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By F. Woller

The territory of Czechoslovakia is well endowed in deposits of a variety of industrial minerals. At present, 29 different types of industrial minerals are mined from some 600 individual deposits in Bohemia and Moravia only. About half of those production centres involves structural materials like aggregate and common brick clays and loams. A significant proportion of industrial minerals produced in Czechoslovakia are exported. Destinations of main products are shown in Figure 1. Production of industrial minerals in Czechoslovakia has a long history. Glass has been produced since the 14th century, sulphuric acid since 1578, graphite since 1750, and chinaware since 1790, to name just a few; but most of the present production comes from deposits developed during the past forty years. For a variety of reasons, only about 30 per cent of registered and explored industrial minerals deposits in the country are in production (Table 1). Two of the reasons may be the complexity of processing or conflicting interests of parties involved, but lack of market research, investment funds, or processing capacity have also had an impact on the level of utilization of the resource base.

Jan 1, 1992

By Milton E. Wadsworth

The evolution of engineering education and research has been profoundly influenced by computer technology and has concomitantly followed changes in this technology. Today, virtually all faculty have access to at least two hierarchies of computers: desk personal computers and at least one echelon higher (workstations or a variety of mid-sized computers). Most faculty have access to three or even four hierarchies: the two listed, plus super-mini and super computers. The ready availability of computers at a low cost has increased dedicated and site-specific computer technology. This has permitted universities to move into the field of macro-engineering, to address increasingly complex problems in resource recovery, manufacturing and many other areas, including important societal problems, like the environment. The creation of university research centers indicates the growing importance of macro-engineering involving large systems of interactive components. Funding agencies have increasingly favored such centers since they cross disciplines, generate inter-university consortia and foster university-industry programs.

Jan 1, 1992

By J. J. Moore

Combustion synthesis, or self-propagating high-temperature synthesis (SHS), reaction systems are discussed with respect to thermodynamics and kinetics. In particular, the effect of the process parameters, e.g. particle size, [All] ignition and combustion temperatures, on these self-sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall actuation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti-X intermetallic shape memory alloys, TiC-AI2O3 and ZrB2-AI203 ceramic composite materials.

Jan 1, 1992

By Harry M. Edenborn, Richard W. Hammack

Experiments were done to determine if a mushroom compost-based sulfate reduction system could be used to treat nickel-contaminated mine waters. Sulfate reduction systems were established in columns containing acid-washed mushroom compost. Simulated mine waters containing 2000 mg/L sulfate and 50 to 1000 mg/L nickel were adjusted to pH 4.5 and pumped through the columns at flow rates between 15 and 25 mL/hr. During the first nine days of operation, virtually all influent nickel was removed in the columns by sorption and ion exchange mechanisms. The nickel removal rate then dropped to 18 to 30 mg Ni/day (7.8 to 12.8 nmol/ g-substrate/day), probably due to low sulfate reduction rates. When sodium lactate was added to the inflow, a sustained and seven-fold increase in the nickel removal rate was observed. Bacterial sulfate reduction rates measured in mushroom compost-based wetlands exposed to coal mine drainage are 2 to 20 times faster than the rates observed in this study. Low sulfate reduction rates in the columns may have been due to the inhibition of microbial activity by high nickel concentrations and the removal of labile organic compounds from the mushroom compost substrate during acid-washing. Results of this study indicate that bacterial sulfate reduction can effectively treat nickel concentrations up to 500 mg/L if labile carbon is nonlimiting.

Jan 1, 1992

By T. D. Murphy

In the fall of 1988 it became evident that the accuracy of sulfur forecasts for Monterey Coal's No.1 Mine needed to be improved. In addition, it became necessary to predict if any individual train shipments during a month would exceed a contract sulfur limit. The challenge was to develop a forecasting process that would take into account the variability of the coal in the ground as well as the difference between laboratory and preparation plant sulfur reduction efficiency, and the effects of mining coal with multiple units. This paper describes how geostatistics and simulation techniques were used to meet this challenge.

Jan 1, 1992

By J. A. Herbst

Successful transitions from micro- to macro-engineering are the keys to effective technology transfer between research and development organizations and industrial end users. At the same time, it has proven to be one of the most difficult tasks that the minerals industry has had to manage. Typically, developers of fundamental information concerning how mineral processing subsystems work have been academics and government scientists. These are the individuals giving the most important input to micro-engineering models that can benefit industrial operations. Publication is the usual route for "attempting" to transfer this technology to the end users. Unfortunately, with such publications, very little direct communication occurs concerning real industry needs or the future steps required to make the particular micro-engineering model useful. In the past, the industry has relied on in-house R&D groups and plant metallurgists to "translate" publications, to provide useful macro-engineering tools for plant applications. To some extent, engineering companies have also been asked to serve this function. However, these firms have been rather ineffective in this area since their conservative nature has caused them to look rather suspiciously at new technology. This approach to technology transfer has worked, albeit clumsily, for the last several decades. This communication system is now on the verge of total collapse due to conditions of the minerals industry. Mining companies can no longer afford the significant overhead expenses of specialized technical staffs. Universities are finding it extremely difficult to interest US students in mineral engineering programs, and funding for such programs is weak. Faculty members involved in micro-engineering research today tend to focus on pure (non-application-oriented) research.

Jan 1, 1992

By P. A. Lindberg

Early Proterozoic ore deposits in the Verde district at Jerome, Arizona have produced 33.7 million metric tons of ore (1893-1975). The United Verde and United Verde Extension deposits produced most of the ore that yielded 1,644,323,100 kg Cu plus large amounts of Au, Ag, and Zn. These deposits are situated on the fractured and hydrothermally altered apex of a large submarine rhyolitic extrusive (Cleopatra formation). Precambrian lithologies are penetratively deformed and at Jerome the Fl folds plunge steep to the NNW. For the past two decades the volcanogenic model has superseded the replacement theory of ore formation.

Jan 1, 1992

By R. P. Stahura

In many ways, conveyors are the lifeline of mining and processing operations. Like arteries in the human body, they continuously supply materials to and carry finished products and waste away from vital on-going operations. And like arteries, when the conveyors are running with less than maximum efficiency and productivity, it spells serious trouble for the operation's overall health. Inefficient conveyors suffer carryback, leading to the build-up of materials on idlers and other expensive components. They spill and leak material at loading zones and conveyor transfer points, causing accumulations that can damage the belt, wear moving components, and increase both clean-up labor and maintenance expense. They wander or mistrack, spilling material and endangering personnel and conveyor components including the belt itself. And through these inefficiencies, they multiply the operation's hidden costs. These added expenses are created in lost production, increased downtime for service and maintenance, and the cost of the replacement of prematurely worn equipment. In addition, the attitude that inefficiency is "good enough" is recognized elsewhere in the organization; as a result, other departments relax or operate at less than peak performance. Quality goes down and with it employee morale.

Jan 1, 1992

By J. C. Norman

The boron review arrived too late to appear in the June issue. The United States was the world's second largest producer and the largest consumer of boron compounds during 1991. According to the US Bureau of Mines, boron mineral concentrate and chemical production in the US totaled about 1.1 Mt (1.2 million st), yielding about 608 kt (670,000 st) of BO, in 1991. Total estimated value was $440 million. That level of production was equal to 1990 revised production figures. Value was greater by $37 million, however, reflecting a strengthening of boron product prices. The US continued to supply essentially all its own boron while maintaining a strong position as a source to foreign markets of sodium borate products and boric acid. Domestic employment in the mining and beneficiation of boron products in 1991 remained at 1100 people, about the same level as in 1989. The Bureau of Mines estimated total world production of boron in 1991 - mineral concentrate and chemical - at about 2.9 Mt (3.2 million st). That corresponds to about 1.2 Mt (1.3 million st) of BO ,. World production in 1991 was about equal to revised 1990 levels. US production Mines and processing operations in southern California were the only domestic sources of boron mineral concentrates and chemicals in 1991. US producers, in order of quantity of production, were US Borax and Chemical Corp., North American Chemical Co., and American Borate Co.

Jan 1, 1992

By S. Behl

A major limitation in developing successful selective flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper a correlation between selectivity of flocculant adsorption and separation efficiency is outlined and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1992

By L. C. Atkinson

A three-dimensional finite element Ground-water flow code has been developed that incorporates saturated/unsaturated, two-regime flow (i.e., both Darcian and non-Darcian) and solves for the seepage face at a surface of outflow. This code is capable of more realistically predicting ground-water inflows to an open-pit mine under the throttling effects of non-Darcian flow. The height of the seepage face on highwalls and the shape of the phreatic surface in the vicinity of the pit that it calculates can also produce more probable estimates of pore pressures for analysis of slope stability.

Jan 1, 1992

By K. L. Whitehead, R. A. Jankowski, N. I. Jayaraman

Most continuous miner sections utilizing flooded-bed scrubbers also use blowing face ventilation. Blowing ventilation, however, interferes with dust capture and minimizes scrubber effectiveness. To enhance the efficiency of the scrubber system and reduce dust concentrations, the Bureau of Mines tested various combinations of operating parameters. Experiments for system efficiency took place in a full- scale model mine at 3.05 m roof height. In general, higher values for scrubber and face airflows resulted in lower dust concentrations. In addition, optimum dust controls would include a face ventilation to scrubber airflow ratio of one. When the airflow ratio was either less than or greater than one, the dust levels in the return and at the operator locations increased. No single dust control technique was the most effective one at all locations due to mutual interaction among techniques.

Jan 1, 1992

By F. Daviess

A requirement for geological controls during orebody modeling results from the recognition of heterogeneous geological characteristics and/or abrupt variations in orebody geometries. While purely statistical methods are often sufficient for modeling uniform homogeneous deposits, and the only recourse for many that are extremely complex, geological interpretations can be extremely valuable as controls during the modeling process. The advent of relatively inexpensive, sophisticated graphical computer hardware and software has focused considerable attention on the three dimensional visualization capabilities now available to the mining industry. Orebody geometries can be easily imported into many systems as wireframe or solid models, rendered with shading and color, rotated in space, exploded into composite parts, zoomed into and otherwise displayed to awe any audience. The requirements for an initially meaningful, accurate, geological interpretation are sometimes lost when the focus is on an apparently complex, highly resolved end product. Details of the initial data and sensitivities of modeling assumptions are not always sufficiently scrutinized. Software capabilities have extended the geopoetic license into three dimensions. The new tools, while greatly facilitating model construction and rendering, have done little to expedite basic data preparation and analysis. This paper attempts to briefly summarize the purpose and method of the construction of geological controls. The examples selected are from wire­framing and block modeling; application software processes commonly used in the mining industry today.

Jan 1, 1992

The floatability of a bituminous coal in NaG solutions was evaluated using a modified Hallimond tube to delineate the role of the electrostatic interaction between bubbles and particles in determining the coal hydrophobicity. Zeta potential measurements showed that bubbles are negatively charged in the entire pH range tested, while coal particles are positively charged below pH 6.0 and negatively charged above it. Also, both sodium and chloride ions were confirmed to act as indifferent ions without any specific effects for both coal particles and bubbles. Flotation as a function of pH exhibited a maximum and minimum at low salt concentrations which is shown to be determined mainly by the coal hydrophobicity as measured by a new hydrophobic levitation technique. At high salt concentrations (above 0.1 mole/dm3), the flotation without such maximum or minimum is controlled by the electrostatic interaction between the bubble and the particle.

Jan 1, 1992

By J. K. Mokka, P. D. Rao, H. K. Lin

Extensive exploration has resulted in delineation of a massive sulfide district on the north flank of the east-central Alaska range. The district covers approximately 400 mi2 and contains numerous stratiform, transposed and some replacement type sulfide deposits ranging in size from less than 1 million st to 20 million st. Five types of ores were sampled for the study. Mineralogical analysis revealed that the minerals are too fine grained for conventional grinding and beneficiation. Hydrometallurgical studies were conducted using ferric chloride as a lixiviant. Ore microscopic studies as well as electron microprobe analyses of minerals in the raw samples and leach residues explained the low recoveries for certain elements as well as sources of impurities that need to be eliminated from the process streams.

Jan 1, 1992

By Charles D. Litton

This paper presents a description of the hazards of smoke from fires, the detectability of smoke using smoke sensors, and the operational characteristics of such detectors. It places in perspective the advantage that smoke detectors have over other forms of fire detection and also provides a discussion of smoke as a significant fire hazard.

Jan 1, 1992

By E. Martinez

A heavy mineral sand sample was tested containing 13% heavy mineral consisting of rutile, zircon, and ilmenite. Eleven tests were run at a mill site with a Mineral Deposit Limited MG 4 spiral to determine the effect of the addition 0; magnets to the spiral compared to conventional gravity separation. Different magnet configurations and field strengths were tested. Optimum results were obtained with the spiral retrofitted with magnets. The heavy mineral content of the concentrate was increased from 55.5% in the control to 64.2% with the magnets. The 8.7% improvement in heavy mineral recovery was due not only to the weakly-magnetic ilmenite, but also to increased recoveries if the non-magnetic zircon and rutile. The increased recoveries were achieved with no loss of concentrate grade.

Jan 1, 1992

By S. Zendejas-Mendivil, E. Pérez-Segura

The Cananea porphyry copper-deposit is the site of the second largest mining operation in Mexico. Mineralization is related to quartz-monzonite Laramide stocks that intrude volcanic and volcaniclastic Mesozoic rocks. The ore deposit is a stockwork and breccia-pipes system with Cu-Mo sulfides and pervasive quartz-sericite hydrothermal alteration. A study was made of the arsenic distribution in the mine and the ore-dressing plants. The arsenic (As) in the mine is related to a feldspathic quartz-porphyry type rock associated mainly with the breccia pipe structures (100-700 ppm As in the Veta 7 Breccia). There is vertical zoning, with As decreasing in the deepest part of the breccias. This As mineralization corresponds to a later sulfide hydrothermal stage. The concentrates are made of Cu, Fe and Mo sulfides and some minor quantities of As minerals. The most important copper minerals are chalcocite-covellite, bornite and chalcopyrite. Some of these minerals have 390-880 ppm As. The main As mineral is enargite[ [Cu2.97Fe0.06(As0.90 Sb0.01Pb0 01 )0.92 S4 051 and there are traces of stibioluzonite-luzonite I Cu, .95(Aso.4vSbu.49)0.9rfS4.07-Cu2 93(Aso.H4Sba.10)0.94S4.13] and of another stibioluzonite mineral type with substitution of As by Bi[Cu,96(Ascr,,'Sb0ccrB'OJ3jI~6S] These minerals contribute 80% of the As in the concentrates.

Jan 1, 1992

By David I. Dr. Hoyer

The Hicom mill is a conical mill in which a ball or autogenous load tumbles within a high-intensity acceleration field. An autogenous Hicom mill with a power density of about 1100 kw/m3 and a volume of just 4 litres reduced a 50 m quartzite feed to 90% passing 38 microns at a feed rate of 160kg/h (in closed circuit with a hydrocyclone). Batch tests have identified fracture, chipping and abrasion breakage mechanisms at pebble sizes of 5 to 50 mm. The special behaviour of the load in Hicom mills was exploited to develop a novel technique for estimating steady state autogenous load size distributions.

Jan 1, 1992

By M. E. Poad

The Research and development review arrived too late to appear in the May issue. The competitiveness of the US mining industry in a world market depends on many factors. The introduction of new and innovative methods, though, can have a significant, long-term impact. As industry cuts back its own long- term research and development efforts, the federal government continues to provide the major support for mining and minerals research. The US Bureau of Mines works with the mining industry and the academic community to develop innovative concepts for the mining and processing of non-fuel minerals. The Bureau’s research focuses on exploration and mining technology, minerals and materials science, processing technology, health and safety and environmental technology. Mine design A conical caving system, being designed by the Bureau, would allow the development of low-grade ore bodies, early startup at lower initial capital costs and increased safety and versatility in development and production. This method is a form of mass caving that allows the ore to be drawn from a central loading point at the bottom of the cone- shaped caving zone (Fig. 1). A simulation laboratory model and computer analysis show initial promise for predicted performance. For tabular, flat-lying ore deposits, the Bureau is investigating a version of the Finnish slot-and-fill system. For this total extraction method, a pattern of rectangular panels is laid out. One panel is extracted in a series of parallel slots and is replaced by alternating-row pillars of backfill. After one panel is mined, equipment and operations are transferred to another panel. By transforming this rectangular layout to a curvilinear geometry, one continuous spiral can be mined without re positioning equipment. Instead of parallel slots and pillars aligned in a rectangle, the slots and pillars are arranged in a spiral.

Jan 1, 1992