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By Hengwei Yan, Zhanwei Liu, Wenhui Ma, Ping Xiong

The sulfur in high-sulfur bauxite not only pollutes the environment but also harms alumina production. This study investigated the removal of sulfur from high-sulfur bauxite by adding Zn or ZnO during the Bayer process. The results showed that the different valence sulfur (S2−, S2O3 2−, SO3 2−, and SO4 2−) in sodium aluminate solution can be effectively removed by adding Zn during the digestion process. Adding ZnO removes the S2− in liquor, but the other sulfur compounds (S2O3 2−, SO3 2−, and SO4 2−) are not affected. The mechanism of sulfur removal has been elucidated, where the S2O3 2−, SO3 2−, and SO4 2− are first reduced to S2−, and after adding Zn, the S2− enters into red mud in the form of ZnS. The ZnO then reacts with S2− to generate the ZnS that enters into red mud. Thus, this is a new and effective method of sulfur removal by adding Zn during the digestion process. The results shed light on the removal of sulfur from high-sulfur bauxite during alumina production.

Jun 24, 2020

By Gregory R. Wessel

Sulfur is a nonmetallic element widely distributed in nature and of great physical and economic importance. It is the 14th most abundant element in the Earth's crust (0.06%) and an important constituent of animal and plant life. Sulfur has been known and used since ancient times for a number of medicinal and industrial uses. At present, most sulfur is used to generate sulfuric acid that is used in a wide variety of industrial processes, particularly the production of fertilizer. Because of this, sulfuric acid (and hence sulfur) consumption is often regarded as a good index of a nation's industrial development. In the past, sulfur was mined from surface occurrences in several geologic environments, and was used in relatively small amounts. With time, the uses of sulfur and sulfuric acid expanded, as has the need for larger quantities of these commodities. Sulfur is now mined from both surface and underground deposits, and is recovered as a byproduct from a number of industrial processes. Despite valiant efforts and years of work by sulfur explorationists and others, many aspects of sulfur mineralization remain controversial. Almost as controversial is the spelling of the word sulfur. The English spelling sulphur commonly is used outside America and in the American sulfur mining industry, but sulfur is the correct American spelling as approved by the American Chemical Society, the American Geological Institute, and many others. Those new to the American sulfur industry often find it puzzling to be reprimanded for using the correct American spelling. Sulfur resources are abundant and widespread, but the extent to which they can be classified as reserves is constrained by pre- vailing prices and extraction technologies. At present, sulfur can be economically mined from very few deposits. The sulfur industry is roughly divisible into two sectors: voluntary (or discretionary) and involuntary (or nondiscretionary). In voluntary production, the mining of sulfur or pyrites is the sole objective, and the recovery of the resource is as complete as economic conditions will allow. During involuntary production, sulfur or sulfuric acid (termed recovered sulfur) are produced as byproducts, and the quantity of the output is dictated by the demand for the primary product. Voluntary sulfur now accounts for only about 35% of the elemental sulfur produced worldwide, and most inves- tigators believe that voluntary sulfur will be less important in the future. Sulfur sources and products are described as follows (after Barker, 1983): Sulfur Sources: Combined sulfur-sulfur that occurs in nature combined with other elements, commonly referring to sulfides and sulfates. Cupriferous pyrites-pyrite containing minor amounts of cop- per sulfides. Hydrogen sulfide-a toxic gas that occurs in petroleum and natural gas. Involuntary sulfur-sulfur produced as a byproduct in response to legislative or process mandates. Native sulfur-naturally occurring elemental sulfur. Nonferrous metal sulfides-opper, lead, zinc, nickel, and molybdenum sulfides that are processed for their metal content. Organic sulfur complex organic sulfur compounds that occur in petroleum, coal, oil shale, and tar sands. Pyrites-iron sulfide minerals that include pyrite, marcasite, and pyrrhotite. Sulfate sulfur-sulfur contained in anhydrite and gypsum. Voluntary sulfur-sulfur produced in response to market demand. Basic Sulfur Products: Acid sludge-contaminated sulfuric acid usually returned to acid plants for reconstitution. Brimstone-synonymous with crude sulfur. Bright sulfur-crude sulfur free of discoloring impurities and bright yellow in color. Broken sulfur-solid crude sulfur crushed to -8 in. Byproduct sulfuric acid-sulfuric acid produced as a byproduct of a metallurgical or industrial process, generally relating to combined sulfur sources. Crude sulfur-commercial nomenclature for elemental sulfur. Dark sulfur-crude sulfur discolored by minor quantities of hydrocarbons, ranging up to 0.3% carbon content. Elemental sulfur-processed sulfur in the elemental form produced from native sulfur or combined sulfur sources, generally with a minimum sulfur content of 99.5%. Formed sulfur-elemental sulfur cast or pressed into particular shapes to enhance handling and to suppress dust generation and moisture retention. Frasch sulfur-elemental sulfur produced from native sulfur sources by the Frasch mining process. Liquid sulfur-synonymous with molten sulfur. Liquid sulfur dioxide-purified sulfur dioxide compressed to the liquid phase. Molten sulfur-crude sulfur in the molten state. Prilled sulfur-solid crude sulfur in the form of pellets produced by cooling molten sulfur in air or water. Recovered sulfur-elemental sulfur produced from combined sulfur sources (including byproduct hydrogen sulfide, but sometimes referring only to sulfur from fossil fuels) by any method. Slated sulfur-solid crude sulfur in the form of slate-like lumps, produced by allowing molten sulfur to solidify on a moving belt. Specialty sulfur-prepared or refined grades of elemental sulfur that include amorphous, colloidal, flowers, precipitated, wettable, flour, and paste sulfur. Sulfur ore-unprocessed ore containing native sulfur.

Jan 1, 1994

By C. Nesbit, N. Duru

During the cyanide leaching process of gold and silver, ores that come from the transition zones which typically con-tains low levels of sulfide may produce one or more of the following reduced sulfur species: sulfide (HS ), polysulfides (Sn ), thiocyanate (SCN ), thiosulfate (S2O3 ), trithionate (S3O6 ), tetrathionate (S4O6 ), pentathionate (S5O6 ) and hexathionate (S6O6 ). The actual speciation of the reduced sulfur species in the circuits will primarily depend on the re-dox potential, pH, cyanide levels and existing sulfur species in recycled process water, as well as the presence of other reac-tive metal species. Development of an accurate analytical method for sul-fur species in cyanide leaching units of gold ores where sul-fur speciation occurs has an important role in explaining the metal recovery deviations. This study presents the speciation of sulfur species and development of an ion chromatography method to analyze the reduced sulfur species thiocyanate, thio-sulfate, trithionate and tetrathionate in cyanide leaching circuits for gold ores. The method developed has resulted in the precise quantification of target sulfur species in leach solutions.

Jun 1, 2024

By J. C. Judd, D. D. Harbuck, M. D. Odekirk

The US Bureau of Mines investigated germanium and gallium extraction from an ore containing 0.089% Ge and 0.036% Ga. While previous researchers concluded that a reducing agent, such as SO2 is needed to extract germanium and gallium from such ore, this research showed that high extractions (87% Ge, 97% Ga) were possible using sulfuric acid alone, if the acid concentration were properly controlled. This control was achieved using a two-stage countercurrent leach circuit. Microprobe analyses revealed that the non-extracted germanium is in solid solution with quartz, and therefore cannot be leached with SO2 or sulfuric acid.

Jan 1, 1992

By D. D. Harbuck

The U.S. Bureau of Mines investigated germanium and gallium extraction from an ore containing 0.089% Ge and 0.036% Ga. While previous researchers concluded that a reducing agent such as 502 is needed to extract germanium and gallium from such ore, this research showed that high extractions (87% Ge, 97% Ga) were possible using sulfuric acid alone, if the acid concentration were properly controlled. This control was achieved using a two-stage counter-current leach circuit. Microprobe analyses revealed that the non-extracted germanium is in solid solution with quartz, and therefore cannot be leached with 502 or sulfuric acid.

Jan 1, 1991

By D. D. Harbuck

The US Bureau of Mines investigated germanium and gallium extraction from an ore containing 0.089% Ge and 0.036% Ga. While previous researchers concluded that a reducing agent, such as SO2 is needed to extract germanium and gallium from such ore, this research showed that high extractions (87% Ge, 97% Ga) were possible using sulfuric acid alone, if the acid concentration were properly controlled. This control was achieved using a two-stage countercurrent leach circuit. Microprobe analyses revealed that the non-extracted germanium is in solid solution with quartz, and therefore cannot be leached with SO2 or sulfuric acid.

Jan 1, 1991

By B. C. Haydon

Manganese silver ores are well known to be refractory towards cyanidation. Various processes have been suggested for improving the amenability of these ores. A sulfurous acid pre-leach is one such process. This paper traces the development and implementation of the sulfurous acid pre-leach process for the retreatment of manganese silver tailings at Tonopah, Nevada. An account of the test work program is presented, followed by a description of the operating plant and specimen metallurgical performance. The paper also summarizes the history of the Tonopah tailings, their mineralogy and makes reference to previous application of the sulfurous acid pre-leach process.

Jan 1, 1984

By C. F. Johnson

Nearly all of the sulphur produced in the world today is converted to sulphuric acid and 49 % is used in the manufacture of fertilizers. In the last few years we have seen the beginning of another chapter in the volatile history of sulphur as the severe shortage of 1963:-67 has been transformed into present-day surplus. Prospects for further aggravation of this situation in the years ahead seem assured. In 1970, western world production showed a rate of increase of 4 -5%, which 1S somewhat less than that of 8% for the period 1963-1967. The rate of growth of consumption dropped considerably in 1968 when the demands of the fertilizer industry fell. During the same period of time, wide-spread demands have been set in motion for a clean environment which indicates that a fundamental change in sulphur supply, demand, and even sources, is likely to result from this upheaval. The sale of sulphur by Poland to the western world has increased and for 1970 was estimated at over one million metric tons. In the next few years, increase in Canadian sulphur supply will stern from two sources;

Jan 1, 1972

By John Chapman, Daryl Hockley, Michael Paul, Silvia Jahn

As part of the waste characterisation program to address site reclamation, WISMUT GmbH initiated 56 columns operated as large-scale humidity cell tests. The columns were initiated to assess the acid generation characteristics of waste rock from 14 waste rock piles distributed around the site. Of the 56 tests, 11 are ongoing and have been operational in excess of 160 weeks. The results to date from these long-term tests are surnrnarised. In particular, the methods for, and importance of, establishing the availability of the carbonate neutralisation potential and acid generation potential respectively, are discussed. Geochemical controls on uranium, and the conformity between the geochemical models MINTEQA2 and EQ3/6 in assessing these controls are discussed. Testing indicates that waste rock with an MS-NP:AP ratio in excess of about 2.7 should result in net neutral pH conditions.

Jan 1, 2000

By David M. Mchaina, Allan E. Hall, Siegfried Rohr, J. D. Botsford

Incidents associated with secondary dust ignitions in the mining of massive sulphide ore deposits are of major concern in Canadian underground metal mines. During stope or development blasting, a highly concentrated cloud of sulfide dust is created and may be ignited, resulting a secondary explosion which releases a considerable volume of sulphur dioxide and possibly other sulphur gases. The consequent pressure, heat and toxic gases can result in loss of life, significant damage to equipment and loss of production. These losses are expensive and should be prevented. Explosions of this type have occurred at the H-W mine of Westmin Resources mainly in the development headings and cut and fill stapes. This paper presents the results of a study conducted at the H-W mine to compare dust sampling methods for explosivity tests. The associated benefits and pitfalls of each sampling technique are examined. The investigative work conducted to develop and test preventive and control methods against sulphide dust ignitions is also discussed. The techniques which will minimize the risk of sulphide dust ignition in metalliferous mines are outlined. A review of current preventive and control measures practised at the H-W mine is also presented.

Jan 1, 1989

By J. A. M. Cano

A brief introduction is made on the existence of sulphides in the top gas of the Midrex Shaft Furnace, giving consideration to the operation of the furnace and the liberation of sulphur as well as its consequential effects on the reduction process. The text shows a study of sulphur distribution in the pellet, emphasizing the importance of this distribution in relation to the liberation of sulphur during the reduction. A study was made to determine the sulphur compounds that exist in the pellets, showing ways of controlling the sulphur distribution and reducing its liberation?during the reduction.

Jan 1, 1989

By Elgin D. Bell

Within the next, year or two, Western Canada should overtake Mexico and France. to become the worlds second largest producer of elemental sulphur, surpassed only by the United States, By 1965, it should produce about 25% of the world's total elemental production and, about 10% of sulphur produced in all forms. In 1952 Alberta had but one small sulphur recovery plant. By 1962, it had fifteen plants with a total designed capacity of almost 6,000 long tons of sulphur per day and actual production of almost one million long tons per year. This decade of dynamic growth was the result of Alberta's rapidly developing natural gas industry. More particularly it was the result of approval in 1960 to export natural gas in large volumes into the United States. Prior approval to export gas from Alberta to eastern Canada and relatively modest volumes to the U. S. had resulted in the construction of several plants but none were of the scale required to serve the U. S. market.

Jan 1, 1963

By Leo J. Miller

Sulphur deposits occur within the upper Salado and Rustler gypsum beds. The formation of a sulphur ore deposit requires large quantities of oil and /or gas, which must find a permeable pathway into the gypsum beds. The Permian beds weathered for 90 million years in an arid environment prior to the advent of a more humid climate at the beginning of the Cretaceous Period. The first Cretaceous rivers enlarged the sinkholes and caverns of the Karstified Permian terrain and deposited coarse conglomerates and sands into the subsurface gypsum beds. The resulting network of caverns and sinkholes, filled with permeable sediments, permitted the free flow of hydrocarbons through gypsum. All sinkholes and caverns infilled with Cretaceous sediments that have penetrated beds of gypsum are associated with sulphur deposits. The Castile gypsum lies directly upon the oil bearing Bell Canyon formation. Sinkholes and caverns filled with Cretaceous sediments occur in the lower Castile. Biogenic calcite and sulphur are adjacent to these sediments. However, faults assume the major role in generating the initial permeability, allowing hydrocarbons to penetrate the lower Castile gypsum. The largest faults are associated with biogenic calcite and sulphur for a distance of 250 meters up from the bottom of the Castile gypsum. It is apparent that two dynamic geological processes are generating permeability within the gypsum beds: (1) the Cretaceous sands decending with difficulty into gypsum and (2) the faults creating permeability in the lower Castile but losing energy through soft bed deformation in the overlying gypsum. Both of these sulphur ore controls are mappable, but another large sulphur deposit of the magnitude of the Culberson Sulphur Mine has yet to be discovered. It appears that massive sulphur deposits are associated with the largest scale examples of each system, that is (1) high densities of deep sinkholes and separately

Jan 1, 1992

By D. C. Sisti

A paper was presented during the 1970 SME Fall Meeting on the Stinson Preparation Facilities by representatives of Beaver Creek Consolidated Cool Company and Heyl & Patterson, Inc. This paper summarized a combined approach to development of a flow diagram and selection of cleaning equipment required to produce a uniform metallurgical coal at maximum recovery with special emphasis on sulphur reduction. These facilities were located in the Elkhorn. Coal Fields of eastern Kentucky and, in particular, the area of Wayland, Knott County, Kentucky, where approximately forty-five- million tons of Elkhorn No. 3 coal could he recovered. The facilities incorporated a Bradford Breaker for reduction of the ROM coal to minus 1-1/2 x 0, 6000 ton-raw coal storage, preparation plant, water clarification and thermal drying facilities, clean coal storage and a 4000 TPH unit train loading facility.

Jan 1, 1973

By L. B. Gittinger

Mr, Chairman, members- and guests of the AIMS, I greatly appreciate this opportunity to speak before you. I hope this is just the beginning of a long and mutually beneficial relationship. This winter I decided to join the other 36 Freeporters who belong to the AIME; and, I applied for membership in the Society of Mining Engineers. To queries as to my interests in the Society, I had this answer: our principal challenge -- more so today, than at any time in my nearly 25 years in the industry -- is discovery and development of new sources of raw materials. I want to join you in meeting this challenge.

Jan 1, 1966

By J. D. Miller, Z. S. Nickolov

Sum Frequency Spectroscopy (SFS) is a powerful nonlinear optical technique to study interfaces at the molecular level. SFS has one major advantage over conventional vibrational spectroscopic methods, such as infrared (IR) absorption and Raman scattering, in that the method is inherently interface specific. As a result, the spectroscopy of molecules residing in the interfacial region can be probed selectively without any contributions from the molecules present in the more pervasive bulk phases. Analysis of SF spectra can yield information on population, structure, and orientation of interfacial species with several nanometers in-depth resolution. The recently acquired SF spectrometer at the University of Utah opens new possibilities for investigation of interfacial phenomena of great importance for separation technology, materials research, nanotechnology, bioengineering. Its application to studies of liquid/gas, solid/liquid, and solid/gas interfaces will be discussed.

Jan 1, 2004

By Robert L. Akright

The Sumich (Victorine) gold mine is located in the Toiyabe Mountain Range on the east side of Victorine Canyon, a north-trending branch off Kingston Canyon in the northwest quarter of Section 27 and southwest quarter of Section 22, T16N, R43E, in the southern end of Lander County, Nevada (Fig. 1). HISTORY Discovered in 1862, the Victorine reached a peak of development between 1872 and 1887. The "Victorine" and "Morning Star" lode mining claims, located on the outcrop of a prominent auriferous quartz vein, were patented in 1869 and 1891, respectively. 1, respectively. Gold ore was mined underground in adits driven, on the level, directly into the side of the mountain. Ore brought to the surface was trammed about 457 m (1500 ft) south on a track constructed along the contour to ore bins. From this transfer point, the ore was moved by aerial tram to the bottom of the canyon then hauled by horse-drawn wagon to the mill located about 3.2 km (2 miles) east down Kingston Canyon. Exact details of the milling process used on the Victorine are lacking, but old reports mention water-driven stamp mills, amalgamation, chlorination, and cyanidation. Gold and silver mill products are reported to have been sent to England for final refining. High-grade gold values of 103 g/t (3 oz per ton) remaining in mine walls and on outcrops, attest to the lack of success in treating the Victorine ore in the early mills. The Victorine mine may have been worked sporadically after 1887 with little success. In 1934, control of the property was acquired by William P. Moloney, an attorney from Marion, OH, who also control- 1 led an interest in the successful Goldacres mine in Lander County, NV. This property was studied, sampled, and metallurgical tests were done in 1934, but no development resulted from this work.

Jan 1, 1990

By Bobby C. Carson

INTRODUCTION The National Park Service is entering the seventh year of monitoring caves for the presence of radon and radon daughter products. The purpose of this paper is to summarize the radiation monitoring program at Mammoth Cave National Park, and to present some of the results of this program. Mammoth Cave National Park completed five years of collecting data on May 1, 1981: although Mammoth Cave encompasses approximately 361 km of underground passageways, this paper will concentrate on only a 2.2 km section of the cave known as the Historic Tour. Included in this paper is a discussion of the methods the Nations Park Service uses to protect employees from exposure to alpha radiation. MONITORING METHODS The National Park Service monitors cave atmospheres utilizing the procedures provided by the Mine Safety and Health Administration in their Radiation Monitoring Training Manual (Anon., 1976). This procedure is described as the Kusnetz Method (Kusnetz, 1956) of radon daughter monitoring. Due to the length of the tours at Mammoth Cave, it has been determined to be the most practical procedure. The Historic Tour is a 2.2 km (1.4 mile) loop through passageways ranging in size from 18 m high by 12 m wide, to 0.9 m high by 0.6 m wide. Seven five minute walking samples were taken for this cave tour by drawing at least 10 1 of air through a 25 mm fiberglass filter utilizing a Monitaire Sampler Pump. The radon daughter concentration levels were determined using an alpha scintillation counter to measure the alpha activity on the filter paper. The Monitaire Sampler Pump was calibrated each day prior to monitoring the cave tour and the scintillation counter was calibrated by procedures described by the Mine Safety and Health Administration (Beckman, 1975) at six month intervals. Guidelines established by the National Park Service and approved by the Mine Safety and Health Administration require weekly sampling when the average working level exceeds 0.30 (NPS-14, 1980). A working level is an atmospheric concentration of radon (Rn-222) daughters which will deliver 1.3 x 10 5 MeV of alpha energy per liter of air in decaying through Ra C' (Po-214). The Historic Tour has continually exceeded the 0.30 working level average and has been monitored weekly. Generally, only radon daughter working level data has been collected on the Historic Tour due to limited personnel. However, other special measurements of the uncombined fractions of radon daughters with wire screens, tsivoglou method for radon daughter sampling (Thomas modification, 1970), and thoron daughter monitoring. These special measurements have not been routine due to time limitations involved in radon daughter sampling of other occupied portions of the cave. SUMMARY OF DATA The Historic Tour has been the most consistantly monitored tour since elevated levels of alpha radiation were found to exist at Mammoth. Cave. It is also the only natural entrance to the main sections of the cave and provided an opportunity to study man made actions upon the natural entrance. For these reasons the Historic Tour was isolated for study. Beginning October 10, 1977, and ending November 20, 1977, a pilot project was undertaken involving the Historic Tour and the practice of covering the natural entrance to this tour with sheet metal in the winter months. The purpose was to study radiation levels on the Historice Tour while the covers were on and off the natural entrance. In this pilot project, comparisons were made with incast air with covers on and off the entrance, and outcast air with covers on and off the entrance. TABLE 1 Incast air Mean W.L. Covers on . . . . 1.46 W.L. Increased 54% Covers off. . . . 0.67 W.L. when covers on Outcast air Mean W.L. Covers on . . . . 1.33 W.L. Decreased 5% Covers off. . . . 1.40 W.L. when covers on The natural entrance was artificially covered in the winter months (Yarborough, 1978) to protect the visitor from the extremely cold incast air, in the first four years of monitoring. The data in Table 1, illustrated in Figures 1 and 2, shows that this action increased the radon daughter working levels on the Historic Tour by 54% when the covers were on the entrance and the airflow was incast. While the air flow was outcast at the natural entrance, it made little difference as to whether the entrance was closed or open. Some interesting findings were observed when

Jan 1, 1981

By S. D. Hill

State-of-the art precious metal recovery practice uses cyanide leach solutions to extract the valuable constituents from ores, wastes, and tailings. Activated carbon is then used as an adsorbent in either a carbon-in-pulp system or counter-current flow columns to concentrate and recover the precious metals. Existing techniques for recovering precious metals from carbon prior to the precipitation or electrowinning of the metal involve either the use of dilute aqueous hydroxide solutions at elevated temperature and pressure or, as in a more recent method, the use of a strong cyanide soak followed by a water strip solution at an elevated temperature. Despite past Bureau efforts in the area of precious metal recovery, the ex- traction of gold from pregnant leach solutions remains the most serious drawback in carbon-in- pulp and heap leach processing of low-grade ores containing precious metal values. A second disadvantage in the current practice is the interference in adsorption and desorption that occurs due to the presence of other heavy metal cations in cyanide leach solutions. Specific objectives of current Salt Lake City Research Center precious metals research are to develop less energy intensive and more economic methods for recovering gold, silver, and by- product metals from low-grade resources. To meet these objectives, we are investigating noncyanide leaching reagents, ion exchange resins, solvent extractants, and novel electrowinnlng procedures.

Jan 1, 1984

By W. R. Reed

NIOSH continues to conduct respirable dust control research for surface mine blasthole drilling operations. Research areas have included testing variables (shroud leakage area, drill deck cross-sectional area, shroud height, collector-to-bailing airflow ratio, etc.) that have the most impact on respirable dust control, development of a dust collector inlet hood, development of a dust collector dump point shroud, and testing of a small diameter water separating sub. This paper summarizes the results of the aforementioned research that has been completed. Additionally, past dust control research for drilling operations of both underground and surface mines completed by the U.S. Bureau of Mines, created in 1910 and incorporated into NIOSH in 1997, is reviewed.

Jan 1, 2008