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By Neil E. Izatt, M. Andre de Ruijter, Ronald L. Bruening, Wesley Young

IBC Advanced Technologies, Inc. has developed ligands, ?amed SuperLig®, which have specific applications in the gold mdustry. These ligands use molecular recognition technology (MRT). One ligand has been developed to selectively recover gold and silver from tailings solutions and from pregnant Merrill-Crowe solutions. Another ligand removes free cyanide, _ th10cyanate, other cyanide species, as well as copper and other base metal cyanide complexes from leached gold-ore solutions. The development of these "species selective'' SuperLig® prod­ucts allows for the more efficient operation of gold recovery processes and opens up the possibility of the economic devel­opment of high-copper gold ores. The resulting gold eluate is a high grade and a high purity stream which will simplify the need for further refming. Engineered systems based on MRT consist of a few unit operations utilizing standard equipment and mate­rials of construction. The process is simple to operate, thereby lending itself to automated modular design, which is both eco­nomic to manufacture and to operate. Test results for the gold and cyanide-copper systems are presented in order to demonstrate the high selectivity and effi­ciency of MRT technology in recovering these species from solution. . IBC Advanced Technologies, Inc. (IBC) and Fluor Daniel, Inc. formed a strategic alliance in late 1994. The goal of the alliance is to combine IBC's scientific expertise in the MRT field with Fluor Daniel's engineering capabilities in the metal­lurgical industry. IBC has its headquarters in American Fork, Utah, USA, where research, development and manufacturing are conducted. Fluor Daniel is an international engineering and construction firm with head offices in Irvine, California, USA. Engineering efforts for the alliance are centered in the Fluor Daniel Mining and Metals Operating Company office in Vancouver, B.C., Canada.

Jan 1, 1996

By Daniel W. Kappes

The 1.8 million tonne Itos tailings deposit is the result of sever­al years of processing by Comibol of the San Jose and ltos Mine ores at Oruro Bolivia. The historic flowsheet consisted of a flotation circuit in which silver-bearing galena and stibnite were concentrated. Approximately half the silver in the ore was not recovered, and the existing tailings contain slightly over 200 grams silver per tonne, in the form of complex sulfides of silver, antimony, lead, and other metals coating grains of pyrite. An extensive laboratory program was conducted to exam­ine conventional processing l)lethods such as cyanide leaching and regrinding followed by flotation. However, the silver-bear­ing sulfides are in intimate contact with the pyrite and the pyrite comprises 30% of the total tailings weight. Cyanide leaching recovers only 40% of the silver and the cyanide consumption is uneconomically high. Flotation produces an upgraded, but still uneconomic, concentrate. For this reason, chloride leaching had been evaluated by Comibol, and in the mid 1980's Comibol undertook an innova­tive test consisting of two 300 tonne field heap leaches using a cold chloride solution. The tests were partially successful, but could not be applied to the bulk of the tailings which are already ground to 50% minus 200 mesh. In 1992, Kappes, Cassiday & Associates undertook to develop a hot agitated chloride leach flowsheet, and is current­ly constructing a treatment plant under a turnkey contract from a Bolivian company, Baremsa, S.A. Using this process, 85% of the remaining silver can be recovered, with significant by-prod­uct credits from antimony and lead. The project features hot, agitated acidic chloride leaching, filtration, crystallization of lead chloride, and precipitation of metals using iron scrap. Arsenic is removed from the precipitate by caustic leaching, and minor metals by furnace refining. Antimony is recovered as the oxide by cupelation, and silver is poured as <lore from the cupel. Production rate will be 600 tonnes per day. Startup is scheduled for late 1995.

Jan 1, 1996

By Norbert Patzelt, Johann Knecht

Future ore reserves of major gold producers in North America and elsewhere will consist of refractory gold ores. About 60 % of the current U.S. gold production is mined in Nevada. Several of the large gold operations in this state indicate that 40 to 90 % of their future ore feeds will contain refractory gold. To com­pound problems, average head grades for refractory U.S. gold ores had fallen from 8 - 9 g/mt to about 4 g/mt by 1991. In Latin America, 52 % of the gold operations will require milling for optimal recovery. Deeper reserves are, like in North America, refractory. Therefore a special treatment process is needed in order to allow for the gold ore to be leached downstream in a conven­tional cyanidation process for a high gold recovery. There are several options available for this oxidation process like treat­ment of the gold bearing ore in pressure oxidation, in a biooxi­dation or in a roasting plant depending on the reason for the refractoriness. If organic carbonaceous matters and sulfides are the prima­ry reasons for the refractoriness, whole ore roasting is a pre­ferred method for the treatment of this type of ore. Since dry ore is to feed to the roaster, a dry grinding mill is advantageous. For the dry grinding system, the moisture content and the ore char­acteristic is of importance. Those parameters decide the mode of the grinding system. For autoclave systems common wet grind­ing systems can be applied. This paper deals with technical aspects for dry grinding plants and gives an outlook on and pos­sibilities for new grinding systems.

Jan 1, 1996

By Paul A. Lahti

Independence Mining Company, Inc. (IMC) has for the past several years processed refractory gold ores at its Jerritt Canyon operation near Elko, Nevada. The ore is typical of those of the Carlin Trend and is refractory due to physical encapsulation of gold in carbon, pyrite, and arsenopyrite. It is also "preg robbing" due to the contained organic carbon that acts as a gold adsorber. Refractory ores require some form of pretreatment before cyanidation to enable economical recovery of gold. The metallurgical facility at Jerritt Canyon is unique in that it consists of two distinct pretreatment methods for the recovery of gold: a chemical process utilizing chlorine and a pyro-metal­lurgical process employing oxidative roasting. This paper pro­vides a comparison of the two methods highlighting flow sheets, pretreatment operation detail, performance comparisons, and pertinent environmental data.

Jan 1, 1996

By Eberhard Stolarski, Michael Tacke

When the oxidized surface gold deposits are mined out, the underlying refractory gold ores become the challenge of treat­ment systems. The size and value ofrefractory gold ore reserves are a function of recovery efficiency and operating cost. The start-up of LURGI's gold roasters at NEWMONT's Carlin site has established whole ore gold roasters as a key to high gold recoveries. The ores from several deposits of the Carlin trend are roast­ed utilizing LURGI / NEWMONT technology, which has achieved gold recoveries approaching 95%. This is in dramatic contrast to the traditional perception that roasting is limited to gold recoveries in the mid 80's. Extensive investigation in pilot scale is required to achieve stable high gold recoveries for most variables in the ore body. The key question for all pilot tests is the classic question of (ROM) run of mine ore roasting or concentrate roasting. All variables are dominated by the leaching/ recovery char­acteristics of the natural ores. The degree ofrecovery improve­ment by roasting / calcining establishes the frame of the eco­nomical conditions. The full range of flexibility is required for the design of the plant to allow for ore variations in heat values, combustible con­tents, agglomeration behavior and off-gas composition. The variables in the ore body influence, therefore, the price of the plant proportionally to its flexibility. Concentrates are usually fairly stable in composition, com­bustion behavior, heat values and particle size since they are a product of the very selective flotation process. Flotation is not the successful process step when the tailings remain high in refractory gold contents.

Jan 1, 1996

By Gregory Owen Lewis, Mark William Johns

The use of resin-in-pulp (RIP) to recover dissolved metal ions from slurries is receiving increasing attention. A number of engineering aspects have been identified as crucial if a RIP sys­tem is to operate efficiently. These are the mixing of the resin and pulp, the transportation of the resin and pulp and the sepa­ration of the resin from the pulp medium. Evaluation of numer­ous alternatives revealed that air agitation is the most suitable means of mixing to effect uniform distribution of the adsorbent and to effect a high mass transfer rate, airlift pumps are the most effective method of transporting the slurry particularly as they are characterized by a low degree of resin degradation and sieve bends are the most suited means of effecting the resin/pulp sep­aration. This paper details the design of the reactor that incorporates the three identified unit operations and presents data obtained from the contactor when operated at a throughput of I 00 000 t/m. The airlift pump was found to be sensitive to pulp density and submergence ratio. The screening ability of the sieve bend was influenced by resin and the pulp density . The reactor is a cost effective, metallurgically efficient unit for the recovery of metal ions from high density slurries.

Jan 1, 1996

By J. E. Cressman, Raj Devarajan

The declaration of bankruptcy by the operator (Summitville Consolidated Mining Company, Inc., SCMCI) of the open pit heap-leach operation at Summitville and the subsequent takeover of the minesite by the USEPA has been a high profile and largely painful event for the mining industry. Shadowed by the ovrall picture has been a continuous effort by technical and operational personnel to treat contaminated water and improve water quality while satisfying various management strategies and budgetary constraints. Summitville's operations history can thus provide a body of knowledge potentially beneficial to operators and managers of present and future mining projects presenting challenges from similar geology, mineralogy, topog­raphy, climate, water chemistry, financial and regulatory ele­ments. This discussion focuses on water treatment operations that occurred at the minesite, initially as part of mining production and reclamation, and later as part of USEPA's emergency response and remedial efforts. All of the treatment efforts have targeted the cyanide and metals contamination associated with process waters from the heap leaching activities, and acid mine drainage (AMD) containing metals such as copper, iron, alu­minum, manganese, and zinc in high concentrations.

Jan 1, 1996

By Lech Bolinski, Joe Shirley

Over two dozen Resin-in-Pulp (RIP) plants have been in operation in the fonner Soviet Union since the beginning of 1970. Currently approximately 50% of the gold produced in Russia, Uzbekistan and Kazakhstan, which equates roughly to 10% of the total world output, is recovered using the RIP technology. An alternative to activated carbon, ion-exchange resin has several advantages for the recovery of gold. Resins are less prone to clay or organic foul­ing and do not require thennal regeneration. They also have poten­tially higher loading capacities, faster adsorption kinetics, and are more resistant to abrasion. The original Russian RIP process was based on engineering expertise developed for uranium ore pro­cessing and has a few major drawbacks. The biggest problem is an 18-30 day resin stripping process, which results in a huge gold lock-up. The problem was recently overcome by the development of a new stripping technology which cuts the time to 12-24 hours. Currently, there is rather limited practical knowledge of the Russian RIP process in the West, but often Western mining com­panies developing gold mines in the fonner Soviet Union are hard pressed by their local joint venture partners to take a serious look into RIP. It is probably only a matter of time before one of these companies will cross Soviet technology with Western engineering and develop a modem RIP process as an attractive option to the current CIP and CIL technologies.

Jan 1, 1996

By Richard M. Crowell, John W. Shield

GeoBiotics has developed a biooxidation technology (patents pending) which involves coating refractory precious metal sulfide concentrates onto a support material and biooxidizing the sulfides in a heap configuration. The concentrates are produced from low or high grade sulfidic refractory ores or existing mine tailings. The process has been found to achieve high gold recoveries asso­ciated with stirred tank biooxidation, but at the low operating and capital costs associated with whole ore heap biooxidation. Improved gold recoveries of up to 98% after biooxidation are reported for 4 representative mines or deposits. The sulfide flotation concentrates were studied using 3 and 6 in. diameter columns or 3 in. drained vats. The refractory sulfide concen­trates biooxidize rapidly in 3 to 12 weeks with substantial increases in subsequent gold recovery.

Jan 1, 1996

By Ken Criley, Marc E. Orman

Identifying the optimum ultimate height for heap leaching ore requires the consideration of a number of competing factors. A primary limitation is the reduction in the permeability of the ore with increasing heap heights. At low permeabilities the heap can blind off, cause serious ponding and runoff, and become very difficult to rinse at closure. The authors present a laboratory methodology that has been successfully used on several projects to identify the maximum height for controlling heap permeability.

Jan 1, 1996

By Sean E. Armstrong, Deepak Malhotra

Gold extraction from refractory ores as a percentage of total gold production is increasing. The processing technology options for treating difficult-to-process refractory ores are also increasing. The best processing option is dependent on many factors including feed grade and the cause for ore refractoriness. The causes for ore refractoriness are many foldCpreg-rob­bing, encapsulation in pyrite, arsenopyrite or silica, presence of cyanocides, presence of cyanide-insoluble gold compounds, etc.1. The first step in the process development of a refractory gold deposit is to determine the cause for ore refractoriness. The traditional approach of undertaking detailed mineralogical examination of ore types, major and minor mineral constituents and their association does not necessarily provide the metallur­gist all the information needed for characterization of gold-bear­ing ores. For process development programs it is desirable to complement traditional mineralogical methods with diagnostic leach testing, which attempts to quantify the deportation of gold in various mineral matrices. This paper briefly reviews the diagnostic leaching proce­dures and its applications for a wide range of gold-bearing refractory ores, both primary and by-product.

Jan 1, 1996

By Tong Deng, Yun Ma

Gold-copper ores have become important gold resources (von Michaelis, 1989), but the gold extraction from such materials posed a challenge due to the detrimental effect of copper species on gold cyanidation. Ammoniacal cyanidation process was rec­ommended (Muir et al., 1989) and practiced (Castello et al., 1992) for gold extraction from the gold ores which contain cop­per at moderate level mostly in form of oxide. This paper pro­vides an example to apply the ammoniacal cyanidation process to processing such a copper bearing gold ore.

Jan 1, 1996

By J. R. Montgomery, T. A. Phillips, F. Blackham, D. J. Adams

Underground water, whether it is a mine seep, in situ leach solu­tion, or a pollution plume, is difficult to track and monitor. Monitoring wells are costly to drill and may be placed in the wrong spot. This report describes a test of an electromagnetic technique to track acid water draining from the Midnite Mine near Spokane WA. The tests successfully mapped the path of acid mine drainage being collected at the mine from two seeps. Several small side branches flowing to smaller seeps and a mix­ing zone where relatively clean water mixed with the acidic water, were also mapped. The study has changed previous opin­ions on the flow of water through the site and will be used as a basis for future site remediation planning.

Jan 1, 1996

By Jeffery S. Thompson

In this report, the effect of catalytic amounts of activators on gold dissolution in clear solutions with gold disks and with slur­ries of gold ores is presented. Activators are nitrogen and sulfur aromatic heterocyclic compounds, which catalyze the gold dis­solution reaction in cyanide and other lixiviant solutions. Gold dissolu!ion studies in clear solutions indicate that the catalyst must bmd to the gold surface to catalyze the dissolution reac­tion. A concentration dependence for activation is observed· the optimum catalyst concentration depends on choice of activtor lixiviant concentration, and solution agitation. Nitrogen and sul fur aromatic heterocycles catalyze gold dissolution in slurries of gold ores with cyanide and other lixiviants. The typical proce­dures of agitated leach and rolling bottles were used to evaluate gold leaching rates. Activation has been demonstrated with a variety of ore types.

Jan 1, 1996

By James L. Hendrix, Michael R. Straka, Emil B. Milosavljevic, Ljiljana Solujic, Neil P. Gallagher

Analysts that utilize the classical distillation procedures for cyanide analysis are often frustrated by the poor reproducibility and repeatability of these techniques. Capital intensive business decisions and environmental management regulations are exas­perated by the fact that the EPA/ASTM approved cyanide deter­mination methods produce data of questionable quality. Reliable cyanide values are important in monitoring the effec­tiveness of the cyanide detoxification procedures. Efficiency and cost of gold and silver cyanidation recovery can also be improved by precise cyanide monitoring in the process itself.

Jan 1, 1996

By Paul Hamilton, Brian Jones

Traditionally,relatively large gold mines in developing countries have relied on imported process plant engineering, design, pro­ject management and advisory skills. In 1995, there was a significant departure from this in Zimbabwe, when a locally based engineering company under­took and completed the construction of a one hundred and twen­ty thousand tonne per month capacity gold extraction plant for the treatment of sands/slimes residues integrated with run of mine ore. This paper describes the challenges of designing, construct­ing and commissioning a Carbon in Leach (CIL) gold extraction plant in a developing country, and discusses the various con­straints associated with it. In addition, the paper reviews the application of technology which is innovative to Zimbabwe, including the use of dewatering cyclone clusters, and two and a half tonne capacity elution/electrowinning convection units.

Jan 1, 1996

By Richard H. Johnson

The Castle Mountain Mine (CMM) is located in the eastern por­tion of San Bernardino County, Southern California, 70 miles south of Las Vegas. The CMM is a joint venture between Viceroy Gold Corp. (75% and operator) and MK Gold (25%). The CMM initially started gold production with an 8,000 tpd cyanide heap leach operation in February, 1992 when the first ore was crushed and delivered to the leach pads. Even during construction and commissioning, design work was under way to engineer and construct a 1,200 tpd Mill circuit to process the higher grade fraction of the ore through use of pulp agglomera­tion. The need for a grinding circuit became evident with the quantity of high grade material delineated during drilling and the amount of visible gold that the geologists were finding in the drill core and R.C. cuttings. Viceroy did not want to stack the higher grade ore on the heap, and it was clear that permitting a tailings pond would, at best, be a long drawn-out affair. An alternative to a tailings facility had to be found.

Jan 1, 1996

By G. A. Plakhin, A. V. Luganov, V. A. Luganov, G. V. Gorbatenko

In order to extract gold from the complex sulphur-arsenic bear­ing raw materials and to remove arsenic and sulphur from the process in an ecologically safe form we have studied oxidizing roasting of highly arsenic gold bearing concentrates with soda, leaching of cinders, processing of the obtained solution and extraction of gold from the cake. There were processed concen­trates containing from 5 to 28% of arsenic, 12-20% of sulphur in the form of pyrite and arsenopyrite. The content of gold in the concentrates was 4-75 git. The roasting temperature was changed in the range of 773-l 173K, the consumption of calcined soda was 75-200% of stoichiometric necessarily for bonding of arsenic and sulphur into the water soluble compounds, the dura­tion of the process was varied in the range of 10-120 minutes. Under roasting in optimal conditions up to 97% of arsenic and 95% of sulphur go into water soluble compounds. The out­put of cake is 65-70% of the concentrates. The extraction of gold from the cake is higher than from the raw concentrates. The technology has been tested on a pilot plant scale

Jan 1, 1996

By Brad Hewitt

Since Campbell Mine began processing ore, there has been a gravity gold recovery circuit. From 1947 to 1982, gravity gold was concentrated through the combination of jigs and mercury amalgamation. In 1982, jigs with concentrating table upgrading commenced and was utilized until the end of 1994. As of January of 1995 to the present, Knelson Concentrators in com­bination with concentrating tables have been employed to achieve a refinable product. An evaluation of the justification used for the last change is the focus of this paper.

Jan 1, 1996

By Paul D. Chamberlin

There are many unit operations applicable to the processing of gold/copper ores. Deciding which are most applicable to your ore can be done using a series of tree diagrams. The diagrams show generalizations, not definitive rules. And the listing of process alternatives on the diagrams is very limited although there are dozens to choose from. Three questions help point the way to proper process selec-tion: 1. How much gold is in the ore? 2. How much copper is in the ore? 3, What is the cyanide consumption when leaching the ore?Halogens can also effectively leach gold ores and gold/cop

Jan 1, 1996