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By Howard E. Kremers

Although more than 100 thorium-rare earth minerals are known, only a few have any commercial significance. Monazite, thorite, bastnasite, and some exotic thorium rare earth ores are reviewed Commercial interest is presently centered on monazite from the Union of South Africa, and thorite from this country. Thorium became commercially important with the development of the incandescent gas mantle about 75 years ago, Gas mantles consist of thorium oxide with small amounts of cerium oxide. The thorium nitrate used to make gas mantles was first obtained from rare thorium minerals, As a matter of fact, this use of thorium is still important and is one of the largest commercial uses for thorium materials. The discovery of monazite sand placer deposits along the coasts of Travancore, India, and in some Brazilian beach s .s, and the development of the old North and South Carolina monazite stream placers gave the mantle industry of 30 to 40 years ago a comfortable inventory of thorium ore. Even today, the thorium industry depends largely upon monazite ores for its source of thorium. This paper will briefly describe some of the major thorium ores and their principal deposits insofar as they relate to the thorium industry in this country. Because of similar chemical and physical properties, thorium always occurs with the rare earth elements and with varying amounts of yttrium. Thorium may predominate over rare earths, as in thorite-type minerals, or may represent only a fraction of the rare earth content. Typical ratios of thorium to rare earths in various minerals are given in Table 1, The average thorium content of the earth's crust is about 12 grams per ton, and in this respect thorium approximates lead, molybdenum, and some of the rare earths in abundance. The ore minerals of greatest importance to the-thorium-rare earth industry are monazite, thorite-type minerals, bastnasite-type- ores, and the family of minerals which is characterized by a preponderance of the heavy rare earths and yttrium. The latter classification includes xenotime, gadolinite, samarskite, euxenite, etc, The first two, monazite and thorite, are of greatest significance.

Jan 1, 1958

By J. Y. Hwang

Processing of fine mineral particles in a slurry is a difficult problem. Methods to make fine particles magnetic have been developed recently and may offer a solution to this problem. Particles of nonmagnetic materials can be selectively rendered magnetic through surface interactions with magnetic reagents. When adsorption occurs, the magnetic susceptibility of the material is increased. Magnetic enhancement at several orders of magnitude can be achieved. Selectivity of the adsorption can be controlled by the functional groups of magnetic reagents and various surface interaction mechanisms. This approach allows a new degree of freedom for the processing of fine mineral particles, even with conventional magnetic means. Separation of valuable minerals and filtration of slimes from tailing ponds and recirculated water are examples of the applications. Basic principles of this technology are discussed in this study.

Jan 1, 1992

By V. S. Tadsen

Today, man is able to probe space because of technological advancements including the ability to control certain combustion reactions very precisely. The recent adjustment of the attitude of Skylab by radio command from earth is an excellent example of such control. It is strange, and indeed unfortunate, that very little is known about the mechanism of combustion of pulverized coal, the primary fuel for rotary kilns. The selection of a coal for direct pulverized firing of a rotary lime kiln may be determined by trial and error, persistence of sales personnel, proximate analyses, grindability, or apparent BTU cost. Occasionally, the only question asked is, "How much lime will it make?" To study the behavior of a particle of coal in the combustion stream of a rotary kiln is most difficult. We must, therefore, discuss the general mechanism of combustion of pulverized coal, and relate this mechanism to the selection of a proper coal for a rotary kiln. The classic three T's -time, temperature, turbulence -must be enlarged upon for a better understanding of the problem. Pulverized coal occupies only 0.01 per cent of the volume of air required for its combustion. This mixture behaves like a gas and the general laws governing the movement of solid particles in gasses are in effect. The differential velocity between air and coal particles depends on forced and natural convection, diffusion, and the length of time each particle is in the combustion space. As a particle of coal absorbs heat from its surroundings, it begins to give off volatiles". These gasses ignite as their kindling temperature is reached, and burn readily because of the excess oxygen immediately available. Combustion proceeds at this stage by the outward diffusion of gas from the coal particle into the surrounding oxygen-rich envelope. We could say combustion at this stage represents a small coal particle surrounded by an envelope of volatiles burning at their point of contact with sufficient oxygen. This release or expulsion of gasses from the coal may result in exfoliation or disintegration of the coal particle. If this occurs, and it is desirable that it should, it will accelerate the final stages of combustion. The escape of volatile material from the particle of coal and its subsequent combustion will cause increased turbulence around that individual particle. Ignition is maintained by radiation from gasses and solids in the combustion system, and most importantly, re-radiation from the kiln refractories and the process load.

Jan 1, 1978

By Harold Rees

[This report supplements and brings up to date a paper prepared earlier this year for presentation at the Eleventh Pan American Railway Congress to be held in Mexico City, October 18 to 31, 1963. In order to acquaint the reader with the background of this project practically all of the first paper is included in the report.]

Jan 1, 1963

By V. Canby

Introduction Located in Russia’s Chukotka Autonomous Region near the Arctic circle and 425km from the seasonal port of Pevek (population approximately 4600), Peschanka (or ‘Anyui’) is perhaps the world’s most isolated CuMoAu porphyry deposit of significant grade and tonnage. In addition to its extreme remoteness (66°36'N/164°30'E) and lack of developed infrastructure, Peschanka is located in one of the world’s coldest regions, with annual average temperatures well below freezing. Soviet exploration up to 1985 defined four zones with inferred resources of roughly 940Mt @ 0.51% Cu, 0.42 g/t Au, 1.4 g/t Ag and 0.019% Mo (1).

Jan 1, 2007

By I. Demers

Doyon mine, Quebec, Canada evaluates the possibility of desulphurizing their tailings to produce material to be used in as cover over the acid generating tailings disposal site. Laboratory tests were conducted and showed that a single-layer cover made of desulphurized tailings placed over reactive tailings can prevent the generation of acid mine drainage. Modelling with the software Vadose/W was undertaken to optimize the design parameters, namely cover thickness, water table position, and residual sulphide content of desulphurized tailings following laboratory work. It was found that the optimal configuration includes a 1 m desulphurized tailings cover containing 0.8%S, with the water table kept at the interface between the reactive tailings and the cover. To maintain the cover performance to reduce oxygen flux towards acid-generating tailings even in the event of a long dry period, a sand layer is suggested to protect the cover from excessive evaporation. It is possible to reach the environmental objective chosen for Doyon mine (10 mol/m2/year) with the protective sand layer, even in extremely dry conditions.

Jan 1, 2008

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By R. Oler

The need for yieldable ground support, particularly in high stress or deep mining conditions, has grown in recent years. This paper highlights some of the current industry limitations and provides selection criteria for a new yielding ground support system, DSI?s Dynatork Bolt. This bolt distinguishes itself by withstanding 16 ? 30 kJ of energy deflecting loads anywhere from 7 ? 20 tons (depending on the energy). A summary of the laboratory test results and case studies will also be presented as a measure of the performance of this dynamic product.

Jan 1, 2012

By Georgene Renner, Chee Theng, William Gleason

"With more than 900 booth spaces sold and 630 exhibiting companies displaying their wares, there was something for all 7,804 attendees on the exhibit floor of the 2015 SME Annual Conference & Expo in Denver, CO Feb. 15-18. The following is a sample of what was offered at the 2015 meeting.3D Laser MappingData collection and data analysis are changing how mining is done. One field in which technological advancements have made safer and more efficient operations possible is through site and slope monitoring.3D Laser Mapping, a United Kingdom-based company, was on hand at the 2015 SME Annual Conference and Expo to display its solutions for the mining industry, including its SiteMonitor4D system.The state-of-the-art laser measurementbased system was developed in partnership with geotechnical engineers and mining surveyors, and is a simple-to-use, reliable solution that has the flexibility and performance to function in a range of monitoring applications.The system measures and monitors the stability of rock faces, landslips and man-made structures, including ongoing, periodic measurement of volumes - stockpiles, cutbacks and waste dumps and has high-speed laser scanning for regular mapping of large areas by mounting the scanner on a vehicle.With specifications that other monitoring techniques cannot achieve, laser scanning opens up a new dimension in mine measurement and monitoring.www.sitemonitorsystems.comA.R. Wilfley and Sons Inc.Founded in 1919, A.R. Wilfley and Sons Inc. has been manufacturing dynamic-seal and static-seal pumps in Colorado for nearly 100 years, delivering its high-reliability, low-maintenance, heavy-duty process pumps and slurry pumps to the global mining industry. The family-owned company is now in the hands of the fifth generation."We are the dynamic-seal experts," regional sales manager Cesar Murillo said. "Most other companies are unable to do 100 percent dynamic seals and have to use mechanical seals or packing," he said, but Wilfley’s sealing technology does away with the need for mechanical seals and packing and their associated problems. As a result, solids and slurry handling capabilities are high, the pump can be run dry, and product dilution is eliminated. The pump can tolerate more misalignment, more cavitation, and more vibration in the pump during operation."

Jan 1, 2014

By D. Marcus

A methodology was developed wherein. the increase in compressive strength, mineralogical changes and pore water composition were all studied simultaneously as a function, of moisturized spent shale curing time. From these results the relationship between the nature of cementation process and the composition of pore water was established. Heavy metals were entrapped in the cementing constituents and the pore water became mainly a solution of alkaline sulfates. While the specific data are applicable only to the material studied, the methodology and general conclusions are useful for evaluating the environmental factors in spent shale disposal and expected leachates composition.

Jan 1, 1984

By Kugan Kuganathan

Pastefill is being increasingly considered as a viable fill by underground mine operators. Mount Isa Mines (MIM) chose pastefill to fill their deep copper mine (>1200m deep) after considering various other types of fill in the feasibility studies. During the development of pastefill at Mount Isa (1996 - to date) the Mining research of MIM developed two cost effective, reliable and simple testing methods and used. With the help of these tests the behaviour of MIM pastefill was studied thoroughly and the most optimum mix design for pastefill was achieved. The MIM's pastefill plant, the largest in the world with a capacity of 450rph continuous pastefill production and unique in the process used, has been built (1998-1999) to produce pastefill to the specification developed through extensive testing program using the Flow Cone and Mini Slump cone Tests. As a consequence, it is now possible to select the optimum pastefill mix designs and predict their flow behaviour in bore holes or pipe lines using only these tests. MIM Blended Tailings Pastefill (BTPF) uses 3-3.55 Portland cement and the cost of pastefill is much lower than the total tailings pastefill, that could be produced from the same tailings.

Jan 1, 2001

By Y. Topkaya, R. E. Johnson, B. R. Palmer, Jia-Jun Ke, Da-Ping Kang

The kinetics of the leaching of antimony oxide ore (Sb2O4) in aqueous hydrochloric acid solutions has been investigated. This dissolution reaction is a heterogeneous solid-liquid reaction. It has been found that the leaching temperature and the concentration of hydrochloric acid turn out to be the significant influencing factors on the leaching rate. The apparent activation energy for the leaching reaction was determined to be 63.5 W/mol within the experimental temperature region of 50O to 90O C. The experimental results indicate that the leaching process is controlled by the rate of the chemical reaction.

Jan 1, 1993

By Robert W. Curtis

Kaiser Aluminum & Chemical Corporation's (KACC) entrance into the alumina market began in 1946 with the purchase of a small plant in Baton Rouge. Louisiana. Since that time KACC has been involved with the design, construct; on, and operation of many alumina plants around the world. One of these plants is located in Gramercy, Louisiana. The Gramercy Works is a multiplant installation consisting of an alumina plant, a caustic-chlorine plant, a petroleum coke calciner and a fluorochemicals plant. Each of these plants require their own specific environmental control programs to abate pollution. Kaiser has made significant progress through the years on their own initiative in pollution control. But many new challenges have been and continue to be created with the enactment of environmental laws. The 1970 Clean Air Act Amendments, the resurrection of the old "Refuse Act" in 1970 and finally the 1972 Federal Water Pollution Control Act Amendments prompted the formulation of our current philosophy towards the abatement of pollution. Since the formulation of these complicated pieces of legislation, others equally complicated, have come to being. The Federal Insecticide, Fungicide and Rodenticide Act as amended by the Federal Environmental Pesticide Control Act of October, 1972, the Toxic Substances Control Act of 1976, the Solid Waste Disposal and Resource Recovery Act of 1976 and the Safe Drinking Water Act sighed in December of 1974 have all contributed to the challenge for an alumina plant to meet regulatory constraints. However, this paper will only discuss the alumina plant?s environmental programs designed to meet compliance with air and water pollution legislation. At the Gramercy Alumina Plant, over $25 million has been spent for pollution control since 1969. The Gramercy Plant is a prime example of KACC's commitment to meeting the environmental challenge.

Jan 1, 1978

By Gary F. Meenan

The industrial practice of froth flotation for upgrading the quality of fine coal is a relatively complex, expensive, and inefficient process when compared to the coarse- and intermediate-size coal cleaning circuits. The differences in cost and process efficiency can be attributed mainly to the lower equipment throughput, the added cost of flotation reagents, and the fact that flotation is typically a manually operated process susceptible to fluctuating feed characteristics that influence the overall operating efficiency. The emphasis in recent years has been on improving the flotation process efficiency and lowering the cost per clean ton. This has been achieved by larger flotation cell designs, implementation of flotation reagent evaluation programs, and improved process instrumentation and control. These developments are reviewed along with other current coal flotation practices.

Jan 1, 1999

Powder River Basin (PRB) mines were originally built to serve power plants designed specifically for their coal. Sulfur was the major concern, with BTU and sodium limiting the market for some. The Clean Air Act has extended the PRB market into plants converting from other coals. These new customers are more sensitive to constituents affecting boiler and precipitator performance. At the same time, the prospect of deregulation is forcing power companies to control cost more stringently than ever. Jacobs Ranch Mine has responded to the changing marketplace with an expanded coal quality and customer service program.

Jan 1, 1998

By Dennis Arthur Fenton

The hydrodynamic bearing was first described by, Reynolds in 1886, and has since been widely applied in motors, engines, compressors, hydroelectric turbines, and other machinery. For various reasons, the hydrostatic bearing currently predominates in the large, horizontal rotating machinery field (e.g. grinding mills). However, the current industry trend towards increasing size and energy efficiency has resulted in renewed interest in the advantages of hydrodynamic bearings. These advantages include structural improvements, reduced bearing friction, improved bearing life, improved transient characteristics, and reduced lubricant pump size and power requirements. In particular, the higher energy efficiency results in substantial savings on large machines. This paper describes some aspects of the design of large hydrodynamic bearings based on thirty years, of experience in the design of such bearings on grinding mills ranging in journal size from 2.1 m to 6.4 m, see Table 1.

Jan 1, 1985

By Q. Feng

Study has been carried out to apply fly ash as a high strength, water-resistant precast construction material through geopolymerization. Experiment results show that the working conditions such as water content, the concentration of NaOH, curing temperature and curing time, significantly affect the mechanical property of geopolymer matrix. Through optimization, an above 100 MPa compressive strength has been achieved with the geopolymerization products. Water soaking tests show that the geopolymerization product has a very high water resistance without losing noticeable compressive strength even after a one month soaking time. To elucidate the geopolymerization mechanism, microscopic techniques such as SEM/EDS and XRD are also applied to investigate the microstructure, the elemental and phase composition of geopolymerization products. The findings of the present work provide a novel method to apply fly ash as a high strength water-resistant precast construction material. INTRODUCTION Geopolymerization is a process of obtaining a polymeric structure from aluminosilicate by dissolving aluminosilicate sources in a strong alkali (NaOH) solution and condensation of free [SiO4] and [AlO4] tetrahedral units (Davidovits, 1985 and 1988; Duxson et al, 2005; Xu et al, 2000, 2002). After being cured at an elevated temperature for a specific time, the geopolymerization product shows a greatly increased compressive strength. Therefore, the product can be used as construction material such as bricks and road pavement. It provides a very promising method to apply aluminosilicate sources such as fly ash as a construction material for a sustainable development. Fly ash is a main industrial waste which needs to be carefully impounded because of its potential impact on environment. Many efforts have been tried to utilize fly ash as construction materials substituting Portland cement because of the following reasons. First, fly ash is a silica/alumina rich aluminosilicate source, which makes the specific material an ideal source for the geopolymerization process. Secondly, the particle size of fly ash is usually very small (< 50 microns) and it saves a lot of energy consumed during the production process of cement for grinding. Thirdly, fly ash is an ideal source for geopolymerization because it is reactive to alkali even at a mild temperature. In the past twenty years, many studies have been carried out on the geopolymerization of fly ash to a make construction material. However, there are some disadvantages associated with the conventional methods of treating fly ash (Palomo et al, 1999; Perera et al, 2007; Temuujin, et al, 2009; Hanjitsuwan et al, 2014). First, in most of the proposed geopolymerization methods, a salient amount of sodium silicate has to be added. It therefore makes it complex whether the achieved mechanical strength of geopolymerization products is due to a real geopolymerization process between fly ash and alkali or just largely the solidification of metal silicate in air at an elevated temperature. Secondly, the authors have noticed that when the geopolymerization product is soaked in water, the solution pH increases sharply and the products will lose its compressive strength gradually in water. Thirdly, the compressive strength of the geopolymerization product as reported is usually less than 50 MPa.

Jan 1, 2019

By D. Murray

"The Mine Improvement and New Emergency Response (MINER) Act included the need for improved chemical technologies to address respiratory protective device inadequacies and refuge alternative development. The National Institute for Occupational Safety and Health’s (NIOSH) National Personal Protective Technology Laboratory (NPPTL) invests in research and development to improve the carbon dioxide (CO2) scrubbing technologies built into these mine safety systems. Testing at NIOSH NPPTL is performed using a custom-designed test system containing a chemical reactor and sensors in a constant flow of simulated expired breath to evaluate chemical performance for the scrubber materials. Current testing procedures focus on device duration or capacity, but do not report criteria needed to effectively optimize chemical performance. In this presentation, testing results which identify the chemical performance roles for CO2 scrubber components will be reported, and specific component chemical activities will be linked to both duration and CO2 absorption capacities. Chemical components being evaluated include hydroxyl, superoxides, metal, and amine active sites, distributed in salts, zeolites, metal-organic frameworks, and microporous materials. INTRODUCTION CO2 absorbents and oxygen sources are at the heart of closed circuit breathing air supply systems used in mining escape and rescue operations. CO2 absorbent technology was first developed for diving rebreathers and has been in use for over a century. Typically these devices include a soda lime formulation of pellets in the 8-12 mesh range. Larger 4-8 mesh particles are used in medical grade “low-flow” applications, since these particles present a lower flow resistance regime more amenable for use with resting individuals. Potassium superoxide and lithium hydroxide formulations are also used, where in each case the formulations involve bulk solid pellets or materials affixed to surfaces. CO2 capture technologies are now under intensive study in the energy and automotive industries, where the pursuit of optimal combustion processes has led to the development of new materials to capture, convert and store CO2, oxygen and carbon monoxide gases. Recent advances in nano-structured and high surface area catalysis have produced novel materials demonstrating chemical performance improvements in these industries, and these improvements may now also be adapted to enhance chemical efficiency and performance in escape and rescue devices. Higher surface area materials offer promise for improving the efficiency, or decreasing the burdens associated with the use of closed circuit respiratory protective devices containing CO2 absorbents. Novel chemicals that display advantages in chemical performance or decreased burden will be examined for inclusion in developing systems such as the next-generation closed-circuit mining escape respirator or refuge alternatives."

Jan 1, 2018

By Rick Coleman

PT Freeport Indonesia’s (PTFI) latest expansion has increased total mill throughput to 125kt/d (137,700 stpd). The most recent expansion included the installation of a semiautogenous mill (SAG) designed to treat more ore than any other single SAG mill currently operating in the world. Also included in the expansion were two large ball mills, rougher and cleaner flotation, including conventional and column cells, and a regrind circuit. All equipment is supported by a modern distributed control system. PTFI’s operations are located in the Ertsberg mining district of Irian Jaya’s Jayawijaya Mountains, the eastern-most province of the republic of Indonesia on the Island of New Guinea. PTFI, the operator, is owned by Freeport McMoRan Copper and Gold (81.3%), the government of Indonesia (9.4%) and private Indonesian investors (9.3%).

Jan 1, 1996

By J. C. Armbrust

The Morenci Open Pit Mine, located in south-eastern Arizona, is owned and operated by Phelps Dodge Morenci, Inc. The Mine has been predominantly a rail mine since its origin in 1937. However, beginning in early 1986, a program was initiated to phase out the rail mining operation and replace it with a more flexible and productive truck haulage scheme. This transformation from rail to truck haulage will be accomplished when the current in-pit crushing and conveying project is completed in late 1988.

Jan 1, 1988