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By G. Van Weert

Refractory ores and concentrates containing silver tend to form Ag-jarosite during autoclave oxidation. Silver extraction from the oxidation products is therefore low, unless a hot lime treatment step to decompose Ag-jarosite precedes cyanidation. Since silver iodide is very stable but soluble in cyanide solutions, the formation and decomposition of Ag-jarosite in the presence of iodine species was studied. Results indicate that Ag-jarosite formation could be prevented in favour of H3O-jarosite and AgI while oxidizing Ag2S under industrial autoclaving conditions, when the total iodine species to Ag mole ratio exceeded 5. Lower ratios gave proportionally more Ag-jarosite and less AgI. Under these conditions existing Ag-jarosite was also found to decompose in H30-jarosite and AgI.

Jan 1, 1993

By R. J. Sweigard

Deep tillage is used widely as a Means of alleviating excessive soil compaction. There has been some concern that the voids created by deep tillage may collapse before a more natural soil structure develops, resulting in recompaction subsequent to deep tillage. A laboratory investigation was conducted to determine the feasibility of pneumatically injecting organic material into the voids during deep tillage to prevent any significant recompaction from occurring. Various amendments were injected into the soil in the laboratory using a small-scale ripping and injection system. Measurements were made of selected soil properties to evaluate the feasibility of this method.

Jan 1, 1993

By W. E. L. Minter

Discussion by R.W. Hutchinson Minter's excellent recent paper (1990) on the great paleoplacer gold deposits of the Witwatersrand and its subsequent discussion (Cheney, 1991) and reply (Minter, 1991) provide an informative, interesting and up-to-date review of the geology of these unique ores and some long enigmatic questions regarding their origin. Clearly summarized by Minter (1990) are the compelling sedimentologic and stratigraphic relationships indicating that the Central Rand Group conglomerates are ancient placers and documenting the fluvio-deltaic conditions of their transport and deposition. As Minter (1991) indicates, Cheney's discussion broadens Minter's 1990 coverage of the subject by considering higher and lower stratigraphic units and by adding detailed comments concerning recently published information about metamorphic and age relationships. Cheney's discussion and Minter's reply also readdress the old controversy of epigenetic hydrothermal vs. syndepositional placer origin for these deposits. This controversy has been resurrected by: • recent recognition of hydrothermally-altered granites (HAGS) in the older Archean basement rocks that lie unconformably beneath the Dominion Group rocks north and west of the Witwatersrand depository; • recognition of greenschist metamorphic assemblages in the Witwatersrand strata; and • the presence of interpreted epigenetic mineral assemblages and textures in some of the deposits. These relationships are briefly discussed by Cheney who suggests they may result from later, superimposed metamorphism and deformation and do not prove that the gold was introduced by epigenetic/metamorphogenic processes. In his paper, Minter (1990) cited the 1986 abstract of a subsequently published paper by Hutchinson and Viljoen (1988) who also considered many of these aspects and attempted to integrate them all in abroad genetic hypothesis. In addition, they emphasized the additional important problem of determining the source for the Witwatersrand gold. Although this issue was partially addressed by Reimer (1984), Mossman and Dyer (1985) and Reimer and Mossman (1990), the question has been generally under emphasized in earlier work and was, therefore, not stressed by Minter and Cheney. Reimer (1985) also emphasized the importance of weathering of the basin's Archean hinterland and its affects on Witwatersrand sedimentation. Since the epigenetic hydrothermal hypothesis was essentially discarded in favor of placerist origin, the gold source for these great deposits has generally been attributed to the weathering of lodes in greenstones or granites of the uplifted, older Archean hinterland to the north and west. However, Hutchinson & Viljoen (1988) present evidence that this explanation is inadequate, as well as data in support of an alternative explanation. They suggest that the gold and accompanying abundant, clearly detrital and auriferous pyrite in the conglomerate reefs were derived by erosional degradation of auriferous-pyritic exhalite previously deposited, by shallow marine discharge of hydrothermal fluids, along the fault-bound northwestern margins of the Witwatersrand depository. The auriferous-pyritic exhalites were generated by fluid-rock reactions in the subsurface, particularly in the highly-altered lavas of the Dominion Group but also in adjacent basement granitic rocks. The process envisaged is comparable to that observed in sea floor hydrothermal systems today, although, in this case, it occurred at the margin of a rapidly subsiding, shallow marine or continental basin. Important evidence for this explanation is the anomalous gold content of the ferruginous, shaley strata occurring throughout the Witwatersrand Supergroup and including the distinctive contorted bed that is an iron formation. These layers have been interpreted (Hutchinson and Viljoen, 1988 and 1990) to represent the more distal, finer-grained, mixed chemical/clastic sedimentary strata. Thus, they are the basinal equivalents of the proximal, auriferous-pyritic exhalites that were deposited along the basin's margin and subsequently reworked by sedimentary processes. This gold source explanation resolves many of the enigmatic questions regarding Witwatersrand geology and the reawakened controversy between proponents of hydrothermal and placerist genetic hypotheses. The theory invokes a hydrothermal origin for the gold in the basin-margin pyritic exhalites, thus explaining the visible hydrothermal characteristics (Figs. 1 and 2). It also provides compelling evidence for placer origin by encompassing all of the fluvio-deltaic processes of clastic sedimentary transport and deposition that are clearly summarized by Minter. These characteristics result from the degradational reworking of the pyritic exhalites along the depository's margins. Fluvial reworking, transport and deltaic redeposition of this detritus, along with additional detritus carried into the depository from the hinterland, then formed the conglomerate reefs. Other enigmatic aspects of Witwatersrand geology include: • the rarity of magnetite and ilmenite (the two most common heavy minerals in placer deposits) and the contrary abundance of leucoxene in the conglomerate reefs; • the presence of differing varieties of pyrite (authigenic, allogenic, compact and porous) all of which are auriferous; and • the presence of well-rounded pebbles, even cobbles, of pyrite that, in view of the brittleness of the mineral, could not have been transported great distances from a hinterland.

Jan 1, 1993

The bromine review did not arrive in time for publication in the June issue. Bromine production in the United States during 1992 amounted to 171 kt (376 million lbs), a 453-t (I-million lb) increase from 1991. Data compiled by the US Bureau of Mines indicates this increase was due mainly to greater exports of elemental bromine and bromine derivatives (flame retardants). Exports increased despite the economic slowdown in Europe and Japan. The United States remains the world's largest bromine producer, with about 42% of the total. Israel is ranked second, followed by the United Kingdom, the former Soviet Union and Japan.

Jan 1, 1993

By T. P. Meloy

Riffles on a shaking table have a major effect on particle separation. This effect is modeled in a spreadsheet.

Jan 1, 1993

By S. K. Kawatra

Outokumpu Electronics has designed a new on-line coal slurry ash analyzer, based on an instrument developed at Michigan Technological University. The primary goal was to build an accurate instrument at the lowest possible cost. The instrument determines ash content from measurements of X-ray backscatter, iron K, fluorescence, and low-energy y-ray absorption. It is capable of measuring the ash content with a standard error of 1.1% ash over an analysis range of 9-21% ash and 7-22% solids. The analyzer was tested on coals from United States, Poland, Great Britain and the USSR.

Jan 1, 1993

By Brij M. Moudgil

Lack of understanding the major process parameters and inadequate scale-up factors have led to the belief that fundamental knowledge is not important for successful flotation plant operations. Flotation of simple and easy to process ores may not require a strong fundamental knowledge base for day to day operations. However, as low grade complex ores are mined and process control is integrated into flotation schemes, it is imperative for a plant operator to acquire a strong background in the basics of the flotation process at hand and/or have access to such a knowledge base at short notice. In order to meet the challenges of unexpected changes in the feed, reagent quality, water chemistry, physical, mechanical and hydrodynamic conditions, the flotation plant superintendent/chief metallurgist must have a strong background in the flotation fundamentals.

Jan 1, 1993

By S. Behl

In the selective flocculation process, polymers with specific functional groups can yield highly selective adsorption and, therefore, high separation efficiency. Selectivity in polymer adsorption may also be attained by specific additives that inhibit the adsorption of the flocculant on some solid surfaces but not on others. Generally, these additives have a different chemical nature than the flocculant. In this study, the lower molecular weight fraction of the flocculant was successfully evaluated as a site blocking agent, leading to higher separation efficiency than obtained otherwise.

Jan 1, 1993

By D. B. Dreisinger, H. J. Sohn, J. S. Sohn, G. A. Kordosky

The transport of lithium through a supported liquid membrane was studied with a mixture of D2EHPA and TBP in kerosene as a mobile carrier. In the flat- sheet supported liquid membrane(SLM) system, experiments were carried out to investigate the effects of concentration of mobile carriers in the membrane solution, hydrogen ion in the feed solution, and temperature on the transport of lithium. Experimental results agreed well with a transport model for permeating lithium across the liquid membrane. The permeation rates of lithium can be explained in terms of diffusion of a Li-complex through the membrane phase. For a practical application of an SLM method, a hollow fiber module has been used and lithium can be concentrated more than three times in 24 hours.

Jan 1, 1993

By Anthony Delvescovo, Gregory F. Aluce, Joseph A. Sopko, Lyle C. Smith

Construction of a 13m shaft through approximately 100m of water bearing soils and another 100m of bedrock was attempted using the Slurry Diaphragm Wall Method with a combination of deep dewatering wells. During excavation within the slurry wall, unexpected groundwater inflows occurred in a structure of loose silty sands. Artificial ground freezing was selected as a remedial method to seal the leaking slurry wall, and as a primary excavation support and groundwater control method for the 30m of overburden material below the base of the wall. Design of the ground freezing system required analysis of both the structural requirements of the unsupported soil, the frost effects against the existing slurry wall and the groundwater control in the area of the breech in the wall. These design procedures are summarized, and construction and excavation techniques and corresponding schedules compared in this paper. Advanced drilling techniques, ground freezing quality control and general contractor procedures for efficient shaft construction are discussed.

Jan 1, 1993

By Po-Wei Tun, Kuen-Yuh Wu, Tso-Min Shih, Hsi-Chiang Fang

The purpose of this study is to investgate the coal dust explosion characteristics and to search for the prevention methods of the coal dust explosion as well as the propagation of the explosion flame of the middle-bearing coal formation in Taiwan by an open type coal dust explosion apparatus in laboratory. The coal samples were taken from the typical middle-bearing formations of the Sam-Ming,Tai-Ho and Lee-Fong coal mines The rock dusts, the free water mixture with coal dust samples and the interval clean out the coal dust in the testing chambers were applied for preventing the coal dust explosion and the propagation of the explosion flame.

Jan 1, 1993

By J. A. Brierley, C. L. Brierley, R. C. II Blake, S. McGinness

A principal long-term goal of this laboratory is to achieve a detailed understanding at the molecular level of the microbial-dependent solubilization of minerals. Three recent advances in this research are summarized. (i) An in situ electrolytic procedure is described whereby large quantities of autotrophic iron-oxidizing organisms may be achieved for fundamental or applied studies. Over 600 grams wet weight of Thiobacillus ferrooxidans were harvested from a single 55-gallon growth vessel. (ii) A basis is presented for classifying some 70 different iron-oxidizing bacteria into one of 4 categories, depending on the type of redox-active electron transport proteins expressed during aerobic respiration on reduced iron. Comparative spectroscopic analyses indicated that different electron transport mechanisms exist in different genera and species of acidophilic bacteria that respire on iron. (iii) A method is introduced to investigate the binding interaction between bacteria and minerals, based on changes in the electrokinetic properties of the two species. Preliminary experiments indicated that the electrophoretic mobilities of pyrite and Thiobacillus ferrooxidans were both altered when the two colloid particles were mixed prior to the actual electrokinetic measurement. The need for more basic information regarding all aspects of the microbial-dependent solubilization of minerals is evident.

Jan 1, 1993

By Jr. Bacon

Kaolin clay is one of the yeoman minerals. It sees duty in almost every aspect of our lives: -in and on most paper products (from modern newsprint to National Geographic and packaging board) sometimes as much as 25% (by weight) of the product -40% of the tile (ceramic, rubber, and linoleum) you walk on. -15 % of the tires you ride on, -30% of the fiberglass filaments in circuit boards, bathtubs, boats, doors, and more, -25% of many housepaints, adhesives, grouts, caulks, and putty -30% of sparkplugs, power insulators, dinnerware. and toilets, -50% of most catalysts (both cracking and emission control) -20% of cosmetic powders. -20% of wire insulation, and animal feed to rocket insulation!

Jan 1, 1993

By A. Shakoor, A. M. Hirt

The compressive strength of coal, and its variation within and between seams, was determined for four Pennsylvania coal seams (Pittsburgh, Sewickley, Upper Kittanning and Lower Kittanning). Large coal blocks were obtained from 12 coal mines (three mines per seam) and cut into 50-mm (2-in.) cubes using a low-speed saw. The cubes were tested for compressive strength, with the results used to compute actual pillar strength. Using the tributary area approach, the pillar stress was determined. The pillar stress and strength data were used to calculate the factor of safety against pillar crushing for each mine. The cube strength was also correlated with various physical and chemical coal properties (density, percent absorption, percent ash, percent sulfur and percent carbon) to see if any strong relationships exist. The coal's mean compressive strength varies from 9.1 MPa (1326 psi) in the Lower Kittanning seam to 37.8 MPa (5480 psi) in the Pittsburgh seam. Between different seams the pillar strength varies from 29.5 MPa to 48.1 MPa (4282 psi - 6981 psi). Although coal strength appears to be weakly related to carbon content, no relationship was found between compressive strength and other physical or chemical properties. Since the values for the safety factor against pillar crushing generally exceed the recommended value of two, the existing pillars are mostly overdesigned. This implies that an accurate assessment of coal compressive strength could result in the use of smaller pillars and, thus, increased coal production.

Jan 1, 1993

By H. Braun, T. Kind, K. Gloe, D. B. Dreisinger, H. Stephan, O. Heitzsch, G. A. Kordosky

Municipal garbage incineration processes with coupled wet flue gas cleaning systems generate effluents containing toxic heavy metals such as mercury, zinc, cadmium and copper. The separation of these metal ions from the obtained scrubbing solutions is possible using liquid-liquid extraction. Extraction studies has been performed both with commercial extractants Aliquat 336, di(2-ethylhexyl) phosphoric acid and novel chelating agents as acyl thiourea and lipophilic oxathiaaza alkanes. Advantages and disadvantages of the investigated extraction systems are discussed. The paper reports on the basic research as well as on the testing in a laboratory scale.

Jan 1, 1993

By Y. J. Wang

A subsystem-based approach to the characteristic curves for a multiple fan ventilation system is presented. The ventilation variables and their relationships associated with a fan branch are considered as a subsystem of the multiple fan system. For each subsystem, the solution curve is generated by replacing the fan with a hypothetical pressure source or, alternatively, by adding a hypothetical pressure source without removing the fan. The projection of the solution curve onto the coordinate planes results in two classes of subsystem characteristic curves: pressure-vs.-quantity and quantity-vs.-quantity. The subsystem characteristic curves are described and illustrated through example ventilation systems. These curves are also discussed using the network equations of a general multiple-fan system.

Jan 1, 1993

By Dennis A. Beiter, Kenneth G. Fields, Richard T. Stoltz

Section 56.5001 Title 30, [Code of Federal Regulations1], establishes requirements for respirable dust exposure in Metal and Nonmetal Mines based on the Threshold Limit Values (TLV's) adopted by the American Conference of Governmental Industrial Hygienists. Respirable dust samples collected by Mine Safety and Health Administration (MSHA) inspectors at a sandstone quarry showed certain workers were exposed to excessive concentrations during development of a "coyote tunnel" that was ventilated with a blowing system. Because exhausting face ventilation systems are known to control dust more effectively than blowing face systems, a change was proposed to improve worker respirable dust exposures. This paper describes the evaluation of the proposed exhausting ventilation system in the quarry's "coyote tunnel" and compares the respirable dust exposures with those measured by the MSHA inspectors with the blowing system. Results showed the proposed exhausting ventilation system reduced respirable dust exposures to less than 20 percent of those measured by MSHA inspectors when the blowing system was used.

Jan 1, 1993

By Dana S. Getman

For 30 years, mining operations worldwide have used diesel-powered mobile machinery to mechanize the mining process. South African diamond mines and some US coal mines have 15 years of experience with this type of equipment. During the past eight years, most of the new gold production from underground mines outside of South Africa has been mined by bulk methods using diesel-powered machinery. The underground mining industry, then, has secured and institutionalized the larger benefits created by a technology that was new to mining engineers in the early 1960s. The state of mechanized diesel-powered underground mining is now mature. To survive, though, mine operators -regardless of commodity mined and position in the commodity cycle-must maximize the benefits of diesel technology. The benefits gained in the next seven to 10 years will be realized by tweaking this component, fine tuning that piece of machinery and demanding optimum use of the technology. Manufacturers of diesel-powered machinery share the condition of maturity with their customers. Larger scale and easy market development have occurred. Much has been made of the potential size of the US coal segment as well as markets in China and the Confederation of Independent States (CIS). Indeed, opportunities do exist in these regions. However, these market development opportunities do not imply the market size trend line remains unchanged. They simply mean the potential market size is within reach. In fact, the market size for the product is shrinking.

Jan 1, 1993

By T. J. Dudek

To be competitive in automotive applications, polymer composites must be processable by high production rate processes like injection molding (IM), reaction injection molding (RIM), structural rim (SRIM) and compression molding. With current fiber reinforced composite materials, performance properties are sometimes compromised to make them compatible with these processes. This is done by decreasing the amount and length of the reinforcing fiber and the viscosity and molecular weight of the polymer matrix. Sheet molding composite (SMC) and thermoplastic polymer blends are examples of polymer composites which are cost effective in many applications and meet the high speed processing requirements for automotive parts.

Jan 1, 1993

By D. Erik Spiller

Mineral processing technologies are being used in the environmental arena for remediation and secondary recovery. Comminution and/or scrubbing for liberation, coupled with separation of the liberated particles, is known as soil washing. Other metallurgical unit operations have found application in remediation and recycling: size classification, gravity concentration, flotation, magnetic and electrostatic separation, eddy current separation, and liquid/solid separation. This paper presents specific examples of the use of these technologies to clean up contaminated soils and plant residues, and to recycle valuable materials from waste streams.

Jan 1, 1993