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By R. Y. Wan, J. D. Miller

Thiohydrometallurgical systems including thiosulfate, thiocyanate and thiourea have been stud- ied as alternative liriviants for the leaching of gold. Research and development of thiohydrometallurgical technology has been prompted by environmental concerns with the use of cyanide and problems associated with the processing of difficult-to-treat ores. These thiosystems have some chemical similarities, enabling gold to be leached in a practical oxidizing environment. However, the solution chemistry of the thiosystems is complicated due to instability of the thioreagents and many other reactions which occur during the gold leaching reaction. In this paper, interference reactions of selected metal ions and sulfide minerals are examined in order to understand important aspects of solution chemistry which control the stability of the thioleaching reactions. Applications using thioreagents as lixiviants for oxide and refractory gold ores are presented.

Jan 1, 2005

Dravo Corporation was founded in 1891 and has long been recognized as a major domestic engineering and construction firm headquartered in Pittsburgh. In 1977, Dravo had revenue of $852.2 million with international business activities contributing $248 million; quite a different picture than envisioned at the turn of the century. Engineering and construction activities still dominate Dravo's most recent history and will do so for the immediate future. However, fluctuations in capital spending by large industrial sectors of our economy during the late sixties were affecting Dravo's planning for continued growth along its traditional lines of business. Diversification was a possible solution to smooth out the upward trend in corporate earnings. One large result of these continuing efforts was the formation of Dravo Lime Company, a vertically integrated, proprietary chemical supplier for the air pollution control market. Briefly retracing the seventies, the passage of the Federal "Clean Air Act" in 1970 supplied the impetus for Dravo Lime Company. This law promulgated limits on the emissions of sulfur dioxide (SO2) from large stationary sources that would affect local air quality. The major industry that felt the brunt of this regulation was the electric utility industry, especially those generating electricity with coal-fired boilers. The law hastened the development of a new industry, flue gas desulfurization (FGD), and is composed of three major segments: (1) the electric utility, (2) the FGD equipment suppliers (the scrubbing modules), and (3) the scrubbing chemical suppliers. Dravo's experience suggested the equipment end of the business but market analysis indicated that our long range corporate goals could be better attained by investigating the chemical processes involved in the removal of the SO, gas. The result being Dravo Lime Company. This paper will briefly describe the Thiosorbic lime scrubbing process and review our innovative mine and calcining facility.

Jan 1, 1978

By J. A. Brierley, R. Y. Wan

Newmont Gold has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for the pretreatment of low-grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the preg-robbing characteristics of the carbonaceous matter in the ores. Therefore, an alternative heapleach process using ammonium thiosulfate was developed to extract gold from these preg-robbing biooxidized ores. The ammonium thiosulfate leach process was successfully applied in both laboratory and pilot plant tests. Satisfactory test results were achieved, encouraging the continuation of process development.

Jan 1, 1998

By R. Y. Wan

Newmont Gold has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for the pretreatment of low-grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the preg-robbing characteristics of the carbonaceous matter in the ores. Therefore, an alternative heapleach process using ammonium thiosulfate was developed to extract gold from these preg-robbing bioaxidized ores. The ammonium thiosulfate leach process was successfully applied in both laboratory and pilot plant tests. Satisfactory test results were achieved, encouraging the continuation of process development.

Jan 1, 1997

By R. Y. Wan

Newmont Gold Company has advantageously used the capabilities of mineral oxidizing bacteria to develop a process for pretreatment of low grade sulfidic and carbonaceous-sulfidic refractory gold ores. The biooxidation process results in the oxidation of the sulfidic minerals with increased exposure of gold for subsequent gold recovery. The biooxidized carbonaceous-sulfidic ores cannot be heap leached with cyanide because of the "preg-robbing" characteristics of the carbonaceous matters in the ores. An alternative heap leach process using ammonium thiosulfate was developed to extract gold from the "preg-robbing" biooxidized ores. The ammonium thiosulfate leach process has been successfully practiced both in laboratory and pilot plant testing. Satisfactory test results encourage the continuation of process development.

Jan 1, 1996

By I. H. Gundiler

Although cyanidation has been universally applied in the processing of gold and silver ores, the search for less toxic alternatives continues. Difficulties encountered in processing ores containing oxidized copper minerals and the inherently slow kinetics of cyanidation have generated a renewed interest in thiosulfate leaching. This process, as well as the catalytic effects of copper ion, were well recognized and widely applied towards the end of the past century. In this study, the effects of copper, ammonia, and thiosulfate concentrations on gold dissolution were investigated using the rotating disk technique. Extraction of gold and silver from an oxidized copper-bearing ore was also studied utilizing a statistical experimental design, and these results were displayed in the form of contour plots.

Jan 1, 1993

By J. Brent Hiskey

Thiourea is a reagent capable of complexing gold and silver. With the proper oxidant, thiourea can effectively dissolve metallic gold and silver. A thiourea leaching system possesses potential advantages over conventional cyanidation including acidic solutions instead of alkaline, cationic complexes in contrast to metal-cyanide anoionic complexes, and faster leaching rates with acidic solutions of thiourea. Generally, the rate of metal dissolution in thiourea solution is fastest when ferric ion is employed as an oxidant. Acidic thiourea solutions for certain applications could offer a nontoxic and noncorrosive option for processing gold and silver. This paper provides information regarding the fundamental chemistry of the acidic thiourea system, and reviews the dissolution of both silver and gold in acidic solutions of thiourea. The recovery of gold and silver from acidic thiourea solution is discussed.

Jan 1, 1981

By J. B. Hiskey

Thiourea is a reagent capable of complexing gold and silver. With the proper oxidant, thiourea can effectively dissolve metallic gold and silver. A thiourea leaching system possesses potential advantages over conventional cyanidation including acidic solutions instead of alkaline, cationic complexes in contrast to metal-cyanide anionic complexes, and faster leaching rates with acidic solution of thiourea. Generally, the rate of metal dissolution in thiourea solutions is fastest when ferric ion is employed as an oxidant. Acidic thiourea solutions for certain applications could offer a nontoxic and noncorrosive option for processing gold and silver. This paper provides information regarding the fundamental chemistry of the acidic thiourea system, and reviews the dissolution of both silver and gold in acidic solutions of thiourea. The recovery of gold and silver from acidic thiourea solution is discussed.

Jan 1, 1981

Factors which cause thiourea consumption in gold-leaching systems include adsorption by gangue mineral particles, complexation with base metal ions, thermal degradation, and oxidation by air/ferric iron. Of these factors oxidation by ferric iron is the most significant factor. Of course, ferric sulfate is desired as an oxidant for the gold leaching reaction, but an excess of ferric sulfate leads to high thiourea consumption. In this regard, the rate of gold leaching by thiourea must be balanced against the rate of thiourea decomposition. It is important to note that the thiourea decomposition reaction in ferric sulfate solution is relatively slow in pure solutions and has been found to be first order with respect to both thiourea concentration and total ferric iron concentration. However, when mineral particles from gold-bearing ores or concentrates are present, the decomposition rate can become quite significant. As might be expected, the catalytic activity of mineral surfaces varies with particle composition and size. Experimental results are discussed with respect to the consumption of thiourea.

Jan 1, 1997

By C. Abbruzzese, L. Piga, P. Fornari, S. Ubaldini, R. Massidda

The effects of certain variables on the extraction of gold by thioureation have been investigated on a quartzose gold-bearing ore using a statistical multifactorial strategy. The factors taken into consideration were milling time (which corresponds to a given grain size), oxidant concentration, thiourea concentration and liquid/solid ratio. The influence of these four variables was ascertained first by a full factorial design at two levels for each variable (16 runs). This permitted the estimation of first-order effects of the factors affecting the process. Then 9 runs were added whose levels were both in the centre of and outside the axes of the previous plan thus originating a central composite design. This permitted estimation both of second-order effects of the factors involved and of parameters of a second-order polynomial model. The results show that extraction of gold depends only on milling time and oxidant concentration, at least in the experimental range considered. The equation fitting experimental data, as calculated by the least squares method, allows a response surface to be drawn. Due to the low gold grade of the ore (6 ppm) statistical analysis could lead to contradictory results, hence strict observance of Gy's rules for sampling and very accurate and precise chemical analyses were required.

Jan 1, 1995

By J. B. Hiskey

INTRODUCTION The extraction of gold and silver from ores, concentrates, and various metallurgical products can be achieved by a number of hydrometallurgical techniques. The solvation properties of alkali cyanide solutions on gold and silver were recognized 200 years ago. A cyanidation process for leaching gold from its ore was patented in 1887 and 1889 by MacArthur and Forrest. The solvent action of thiosulfate on gold and silver was observed over 100 years ago. Recently, several patents have been issued for processes using ammonium thiosulfate as lixiviant for precious metals, Berezowsky, et. al (1978) and Kerley (1981). Tozawa and and coworkers also examined the dissolution of gold in ammoniacal thiosulfate solution. Thiourea leaching of gold and silver initially discussed by Plaksin and Kozhukhova in 1941 but has received only limited attention since that early work. Use of thiourea as an alternative to cyanide was the topic of several papers presented at the 1981 AIME annual meeting In Chicago, Illinois. Hiskey provided a review of the fundamental chemistry of the dissolution of gold and silver in acidic thiourea solutions. Pyper and Hendrix reported on the leaching of a finely disseminated gold ore using thiourea as a lixiviant. The review article(6) previously presented was fairly comprehensive covering Important contributions to the chemistry of thiourea and the processing of gold and silver with acidic thiourea solutions. A search of the technical literature was made to determine recent (since 1981) progress and developments in applying thiourea to the processing of gold and silver. This review reveals that Soviet and Eastern European scientists are continuing to make major contributions to our understanding of thiourea/precious metal systems.

Jan 1, 1984

By Cheryl M. McInnes, Graham J. Sparrow, James T. Woodcock

Three composites, assaying about 3 g/t Au and 0.75% Cu, were investigated. Each contained oxide copper minerals, iron oxides, and silicates. One composite also contained copper and iron sulphides. Maximum gold extractions by thiourea leaching were obtained after copper removal by acid pre¬leaching at pH 1.5 and redox potentials of 400 mV (Pt versus SCE). Best thiourea leaching conditions were pH 1.5, redox potentials over 200 mV, and 0.4% thiourea. This gave 90% gold extraction in 2 h with thiourea consumptions of 25 kg/t. Lower potentials gave poorer extractions. Ferrous iron additions before leaching halved thiourea consumptions. Longer leach times and the presence of sulphide minerals sometimes resulted in reprecipitation of gold.

Jan 1, 1989

By Rudolf E. Greuer

Introduction The Institution of Mining and Metallurgy and the Institution of Mining Engineers organized the Third International Mine Ventilation Congress held in Harrogate, England. Sixty-one papers were presented and about 300 participants registered. About 30% of the participants came from Great Britain, 20% from South Africa, and about 5% each came from Australia, Canada, China, France, US, and West Germany. The remainder of the participants came from 18 other countries. Eleven of the papers presented dealt with methane, three with diesel exhausts, four with dust, four with radioactivity, 18 with heat, and 15 dealt with main and auxiliary ventilation. Six of the papers dealt with mine fires, which is a boundary region between main ventilation and gas concerns. Ventilation Congress proceedings are available. See ME, December 1984, page 1687, New Books page. With CH4 and radioactivity topics, the Australians dominated since they are becoming large coal and uranium producers. With diesel exhausts, the most important problem in highly mechanized mines, the North Americans were prominent. The South Africans, working in 90% SiO2 in their gold deposits, were preeminent in presentations on dust. They also led in topics related to heat, joined by the West Germans whose mines are getting deeper. In main and auxiliary ventilation, Great Britain and West Germany provided the majority of contributions. Methane The large number of methods for the precalculation of CH4 liberation in longwall mining all contain three elements: gas content of the coal, gas emitting zone (or influence zone of face), and degree of gas emission. Determination of the gas content, commonly accomplished by taking coal samples, does not pose much difficulty. But this is not the case with the other two factors. Most existing approaches rely on rock mechanics observations. Some only rely on intuition or speculation. The West German coal mines conducted a large research project between 1977 and 1982, in which gas pressures around longwall faces were measured. Gas pressures and gas contents can be related. Therefore, influence zone and degree of gas emission can be determined simultaneously. The precalculation of CH4 liberation in room-and-pillar mining is simpler. Since foot and hanging walls remain essentially intact, gas pressure distribution and gas flow can be calculated using hydraulics equations. A key to these calculations is permeability. A group of Australian researchers reported that the permeabilities of rock under three dimensional stress differs from rock under destressed conditions. This fact was known, but no systematic observations existed. These were provided. Methane drainage has been practiced for more than 40 years. It is used with great success in longwall operations. Some of the West Germans think that methane drainage from the footwall is neglected. Under certain geological conditions, they claim this is as important as drainage from the hanging wall. A research project was presented in support of this claim. Considerable efforts have existed for more than 10 years to use methane drainage in room-and-pillar mining. A paper described the accomplishments of Consolidation Coal Co. Since coal and rock are not fractured as much as in longwall mining, gas transport takes place by the slow diffusion from micropores into the cleats. Then, it is transported by laminar flow along the cleats until a drainage borehole or the mine workings are reached. Boreholes about 300 m (1000 ft) long can reduce the gas content of a band of coal 100-m (330-ft) wide by 50% in one year. A paper from India described methane drainage from gob areas. A French paper reported that especially high methane concentrations can be drained from gob areas if the face ventilation is descensional. Methane buoyancy and ventilating pressures compensate each other, and little air dilution by leakage takes place. Another French paper described a newly developed gas and air velocity monitoring system making use of a microcomputer. Four papers on methane dealt with gas outbursts. Two Australian contributions described the problems encountered with CH,-CO2 mixtures and the attempts to solve them with drainage boreholes having 10 to 20-kPa (1.5 to 3-psi) suction pressures. A Hungarian paper described problems and attempts to reduce the risks of gas outbursts in Hungary. Prediction of gas outbursts in coal seams was the focus of an English paper. Observations show that they are frequent when coal, through its geological past, has become soft and brittle with a resulting increased desorption rate. An instrument for gravimetric de-

Jan 1, 1985

By P. Schiavi

A trend towards the independent verification of sustainable development reporting and assessment using third party certification can be discerned in the global minerals industry. Various codes that provide for the third party assessment and certification of performance against a range of externally developed sustainability indicators are being adopted by minerals companies, and there is also considerable activity in the broader area of third party assurance. Using a sociological approach, this paper examines the reasons why third party certification schemes are appearing in the minerals industry to address sustainable development imperatives in preference to other forms of regulation, and considers the broader implications of this trend. Data are drawn from a series of qualitative, in-depth interviews conducted with some of the key players in the development and adoption of certification schemes in the minerals industry, with executive managers of a range of large mining corporations, with representatives of global non-governmental organizations that are active in mining issues, and with government officers responsible for the regulation of mining corporations in Australia. Factors responsible for the emergence of the new certification schemes include: increasing demands from stakeholders for greater credibility in reporting against sustainable development indicators; broader contextual factors including globalization and neoliberal policies; and issues relating to trust and risk. Using insights from our research, and the work of others in this field, we identify some of the critical features of a credible third party certification scheme, and note some of the challenges for the design and implementation of such schemes. We conclude by discussing some of the broader implications of third party certification as an emerging form of regulation in the minerals industry.

Jan 1, 2007

By Lynn Huntsman

INTRODUCTION The Sunnyside mines of Kaiser Steel Corp. are lo¬cated on the west flank of the Book Cliff Range, a tongue of the Wasatch mountain range in Utah. The mines are 193.12 air km (120 air miles) southeast of Salt Lake City and 40.23 km (25 miles) east of the town of Price. The area has a semiarid climate with an an¬nual rainfall of 304.8 to 381 mm (12 to 15 in.) and a temperature range of -23.3 to 32.2°C (-10 to 90°F). The base of the Book Cliff Range is approximately 1981 m (6500 ft) in elevation with some mountain peaks in excess of 3048 m (10,000 ft) (Fig. 1). The Sunnyside mines were opened in the late 1890s and have been operated continuously since that time. Kaiser Steel leased the No. 2 mine in 1942 and pur¬chased the entire property in 1950. There are three mines adjacent to one another, each with its separate access, ventilation, and haulage. The three mines en¬compass an area extending 12.87 km (8 miles) along the outcrop and dipping northeasterly 2.41 to 3.22 km (11/z to 2 miles) into the Book Cliffs. During 1975, only the No. I and No. 3 mines were operating to sup¬ply 908 184.7 t/a (1,000,000+ stpy) of clean coal to the Kaiser Steel mill at Fontana, CA. Sunnyside coal is blended with coal from the Kaiser Steel mine near Raton, NM, and with purchased coal from noncompany sources to form the mix for the coke ovens. At that time, Sunnyside operated three longwall units and five to seven continuous miner units. Typical production for that time came from one miner unit pillaring an area not conducive to longwall mining; one or two miner units on construction or modernization projects, and the remaining units used to develop future longwall panels. Longwall mining has been a part of the Sunnyside scene since 1961 when the first panel was set up in the lower Sunnyside seam of the No. 3 mine. Through 1975, 27 longwall panels were mined (Fig. 2). Of the more than 47 173 604 t (52,000,000 st) of clean coal that were taken from the property through 1975, 6 350 292.9 t (7,000,000 st) were mined by longwall methods. Coal was brought to the surface in 4.5-t (5-st) mine cars and crushed to -152.4 mm (-6 in.) before entering the preparation plant. Coarse coal is cleaned by Baum jigs and fine coal (-28 mesh) is cleaned in flotation cells. The coal is reduced to 50.8 x 0 mm (2 x 0 in.) and belted to an aboveground storage pile with a ca¬pacity of approximately 113 398.1 t (125,000 st). The coal is gravity fed through two 1.52-m (5-ft) diam culverts directly into railroad cars, which pass beneath the storage pile through an arched excavation. Eighty-four 90.7-t (100-st) cars make up a unit train which makes the round trip to the steel mill in four days. Additional trains are scheduled in as demands dictate. Loading rates in excess of 13 607.8 t/h (15,000 stph) have been attained. Geology The coal seams of this area are of Cretaceous age and are classed as a medium volatile bituminous coal. coal, with a sulfur content less than 1 % and 6 to (20-mile) zone of the Book Cliffs, and this area is owned or under lease by either Kaiser Steel or US Steel. Coal in adjacent areas is noncoking but an excellent steam coal, with a sulfur content of less than 1 % and 6 to 7% ash. Sunnyside coal contains 40% volatile, 53% carbon, less than 1 % sulfur, and 51/2 to 61/2 % ash after washing. There are two minable seams throughout most of the Sunnyside property known locally as the upper and lower Sunnyside. Separation between the seams varies from less than 300 mm (1 ft) near the southern boundary adjacent to the US Steel Columbia mine, to over 12.19 m (40 ft) in areas of the No. 3 mine in the center of the Sunnyside property. The upper seam varies in height from 1.2 to 1.98 m (4 to 61/2 ft) while the lower seam varies in height from 1.52 to 4.28 m (5 to 14 ft) in areas of No. I mine where the two seams apparently come together. The majority of early work was con¬centrated in the upper seam which has a stronger roof and a lower sulfur content. When Kaiser Steel began mining the No. 3 mine in the early 1950s, it mined in the lower seam beneath the old workings with conven¬tional and continuous mining equipment. Numerous bounces and pressure points created by unextracted pillars and barriers in the upper seam made this a low¬production, high-cost mine and brought about the ad¬vent of the first longwall system. The first unit, while small by today's standards, successfully mined panels that had been all but given up and saved the mine from closure. There were areas that could not even be mined by longwall because of the erratic extraction in the upper seam. The system was successful enough to allow operations to gain access to and develop virgin areas of the upper seam. Development of longwall mining in the No. 3 mine has been confined to the upper seam since late 1964. With the almost complete extraction afforded by the longwall system, it is felt the lower seam can be successfully worked in future years (Fig. 3). In most of No. 1 mine, only the lower seam (or lower seam and upper seam combined) is minable, except in the northwest portion where a rock split has again separated the seam into two 1.83 to 2.13-m (6 to 7-ft) thick beds. In this area, the upper seam or upper split is being mined. The separation between seams at the present workings in this area varies from 0.609 to 6.1 m (2 to 20 ft). It is hoped that most of the lower split can be mined using shield supports and/or what¬ever new technology is developed in the coming years. The coal seams in this area dip to the northeast at an average grade of 10%. The dip near the outcrop reaches 22% and gradually decreases downdip. Over¬burden ranges from a few meters at the outcrop to 762 m (2500 ft) over some of the deeper workings. In the next several years, some overburden will be in excess of 914 m (3000 ft) as the lower mine workings extend ever deeper under the Book Cliffs. To cope with the

Jan 1, 1982

By Charles T. Holland

INTRODUCTION Insofar as I am aware, the term rock mechanics was not in the English dictionary in 1930 when I started my graduate program at West Virginia University. Hence, I never thought that I was undertaking studies in rock mechanics when I undertook to write a thesis on the physical properties of West Virginia coal. In this case, the subject was primarily concerned with the compressive strength of coal, the elasticity of the coal, the physical weathering properties of the coal and its friability. These days investigations of rocks pertaining to such properties are included in the term "rock mechanics". Other than this aspect, the principle interest in this part of my program was that I became interested in the strength of coal from the standpoint of structural purposes, and also became cognizant of its elastic properties as well as its energy storing properties. This research also tied in with a remark that Professor Lawall made in a Mining Methods class in 1928 when he remarked that a peculiar thing was happening in the southern part of West Virginia, namely, in the Pocahontas coal field. His remarks were to the effect that pillars were blowing up in the mines and when asked why he replied the cause was not known. The failure of three-inch coal specimens, especially those in stronger coal, in non-hydraulic actuated testing machines was reminiscent of his description of those pillar bursts or bumps.

Jan 1, 1971

By Robert McEwen

Conveyor equipment beyond its prime chronically suffers from a lack of understanding in today's plant environment regularly delivers more material than original designers ever expected. A case in point is a belt conveyor in a major hard rock mine/milling operation asking to bring the unit up to current standards while eliminating spillage and reducing airborne dust. The challenge was to keep the system going by revamping the system while keeping the same footprint and allowing for higher production rate. Thirty years of daily maintenance and dust collection costs have virtually disappeared by the end of this challenging upgrade.

Jan 1, 2008

By James G. McKelvey

Owners have seen several major tunnel projects in recent years fall victim to a general reduction in the number of bidders as well as an erratic range of pricing. It should be noted though that this is not a universal trend and some projects have seen good competitive bids. Contractual terms and conditions are an important factor in attracting good competition. The Front End documents of tunnel projects have come under increasing scrutiny as tunneling contractors in the U.S. industry are looking much more closely at their risk exposure in the contract terms and conditions. Considering the amount of tunnel construction work upcoming in North America, it is important that General and Special Conditions are put together in a way that provides a reasonable basis to execute the Contract and also provide a fair, balanced and swift way to resolve disputes.

Jan 1, 2008

By William C. Beebe, Russell E. Martin

An account of driving and concreting two 900 m railroad tunnels for the Denver and Rio Grande Western Railroad under emergency conditions. Details the importance of on-site decision making by the Owner in completing the project successfully in record time. A general description of the geology and construction methods. The Thistle Drainage Tunnel drained water impounded behind the Thistle slide and serves as permanent diversion of the Spanish Fork River and Thistle Creek around the slide area. The project involved 684 meters of 5 m horseshoe tunnel, a 5 m diameter raised shaft and 23,000 cm of cut excavation.

Jan 1, 1985

By Alfred L. Anderson

Thorite and rare earth deposits in the Lemhi Pass area of southeastern Lemhi County, Idaho, are contained along complex shear and fracture zones and in reopened gold-quartz veins and copper lodes in quartzitic and phyllitic rocks of the Pre-cambrian belt series. Some of the shear and fracture zones are several tons of feet across and comprise broad zones of irregularly mineralized rock. These lodes contain a notable concentration of thorium and rare earth elements along with considerable amounts of barium, .potassium, calcium, iron, aluminum, phosphorus, sulfur, and silicon. The principal minerals are thorite, locally allanite, monazite, xenotime (?), apatite, specular hematite, barite, potash feldspar, occasionally calcite and quartz. Exept for some of 'the specular hematite, barite, reddish feldspar, calcite and quartz, the minerals are not distinguishable without the microscope. The thorite and locally allanite were deposited first, then the monazite and other phosphates, which were in turn followed successively by barite, potash, feldspar, calcite, and quartz. In exceptional cases, deposition of thorite and specular hematite was repeated after the feldspar. Some of the deposits contain several percent thoria, but the average os generally under one percent. The rare earth content is comparable with that of the thoria. The deposits appear to be of hydrothermal origin and are probably related genetically to late Cretaceous or early Tertiary igneous activity, manifested locally by a few dioritie and lamprophyric dikes.

Jan 1, 1959