Search Documents

By Nikhil Dhawan, Shrey Agrawal

India’s most extensive renewable energy expansion program targets 280 GW of solar energy by 2030. Due to the massive generation of photovoltaic waste (expected 34,600 T by 2030), stringent recycling effort to recover metal resources from endof- life PVs is required for resource recovery, circular economy, and subsequent reduction in the environmental impact. The present study investigates the recycling potential of end-of-life silicon solar modules. The feed characterization reveals that most of the values in PV modules are concentrated in the frame (pure Al), Si wafer (72–84% Si, 9–12% Al, and 0.13–0.71% Ag), and electrical connections (Cu wire coated with Sn). The Si and Ag values in the feed were beneficiated using water fluidization, and concentrate with 90% Si and 2% Ag was attained in the underflow concentrate. Ag values were recovered in the form of AgCl by leaching in nitric acid and precipitation. After the purification step, the residue containing 99% Si can be further utilized to fabricate Si wafer and Al-Si alloy. The preliminary cost estimations suggest that the proposed process is economically viable for the recycling of solar panels with the maximum value generated from the AgCl precipitate followed by Al panels and Si wafers.

Nov 14, 2022

By Elif Emil-Kaya, Bernd Friedrich, Merve Papakci

Samarium (Sm), one of the rare earth elements (REEs), and cobalt (Co) are used in the production of SmCo permanent magnets, which have excellent temperature stability, corrosion resistance and oxidation resistance. Of the two types of SmCo magnets, one contains a high amount of iron, approximately 15.2 percent. This paper focuses on the recycling of iron (Fe)-bearing SmCo. In this study, an oxidative leaching process with nitric acid was developed to eliminate iron through in situ hydrolysis and to dissolve REEs and Co. The influence of experimental conditions on the formation of an amorphous iron compound through the hydrolysis of Fe3+ in a nitric acid environment was thoroughly examined based on a Taguchi orthogonal array. The optimal parameters for oxidative leaching were determined to be an acid concentration of 3 mol/L, a solid-to-liquid ratio of 1/10, and a process temperature of 60 °C.

Jul 1, 2024

By F. Ferella

In this paper several leaching tests were per-formed to optimize the leaching section of a hydrometallurgical process for the recycling of alkaline and zinc-carbon batteries. Zinc and manganese oxides were dissolved by an acidic-reductive leaching using sulphuric acid and oxalic acid as reductant. Leaching tests were developed according to a full factorial design. The operational variables were pulp percentage, sulphuric acid concentration, temperature and oxalic acid concentration. Additional tests were performed to evaluate the precipitation rate of Mn and Zn oxalates. Finally a hydrometallurgical process were proposed for the recycling of alkaline and zinc-carbon batteries, in which Zn and MnO2 are recovered from purified solution by electrowinning: Zn is recovered as metallic compound, while Mn can be recovered as electrolytic manganese dioxide (EMD), but recovery of further manganese compounds is possible with simple process changes.

Jan 1, 2006

By Rod L. Norfleet

Cemented tungsten carbides are a sintered powder - metallurgical product essential to modern industry. Because of their moderate unit price and our dependence upon foreign sources for the component raw materials, a growing recycling industry has developed in the United States. There are two basic approaches taken to recycling cemented carbides; those which leave constituting materials unaltered or direct-reuse and those which separate the constitutes back to the raw components. To separate the carbides back to their raw components usually requires expensive chemical processing and is thus confined to the lower value materials such as grinding sludges. The direct-reuse methods recycle cemented carbides back to an intermediate level, a powder capable of being recompacted and resintered into a functional end-product. The three most commonly used methods of direct-reuse recycling, the coldstream process, bloaching and the Bernard or zinc process, are reviewed,

Jan 1, 1984

By K. Park, J. Sohn

Recovery of industrially useful metals from various secondary sources is an important issue in Korea whose natural resources are limited and needs in the strategic metals are on the rise. In order to meet such needs, researchers at the Korea Institute of Geoscience and Mineral Resources have launched a number of projects to help the nation to recover various metals from secondary sources. In this study, silver is successfully recovered from spent silver-oxide batteries first by distillation to remove mercury. The distilled residue was next subjected to leaching of silver using nitric acid. The study involves finding optimum conditions to leach silver from the distilled residue and subsequently to recover silver from the leach liquor by chemical precipitation. The chemically precipitated products are then subjected to reduction roasting to recover silver metal.

Jan 1, 2002

By N. S. Kim

Economically favored Cr and Cu leaching out process from spent power plant fly ash (PPFA) had been investigated. PPFA, bearing of C, S, V, Ni, Cu and Cr, has been widely used as an assistant fuel in cement industry. Recent environmental regulation in S. Korea prohibits using PPFA as a fuel. Many researchers have also studied on extraction V and Ni from PPFA. Due to low concentration of V and Ni, 2% and 1%, respectively, economical and environmental friendly process could not be found. In this study, Cu and Cr have been removed in an economical way and which satisfied with KS Extraction Test. The rest unburned carbon, V2O5 and NiO2 in residue were found to be applicable for indoor and outdoor colored bricks or deodorant panel. Various parameters such as pH, lixiviates and time on leaching behavior were investigated in order to leach Cr and Cu remaining C, V and Ni. Keywords: Fly ash; Selective extraction; Ammonia; Deodorant panel

Jan 1, 2009

By F. Ikumapayi

In order to predict and minimize detrimental production problems due to the recycling of process water in sulfide ore processing, the influence of major species, calcium and sulfate in process water on sphalerite flotation was investigated through Hallimond tube flotation, zeta potential, diffuse reflectance Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) measurements using sphalerite mineral sample. Assessment of process water species in flotation was done using deionized water, process water and simulated water containing calcium and sulfate ions in experiments. Hallimond flotation shows increased sphalerite float-ability in process water compared to deionized water, but no significant effect on the presence of calcium and sulfate ions in deionized water using isobutyl xanthate as a collector. The presence of calcium ions reduced the sphalerite?s negative zeta potential, while at higher concentrations, a charge reversal occurred, at about pH 11. FTIR and XPS studies revealed the presence of surface-oxidized sulfoxy and carbonate species on sphalerite at pH 11.5 in deionized water, process water and water containing calcium and sulfate ions. These surface species do not influence xanthate adsorption.

By F. Ikumapayi

Hydrogen peroxide production was measured during the grinding of a complex sulfide ore, and its oxidizing effect on solid surfaces was investigated using Fourier transform infrared spectroscopy (FTIR) with diffuse reflectance attachment measurement. In turn, an attempt was made to correlate the formation of hydrogen peroxide, surface oxidation and sphalerite flotation. Additionally, in order to predict and minimize detrimental production problems due to the recycling of process water in sulfide ore processing, the effects of major components of calcium and sulfate species present in recycled process water and the effect of temperature on sphalerite flotation were investigated through bench-scale flotation tests using complex sulfide ores. The significance of process water species in flotation was studied using tap water, process water and simulated water containing calcium and sulfate ions. Formation of hydrogen peroxide was revealed during the grinding of the complex sulfide ore, and its formation was counteracted by diethylenetriamine (DETA). The FTIR spectrum of the pulp solid fraction showed varying degrees of oxidized surface species, which are related to the concentration of H2O2 analyzed in pulp liquid. Bench-scale flotation using two different complex sulfide ores showed that sphalerite recovery is better in process water than in tap water. Flotation results also indicated a varied recovery of sphalerite at different temperatures in either tap water or process water.

By Steve Kral

The Red Dog zinc-lead deposit, said to be the world's second largest, is located inside the Arctic Circle in northwestern Alaska - a location too harsh and remote for some mining companies but just right for Cominco Ltd. The complex has been in operation since November 1989 and is producing 508 kt/a (560,000 stpy) of zinc concentrate, 109 kt/a (120,000 stpy) of leadconcentrate and 45 kt/a (50,000 stpy) of an Imperial Smelter Feed, a combined zinc-lead mixture that is too small to separate. All of this concentrate production derives from a relatively modest mine production of 5.4 kt/ad (6000 stpd) extracted from a surface pit. Despite being a high-grade zinc-lead deposit, Red Dog's metallurgy is complex, requiring a very fine grind and use of column cells for flotation. The Red Dog complex is located in the DeLong Mountains. They are characterized by eight stack and folded thrust blocks that contain sedimentary and igneous rocks. The Red Dog deposit is located in the second lowest thrust and ist hosted by late Mississippian to Permian age black shale, the Ikalukrok member of the Kuna formation. The Red Dog mining complex is operated by Cominco Alaska, Inc., a wholly owned subsidiary of Cominco American, Inc, which, in turn, is owned by Cominco Ltd. In 1980, the deposit region was acquired by NANA Corp. as part of the Native American Claims Act Settlement of 1971. NANA is one of 12 such Native Corporations in Alaska. In 1982, NANA and Cominco American signed a develop¬ment agreement and formed Cominco Alaska to manage the project.

Jan 1, 1992

By James Matlock

The announcement of a minable reserve of 13.6 Mt (16 million tons) averaging 0.9 g/t (0.027 oz per ton) Au and 2.4 g/t (0.71 oz per ton) Ag for the open pit-heap leach reserve at Red Mountain No. 3 in Ouray County, Colorado, by Cornucopia Resources in November 1985 brings another open pit-heap leach precious metal ore body to the production stage. With about 8.2 Mt (9 million tons) of waste and metallurgical studies showing acceptable recovery rates, low reagent consumption, and good final percentage recovery, Red Mountain is a discovery that will add to the precious metal inventory of the US. Frank Baumgaruler of Denver, CO, recognized the precious metal potential in Red Mountain No. 3 and acquired all of the old claims. James Matlock conducted a field reconnaissance over Red Mountain No. 3 independently of the Baumgartner activities and recognized epithermal alteration and mineralization in the Tertiary volcanics. He recommended acquisition of the ground and was able to obtain rights and drill six core holes for Amoco in 1982. Amoco drilled a further nine core holes in 1983, but then dropped the property. Cyrano Resources examined the data and through its consulting geologist, V.F. Hollister, acquired the rights dropped by Amoco. In 1984 Cyrano began further drilling of the ore zone demonstrated by Amoco but they were then acquired by Cornucopia Resources. Cornucopia completed development of the property and commenced the permitting process in 1986. The property was recognized as a disseminated gold deposit by both Baumgartner and Matlock, and both deserve credit for properly evaluating mineralized outcrop in the Tertiary volcanics. However, Cornucopia recognized the profit potential in the heap leach exploitation of the ores and de- serves credit for completion of premine feasibility studies. The discovery is clearly a geological one, but the premine engineering studies were essential to the conversion of the prospect to a commercial mining enterprise. The deposit lies on the circular bounding fault of the Silverton caldera. Two reprints follow that help understand the geologic setting of the ore controls.

Jan 1, 1990

By A. Taghavi, I. Hassan, A. Solecki

"The Eglinton Crosstown Light Rail (LRT) Project is part of an $8.4 billion investment to expand transit in the Toronto, Canada area and is the largest transit project initiated in Province’s history. Settlement control and impact to over 1400 adjacent structures due to tunnelling was identified early as a critical project risk. The ground conditions along the 10km tunnel alignment consist of water bearing soft ground deposits (clays, sands, silts) which required careful analysis and control during design and construction. This paper will describe the process used to analyze settlements along the numerous of adjacent structures and evaluate achieved settlement results to those used during design. The paper will demonstrate that with the appropriate design specifications, selection of modernized EPB machines, and contractor performance, settlement can be maintained well below typical industry (volume loss) standards, expanding the application and suitability of soft ground tunnelling in sensitive settlement areas. INTRODUCTION The Eglinton Crosstown Light Rail Transit (LRT) Project is part of an $8.4 billion (2010$ CND) investment from the Ontario provincial government to expand transit in the Toronto, Canada area. The project is being developed by Metrolinx, an agency of the Government of Ontario to provide 19 kilometers of dedicated LRT service connecting the City of Toronto from the west to east along Eglinton Avenue. Upon completion in the year 2020, the Crosstown will be the first LRT constructed in Toronto. It will link regional and local transit, cut travel time along the route by half and provide over a thousand jobs during construction."

Jan 1, 2016

By H. Burton

"The selection of the ultimate pit shell has a major impact on the overall value of a mining project. The size and shape of this pit drives the selection of pushbacks, equipment, and project strategy, each of which are significant in their own right. Optimization of the ultimate pit shape is typically done using the Lerchs-Grossman algorithm with inputs of production costs, commodity prices, and pit slope constraints. This method ensures that every tonne mined is profitable but does not take into consideration the timing of material release. This timing is essential when calculating the Net Present Value (NPV) of the project, which is one of the most popular metrics for valuing deposits. Often, when the mining schedule and discounting are applied, material that was considered profitable before discounting becomes sterilized. The objective of this paper is to show the methodology for improving ultimate pit selection by considering the production schedule. Application of this technique will generally produce a smaller and higher-value pit than using the Lerchs-Grossman algorithm alone. INTRODUCTION The Lerchs-Grossman Algorithm was developed in the 1960s and exists to produce a mathematically optimum shape for open pit mines (1). This algorithm is now an industry leading technique for producing the theoretical optimum shape for open pits and is used in many popular pit optimization and strategic planning software packages, such as GEOVIA’s Whittle. The Lerchs-Grossman (LG) Algorithm is based on graph theory and optimizes on the assumption of non-discounted cash flows. This produces a mathematically optimum shape, but does not consider the timing with which the material will be removed from the ground. This is an important consideration, given that one of the most popular metrics for evaluating mining projects is Net Present Value (NPV) (2), which relies on the timing of cash flows as a major differentiator between options. This paper will discuss issues inherent in the use of ultimate pit selection based on undiscounted economic factors and illustrate a simple technique in Whittle, a leading software package, which can be used to improve the NPV of projects."

Jan 1, 2015

By M. Menegaki

Restoration of abandoned mine sites is still one of the weak points of mining practice. The latter stands especially for the case of the surface coal and lignite exploitations, where the extended size of the disturbed land and the drastic changes to the geomorphologic features do not facilitate the implementation of a cost effective and environmentally sound reclamation plan. The paper examines the parameters involved towards the legal requirements for the reclamation of the first lignite exploitation in Greece, namely the ?Plakes? mine, located at Euboea, due to the particularities of the site. Then an integrated redesign procedure is presented, aiming at minimizing aesthetic degradation, confronting technical difficulties and preparing the site to accept new uses.

Jan 1, 2005

By Thomas M. Goodell, Timothy D. Arnold

Dilute-phase pneumatic conveying has been used in the mining industry since the 1920s. It has primarily been used for the hoisting of coal and salt ores, and as a transportation medium for backfill material. More recently there have been investigations into a wider variety of applications, which this paper addreses. The paper will point out some deficiencies in the system. It 1s not the "champion" of the mining industry, but rather an excellent srste?1 with a variety of applications that may not have been studied m enough detail. The most imaginative applications to the Redpath Pneumatic Conveying System have been initiated by persons needing an innovative application to a specific predicament.

Jan 1, 1992

By R. Oler

The mining industry?s traditional preference for protective coatings in corrosive environments, due to cost considerations, has been to apply galvanized and epoxy coatings. As a result of extreme pH levels and the limitations of current products, a new coating has been developed to withstand severe conditions. Harsh chemicals and corrosive groundwater pose added challenges to mines in maintaining long term ground support which demands continuous rehabilitation. This paper highlights the challenges and identifies a solution by applying a new economic coating to DSI?s Omega Bolt? that withstands the most corrosive of conditions. [ ]

Jan 1, 2012

By Justin Carl, Aliuddin Mohammad, Gordon Evans, Steven Bealby, Carlton Ray

"The District of Columbia Water and Sewer Authority (DC Water) is implementing the $2.2-billion DC Clean Rivers Project (DCCR) to control combined sewer overflows (CSO) to the Anacostia and Potomac rivers and Rock Creek, and to provide flood relief to the Bloomingdale and LeDroit Park neighborhoods in the District of Columbia. The long-term control plan complies with the requirements of a Federal Consent Decree entered into by DC Water, the District of Columbia and the United States, as represented by the U.S. Environmental Protection Agency and the Department of Justice. The Northeast Boundary Tunnel, a design-build project, will store combined sewage and deliver it to a system of downstream tunnels and ultimately to the Blue Plains Advanced Wastewater Treatment Plant (Blue Plains), where it will be treated. In addition, the Northeast Boundary Tunnel (NEBT) is a major project associated with the mayor’s task force to alleviate extreme flood events in Bloomingdale and LeDroit Park. The Northeast Boundary Tunnel Utility Relocations (NEBTUR) design-bid-build (DBB) project is an accelerated component of the Anacostia River System, as shown in Fig. 1. During dry weather conditions, the entirety of the sewage in the combined system is conveyed to Blue Plains.During storm events, when sewer pipe capacity is exceeded, the flow, which is a mixture of sewage and stormwater runoff, overflows into receiving waters through outfalls. There are a total of 47 active CSO outfalls along district waterways.The influx of storm runoff into the combined sewer has an additional impact on the communities of Bloomingdale and LeDroit Park. The sewer system is outdated and undersized. In these neighborhoods, when the capacity of the sewer is exceeded, localized flooding occurs and backups into adjacent residences are prevalent. In any given year, there is a 50-percent chance that flooding will occur in these neighborhoods."

Jan 9, 2017

By L. Darkwah

The use of explosives in coal mining inevitably results in oversize, midsize and undersize (fines) products due to fragmentation. The oversize can be broken into smaller sizes by further processing. However, the undersize have a negative affect on the efficiency of a mining operation. Therefore, limiting the amount of fines can be economically crucial. This paper concerns investigations aimed at reducing fines generation in coal mining. Inherent fractures were identified as one of sources of fines generation. This paper is centered on establishing a relationship between the fracture occurrence, the explosive properties and the blast outputs, which are evaluated in terms of the fines generated.

Jan 1, 1998

Explosives are used to mine coal. Any blast results in three size categories of products, namely over-, middle-, and under-size. Boulders can still be broken smaller in further operations after blasting. The under-size, for instance coal fines, negatively affects the mining efficiency. Their reduction ensures better returns. The paper concerns investigations aimed at reducing coal fines' generation. Inherent fractures are identified as one of source of fines. The discussion is therefore centered on establishing a relationship between the fracture occurrence, the explosive properties and the blast outputs evaluated in terms of the fines generated.

Jan 1, 1996

By David D. Gallagher

Customer demand for greater efficiency and reduced operational costs on modern overland conveyors has focused attention on the conveyor belt's rolling resistance properties. Studies have indicated as much as 60% of the power losses on a long horizontal conveyor can be attributed to the indentation of the pulley cover rubber as it passes over idlers. This paper will compare tan delta values of different compounds with large scale rolling resistance test data from the University of Hannover. Results will then be compared to actual power consumption data gathered on several long overland conveyors using identical belt construction except with different pulley cover compounds. Concluding comments will be made indicating substantial operating cost differences based on the rolling resistance of the cover compound.

Jan 1, 2000

By Phillip J. Maddex

After the presentation of a co-authored paper, "The Cost of Transporting Ores and Raw Materials in World Markets", at the February SME meeting, one questioner commented, "You have been talking about the large shipper and ship loads. What does the small shipper do?" This paper will attempt to answer that question, at least in part. Probably the questioner hoped to hear about specific new tools and new techniques that he could apply. But one paper could only scratch the surface of the vast fund of information available; so rather than talk specifics we should take basics, that is, people, management and technology.

Jan 1, 1967