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By Harold W. Lipper

BUREAU OF MINES helium plants produced a. record-breaking 477 million cubic feet of this essential element in 1959. The supply of helium was less than the demand before operations were resumed at the Navajo plant in July and begun Sit a. new plant at Keyes, Okla., in August. Helium was in abundant supply after August, and the informal allocation system which had been in use intermittently since 1955 was discontinued Delivery of 26 new tank cars in August and September increased the total in the tank-car pool to 163. Defense and space agencies and the Atomic Energy Commission continued to use more helium in their operations and research.

Jan 1, 1960

By T. A. Henrie

The Federal Bureau of Mines has investigated methods of sodium reduction of titanium chlorides to produce high purity titanium metal (14).4/ This investigation was made to obtain a better understanding of the reactions involved in sodium reduction of titanium chlorides and was part of the Bureau's activities toward improving the technology of titanium. Theoretical and experimental evidence show that sodium reduction of titanium tetrachloride occurs by stepwise reactions. The first stage reduction between sodium vapor and vapors of titanium chlorides produces titanium di-and trichlorides which subsequently condense with sodium chloride to form a salt mixture. The second stage reduction takes place in the condensed salt mixture between sodium and titanium subchlorides. Final reduction is a heterogeneous reaction between two separate phases, the a phase which consisted of sodium dissolved in sodium chloride and the ß phase titanium subchlorides dissolved in sodium chloride. The mechanism of the heterogeneous reaction between these phases is electrochemical in nature. The model proposed is a galvanic reaction at the interfacial region.

Jan 1, 1960

By I. Iwasaki

In recent years the rapid depletion of high-grade iron ores and the demand by blast furnace operators for increasingly low-silica ores have stimulated interest in flotation studies of low-grade iron ores, such as wash-ore tailings and oxidized taconites. Four processes have been reported for the flotation separation of these iron ores--anionic and cationic collection of the iron oxides, cationic collection of siliceous gangue, and anionic collection of activated siliceous gangue (5).5/ The effectiveness of any one method, however, depends largely on the mineralogical composition and on the physical structure of the sample; hence, a comprehensive study of the floatability of the individual minerals occurring in these materials is essential. A review of the literature shows that the floatability of hematite and magnetite has been frequently investigated, whereas very little corresponding information is available for goethite, or for its more earthy form, limonite, both of which are abundant in the Mesabi and Cuyuna ores (19). The purpose of this investigation was to formulate general information on the floatability of goethite. Vacuum flotation, contact angle measurement, and simplified flotation tests using a modified Hallimond tube were used. The experimental results were correlated with the electrokinetic properties of goethite as determined by streaming potential measurement. The results were used to interpret the batch flotation tests made on an artificial mixture of quartz and goethite.

Jan 1, 1960

By A. L. Engel

This report describes laboratory-scale experimental treatment of six base-metal ore samples taken by engineers of the Bureau of Mines, Region II, while investigating ore deposits in California and Nevada. The information is of interest in developing the mining districts represented or when similar ores from other sources are being studied. Simple treatment methods were employed as far as possible. More complex treatments also were tried when necessary. The possibilities and limitations of the methods applied to the several ores are shown by the data herein reported.

Jan 1, 1960

By J. S. Tosh

The Federal Bureau of Mines has investigated the equilibrium of the system potassium carbonate (K2C03) potassium bicarbonate (KHCO3) potassium bisulfide (KHS) carbon dioxide (C02) hydrogen sulfide (H2S) water (H20). Partial pressures of hydrogen sulfide, carbon dioxide, and water vapor were measured at 70° to 130° C. over solutions of 20-, 30-, and 40-percent-equivalent potassium carbonate containing from 20 to 3,000 grains of equivalent hydrogen sulfide per gallon of solution. This study was made to obtain equilibrium data for evaluating the feasibility of using solutions of hot potassium carbonate for removing, hydrogen sulfide from gas mixtures. The equilibrium partial pressure of hydrogen sulfide may be correlated with the ratio of the molal concentrations of the solutes (KHC03) (KHS)/ (K2CO3). The relationship is shown graphically for the 30- and 40-percent solutions. Once this ratio is determined, the partial pressure of hydrogen sulfide can be obtained from the curves. The equilibrium data show that effective removal of both carbon dioxide and hydrogen sulfide can be achieved simultaneously with hot solutions of potassium carbonate.

Jan 1, 1960

The first metal-mine accident-prevention course was prepared and published in 1942-45 as a series of seven miners' circulars (Nos. 51-57). The course has been broadened in scope, revised, and brought up to date and is being published as a similar series of seven miners' circulars (Nos. 51-57, revised) on accident prevention in metal and non-metallic mines. These circulars are as follows: Injury Statistics (Miners' Circular 51), dealing with general statistics on injuries from accidents at metal and nonmetallic mines, including causes, costs, and the use of investigations and reports of all injuries.

Jan 1, 1960

By D. D. Walker

Scheelite, the most abundant tungsten mineral in the Philipsburg region of Montana, is found in replacement deposits and along fissures and cracks in limestone at various distances from contacts with acidic igneous rocks. It also occurs at the limestone-igneous contacts, but typical garnet tactites are developed in only a few places in the region. The most favorable host rocks for scheelite mineralization are the Jefferson, Hasmark, and Madison limestones. Scheelite is exposed in float, outcrops, and surface and mine workings along a 2-mile-wide belt extending southwest from Lost Creek beyond Silver Lake, a distance of 15 miles or more. (See fig. 1.) Some scheelite is found in veins formerly mined for silver. Powellite and molybdenite occasionally are present with the scheelite. Hubnerite occurs in quartz veins in the Black Pine area 10 miles northwest of Philipsburg. These quartz veins occur in the quartzites of the Precambrian Spokane formation. Tungsten production in the region has come almost exclusively from scheelite deposits, both lode and placer. During a 6-year period beginning in 1943 a total of 142.0 tons of 63-percent W03 concentrate was produced by H & H Mines Co. In the early 1950's, the Trigger mine produced 4,000 tons of 1-percent W03 ore and the Tip Top 650 tons of 2.0-percent W03 ore and 2,906 tons of 2.2-percent ore. There has been sporadic production from some of the smaller properties in the area.

Jan 1, 1960

By M. M. Gilkey

Pegmatites in Colorado occur for 150 miles along the Front Range (eastern-most range of the Rocky Mountains) from Larimer County on the north to Canon City on the south, and west into the Gunnison area. Many of the deposits have been classified. Minerals found in the various dikes include beryl, scrap and possibly punch mica, lithium-bearing minerals, columbite-tantalite, feldspar, and several rare minerals. Pegmatites are abundant in the Crystal Mountain district in Larimer County. About 5 miles south of the Crystal Mountain district and often identified with that district is the Hyatt pegmatite area. The Hyatt Ranch deposit has attracted particular attention because of the comparatively high beryl con-tent of the upper part exposed in opencut workings.

Jan 1, 1960

By James S. Browning

Heavy liquids have been used to separate minerals of different specific gravities for many years.4 5 6 7 8 9/ The method permits substantially quantitative evaluation of a variety of minerals and requires much less time than the usual methods of chemical analysis. This Bureau of Mines investigation was conducted to determine the applicability of heavy liquid mineral separation to the evaluation of certain spodumene and kyanite ores, prepared mixtures, and plant products. After careful standardization of the particular mineral and associated gangue, estimates of chemical analyses could be obtained from results of heavy liquid separations.

Jan 1, 1960

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

By D. E. Ingersoll

This report describes the preparation characteristics of anthracite from the Mammoth and Holmes veins in Schuylkill County, Pa., as determined by the Federal Bureau of Mines laboratory separations at specific gravities of 1.50 to 1.90. The Holmes vein anthracite contains approximately 13 percent ash, and the Mammoth vein contains about 9 percent as fed to the breaker. Crushing Broken, Egg, and Stove sizes from each vein produces Pea-size anthracite of lower ash content than that contained in Buckwheat No.1 size and smaller. The Buck-wheat No.5 size has the highest ash content of all the sizes examined. Potential recovery from a mixture of the two veins as received at the breaker, separated at 1.90 specific gravity, is approximately 64 percent of the feed at 11.0 percent ash. The same materials separated at 1.80 specific gravity yield about 61 percent with an ash content of 10.1 percent. All rejects are from the Holmes vein, because the entire Mammoth material is less than 10.0 percent ash.

Jan 1, 1960

By J. D. Ramsdell

The purpose of this investigation was to determine the effects of the impurities, oxygen, nitrogen, carbon, and iron (in low percentages) on the mechanical properties of electrolytic titanium. The strength and hardness of binary Ti-O, Ti-N, and Ti-C alloys are linear functions of alloy content in the composition range investigated. Compared to oxygen and carbon, nitro-gen is the most effective strengthener and hardener, followed by oxygen, then carbon. When the carbon concentration is above 0.10 percent, carbides are present, and strength and hardness are relatively unchanged. For equivalent hardness levels, Ti-Fe alloys are stronger than binary titanium alloys containing oxygen, nitrogen, or carbon. However, the strengthening is related to the presence of transformed beta in the structure.

Jan 1, 1960

By D. E. Redmon

Exploration of hidden mineral deposits becomes increasingly important as known ore reserves are depleted. The primary objective in any exploratory program is to obtain enough reliable information to evaluate accurately the potential of the mineral deposit. Constant improvement in equipment and technique has established drilling as one of the most valuable methods of exploration. This paper presents the results of studies of several drilling methods currently used in the search for uranium deposits in sedimentary formations from surface drill sites. Also presented is a description of drilling with wire-line equipment from an underground location in metamorphic rocks. The studies were conducted in the Colorado Plateau area and in northwestern New Mexico and Wyoming. Statements of a general nature pertain to conditions or situations existent in those areas.

Jan 1, 1960

By D. C. Fleck

This report describes a method of using sodium for reducing titanium tetrachloride, developed at Boulder City, Nev., as part of the Federal Bureau of Mines effort to improve the extractive metallurgy of titanium. Finely divided titanium metal, titanium lower chlorides, or a mixture thereof was produced in a continuous operation at temperatures between 105° and 205° C. by the reaction of molten sodium and vaporized titanium tetra-chloride in an agitated bed of finely divided inert solids (powdered sodium chloride or the reaction products). Composition of the product was controlled by varying the relative quantities of sodium and titanium tetrachloride used. A description of the operations and analytical data of the reaction products are given.

Jan 1, 1960

By R. V. Higgins

Tarner (1),3/ Muskat (2), and Schilthuis (1) have presented methods of calculating oil recovery by the expansion of dissolved gas with and without return of gas to the reservoir. Although electronic computers have eliminated the tedious and time-consuming calculations (4) required by each of these methods, many petroleum engineers do not have access to electronic computers. For these engineers a short method is presented that uses the Tarner method as a base. Moreover, for engineers who have access to computers and have not as yet prepared a program, the short Tamer method requires less computer time than the long iterative methods. In the proposed short method, no plotting of the calculated data is required to determine a point of intersection described in the original Tarner presentation, as only one calculation is needed to determine the value sought, or two calculations if greater accuracy is desired.

Jan 1, 1960

By R. L. Montgomery

Heats of solution of yttrium chloride and oxide in hydrochloric acid were measured by Bureau of Mines researchers. Using the heat of combustion of yttrium mentioned in the literature, the Bureau calculated the heat of formation of yttrium chloride to be -239.16 + 0.50 kcal./mole. The Bureau experiments gave evidence that the heats of solution of yttrium chloride from the literature are mostly too low because of water and/or oxychloride impurities. Heat of combustion of yttrium (8)3/ and its heat of solution in hydrochloric acid (2, 14) have been measured. The earlier heat of solution measurement (2) is unreliable because of possible potassium contamination (4). Heat of solution of yttrium chloride has been measured by three researchers (3, 9, 15), who obtained widely different results. Spedding and Flynn (14) report the heat of formation of yttrium chloride as -232.69 kcal./mole from their solution studies. The present work was designed to check the reported heats of solution of yttrium chloride and to determine the heat of solution of yttrium oxide. The latter measurement would allow the results of solution and combustion data for yttrium to be intercompared.

Jan 1, 1960

By F. E. Block

This investigation was made as part of a larger program to develop basically new methods for preparing yttrium metal in high-purity form. It was performed under a cooperative agreement between the U.S. Atomic Energy Commission (AEC) and the Federal Bureau of Mines. Laboratory-scale tests were made to devise methods for preparing high-purity, anhydrous yttrium trichloride, for reducing the yttrium trichloride with sodium or lithium, and for consolidating the resulting yttrium sponge into ingots.

Jan 1, 1960

By C. M. McKinney

Bureau of Mines routine crude-oil analyses of 42 samples from 37 fields in the major producing areas in Mexico are presented in this report. Table 1 includes information on the source and general characteristics of each sample. Table 2 gives a summary of analytical and computed data. A map (fig. 1) shows approximately where the samples were obtained. ACKNOWLEDGMENTS Grateful acknowledgment is made to Alfonso Barnetche, manager of production, and Ing. Francisco Inguanzo, assistant manager of production, both of Petroleos Mexicanos, who supplied the crude-oil samples and furnished information concerning their sources.

Jan 1, 1960

By W. T. Wertman

LABORATORY research has been started at the Bureau of Mines Morgantown Petroleum Research Laboratory, Morgantown, Va., to investigate the possibilities thermal-recovery methods for producing crude oils of high API gravity found in oil reservoirs of the eastern United States. This bibliography on thermal methods of oil recovery was compiled as a part of the work. Crude oil discoveries to December 31, 1958, in the United States were estimated to exceed 270 billion barrels. Cumulative production of crude oil through 19.55 was about 60 billion barrels, and the American Petroleum Institute estimates that an additional 30.5 billion barrels are economically recoverable by present methods. On this basis, about two-thirds of the oil that has already been found can be classified as economically unrecoverable for lack of a satisfactory method. The rap icily rising costs of proving new deposit; of domestic petroleum, the lack of new discoveries of large oilfields in the united States, and I he growing demand for crude oil have caused an acceleration of research to develop new or improved methods fur producing "unrecoverable" oil in known reservoirs.

Jan 1, 1960

By R. W. Stahl

Increasing use of continuous miners, especially the boring type, has focused attention on the inadequacy of face ventilation in coal mines. The bulk of the machine, the rapid advance of working faces, and the increased liberation of methane from the larger expanse of freshly exposed coal surfaces have created ventilation problems that were unknown with conventional mining equipment. Ignition of gas, especially that caused by machine bits striking hard rock or pyritic inclusions, have increased at an alarming rate. As the mines penetrate beds under thicker cover at an ever-increasing rate of face advance, this problem will probably increase unless face ventilation is improved. A previous survey, described in Bureau of Mines Report of Investigations 5414, Auxiliary Ventilation of Continuous Miner Places, disclosed that auxiliary fans with tubing generally improved circulation of air and removal of gas at the face. The study here reported attempts to examine, face ventilation at various mines and to note any plan or innovation of. air coursing that industry might adopt to reduce the danger of gas ignition. ACKNOWLEDGMENT The mines visited were very cooperative in the study-and-generously supplied any data requested.

Jan 1, 1960