of Bureau of Mines continuing research on thermal fragmentation of rocks. The potential of internal heating techniques for rock fragmentation is discussed. A concept of rock fragmentation with rapid inter¬nal heating of a localized inner volume of rock is advanced The energy required for rock fragmentation is made available by creating a required vol¬ume of localized heating. The fragmentation of rock using the proposed method is analyzed and qualitatively compared with the results of experiments with Charcoal granite, Dresser basalt, and Sioux Quartzite. High frequency dielec¬tric heating below 100 MHz is used in the study as an example to examine the working of the concept. The selection of operating conditions for the experi¬mental heating is explained. Fragmentation of Charcoal granite and Dresser basalt test rock blocks is achieved for localized heating below 550° C. The heated volume required for fragmentation is observed to be less than 2 percent of the test block volume and the electrical energy consumption is in the order of 3.5 to 6 5 kwhr/m3 The method offers a possibility for in situ fragmenta¬tion of rocks, favorable for internal heating. The method is highly dependent on rock properties governing internal heat generation The efficiency of dielectric heating in the experimental study is observed to increase with increasing dielectric loss of the rock material, ranging from about 10 percent in Sioux. Quartzite to about 50 percent in Dresses basalt

Jan 1, 1970

By L. C. George

Addition of an acid waste to an alkaline cyanide waste was investigated for five different combinations of electroplating wastes. At the optimum final pH values of the mixtures, metals and cyanides were almost quantita¬tively precipitated. No evolution of hydrogen cyanide was detected by a few additional processing steps, significant amounts of variable metals were recovered for recycling the waste-plus-Waste step is attractive because no reagents are required, metals arc concentrated, and a relatively harmless effluent that meets most water quality Standards for cyanide content is produced.

Jan 1, 1970

By S. Akhtar

Interstitial compounds of iron, cobalt, and nickel, and their binary and ternary mixtures with silver, gold, palladium, and platinum were prepared and tested as fuel cell catalysts. The first step in the preparation of the interstitial compounds consisted of preparing finely divided metals. This was done either by the Raney method or by reduction of precipitated hydroxides of the metals. The finely divided reduced metals were then treated with carbon-and/or nitrogen-containing gases to prepare their carbides, nitrides, and nitrocarbides. The materials were tested for cathodic activity towards O2 and for anodic activity towards H2, C3H8, NH3, CO, and N2H4 in acid and alkaline electrolytes at 25° to 90° C in half-cell assemblies. Samples of carbided and nitrocarbided INi-lAg-1Au were about one fifth as active as Pt-black in the reduction of O2 in 35 percent KOH solution, whereas the activities of several interstitial preparations exceeded the activity of Pt-black in the reduction of O2 in 12M KOH containing N2H4. Nitrocarbides of x-Fe2C, 3Ni-1Au, and 1Ni-3Au were effective catalysts for oxidizing N2H4 in liquid NH3 containing NH4SCN. Corrosion of the catalysts by electrolytes was severe in many cases.

Jan 1, 1970

By Richard L. Fischer

Constant-volume charges of precipitated PETN (pentaeythrite tetranitrate) at three specific gravities (0.50, 1.00, and 1.50) were used in laboratory tests to examine the effects of changes in explosive properties on free-surface displacement pulses and on crater dimensions. The tests were performed in large blocks of cement-mortar. The values for the detonation velocity, detonation pressure, specific energy, energy density, and energy release rate were calculated from the explosive loading density. Calculated explosive properties were correlated with free-surface displacement pulse measurements, strain energy, and measured crater dimensions. Increases in explosive properties resulted in increased free-surface displacement pulse parameters and crater dimensions. The loading density, detonation velocity, energy density, detonation pressure, and energy release rate were found to be best indicators of explosive performance. Simple acoustic relationships involving impedance ratios were examined and could not be used to predict peak displacement amplitude or strain energy. Data are presented in the customary English units as well as the International System of Units (SI).

Jan 1, 1970

By R D. Fleming

A single-cylinder research engine was operated on pure hydrocarbons and simple (two-component) mixtures of pure hydrocarbons to study the effect of fuel composition on exhaust emissions from a spark-ignition engine. Used as fuels were three pure hydrocarbons that represented the primary hydrocarbon types present in commercial motor fuels: A paraffin (2,2,4-trimethylpentane), an olefin (2,4,4-trimethylpentene-2), and an aromatic (meta-xylene). The engine was operated at the same equivalence ratio for all of the fuels used in the experiment. Exhaust gas samples were collected and quantitatively analyzed for carbon monoxide, carbon dioxide, hydrogen, nitrogen oxides, aldehydes, and hydrocarbons. Exhaust hydrocarbons were separated and quantitatively measured with a chromatographic system employing a flame-ionization detector. Unknown hydrocarbons and oxygenated materials in the exhaust were identified with a Time-of-Flight mass spectrometer coupled to a chromatographic system. The results of the exhaust gas analyses showed that ethylbenzene, l-methyl-3-ethylbenzene, and l-methyl-3-vinylbenzene were more abundant in the exhausts from either 2,2,4-trimethylpentane--m-xylene or 2,4,4-trimethylpentene-2--m-xylene fuel mixtures than in exhaust produced from m-xylene. Also, the pure 2,4,4-trimethylpentene-2 fuel produced smaller amounts of C2 to C7 olefins in the exhaust than that produced by the pure 2,2,4-trimethylpentane fuel. The exhaust from pure m-xylene fuel contained aromatic hydrocarbons of higher molecular weight than the parent fuel. The amount of total hydrocarbon (moles of exhaust hydrocarbon per mole of fuel used) in the exhaust from the three pure fuels decreased in the following order: 2,2,4-trimethylpentane > 2,4,4-trimethylpentene-2 > m-xylene. The hydrocarbon mole-fractions of unreacted fuel in the exhausts produced from each of the pure fuels were 0.20 for 2,2,4-trimethylpentane, 0.13 for 2,4,4-trimethylpentene-2, and 0.66 for m-xylene.

Jan 1, 1970

By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By Victor R. Spironello

Applications of three experimental design techniques to smelting operations are explained. The report describes a factorial design using three variables at two levels, a fractional factorial design which investigates seven variables, and response-surface methodology for optimization of electric- furnace smelting processes. These methods may be applied with a minimum of trials and at little expense. Further, the writer knows of no reasons why the same methods could not be applied to other operations as well, such as steelmaking.

Jan 1, 1970

By John R. Zelonka

Models made by encasing strain-gage networks in epoxy are described and evaluated. With this technique relatively complex models can be constructed in which any number of gages can be located and alined precisely. Although the gages are an integral part of the model matrix, they create no important mechanical or thermal stresses. Model construction techniques and experimental data proved reproducible and reliable. In addition, the sGlution obtained with these models to the problem of the state of stress around a circular hole in a plate subject to a plane stress condition was in agreement with theoretical, photoelastic, and finite-element solutions.

Jan 1, 1970

By James H. Russell

Alkalized alumina (an active form of sodium aluminate) has been considered as a sorbent for the removal of sulfur dioxide from industrial flue gases. Four rate equations, each based on a different mechanism, were compared with the results of thin-bed sorption tests. It was found that each equation agreed with the experimental results, within experimental variance, over most of the range of sorption studied. First-order rate equations were generally satisfactory in explaining both sorption and regeneration. It is concluded that the equations developed are adequate for the design of commercial fluidized beds for the sorption of SO2 from industrial flue gases and regeneration of the alkalized alumina.

Jan 1, 1970