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By M. Okido, W. Wei, L. Chai

The kinetics on the growth of Thiobacillus ferrooxidans was studied by use of series piezoelectric quartz crystal ( SPQC ). Arsenic ioninhibits the growth of Thiobacillus ferrooxidans, which is consistent with the previous results by other measuring method. This further demonstrates that the SPQC can monitor the chemical activity of the growth of Thiobacillus ferrooxidans. Cupric ion accelerates the growth of Thiobacillus ferrooxidans. The mechanism was discussed, it was considered that copper promotes the protein enzyme of Thiobacillus ferrooxidans, rustic yanin, to form over the range of cupric ion concentration studied. There action order of cupric ion in accelerating the bacterial growth is 0.067. The growth of Thiobacillus ferrooxidans is dependent on temperature, the apparent reaction activation energy decreases from25.56 kJ / mol to 18.32 kJ / mol because of the addition of 10 mg / L Cu(II) to the bacterial growth solution of pH 2.0 at initial inoculum of 10%.

Jan 1, 2000

By Taneomi Harada

Mine drainage has high acidity and sometimes contains more than the allowable concentration of ionized iron. In such a case, mine drainage is neutralized with calcium carbonate and calcium hydroxide to separate precipitates, such as the iron hydroxide and gypsum generated. Currently, most of these precipitates are not utilized and are accumulated in tailing dams. As a result, the service life of the tailing dams is reduced. This becomes a matter of concern, since securing sites for such dams is difficult. A most effective means of solving this problem would be to promote utilization of these neutralized precipitates. This paper reports on the results of studies on neutralized precipitates produced at the old Matsuo Mine (Iwate Prefecture), which has the largest neutralization treatment facility in Japan. As a result of the studies, the following was proposed regarding application of neutralized precipitates. Utilization as ferrite: Mix ferrous hydroxide and ferric hydroxide in water to synthesize magnetite-like ferrite, to be used in the manufacture of magnetic markers for a mobility support system for blind pedestrians, or in producing magnetic fluids for sink-and-float separation of nonmagnetic metals and nonmetals. Utilization as hematite: Bake ferric hydroxide to produce hematite, thereby extracting metallic iron for paint pigment as well as for the manufacture of ironware by local industry. Production of aluminum sulfate: Precipitate aluminum ions from water and add sulfuric acid to produce aluminum sulfate.

Jan 1, 1995

By R. Venugopal, T. C. Rao, M. Vanangamudi

Introduction The kinetic approach, to understand a process in detail, has been extensively used in the unit operations of many engineering systems. In green pelletization, the kinetic studies have been mainly oriented towards quantifying the growth mechanism (Kapur and Fuerstenau, 1964; Sastry and Fuerstenau, 1977; Capes and Danckwerts, 1965; Kapur and Fuerstenau, 1966; Kapur, 1972) and in a few cases, relating the rate of growth with added liquid content (Kapur and Fuerstenau, 1964; Newitt and Conway-Jones, 1958). Studies on the kinetics of green pelletization, in terms of the order of the kinetics are virtually non-existent. Sastry and Fuerstenau (1970) classified the agglomeration process into "free in-space" (dilute particle system) and "restricted-in¬space" (highly dispersed particle system) and noted that the former is a second-order process while the latter corresponds to a pseudo first-order rate process. The present paper attempts to describe the kinetics of green pelletization, in terms of order of the kinetics, using pyritiferrous shale as the material system. Experimental Pelletization experiments were carried out using -100 mesh pyritiferrous shale, in a laboratory disc pelletizer, at four intervals of pelletization time (15, 20, 25 and 30 min). The green pellets obtained were size analyzed. The size distribution of pellets has generally been represented by a single parameter such as the mean granule diameter, ratio of maximum and minimum pellet diameter, etc. In the present study, the d50 (50% passing size) of pellets has been considered to represent the size distribution of pellet. Kinetic equations The process of size enlargement is considered analogous to chemical reaction and a general kinetic equation of nth order for growth of pellets is given as

Jan 1, 1990

By V. G. Grechanyuk

The paper presents the mechanical properties of Cu-Mo composite materials depending on the molybdenum content. The influence of structural defects on the mechanical-physical properties of the condensates at stretching testing as well as of the lamellar grain dimensions upon the mechanical properties of Cu-Mo composite materials is also presented.

Jan 1, 2008

By U. B. Kodukula

The iron ore beneficiation plant at Serra-Azul Mines of ArcelorMittal, Brazil operates at a rated capacity of 3.2 million tons per year. The ore is concentrated using magnetic separation, jigging, hydrocyclones and spiral concentrators. The tailings from the process plant are generated from classifier overflow of 135 tons per hour dry solids and thickener underflow of 48 tons per hour dry solids. A systematic experimental program was carried out using Multi-gravity separator (MGS), and wet high-intensity magnetic separator (WHIMS) for recovering the iron values from both of the tailing streams while minimizing the total quantity of tailings to be discarded. The classifier overflow contained 32.3 percent iron, 49.9 percent silica and 2.18 percent alumina and was 45 percent finer than 45 microns in size. The thickener underflow sample contained 47.3 percent iron, 27.6 percent silica and 2.49 percent alumina and was 16 percent finer than 45 microns in size. Separation results on the classifier overflow sample with the MGS indicated that a concentrate containing 62.1 percent of iron, 10.8 percent silica and 0.36 percent alumina can be achieved with a weight recovery of 24.5 percent. The results with WHIMS at 6500 Gauss indicated that concentrate containing 62.6 percent iron, 8.3 percent silica, and 0.65 percent alumina can be achieved at a weight recovery of 34.7 percent. 4.7 percent. WHIMS studies at 6500 Gauss on thickener underflow sample indicated that a concentrate containing 61.4 percent iron, 8.8 percent silica, and 1.74 percent alumina can be achieved at a weight recovery of 57.2 percent. Based on these results, and further in-house test works, a WHIMS installation was adopted for the recovery of iron values from the tailings in the operating plant at ArcelorMittal Serra Azul Mines, Brazil.

Feb 23, 2014

By L. Xu, R. Bhaskar

While a NIOSH accepted procedure exists for determination of quartz in the respirable dust samples from coal mines, no specific procedure has been defined for quartz determination in bulk samples. In this study, the effect of particle size on the estimation of quartz using the infrared technique was evaluated. Several laboratory tests were performed to determine the dependence of the infrared absorbance peak height on the different sizes of quartz particles. The significant dependence observed between quartz particle size and the measured peak height indicates the potential for erroneous interpretation of the quartz in bulk samples depending on how the samples are prepared. A procedure to reduce the effect of size in the determination of the quartz content is suggested.

Jan 1, 1994

By T. C. Rao, D. D. Patil

The fishhook effect, wherein the recovery of fine particles in the underflow increases with decreasing particle size, has been observed in hydrocyclone classification. A systematic study was carried out to determine the factors affecting the recovery of very fine particles to the underflow. Attempts were made to identify factors, i.e., design and operating variables, that affect the size at which this phenomenon occurs. Experimental results show that the sizes at which the fishhook effect occurs is mainly a function of feed size distribution and solids concentration and is less dependent on the design variables.

Jan 1, 2002

By D. Hongjun

In this paper, the flotation rule and behaviors of kyanite-group polymerphous minerals were studied in modified Hallimond tube in detail. Furthermore, the energy change of collector/mineral systems before and after adsorption and the net charge densities of the atoms on the minerals surfaces were calculated by use of quantum chemistry. The flotabilities in minerals were successfully explained.

Jan 1, 1995

By Maurício L. Torem, Isabella A. Scorzelli

Taboca Mining is one of the largest producers of tin in the world. In its pilot plant, significant amounts of a middling of 90% xenotime (YPO4) and 10% zircon (ZrSi04) are produced. Until now, these minerals of this ore body could not be separated successfully. This paper presents some aspects of the fundamentals of xenotime and zircon flotation with anionic (fatty acids) and cationic (amine acetate) collector, as well as the influence of the superficial leaching of the minerals with cold HCI and HNO3 on the floatability. The mineralogical studies showed that both minerals are optically liberated in -212+106 µm size fraction. Surprisingly, SEM analysis indicated that both xenotime and zircon contain very small inclusions (1-5 µm) of thorite (ThSiO4). On the other hand, zircon is fairly metamictizated giving rise to malacon. Zeta potential tests showed that the isoelectric points of xenotime and zircon correspond to a pH value of 4.5 and 4.7, respectively.The pretreatment with HCI and HNO3 displaced the isoeletric point (IEP) of the minerals to the left. The microflotation tests indicated that the floatability of both untreated and treated minerals are quite similar in the presence of the collectors studied in this work. Adsorption mechanisms are also suggested.

Jan 1, 1995

By Zhuang Jianming, Liu Qinxia, Yuan Mingliang, Mei Xiangong, Chen Jin

Up to now, the leaching of manganese carbonate ore is usually performed at high temperature of 363K and the leaching rate is lower than 90%. Although in laboratory test, the leaching rate is only 90%. This paper introduced an improved method for leaching of manganese carbonate ore. Certain ammonium salt was added to the pulp to raise the solubility of Mn2+ and reduce the adsorption quantity of Mn2+ on the ore surface. Experimental results show that a leaching rate over 95% can be obtained at the temperature >273K. The activation energy is calculated to be 7.15 KJ/mol and is lower than that of normal leaching technique. The effects of the parameters, such as particle size, pulp density and initial acid concentration on the process results are investigated. A leaching rate higher than 95% can be obtained under the following conditions: particle size below 0.25mm, leaching time 60 min, stirring speed higher than 960 r.pm. H2SO4:MnCO3>1 .2, pulp density 105-205 g.L-l. A kinetic model was deduced, verifying with actual experiments. It showed that the model can describe the leaching process successfully.

Jan 1, 1995

By L. Alagha, O. Molatlhegi, S. Khatibi

"In the present study, the effect of organic/inorganic (hybrid) polyacrylamide polymer on fine coal flotation was investigated. Raw coal samples contain about 37% of ash-forming mineral at a feed size of -75 + 38 um were subjected to flotation tests in the presence of in-house synthesized hybrid Al(OH)3-PAM at different polymer dosages and pH values. Results show a significant improvement in both combustible recovery and ash rejection at 1 ppm polymer dosage. Further improvement of combustible recovery was obtained when flotation was performed at pH 5. Interfacial properties of coal particles before and after flotation were examined through electrokinetic (zeta potential) measurements of coal/water slurries. Zeta potential vs. pH curve were established and compared. In the case of raw coal/water slurry, zeta potential-pH curve resembles the ash-forming minerals (silica and clays) more than coal. After Al(OH)3-PAM-assisted flotation, the zeta potential of froth/water slurry shifted to more positive values point which strongly indicates significant removal of ash-forming minerals from coal by Al(OH)3-PAM. INTRODUCTION Coal has been a major commodity in meeting the world energy demand during the past several decades (Milici et al., 2013). According to the international energy agency, global coal demand will continue to increase for the coming decades. With increasing world population, the global electricity demand would also increase as more people would get access to basic electricity especially in developing countries (Maggio & Cacciola, 2012). Due to this increase in energy consumption, operations in coal mining and beneficiation processes have been highly mechanized to meet the demands. This mechanization has increased the quantity of raw fine coal particles produced which contain high amount of ash-forming mineral matter (slimes). Aplan et al., have reported that the major constituents of ash-forming minerals in U.S.A coal are clay minerals such as kaolinite, montmorillonite and illite (Aplan, 1997). Conventional froth flotation for fine coal cleaning suffers mainly from two major problems: 1) Low recovery of ultrafine coal particles due to slime coating by ash-forming minerals, and 2) The lack of selectivity, which results in the flotation of middlings and entrainment of mineral fines in the froth (Polat et al., 2003). Slime coating on both valuable and air bubbles have been proposed to explain the observed reduction in flotation recovery especially when fine grinding is required. In this case mineral matter may be degraded to extremely fine or colloidal sizes thereby creating difficulty in the water clarification process such as flotation. Slimes inhibit bubble-particle attachment, and increases reagent consumption due to the increase in solid/liquid interfacial area, resulting in low coal recovery."

Jan 1, 2015

By Ruoming Gong, Arindam Samanta, Ragula Bhaskar

Three studies conducted at the University of Utah relating to the effect of scrubbers on face airflow patterns, the resulting dust exposure of operators and the development of a throat scrubber for continuous miners are summarized in this paper. The first study involved full-scale laboratory tests to determine the potential dispersion patterns and transport of dust at a continuous miner face, using different ventilation configurations and a scrubber. Concentration maps were developed and potential exposures at operator positions were examined. The second study involved the development of a 3-D numerical model to predict airflow patterns generated by a scrubber at a continuous miner face. The model was designed to evaluate the role of various face parameters on airflow patterns at a miner face and to complement the full-scale testing. The third study involved the design and fabrication of a low profile hydraulically powered continuous miner throat scrubber. The scrubber uses three hydraulic motors and small diameter fans to draw about 3000 cfm (1.42 m3/s) of air and uses a flooded bed scrubber to filter dust particles.

Jan 1, 1993

By R. A. Jankowski, R. Gong, R. Bhaskar

The control of respirable coal dust in continuous mining sections involves careful analyses of the generation and transport of the dust, including airflow pattern analyses. Potential dust control devices must be evaluated based on their effect on both local dust transport and potential dust exposure of face personnel. The development of larger and more productive continuous miners increases the need for research on dust control and improvement of visibility in the face area. Two studies relating to underboom dust control are discussed. The first study involved the valuation of potential underboom dust control techniques to reduce operator exposure to dust and determining the relationship between the positioning of exhaust ventilation and the exposure of face personnel as a function of face and operating variables. The study involved full-scale laboratory experiments using a state- of-the-art data acquisition system. The second study related to the use of foam under a continuous miner boom and its effect on silica concentration and respirable dust. The foam study was performed in a coal mine. The laboratory studies involved the fabrication of a full-scale test facility and development of a computer based data acquisition system. This was followed by baseline data collection, smoke trace tests, detailed performance testing of various underboom dust control measures and data analyses. The underground foam test involved the design and installation of the foam generation and delivery system, testing, and data evaluation. The results of the studies are summarized in this paper.

Jan 1, 1991

By U. B. Kodukula

Attempts are made to evaluate the feasibility of using a water-injection cyclone for the concentration of iron ore fines. The separation characteristics of clay fines, containing large amounts of alumina and silica, from the iron values are discussed. The effects of critical variables, such as injection water rate, truncated cone diameter, spigot opening and vortex finder diameter, on the performance of a water-injection cyclone in terms of iron, alumina and silica grades; iron recoveries; and alumina and silica rejections are discussed. A set of 16 full-factorial experiments (24) was carried out to gain an understanding of the individual and interaction effects of the variables. The results indicate that classifying iron ore fines containing 63.0% iron, 2.5% alumina and 3.5% silica through a water-injection cyclone can produce concentrates with iron grades greater than 66.0% and alumina and silica contents less than 1.5% and 2.0%, respectively, at different study conditions. The achievable iron recovery values are greater than 88%, and alumina and silica rejections are more than 80% and 50%, respectively, within the specific study conditions. While the truncated cone diameter, injection water rate and spigot diameter influences the alumina rejection to a considerable extent, it is mostly influenced by the vortex finder diameter. The iron recovery and silica rejection values are mostly influenced by spigot diameter and truncated cone diameter. The effect of injection water on the concentration characteristics depend on the prevalent truncated cone diameter and spigot diameter conditions.

Jan 1, 2008

By S. K. Kawatra, T. C. Eisele

Although column flotation is known to be more effective than conventional flotation for cleaning fine coal, little attention has been paid to the considerable sulfur removal potential of this process. Whereas conventional flotation can only with difficulty remove pyritic sulfur from coal, flotation columns can make this separation readily due to their greater selectivity. This project has used a modified flotation column to remove pyrite from fine coal. This column has been shown to be capable of removing 70 to 85 percent of the pyritic sulfur from coal while recovering 80 to 85 percent of the total calorific value. However, the remaining pyrite is too finely disseminated to be readily removed by physical means. Currently, experimentation is in progress using bacterially-catalyzed dissolution of pyrite in acid solution to remove ultrafine pyrite and aid in the removal of coarser pyrite inclusions.

Jan 1, 1988

By B. Lin, C. Tang, Z. Chen

Earthquakes, underground impact pressures and rock bursts all produce acoustic emissions. The rate of these emissions can be used to describe rock instability. In this study, it was found that acoustic-emission rates obtained by simulating a twin sample (rock-rock) model could be used to indicate the acoustic-emission-rate characteristics during rock instability. A computer simulation and two case studies support this conclusion.

Jan 1, 1997

By Sundar S. Saluja

Efficient and re1iable methods of fragmentation through blasting have been sought ever since the introduction of black powder in mining operations, but the pace of investigation became faster with the discovery of nitroglycerine. The development of modern measuring instruments and the need to blast more rock with the least damage has made the study of blasting mechanics and its application more important, particularly since the oil embargo. Investigations into the practical approach evolved by Daws (1909) and the work done to make it more useful is discussed. The work of several investigators is touched upon with particular reference to the development of computer programs to simulate and optimize blasting operations.

Jan 1, 1986

By Robert Kimutis, Lihong Zhou, Mark Mazzella, Jim Addis

Due to the surge in shale gas production, a substantial number of unconventional shale gas wells have been drilled across U.S. coal reserves. Gas breaches resulting from damaged wells pose a considerable safety risk to miners. This paper investigates how a ventilation system can effectively manage breached gas through a network-based numerical model and laboratory-scaled physical model. Several hypothetical gas breach scenarios in a longwall area are simulated, exploring factors influencing gas mitigation. The study establishes correlations between breached gas inflow and gas concentration at critical locations. The findings in this study provide valuable insights for managing mine ventilation systems and enhancing coal miner safety.

Feb 1, 2025

By X. Wang, Y. Luo

The propensity of coal spontaneous combustion can be evaluated using various laboratory testing methods, such as R70 adiabatic tests, thermal gravimetric analyzer (TGA) tests and critical self-heating temperature (CSHT) methods. Each of the methods has its unique characteristics and index for classifying the propensity of self-ignition of coals. Accountable relationships among the propensity indices of different methods should be established. Using the newly established R70 and TGA testing setups in our ventilation laboratory, samples from U.S. coal mines have been collected and tested. The TGA is a relatively new quantitative method. A test can be conducted in a relatively short time, within about one and a half hours, compared to the adiabatic tests. The temperature and weight of the sample can be measured with high precision and then used to determine the activation energy of the coal, which is a good indicator of the potential for self-heating. Under a specific experimental design, the TGA technique could perform the proximate analysis for determining coal quality parameters (e.g., moisture, volatile matter, fixed carbon and ash content). These parameters can be used in an empirical equation for assessing the potential for coal self-ignition. The trend of activation energies determined using TGA techniques is reasonably consistent with the trend of activation energies determined using adiabatic tests. As a case study, a comparative analysis of these two methods for determining activation energy was made on coal samples collected from Indiana. The kinetics of the spontaneous combustion mechanism has been explained. If the functional groups of a coal such as hydroxyl (-OH), carboxyl (-COOH), methyl (-CH3), etc., activate more easily with a small amount of activation energy at a relatively low temperature, the coal will have a higher potential for self-heating. With the kinetic and coal quality parameters determined by the TGA setup, it has been found that the coal with a low potential for self-ignition has low self-heating rate, a high activation energy and a high minimum self-heating temperature.

Jan 1, 2012

By S. Siddiqua

Diffusion is known to be the main transport mechanism of contaminants in fine-gained soils. To date, it is still common practice to estimate contaminant migration in the Bangkok Clay by means of pure advection models. A series of experiments with various chemical species was performed to determine transport parameters such as the diffusion coefficients and the distribution coefficients. The soil used was saturated undisturbed Soft Bangkok Clay. Column experiments were utilized in a number of laboratory tests involving advective-diffusive migration. Effective diffusion coefficients of different ions were back calculated from the test results. The distribution coefficients were determined from the results of the column tests and batch test. The results indicate that the evaluated parameters are in the range of values obtained from other researchers on similar kinds of soil. Based on this results contaminant migration by diffusion in the Soft Bangkok Clay can now be performed.

Jan 1, 2005