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By K. G. Matshika

"Nickel electroplating from sulphate electrolyte is an efficient process. To achieve good quality cathode, however, parameters such as temperature, nickel concentration, pH, electrode alignment, electrolyte flowrate and additives must be optimised, because these affect cathode morphology and current efficiency. It is also important to control the clarity and contamination of the electrolyte, as these have a considerable effect on the quality of the cathode surface. Delamination, surface roughness and pitting on the cathode surface can be caused by incorporation of solid particles or impurities form the electrolyte. Three types of solid particles were investigated: cuprous selenide, barium/ lead sulphate (co-precipitated) and ferric hydroxide. These particles can be found in industrial electrolytes, especially if there is a problem with the filtration step or contaminants have reacted to form insoluble particles. A rotating cylinder Hull cell was used for this investigation. It is found that the effects on morphology depend on the type of solid, concentration, particle size, current density and electrolyte flowrate. Cuprous selenide is the most detrimental, especially at higher concentrations, higher current densities and low flowrates. Increased rotational speed offers a uniform sheet of fine gas bubbles across the surface of the cathode which reduces the thickness of the diffusion layer of liquid adjacent to the cathode and increases the rate of mass transport to the cathode from the bulk liquid. INTRODUCTION Electrowinning operations are important when recovering associated by-products of nickel production, such as copper, cobalt and zinc, from pressure leach solutions. The base metal mineralization associated with platinum-group metal (PGM) production yields significant quantities of copper and nickel as by-products. The base metal refinery is vital in PGM processing as it increases the PGM concentration from mined ore by a factor of 400, in comparison with concentration by flotation (20 times) and pyrometallurgical processing (20 times) (Crundwell et al., 2011). Anglo American Platinum Ltd produces nickel cathodes by electrowinning and purges sodium from the base metal refinery in the form of sodium sulphate at the Rustenburg Base Metals Refinery (RBMR), as shown in Figure 1. This is the Sherritt acid leach process used in most base metal refineries to ensure no loss of PGMs and shows the subsequent purification steps for copper and nickel. Other refineries in Zimbabwe, such as Bindura and Empress, use the Outokumpu leach process (Pavlides, 2001)."

Jan 1, 2015

By J. A. Wates

Stope backfilling in South African gold mines uses the coarser cyclone fraction of the gold tailings. The disposal of the overflow from the cyclones, which is finer and of higher moisture content than normal gold tailings, presents some problems. This paper describes an investigation undertaken to define the parameters that are required for a quantitative and qualitative assessment of the operation and stability of slimes dams built of such material. However, seeing the investigation was conducted on the slimes from only one mine, it is recommended that, until a wider range of data becomes available, tests should be conducted for each individual mine.

Jan 1, 1988

By B. Z. Weiss, N. R. Comins, F. Blum

Some aspects of the mechanical behaviour of chromium-containing dual-phase 3CR12 steel were investigated as a function of the temperature and strain rate. The yield stress was found to depend on both the temperature and the strain rate, with no substantial differences between the longitudinal and the transverse directions. The strain-rate sensitivity decreased with increasing temperature. The yield stress could be presented as a function of a temperature-strain-rate parameter. Impact test results showed substantial differences between the energy absorption of the transverse and longitudinal specimens above the ductile-brittle transition temperature. Changes in energy absorption with temperature were gradual for specimens in both orientations, and the transition from ductile to brittle behaviour occurred between 373 and 173 K. Strain rates ahead of the tip of notches with different geometries were calculated and measured experimentally.

Jan 1, 1990

By S. S. Makgato

In this study, coke oven tar additions over a range of 0?8 wt.% were evaluated as a possible substitute for imported coal fractions. The coke oven tar used was collected from tar decanters in the byproducts section of the coking plant. The moisture content in the tar varied depending on the residence time and water carryover from the coke oven tar separators to the storage tanks. Moisture contents of 1 wt.%, 3 wt.%, and 6 wt.% were investigated in order to evaluate the effect on coal blend, carbonization, and coke properties. At 6 wt.% moisture content with 6 wt.% coke oven tar, although the coke quality improved the yield showed a 4% decrease. On the other hand, 1 wt.% moisture content with coke oven tar of 6 wt.%, increased the yield by 1% and the coke quality improved. However, the latter process was characterized by an excessive increase in wall pressure and pushing energy, both of which are detrimental to the oven walls. The optimum moisture content in coke oven tar was found to be 3 wt.% with a coke oven tar addition of 6 wt.% in the coal blend. With these conditions, the coke properties improved and wall pressure and pushing energy were acceptable. However, a decrease in coke yield of up to 2% was observed. Despite this, coke oven tar addition is considered to be a viable option based upon economic factors of a reduction in the quantity and cost of imported coking coals that is required to achieve the same optimum final coke product. Keywords coal substitution, coke oven tar, tar moisture, coal blend, coke, coke quality.

Nov 1, 2013

In the investigation described here, it was found that the main effect of temperature is on the rate of flotation, and that adsorption of the reagent is not rate controlling. Above 10°C, the flotation rate of pyrite and gangue increases almost exponentially with a rise in temperature. Below that temperature, the flotation rate of pyrite shows a sudden marked decrease, that of gangue increases, and the sulphur grades are significantly poorer. In the flotation of pyrite, the mass transfer of the pyrite from the pulp to the troth is thought to be the ratecontrolling step, whereas the flotation of gangue is controlled by the combined effect of the stability and velocity of the froth and the viscosity of the elutriating medium. The latter is probably the controlling effect at temperatures below 10°C. Little difference was noted in the recoveries (provided no time limit was set) with changes in temperature; hence adequate recoveries can be obtained at Iow temperatures by the introduction of longer residence times for the pulp. The adverse effects of Iow temperatures on grades can be overcome only by additional cleaning or by heating of the pulp.

Jan 1, 1984

By G. A. Slabbert

The paper describes work undertaken to identify the influence of the matrix structure on the metal dusting rate of stainless steel alloys. Specifically, the difference in metal dusting rate between austenitic and ferritic stainless steels of similar chromium contents was investigated. The alloys were exposed to metal dusting conditions and their performance compared by weight loss, optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman spectroscopy. The specific gas mixture used for all the tests were 18.9% CO-79.1% H2-2% H2O at 650°C. For austenitic stainless steels, Types 304, 321, 316, and 316Ti were compared to two ferritic grades, namely Types 430 and 441. The resistance of the ferritic grades was found to be significantly better than that of the austenitic grades. This was attributed to greater permeability of chromium through the matrix structure to maintain the protective oxide scale. The results will be used in the development of novel alloys to combat metal dusting.

Jan 1, 2013

By M. Rudolph, J. Sygusch

Froth flotation is well-established and efficient in the selective separation of valuable particles from unwanted material with sizes ranging from 10 μm to 200 μm. However, when it comes to the separation of ultrafine particles (< 10 μm) there are still some challenges, or rather opportunities. This research aims at developing a method for the separation of ultrafine particles based on multiple particle properties. Amongst such properties are wettability, morphology (shape or roughness) and size with applications not only in mineral processing but in general chemical engineering. In this study, three differently shaped fractions are used as valuables for testing: spherical particles, elongated particles and irregularly shaped particle fragments; together with ultrafine magnetite as the gangue material, in order to investigate the effect of particle morphology on ultrafine particle flotation, as well as wettability, which is varied by esterification using alcohols. Flotation tests are carried out using a novel flotation device that was designed especially for the flotation of ultrafine particles, combining advantages from machine-type froth flotation and column flotation. The results showed that, in contrast to previous studies, recoveries for ultrafine spheres were higher than for ultrafine fragments for all wettability conditions, and hydrophobisation generally increased particle recoveries for said morphologies. Tests using fibres showed different behaviour as hydrophobisation had negative effects on their recovery, despite increased selectivities and kinetics. These findings suggest that apart from influences of particle properties within the suspension zone, their effects on the froth characteristics should be studied in more depth. Keywords: Ultrafine particles, Flotation, Particle shape, Wettability, Esterification of glass, Hydrophobisation

Jan 1, 2020

By E. V. Lilford

The South African Minerals Development Act (?the Act?) has been promulgated and will come into full force and effect once it is gazetted. Thereafter, all Old Order mineral rights will have to be converted into New Order mineral rights within a 5-year period, probably by the end of 2008. The conversion of rights will be achieved only with the demonstrated inclusion of empowerment groups in the conversion applications. In addition to the Act, the first draft of the proposed Royalty Bill (?the Bill?) was released during the week beginning 17 March 2003. Comments on the Bill?s contents had to be submitted before 30 April 2003. The contents were to be considered in terms of applicability and acceptability to the South African minerals industry, where after proposed comments and suggested amendments were to be submitted to the relevant State Treasury office. Specifically referring to the Bill, the general response from the industry is one of concern. Since any royalty is tantamount to a tax, the general feeling is that the current mining taxation rates are already internationally competitive and to increase these effective rates, notably at differing rates depending on commodity type, will have an adverse impact on the South African mining industry. A number of these impacts can be mitigated to some degree, depending on the flexibility of the State to address the major concerns.

Jan 1, 2003

By P. R. Jochens, D. D. Howat, A. A. Hejja

The effect of the reactivity of lime on desulphurization efficiency in the basic oxygen furnace A. A. HEJJA, Dipl. Ing. (Budapest) (Visitor) D. D. HOWAT, B.Sc. (Glas.), Ph. D., F.I.M. (Fellow) P. R. JOCHENS, Pr.Eng., M.Sc. (Eng.) Rand, Ph.D., A.I.M. (Member) The iron charged to the basic oxygen furnace at the steel plant of Highveld Steel and Vanadium Corporation has a relatively high sulphur content. Considerable emphasis is therefore placed on the reactivity of the lime. An investigation of the lime used at the steel plant showed that its reactivity had deteriorated considerably both during transport from the supplier (Northern Lime Company) and during storage and handling at the steel plant. The deterioration on the steel plant is the more severe, and is due to hydration and carbonation. Rapid deterioration is a characteristic of highly reactive lime when exposed to the atmosphere. Plant tests showed that the desulphurization efficiency decreases with a decrease in the reactivity of the lime. The addition of slag rich in manganous oxide to the furnace considerably improved the efficiency of desulphurization that can be achieved with limes of lower reactivity and with lime that has deteriorated. A decrease in particle size of lime of lower reactivity greatly increased the desulphurization efficiency. Less lime of higher reactivity is required for the same degree of desulphurization to be achieved. Lime of higher reactivity gives rise to slags with lower ferrous oxide contents and hence the steel yield is increased.

By P. R. Jochens, A. A. Hejja

The effect of the reactivity of lime on desulphurization efficiency in the basic oxygen furnace by A. A. HEJJA,D. D. HOWAT, andP.R.jOCHENS Published in the Journal March 1973. DISCUSSION R. E. Leyman* The authors discuss in detail the effects of transport and storage at the steel plant on the reactivity of lime as measured by the DIN Reactivity Test. They attribute the deterioration in reactivity to the absorption of water vapour and carbon dioxide, but make no mention of the possible role of atmospheric sulphur dioxide in this respect. The significance of the mineralogical and surface characteristics of gold grains in the recovery process by C. E FEATHER and G. M. KOEN Published in the Journal February 1973. AUTHORS&apos; REPLY TO DISCUSSION (Published in the Journal July 1973) H. P. Carlisle Mr Carlisle&apos;s questions and observations will be dealt with in the same order as they were raised. 1. How were the mass percentages of the grains determined from the sizes measured in polished section?

Jan 3, 1973

By M. Le Roux

The dewatering of coal, and particularly fine coal, continues to challenge coal prepatration engineers to find a cost-effective solution. With known world oil reserves being depleted daily, it is envisaged that the future price of coal may justify the use of thermal drying to achieve lower coal product moisture levels. The effect of exposure of the coal to elevated toemperatures on the mechanical strength of the coal was investigated. It was found that temperature does not play a major role in determining the volume breakage of a particle and that other variables such as orientation during impact has a much greater influence. A double breakage mechanism was reported during the grindability tests. Surface, as well as volume breakage, occurs for the first 4 minutes while only surface breakage takes place thereafter. Due to this double breakage action, it was found that exposure to temperature does play a role in the amount of breakage and breakage rates during grindability tests. It was also concluded that a particle will break to an optimum size due to impact, after which only its surface will grind away as it is subjected to breakage forces.

Jan 1, 2008

By A. R. L. Thoresson, S. J. Lennon, F. P. A. Robinson

This paper reports and discusses experimental work carried out on heavy nickel-electroplated turbine-disc steel. Mechanical and fatigue tests were used to determine whether the coating was suitable for turbine-disc applications. It was concluded that dehydrogenation treatment is necessary in order to produce compatibility of the coating and substrate

Jan 1, 1988

By M. Rudolph, A. van Hall, G. Öktem, S. G. Özkan, A. Hassanzadeh

Despite the four-decade study on ultrasound’s (US) impact on mineral’s floatabilities, there is still not clarity regarding its role in mineral surface wettability. For this purpose, the present investigation endeavours ……the hydrophobicity and floatability characteristics of a chalcopyrite-pyrite-quartz (Cp- Py-Qtz) system in the presence and absence of an ultrasonic pre-treatment. The ultrasonic process was carried out by a sonopuls at a constant frequency of 20 kHz with an adjustable power level from 30 to 200 W. Initially, the impact of sonication time (15, 30, 45, 60 and 90 s as well as 10, 20 and 30 min) and power magnitude (30, 60, 90, 120 and 180 W) were evaluated while the dissolved oxygen, temperature, conductivity and pH were also monitored. Collector-less micro-flotation tests were carried out on the non-pre-treated and the US pre-treated samples at 60 W and 15 s. The samples’ hydrophobicities were determined by the drop shape analysis approach. The dissolved-oxygen level was varied using a mini bench pressurised water reactor to study the effect of O2(aq) concentration on the chalcopyrite and pyrite wettability characteristics. The results showed that the minerals’ hydrophilicities were relatively more sensitive to the sonication’s time than its power that resulted in reducing all three minerals’ hydrophobicities. In addition, it was found that the dissolved-oxygen content and creation of sub-micron sized bubbles led to an improvement on chalcopyrite and pyrite hydrophobicities. Finally, we proved that the Cp’s floatability increased and Qtz’s recovery reduced while being subjected to the ultrasonic irradiation (15 s at 60 W); however, Py’s recovery remained constant. This conclusion confirmed the possibility of a selective separation in ultrasound-assisted copper ore flotation. We recommend that further advanced investigations be conducted, using an X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) to thoroughly understand the surface modifications induced by the ultrasonication

Jan 1, 2020

By D. E. Ng?andu

The experience of Mufulira concentrator, of the Zambia Consolidated Copper Mines Limited, with underground mine drainage water, which is used in milling operations is discussed. It is shown that the underground mine water has a deleterious effect on flotation performance. The adverse effect of the underground water was successfully negated by adding lime into the primary ball mills and increasing the pH of the slurry, from a ?natural? pH of 8 to the flotation pH of 10.5. Traditionally, the pH modifier, quicklime, had been added downstream of the milling. Changing the lime addition point further reduced lime consumption by 50%,?a key issue as lime accounted for over 60% of the Mufulira flotation reagent costs. The nature of the effect of the underground water at Mufulira, particularly the sensitivity of the flotation to the pH at which the milling was conducted, characterized galvanic interaction. A large-scale plant situation is presented in which the desired electro-chemical response in the flotation was achieved, by a deliberate manipulation of the milling environment. The experience provides practical testimony of a more fundamental role for the milling process, other than the mere physical preparation, i.e. size reduction and liberation, of mineral particles prior to flotation.

Jan 1, 2001

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By A. P. Van Wyk, G. Pirnaar

The effect of vanadium on the susceptibilities of chromium and chromium-nickel steels to reversible temper embritlement was evaluated. The steels investigated were approximately equivalent to steels of as 970 Grade 708A42 and as 970 Grade 817M40, the major difference being that molybdenum had been replaced by vanadium in various concentrations. It was found that the vanadium had a detrimental effect and, in al the concentrations tested, enhanced the susceptibility to reversible temper embritlement of both the chromium and the chromium-nickel steel. The detrimental role played by vanadium in reversible temper embritlement is explained by a consideration of the effect of vanadium carbide, as well as of free vanadium, in solid solution in ferrite.

Jan 1, 1987

By J. H. Viljoen, J. F. Morrison, C. H. Wyndham

SYNOPSIS Heart rates, oral temperatures, shovels/min and number of 3/4 ton cars/hour trammed over distances of up to 350 ft were measured in samples of 6-10 miners, engaged in tram-shovelling, at 76°, 84°, 86°, and 89°F wet bulb temperatures in stopes in a mine. From the results it has been concluded that a man with an &apos;average&apos; maximum oxygen intake capacity of about 2. 8 litres/min should be able to work: at 6 shovels/min, or 30 cars/shift per two men, at 76°-84°F; at 5 shovels/min, or 27 cars/shift per two men, at 86°F; and at 4 shovels/min, or 24 cars/shift per two men, at 89°F wet bulb air temperatures. INTRODUCTION A number of gold mines in South Africa still use tram-shovelling extensively. In this method of rock removal from the face of the stope, Bantu mine workers load rock into cars and tram the cars to a centre gulley where they are emptied. Previous studies from this Laboratory3 have shown that tram-shovelling is one of the most arduous tasks underground. The rate of energy expenditure is relatively high, being an oxygen consumption of about 1.4 litres/min over a period of some hours. In cool air conditions the upper limit to the rate of production of the well-motivated men employed on tram-shovelling has been shown1 to depend upon their capacities for physical work of an endurance nature (as measured by their maximum oxygen intakes). However, in hot conditions the factors which set the upper limit to the rate of production are different. They are primarily the ability of the body to maintain a heat balance between the rate of heat production, due to physical work, and the hot atmosphere, so that the men do not develop excessively high body temperatures8. In order to give mine managers guidance on the &apos;optimum&apos; rate of production of Bantu mine workers engaged upon tram-shovelling under different temperature conditions underground a study was carried out in a mine. The number of shovels per minute and cars per hour were recorded and heart rates and oral temperatures were measured throughout the duration of the shift on samples of 6-10 Bantu mine workers in different air conditions. The results of the study are recorded in this paper and conclusions are drawn as to the number of shovels per minute and cars per hour which Bantu mine workers of &apos;average&apos; maximum oxygen intake capacity should be able to produce at wet bulb air temperatures of between 76° and 89°F without either excessive fatigue or danger of heat illness.

By A. C. Mulholland

The electrical control of three-electrode submerged-arc furnaces suffers from a number of complexities, mostly due to the nature of the furnace electrical circuit providing power to the furnace where the three electrodes are interconnected within the furnace through the molten metal bath. This gives rise to what is known as the interaction effect 2, where variations in one electrode?s current can cause comparable changes to the currents in the other electrodes, particularly in larger furnaces with low power factor. Resistance-based control of the electrode penetration has largely alleviated these problems, since the resistance encountered by each electrode is predominantly dictated by the length and conductivity of the current path from the electrode?s tip to the molten metal bath, which acts as the three-phase circuit?s floating neutral point. Hence resistance changes due to tip position or conductivity changes beneath one electrode do not affect the resistances beneath the others, effectively decoupling the control of the individual electrodes1. Although resistance-based control is therefore generally accepted as superior to current-based control for the regulation of submerged-arc furnace electrode penetration, a few furnace operators still prefer to use current control under specific furnace conditions. This paper presents the results of analysing the performance of both current and resistance-based control in typical scenarios encountered on industrial furnaces, taking into account a number of factors including electrode penetration, power distribution, efficiency and asymmetry of the electrode currents. In order to accomplish this, three typically encountered scenarios were simulated. The results obtained show that resistance control provides more benefit in all cases, however, the uneven electrode current distribution generated by resistance control when electrodes are on top stops may cause some concern if baking of the electrodes is required in this scenario.

Jan 1, 2009

By B. Genc

After the explosion at Middelbult Colliery, South Africa in May1993, which claimed 53 lives, the South African Coal Mining Industry and the Safety In Mines Research Advisory Committee (SIMRAC) united forces to establish a surface facility to develop and test on-board flame suppression systems for continuous miners and roadheaders. The first test that was conducted in this newly constructed test tunnel at the Kloppersbos Research Facility, CSIR was in July 1995.Since then 70 tests have been conducted using the facility and have focused on on-board active ignition suppression systems for continuous miners (CM) and road heading (RH) machines to enhance the safety of South African mine workers in collieries. These suppression systems are mounted on the CM or RH machine and detect the occurrence of an ignition by means of light-sensitive sensors. The electronic signal from the sensor triggers the suppression system, creating a flame-suppression curtain, containing and extinguishing the flame in the immediate vicinity of the ignition. Forty-three tests have been conducted with an active on-board suppression system present inside the test tunnel. Since flame propagation speed is an extremely important parameter, the CSIR-Miningtek made the results of the test programme available for re-analysis. Flame speed depended on whether a machine was present in the heading or not, the geometry of the heading and the volume and composition of the explosive mixture of gas. Flame speeds of up to 190 m/s were recorded. However, the active suppression systems were almost always successful in containing flame propagation.

Jan 1, 2002

By P. R. Jochens, D. D. Howat, M. S. Rennie

The slags arising from ferrochromium plants were simulated by additions of CaO and Fe2O3 (6 per cent each), Cr2O3 (7 and 12 per cent), and Fe2O3 and Cr2O3 together (6 and 12 per cent respectively) to slags in the MgO-Al2O3-SiO2 system. These additions were made to slags having an SiO2 content of 45 per cent and an MgO-to-Al2O3 ratio of 4 to 3 or 3 to 4. The effect of these oxide additions on the liquidus temperatures, electrical conductivities, and viscosities was determined. The additions of CaO and Fe2O3, although having little effect on liquidus temperatures, decreased viscosity and increased electrical conductivity. The addition of Cr2O3 raised the liquidus temperatures considerably, and tended to decrease viscosity in the temperature range 1 700 to 1 800°C and to increase electrical conductivity.