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By N. Sheikh

In galena flotation, lead ethyl xanthate, Pb(EtX)2, is precipitated and is physically adsorbed in the form of multilayers on the chemically adsorbed first layer of Pb(EtX). 1,2) The solid particles are coated with layers of Pb(EtX)2 in heterogeneous manner over surface areas possessing both anodic and cathodic character (3,4) It is anticipated that the mode of formation of Pb(EtX)2 and the number of ions present, together with stable or unstable by-product species, have great influence on the surface characteristics of galena. The information obtained from a study of these parameters may have important practical applications in flotation. Lead ethyl xanthate is sparingly soluble in water. The metal and xanthate ions released to the aqueous solution during its dissolution undergo various types of reactions depending upon the pH values of the system. Extensive work (5,6) has been carried out to elucidate the mechanism involved in acid decomposition of xanthate ions. Different decomposition paths (7,8) have been proposed for the hydrolytic decomposition of xanthate in neutral and alkaline solutions, The concentrations of lead ions vary due to a number of chemical reactions, regulated by the pH and the temperature of the bulk phase. The hydrophobic character of Pb(EtX)2 may change with the nature of chemical reactions. Some of the numerous by-product species in solution may adsorb on the solid and change the properties of surface film either favourably or adversely. The flotation performance of galena, therefore, may depend to a considerable extent on the physical and chemical stabil¬ity of Pb(EtX)2 layers. Since little work has been reported in literature dealing with the stability of Pb(EtX)2 and its correlation with the flotation of galena, attempts have been made In this study to evaluate the behaviour of freshly formed Pb(EtX)2 in aqueous systems at various pH values.

Jan 1, 1971

By Otis M. Clarke

The Eufaula bauxite-kaolin district in southeastern Alabama is an important source of raw material for the refractory industries in the United States. At the present time, five companies are mining and processing bauxite and kaolin from this district and a sixth company is holding substantial reserves. Mining operations are expanding, but finding new ore reserves is a major problem. The Geological Survey of Alabama sponsored geologic research in the Eufaula district to: 1) investigate the utilization of sandy kaolinS and other clays associated with bauxite-kaolin deposits; 2) find limits of the bauxite district, looking for possible extensions; and 3) study the geology of the district, looking for patterns or trends that may aid in finding new ore reserves. This work was done with the full cooperation of mining companies operating in the district and property owners. Research was aided by the U.S. Bureau of Mines and the University of Alabama. The investigation included detailed geologic mapping of mines, drilling in selected areas, and making mineral analyses of bauxite and clays. The mapping was performed primarily by pace and compass because of the complexity of the deposits studied, but aerial photographs were used to a limited extent. Drilling included both auger and core drilling. The auger drilling was limited to 100 feet, but core holes were drilled as deep as 200 feet. The term 'bauxite,' as used here, indicates a mixture of minerals containing more than 50 percent gibbsite. Bauxitic clay is a mixture of gibbsite and kaolinite that contains more kaolinite than gibbsite. The term "kaolin" indicates a clay composed of predominantly kaolinite. Other clays in the Eufaula district are composed of kaolinite, illite, quartz, mica, and goethite or hematite.

Jan 1, 1971

By Laszlo Valentyik

Heavy media separation (HMS) is one of the most widely used gravity methods in the mineral industry. The feed is separated, according to the specific gravities, into two products; float (light) and sink (heavy) particles. The universal acceptance of the process is due to simplicity, efficiency and robustness for ease of control. However, if optimum separation is desired during the operation of heavy media plants, a delicate balance of a number of variables is essential. Among the variables, the two which are generally the most frequently checked and controlled are specific gravity and consistency of the medium. The latter is a function of the settling rate of the media. The medium is generally made up of finely ground ferrosilicon, magnetite, galena, shale, quartz sand, clay contaminants and water. The frequently present clay in the medium acts as a stabilizing agent, since the coarse heavy medium solids (called media) would quickly settle if they were mixed only in water. Clay concentration of the medium varies between 3-7% by height (1,2). Although clay is essential for reasonable media stability, clay concentration greater than 7-8% imparts too high a viscosity to the medium, and the feed cannot accurately stratify and therefore separate into the required products. To be on the safe side, plant operators clean the medium from most of the clays, and would rather work at a lower stability than have a very viscous medium on their hands. The most recent advance in the area of consistency control rlas made by the introduction of atomized (spherical) ferrosilicon (3). This extended the upper limit of the use of ground ferrosilicon from 3.3 to approximately 3.6, broadening the range of the optimum operating conditions. A viscosity control method was also worked out by the use of low cost additives which lower viscosity while retaining a favorable low setting rate (4). Recently (5) polymers have been successfully used in oil well drilling muds then the requirements were mainly to suspend and transport cuttings during the periodic shutdowns and dril1ings respectively. The rheological properties of these polymer suspensions are such that they present an infinite viscosity to

Jan 1, 1971

By Vernon N. Cox

From comments and questions concerning the meaning of USNR, and "why is the Navy in the mining business?" I believe it is worth while to establish the background and purpose of our company. We are a stock company formed by the purchase and reorganization of a company known as the U. S. Natural Gas Corporation. In May 1969, a group of investors with Mr. Robert L. Katz as president and chief executive officer, created United States Natural Resources, Inc., to develop and purposively use our Natural Resources in four areas: 1. Mines and Minerals 2. Forest Products 3. oil and Gas 4. Recreational Lands As final proof that we are not a government organization, I simply state. "We pay taxes." The mining division was formed in October 1969, with the completion of the merger of USNR and Vibration Measurement Engineers, Inc., Of Evanston, Illinois. Throughout the industry we were known as "VME," our company supplied consulting service in the field of seismic energy control, mining consulting and. we operated drilling, blasting and, contracting organizations in several areas of the country. Since that time we have developed and acquired producing properties in Quarrying, Coal Mining and Cement Copper Production.

Jan 1, 1971

By Enrique Levy

The publication from which this paper was abstracted is the first at-tempt to correlate all the metallogenic deta compiled by the author for the preparation of the 1:2,000,000 Metallogenic Map of Central America. It is not a treaty of metallogenic theories but rather a careful effort to postulate metallogenic provinces and epochs with the intention to stimulate other geologists and mining companies familiar with the area to criticize and improve on the ideas proposed. The sole purpose being to find new mineral deposits for the betterment of our people.

Jan 1, 1971

By Marcus M. Key

Silicosis among metal miners is an ancient disease, probably as old as mining itself.' However, the primitive forms of mining were not productive of much silica dust, and the short life span of slaves used in mining probably precluded the development of more than a few sporadic cases of silicosis. Early diagnostic terms of miners' asthma and miners' phthisis suggested an occupational relationship and a tubercular component, but little attention was given to silicbsis until the turn of this century when epidemics of silico-tuberculosis arose due to the great expansion of the mining industry in the United States, especially silver and gold mining. The expansion was accompanied by mechanization and the introduction of pneumatic tools, which generated increasing amounts of fine silica dust. Mining communities were crowded and hygiene was poor.' The tubercle bacillus would probably have flourished even without the predisposition of silicosis.' As is so often the case in occupational health, biostatistical analyses first called attention to the problem, and environmental-medical studies later confirmed its existence. The bio-statistical analyses were occupational mortality statistics compiled by the Prudential Life Insurance Company in 1907, showing evidence of excessive mortality from tuberculosis and relationship to dust exposure. I The

Jan 1, 1971

By C. G. Hunkin

In situ, or in-place leaching is concerned with the extraction of metals from natural mineral disseminations without removal from their geologic location which, in many cases, amounts to the reversal of the deposition process accompanied by a presumed increase in velocity of the processes, if the project is to be profitable. Solution mining processes involve removal of minerals such as sulfur, common salt, and potash, generally leaving cavernous voids, in contrast to in situ leaching which term is applied to the selective dissolution of a mineral from its gangue without sensible disturbance of the formation. Where such a process can be operated, the advantages are manifold and have been so recognized by miners from the earliest days of mining. Recent technological developments have encouraged a reassessment of the status of in situ leaching, and it now appears possible to extend the application of the method from a few isolated special situations to many uranium and copper deposits. Anaconda's interest in the techniques stems from long experience with vat and heap leaching, 'dump leaching, and natural leach activities associated with several established mines. Increasing activity through-out the industry has been noted, particularly in leaching low grade pillars and the peripheral zones of operating mines, often by the introduction of leach solutions via boreholes drilled from surface. Reactivation of dormant mines] using similar techniques has been successful. Over the long term, environmental improvement activity will lead to excess sulfuric acid production, even to a disposal problem. The cost of leach solutions and reagents must be reexamined in this light. The mineral industry now classifies as uneconomic deposits of readily soluole minerals whose potential value, on a per acre basis, may De several times that of many currently profitable oil field reser-

Jan 1, 1971

By Wilfred Walker

Much is known of the geography of the Alpine orogeny because it has now ended and all geosynclines are in their terminal, cordilleran form. The principle of sea floor spreading, continental drift, and mantle cells has gained general acceptance, but the number and position of the cells, even during the Alpine orogeny, is controversial. The oceanographers have demonstrated the uprises and in this paper it is suggested that downflows are marked by island arcs in the oceans and geosynclines (now cordillera) in the continents, for a total of about a dozen cells. Major mineral deposits associated-with the Alpine downflows are porphyry copper, molybdenum, nickel, chrome, lead-zinc-silver, gold, mercury, tungsten, and tin. Amore precise environment is known for some of these metals, for example, nickel, chrome, and mercury in flysch (which flanks mantle downturns), Ten major orogenies have taken place from 3500 m.y. to the present, Their re¬construction and metallogenesis is the subject of a continuing study.

Jan 1, 1971

By E. Kenneth Siroky

The concept of ultrasonic measurement was originally applied to marine operations. Sonar . . . standing for Sounding, Navigation and Ranging, was developed for military uses. Today Sonar has become very important to the fishing fleets and marine construction industries where its applications cover a wide range of uses our company, in addition to the inair ultrasonic equipment as discussed in this paper, is also deeply involved in marine sonar and works primarily with oceanographic research and fishing industries. Ultrasonics, by simple definition, are sound waves beyond the audible range of the human ear and are generally accepted to be waves over 20,000 cycles per second. When applied to level measurement, the principles of ultrasonics are basically quite simple. A sound pulse is initiated at a point in time and the time interval for the echo from that pulse to return can be interpolated into distance. The speed of sound in air under standard conditions is approximately 1,100 feet per second, or if converted into more meaningful information as related to distance measurement, the time required for sound to travel one foot round trip is 1.78 milliseconds. An early application for ultrasonic level monitoring equipment was in large grain elevators. Prior to ultrasonics, the common practice of inventory measurement was to have an employee walk around the top of these large grain elevators, which are often over 100 feet above ground level, and drop a weighted rope or chain down into the silo to determine the level of the grain. Needless to say, this was a slow process and could be extremely unsafe, especially during windy and snowy weather conditions. An alternate

Jan 1, 1971

By Richard L. Gordon

At almost no time since the end of World War I has the coal industry been free from serious threats to its competitive position. At present, the critical question is whether the industry can maintain its position in the electric power market and this paper reviews the prospects in this area. Our report is part of a study, supported by Resources for the Future Inc., dealing with coal demand in general. Like most elements of coal economics, it has received much less analysis than problems in other energy sectors--a defect we felt worth correcting. We have concentrated on electric power elements of the market. The nature of the coal market makes this the natural choice. Three markets absorb over 80 per cent of coal production and are considered in our overall work. The completely excluded sectors are largely catchall categories in which coal use is declining anyway. Comparing the three markets included in the overall study, we see: modest growth is the most optimistic forecast for metallurgical coke; export growth depends to a large extent on policies of foreign governments. Electric power use, however, has rapidly grown to absorb over half of coal output and coal's prospects depend almost entirely on continued expansion of this market. Throughout the 1960's the demand for coal used to generate electrical power in the United States grew at an average rate of 6.5 per cent annually. This growth rate will be sustained until at least 1976.

Jan 1, 1971

By F. Montgomery Lyon

Pyritic sulfur in coal occurs as discrete mineral particles, and its liberation and physical rejection is the primary target for coal desulfurization. An acceptable solution to the pyrite removal problem from fine coal is not found in the standard methods of coal cleaning such as jigging, heavy-medium separation, tabling, and hydro-cycloning. Although fine coal is an ideal size for froth flotation, this method, as currently practiced is also unsuitable as the fine pyrite usually floats with the coal. One possible solution to this problem may be the froth flotation of pyrite from coal. This reverse flotation scheme would have the major advantage of removing both free pyrite and locked pyrite-coal combinations. With this possibility in mind, we have, as a first step, compared the flotation and adsorption. characteristics of an ore-pyrite and coal-pyrite with potassium-ethyl-xanthate as a collector 1 Related Research. The action of ethyl-xanthate on coal has been studied 2 by Horsley. He measured the contact angles of coal in distilled water and in the presence of purified ethyl-xanthate. The results indicated that the xanthate was not adsorbed by the coal. Additional contact angle data were obtained to determine the effects of cupric, ferric, and ferrous salts on the system. Then either the ferric or cupric salts were in, solution with the xanthate, there was an increase in the natural contact angles of the coal. This indicated that these heavy metal ions activated the flotation of the coal with xanthate. However, ferrous iron did not act as an activator. Horsley stated that the most attractive explanation was that the xanthate is oxidized to dixanthogen in the presence of the ferric and cupric ions.

Jan 1, 1971

By Joseph M. Chelini

The report shows the sensitivity that nine different cash-flow factors have on the discounted rate of return calculated from feasibiliity- studies on potenital open-pit orebodies of silver, copper, and uranium. Cash-flow factors of "grade", "market value", and "recovery" are. the most sensitive. This verifies the need of reliable estimates for these factors. The cost of evaluation of "preproduction cost" is the least sensitive. This gives credence to the fact that more consideration should be given to compiling sufficient data, as the largest financial losses are not in the cost of evaluation but rather in the abandonment of an unprofitable mining operation after a commitment of capital is made on the basis of an incomplete evaluation. Sensitivity analysis of cash-flow factors enhances evaluation programs by disciplining the collection of data and allowing more realistic distribution of evaluation monies.

Jan 1, 1971

By R. C. Emmett

Waste treatment in the mining industry is by no means a new problem to this field. In a sense, the entire process from ore to finished product is one of waste treatment - the separation of a relatively minor quantity of desired component from valueless material. Where it has been necess-ary or economical to practice conventional waste treatment or pollution control methods, such as dust collection, water recovery from tailings, or impounding of residues for future treatment, this has been done. Generally the containment of hazardous pollutants such as arsenic and cyanide also has been followed in modern times. But it is only recently, with the public outcry for the elimination of all forms of pollution, "that the industry has been forced to solve what often appears to be a myriad of difficult and costly waste treatment problems, or be faced with the alternative of closing down the operation. It is the objective of this paper to describe new as well as conventional approaches to these problems, specifically as might be applicable to liquid-solids separation methods. Host wastes in the industry are present either as solutions or slurries, or can be most advantageously handled by conversion to this form, such as in scrubbing noxious gases and dusts with water. Separation of the solids and purification of the aqueous effluents are, therefore, often the principle problems.

Jan 1, 1971

By Y. J. Wang

This paper deals with the application of linear programming to the solution of mine ventilation network problems which involve only the controlled splitting of air. An airway whose air quantity is to be controlled to a prescribed value is called a "fixed-quantity" airway. In a network where the fixed-quantity airways are increased in number and are distributed such that the air quantities for the remaining airways are uniquely determined by Kirchhoff's first law, the problem reduces to determining the head losses and locations for air regulators and fans. This is one of the network problems encountered most often in underground coal mines. By formulating Kirchhoff's second law as a set of linear constraints and the total air horsepower supplied by fans as a linear objective function which is to be minimized, the problem is analyzed through the technique of linear programming. Some important properties of the problem are discussed and examples are presented.

Jan 1, 1971

By McCarthy. Richard E.

The prime movers of the Centralia Project, the surface coal mine and the power plant, private utilities are very aware of public attitudes. They have established and maintain the reputation for leadership in public service and are genuinely concerned that this project initiate the pro-grams and design the hardware to answer the question :What will be the impact of the mine and the plant on the physical environment, i.e., the air, soil and the water." So in the beginning almost as soon as the decision had been made to go ahead with the project, officials of the two private utilities, Washington Water Power and Pacific Power & Light went on record and publicly stated time and again that the overall approach of the Operators would be to do all that was reasonably possible to safeguard the environment. This attitude became part of the thinking of the project planners, part of the design of the power plant and part of the plan for the surface mine. The coal to be mined is from the Skookumchuck formation. The formation is Late Eocene and is made up of poorly consolidated marine and non-marine deposits. The major overburden removal equipment is a bucket-wheel excavator -conveyor system and a 56 yard dragline. Mining of the coal will be done with truck and shovel. The coal is processed, washed and crushed to 1 ¼ " for delivery to the power plant. The muddy water created by the washing process is chemically treated and the solids removed by a thickener-vacuum filter system.

Jan 1, 1971

By R. F. Yap

Although laboratory studies of tin flotation have been reported as far back as the 1920`s(1), the commercial application has only been realized within the past few years(2,3). The principal technical difficulty in the application of the process to tin ores has not been in the flotation of cassiterite itself, this mineral being readily recoverable with the common collectors, including xanthates with heavy metal ion activation(2). The difficulty has been with the depression of the gangue minerals commonly associated with tin ores, and to a lesser extent with the problems of collector consuming semi-colloidal minerals which are in some cases present. The application of sulfosuccinamate collectors to flotation of cassiterite from the Catavi, Bolivia, slime tailings has recently been described(3). The investigation which led to this successful process development included studies of other samples of gravity plant tailings as well as of lode tin ores. A common flowsheet with few significant variations was applied to most of these ore samples with acceptable results. In the following the process is described and the results of its application to samples from Bolivia and elsewhere given. Among the factors considered are: gangue depression, particle size and slime effects, and reagent and pulp density levels.

Jan 1, 1971

By James Crosby

The Urad property had been worked intermittently for over 50 years before American Metal Climax (AMAX) started an extensive exploration program on this property in 1961. The detailed studies of the property proved a large ore body of low grade molybdenum ore that could be mined by modified panel caving methods. Mine development and mill construction for a 5000 TPD operation was completed in July 1967. The Urad mine and plant site is located 55 miles west of Denver near Berthoud Pass. The plant elevation is 10,200 feet. The crushing plant is located underground because available surface area is re¬stricted by snow slide hazards. Crushing plant layout and ventilation system design for the Urad mine was based on our operating experience at similar crushing facilities located at the Climax operations. Low speed conveyors of generous width, adequate exhaust volumes at all ore transfer locations, large hoods and good conveyor skirting have made the Urad underground crusher dust control operations very satisfactory. Good maintenance and cleanup of the crusher facilities have made a clean working area with very low dust exposure. The ore from the mine is dropped approximately 1000 feet through ore passes to scraping drifts above the crusher and then transferred to the coarse ore bin by 150 h.p. slusher hoists. A reciprocating plate feeder under the coarse ore bin feeds a 48 x 60 jaw crusher. Ore from under the crusher is conveyed on a 48 in. belt to a vibrating screen where oversize passes through a 7 ft. Standard cone crusher. The crushed ore along with the screen undersize is conveyed on a 42 in. belt to a 1000 ton surge bin.

Jan 1, 1971

By Howard V. Sears

Prospecting in its modern context means simply the gathering of information on which, to base plans for the utilization of our mineral resources. One prospecting system familiar to T. V. viewers is the pan of the old gold prospector which, while he prospected, could produce the wealth which financed him in his search. Present day geophysical "prospecting" systems, which are based on the real or supposed responses of an ore specimen, to various stimuli finder controlled laboratory conditions, are promoted as means of reducing the cost of prospecting. The universal drawback to all geophysical systems is that they yield "soft" data which are only presumed to be analogous to ore mineralization until they can be calibrated, by conventional prospecting systems, to each actual mineral environment being tested. By this time the system usually is no longer cheap. Since the raw data are too esoteric to be used until interpreted by geophysicists, usually in the light of their own personal theories and experience, the certainty of multiple interpretation is introduced. The concept of prospecting, at St. Joe Minerals Corporation's Viburnum, Fletcher and Brushy Creek mines in the new Missouri Lead Belt, encompasses surface diamond drilling for preliminary exploration, the sub¬sequent development of ore body tonnages and grades and the establishment of mining parameters. The predominantly flat-lying mineralized formation is mined by room and pillar stoping. In an operating mine, jackhammer holer are drilled in backs and bottoms of stopes, and chip samples are taken for assay, concurrent with mining. Thus irregularities in ore bodies or nearby discontinuities are not overlooked which are above or below the general mine

Jan 1, 1971

By Steven L. Webb

In 1965, Monsanto started planning of a new dike (No. 15) for use in disposing of ore tailings at its Columbia, Tennessee phosphorus plant. Generally, in the phosphorus industry only clay tailings are produced making it necessary to borrow fill for construction of a retaining dike. Borrow area investigations indicated that weathered shales and limestones adjacent to the dam site would provide adequate construction materials. It was proposed that the more clayey weathered shales would be used for the impervious core and the more granular weathered limestones would be placed in the outer shell of the dike. A dike section is shown in Figure 1 with gradation curves for core and shell materials in Figure 2. Figure 3 shows an aerial view of the tailings pond and dike during first-stage construction. Although the borrow area explorations indicated that the weathering of the sedimen-tary deposits was highly irregular, it was not considered necessary, at the time, to specify special excavation techniques that would ensure a thorough blending of the materials in the borrow pit. Instead, because of the short haul distance, a scraper operation for both clay core and granular shell materials was adopted as the most economical construction method. Using this materials-handling technique, variations in permeability could be expected in the compacted layers inthe embankment. Where continuous layers of less clayey limestones were placed in the core of the dam, extending from the upstream to downstream shells, seepage losses would be expected to increase substantially. Upon completion of the damn 1966, and shortly after reservoir filling, it was apparent that the construction technique used had resulted in the formation of pervious layers through the clay core. Excessive seepage on the downstream face of the dike was noticeable within a very short time. A monitoring program was established, using piezometric observations and flow measurements. These data indicated that seepage should be reduced and the application of an asphaltic emulsion

Jan 1, 1971

By Charles G. Zink

Early anthracite "deep mining" methods, production, manpower. underground transportation, labor, safety and reserves are reviewed and compared to the present and to future requirements which must be met in order to economically win the fourteen million tons of untapped reserves and to keep the product competitive in the market place.

Jan 1, 1971