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By C. J. Van Niekerk, D. R. Allen

The electrolytic extraction of zinc at the Zinc Corporation of South Africa Limited by C. J. VAN NIEKERK, B.Se. (Hons.)(Poteh.), M.Se. (Unisa)(Fellow) and D. R. ALLEN, A. Met. (Sheffield) (Member) This paper gives a brief account of some modifications that were made to the process of zinc electrowinning practised by the Zinc Corporation of South Africa Limited. Some changes in the materials of construction are also described.

Jan 2, 1977

Results are presented on the elution of gold cyanide and base-metal cyanide complexes from strongand weakbase resins. It is shown that thiocyanate anions, zinc cyanide anions, and thiourea in acid solution are effective eluants of strong-base resins, but that it is generally necessary for electrowinning to be incorporated in the elution cycle if fast rates of elution are to be achieved. Weakbase resins are eluted with sodium hydroxide solution, which is shown to be far simpler and far more effective than the elution of strong-base resins. The effects of parameters such as concentration of the eluant, temperature, and electrowinning efficiency on the rate of elution of the resins are examined.

Jan 1, 1984

One of the main bottlenecks in the carbon-in pulp process for the recovery qf gold is the elution procedure, which typically requires the heading of caustic cyanide eluants to high temperatures for 16 to 24 hours. The present work demonstrates that sodium sulphide solution as an alternative eluant can effect complete elution in about 4 hours at ambient temperatures. Elution efficiencies of around 100 per cent were obtained in 4 hours with a single pass of eluant containing 0,2 M Na2S and 0,4 NaOH about 10 bed-volumes of eluant The initial rate was slow over the first hour of elution, probably because the activated carbon catalysed the oxidation of sulphide to polysulphide. Elution efficiencies of around 100 per cent were also obtained in less than 4 hours during the batch elution of carbon at liquid-to-solid ratio of about 100. Lower liquid to solid ratio resulted in the re-adsorption of gold, probably owing to the oxidation of sulphide to polysulphide, with the resultant formation of gold complexes that were eluted less readily. Improved rates of elution were obtained at higher sulphide concentrations and pH values greater than about 13. Higher temperatures increased the initial elution rate, but lowered the overall extraction efficiency, probably because of the deposition of elemental gold on the carbon. Variation of the ionic strength by the addition of NaCl had no defect on the elution, which confirms that the elution mechanism in the case of sulphide is different from that when cyanide or I1)1droxide is used as the eluant. It is proposed that the elution of gold by sulphide solutions proceeds by means of an initial step that involves the reaction of polysulphide ions with the adsorbed aurocyanide speeds, forming AuCN on the carbon and thiocyanate in solution. This step is followed by the formation of poorly adsorbed complexes with sulphide ions, such as [AUS3-2]-The presence of polysulphides, whether generated in situ by the catalytic oxidation effect of activated carbon or by the addition of elemental sulphur, reduces the elution rate and efficiency dramatically. This is probably due to the formation of complexes such as AUS-3 and AUS-2 , which have a high adsorption affinity.

Jan 1, 1994

By D. Duncanson, R. J. Davidson

The elution of gold from activated carbon using deionized water by R. J. DAVIDSON, M.Sc., Ph.D. (Rhodes) (Visitor) and D. DUNCANSON, H.N.C., B.Sc. Hons. (Strathclyde) (Visitor) The pretreatment of gold-loaded activated carbon with a relatively strong sodium cyanide solution prior to elution with deionized water at 90 to 125°Chas been shown to have a most beneficial effect on the elution of gold. The findings emphasize the important role played by the calcium cation and the hydroxyl anion in effecting efficient elution of gold. The elution of the relatively unstable complexes of silver and base metals with cyanide was also significantly affected by the ratio of the sodium cyanide to sodium hydroxide in the reagents used in the pretreatment stage. It was demonstrated that the use of 0,5 bed volume of a pretreatment reagent comprising 10 per cent sodium cyanide stabilized with I per cent sodium hydroxide for safety reasons resulted in a virtually 100 per cent recovery of adsorbed gold, silver, and base metals on subsequent elution with deionized water. The elution procedure takes a relatively short time, about 14 hours at 90°C (7 bed volumes) or 3 hours if pressure elution at 125°C (4 to 5 bed volumes) is used. Because the mechanism of elution after pretreatment entails the shifting of a physical rather than a chemical equilibrium, the higher the gold loading on the activated carbon, the more efficient is the elution procedure. When compared with other elution procedures, the proposed method appears to have several economic advantages.

Jan 7, 1977

By G. T. van Rooyen

The susceptibility of a low-alloy steel that has been hardened and tempered-826 M40 (EN26)-to embrittlement by strain aging during service was simulated by artificial aging of specimens at 100°C. It was found that the brittle transition temperature of both monotonic and cyclically strained material was increased by only about 25°C as a result of strain aging. It is concluded that the susceptibility of low-alloy steels in the hardened, tempered condition is less than that of low-carbon steel, and that such steels qualify for exemption of the periodic 'annealing' required by the Mines and Works Act.

Jan 1, 1986

By N. B. Strydom, H. H. E. Schroder, A. van der Linde

This paper describes a study of the destination of the mercury that is present in the ore during the recovery of gold. It was found that over 96 per cent of the mercury passed through the process untouched. A small amount finds its way into cyanide solution, and is concentrated with gold in Zinc dust as Merrill precipitate. When the precipitate is calcined, the mercury is driven off and finds its way into the atmosphere. However, dilution of the stack gas in the atmosphere appears to be sufficient to prevent hazardous concentrations arising at ground level. No other significant concentrations of mercury were found at any stage of the process. The amount of mercury lost to the atmosphere by this mechanism appears to be less than 200 kg per year throughout the gold-mining industry in South Africa. Virtually no mercury vapour could be detected in the air in the smelt-house. Slight increases in mercury concentrations above background level were observed in soils around the reduction plants and in the discharge or return waters, but no environmental stress is anticipated from these increases.

Jan 1, 1982

By D. A. Singer, J. C. Griffiths

"One of the most useful approaches to a complex problem is to model the system which gives rise to the problem and to perform simulations through the model to find appropriate solutions. The Engel Model may be used as such a simulator to investigate the problem of the exploration for natural resources.The Engel Model is based on a two-stage search procedure in which a known area (A) which contains m prizes is subjected to search by n coverings. During the first-stage search the sensor system records signals which may be a response from prizes (that is, true signals) or may be false. Signals tend to cluster around a prize and a cluster size consists of s signals. If a circle of radius R is drawn around each signal some will overlap and the overlap from s signals contains a prize. The cost of a single covering in which each point of the area comes under observation once, is designated E1. Second-stage detailed search is expensive and is confined to areas of overlap of s circles; it leads to the location of prizes. Second-stage search of the whole area costs Ea units. The expected value, V, of a prize is known and its development cost is E3 units.The sensor system characteristics are defined by the circle of radius R around a signal, which should be small compared with the total area A and enters the model as a parameter a x R2/A. The probability of a false signal during a single covering of a circle of radius I is a known constant, A.This model was applied to the search for uranium ore bodies using two different types of occurrence. In the first, the Wyoming Basin type, the area is relatively large (A = 1 496 square miles) and a few (m = 4) large prizes occur (expected value V = $30 million). In the second area, which represents the Ambrosia Lake region of New Mexico, the area is smaller (A = 212 square miles) and contains many (m = 200) smaller prizes (expectedvalue of a prize V,$2 million). The three costs, E1, E2, E3, are adjusted to the different circumstances in the two areas.Simulations were performed using n = 1 to 40 coverings with cluster sizes s = 0 to 19; the radius R was varied from 0.52 to 3 miles (and, therefore, a = 0.002 to 0.133 0, respectively, dependent on the area of interest). The value of A was varied from 0.01 to 0.10.Profitable programs were found over a wide range of the parameters; the two areas required different strategies to achieve maximum profit. In the Ambrosia Lake region a few passes (n = 4 to 6) with small cluster sizes (s = 2 to 6) are more profitable, whereas in the Wyoming Basin region a large number of passes (n = 35 to 40) and cluster sizes of s = 5 to 10 are most profitable.As pointed out by Allais (1957) the larger prizes are the most important in deciding the successful outcomes of exploration programs, and the profit margin in the search for a few large prizes is sufficient to yield success over a wide range of programs. Such programs require very large investments if they are to be successful.To refine the Engel Simulator as a decision-maker in selecting the most profitable exploration programs it is necessary to obtain firm estimates of the sensor system characteristics, that is, of R, a and ? (lambda)."

Jan 1, 2014

By M. Rudolph, R. Tolosana-Delgado, G. van den Boogaart, M. Reuter, U. Peuker

This paper addresses the challenge to define a concept of entropy (state of order) for a textured particle system. Both the particle texture, the intergrowth respectively, and the particle size influence the order of a particle system. The smaller the particles become, the more particles form the solid system and the more permutations of the structure of the particle bed are possible. The texture within a particle is fixed, as long as it is not subjected to changes due to comminution, flocculation or agglomeration. The paper will present a definition of entropy, which is able to reflect qualitatively and quantitatively the intergrowth and the size (distribution) of the particles. Theoretical examples will show how different breakage mechanisms can be identified using the entropy definition. Furthermore, we will define the specifications for data sets to calculate the entropy of a particle system. Keywords: Milling, mineral liberation, intergrowth, statistical entropy, modelling

Jan 1, 2020

By F. Shaw, E. C. Chemaly, A. F. S. Schoukens

Steel-plant dusts are hazardous waste materials, containing toxic constituents such as lead, cadmium, and hexavalent chromium. These dusts can be treated by a number of thermal processes, which are described as used in Western Europe and the USA. A detailed description is then given of the thermal Enviroplas process, which as developed at Mintek and produces disposable slag and valuable byproducts such as ferroalloys containing chromium and nickel, and fumes high in zinc oxide.

Jan 1, 1993

By P. R. Labrum, H. A. D. Kirsten

The literature on shotcrete is reviewed with the object of identifying aspects that have not been addressed specifically in terms of its structural performance and manufacture as applied to underground mines. The programme and results of a series of full-scale tests on mesh- and fibre-reinforced shotcrete panels are presented, from which it is concluded that fibre-reinforced shotcrete is competent, especialy at large deformations, and is equivalent in structural performance to mesh-reinforced shotcrete for a fibre content of 3 per cent by mass: furthermore, that the support design systems developed for mesh-reinforced shotcrete are directly applicable to fibre-reinforced shotcrete. The Q-NATM system for the design of temporary tunnel support is presented briefly as one such system. It provides for the integrity of the excavation to be considered in terms of its competence and displacement determinateness, and represents the first systematic procedure for the design of temporary tunnel support. Finally, the support designed on the basis of the Q-NATM system for the main and cross-cut tunnels on the production level in the proposed BA5 block cave at Premier Mine is presented as a practical example of the design of fibre-reinforced shotcrete as part of an overall support system.

Jan 1, 1990

By B. Genc

Improving student success rates without compromising the quality of graduates is one of the biggest challenges expanding university programmes are facing in South Africa. By establishing a new Mine Design Laboratory (MDL) for higher learning in Mining Engineering, the School of Mining Engineering at the University of the Witwatersrand (Wits Mining) has achieved one of the important goals in its five-year strategic plan, i.e. to improve throughput in all years of study. Although the establishment of the laboratory has been a costly exercise, results so far have shown an improved success rate in most subjects taught in the facility. This paper outlines the design and equipment of the laboratory, the facilities incorporated, a comparison with the old laboratory, and the performance of students?all of which indicate how important it is to have proper facilities to improve the teaching of, and learning by, large classes. Through this initiative, Wits Mining has taken an important step that will contribute to addressing the skills shortages in the mining industry.

Jan 1, 2012

By B. Genc

Improving student success rates without compromising the quality of graduates is one of the biggest challenges expanding university programmes are facing in South Africa. By establishing a new Mine Design Laboratory (MDL) for higher learning in Mining Engineering, the School of Mining Engineering at the University of the Witwatersrand (Wits Mining) has achieved one of the important goals in its five-year strategic plan, i.e. to improve throughput in all years of study. Although the establishment of the laboratory has been a costly exercise, results so far have shown an improved success rate in most subjects taught in the facility. This paper outlines the design and equipment of the laboratory, the facilities incorporated, a comparison with the old laboratory, and the performance of students?all of which indicate how important it is to have proper facilities to improve the teaching of, and learning by, large classes. Through this initiative, Wits Mining has taken an important step that will contribute to addressing the skills shortages in the mining industry.

Jan 1, 2012

By E. F. W. Buermann

This paper, which is meant to be read in conjunction with the other papers on the Grootegeluk Coal Project in this Issue (J. S. Afr. Inst. Mm. Metal/., vol. 82, no. 12. Dec. 1982) deals with the extent to which civil-engineering infrastructure had to be provided for that project, near Ellisras in the Transvaal.

Jan 1, 1982

By H. Van Aswegen, C. V. B. 0unningham

The need for the more accurate measurement of blasting results has increased substantially with the proliferation of the types of explosives available to mining operations in South Africa. The primary object of blasting is the production of broken rock of a specific size distribution. A method for the measurement of size distribution, more popularly known as fragmentation, is being developed at Sishen Iron Ore Mine, and the object of this paper is to describe the method briefly and so encourage an exchange of views on reliable methods. Once the fragmentation of broken rock can be assessed reliably, meaningful conclusions can be drawn from blasting trials. It will then be possible for equipment productivity to be related to muckpile properties, with the accompanying advantages.

Jan 1, 1986

By A. P. Cook

Gas samples were taken from a wide range of target areas on dumps arising from coal mining activities. Some of the dumps had largely burned out, some were still burning, some were in the process of rehabilitation, and on others rehabilitation was essentially complete. It was found that rehabilitation was very effective in reducing emissions to tolerable levels. Even incomplete rehabilitation reduced the CO2 emissions to less than about 1 kg/m2/a, whereas some unrehabilitated areas showed emissions of over 100 kg/m2/a. Some areas where there was active combustion taking place were also sampled, and they showed as much as 7 000 kg/m2/a, but the areas concerned were very small and their total contribution accordingly low. Analyses were also made for SOx, NOx, NH3, and CH4, but these were generally (and unexpectedly) at very low levels. The mines sampled represented 53 per cent of all surface coal mining activity. Accordingly the estimated total emissions were scaled up, to arrive at estimates of 1950 000 ± 350 000 t/a C02, 2040 ± 580 t/a SOx, 306 ± 85t/a NOx, and 31 ± 9 t/a NH3 for all surface mines. Methane was detected only from burning coal, and due to the difficulty in sampling, no reliable estimate could be made of these methane emissions.

Jan 1, 2012

By C. Marais

The use of machine vision in the monitoring and control of metallurgical plants has become a very attractive option in the last decade, especially since computing power has increased drastically in the last few years. The use of cameras as a non-intrusive measurement mechanism not only holds the promise of uncomplicated sampling but could provide more consistent monitoring, as well as assistance in decision making and operator and metallurgist training. Although the very first applications of machine vision were in the platinum industry, no automated process control has been developed for platinum group metals (PGMs) as yet. One of the reasons is that to date froth features could not be related to key performance indicators, such as froth grade and recovery. A series of laboratory experiments was conducted on a laboratory-scale platinum froth flotation cell in an effort to determine the relationship between the platinum grade and a combined set of image features and process conditions. A fractional factorial design of experiments was conducted, investigating 6 process conditions, namely air flow rate (x1), pulp level (x2), collector dosage (x3), activator dosage (x4), frother dosage (x5) and depressant dosage(x6), each at levels. Videos were recorded and analysed to extract 20 texture features from each image. By using artificial neural networks (ANN), the nonlinear relationship between the image variables and process conditions and the froth flotation grades could be established. Positive results indicate that the addition of image features to process conditions could be used as sufficient input into advanced model based control systems for flotation plants. Keywords Flotation, machine vision, image analysis, neural networks.

Jan 1, 2011

By J. W. de Kock

The estimation of some properties of South African coals from proximate analyses by J. W. de KOCK, Pr. Eng., Ph.D. (Chem. Eng.) Cantab. (Fellow) and J-P. FRANZIDIS, B.Sc. (Chem. Eng.) (Visitor) Correlations have been obtained whereby calorific values, ultimate analyses, and Hardgrove Indices can be estimated from proximate analyses of South African coals. This has been done by the application of stepwise multiple linear-regression analyses of a mass of data published by the Fuel Research Institute.

By D. W. Boydell, E. B. Viljoen

A flowsheet incorporating rotary-drum filtration for the solid-liquid separation step, followed by solvent extraction for uranium purification, is used as a standard against which four flowsheets are compared. These flowsheets employ either counter current decantation or belt filtration for solid-liquid separation, and either solvent extraction or continuous ion exchange plus solvent extraction for the purification step. Sales revenue, taxation, capital expenditure, and operating costs are estimated. These factors are taken into account in the calculation of an incremental net present value for each circuit by the discounting of cash flows at 25 per cent per year over a projected life of 15 years. For the material used in these examples, the highest net present value results from the circuit that employs belt filtration followed by continuous ion exchange and solvent extraction.

Jan 1, 1978

By R. Altindag

The rock brittleness is one of the most important rock properties that affect the drill-ability of rocks. It is supposed that the increase in rock brittleness causes the increase in penetration rate. The drill-ability of rocks depends on many factors. These factors can be separated as two parts depending on a machine, bit type, rotational speed, thrust, blow frequency, flushing, and rock properties, brittleness, compressive strength, structure, hardness, etc. In this paper, the relationship between brittleness and drill-ability index, which is used in the prediction analysis of the penetration rate of rotary blast hole drills, were examined using regression analysis. It is also seen that significant correlations exist between brittleness and the drill-ability index.

Jan 1, 2002

By J. Rogans

This paper discusses the comparative performances of the three activated carbon adsorption circuits at the West Wits operations of Anglogold. These circuits consist of two pump-cell circuits (at Two Plant, formerly Elandsrand and at Three plant) and a conventional counter-current adsorption circuit (at Mponeng plant). The implications of the improved performance of the pump-cell plants are discussed.

Jan 1, 2002