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By M. Rieber

The recent history of the mercury market results almost entirely from U.S. Government actions. Its derived demand has been curtailed by U.S.E.P.A. mandates; its supply has been augmented by U.S.D.L.A. controlled stockpile releases. The resultant prices have altered its market structure, impacted mercury mining, refiners and recyclers, and affected international production and markets. From a marketplace product mercury is rapidly becoming a disposal problem. Other minerals may follow in its wake. This paper reviews developments in demand, particularly in relation to environmental constraints. Supply side impacts are considered. The impact of stockpiles, both as a market overhang and as a potential supply is reviewed. Government stockpile disposal activity is emphasized, but the size, estimated disposal rate, and quality of the private stockpiles are considered, as is the potential availability of additional material from shut-in mines.

Jan 1, 1995

By Norbert Patzelt

The high-pressure grinding roll was introduced about 10 years ago and has established itself in many applications. Most of these machines are used in grinding circuits in the cement industry. A few operate in conventional mineral-processing plants. Polysius has sold more than 350 Polycoms worldwide. An exception is diamond-ore processing in South Africa and Australia. This type of grinding system increases diamond liberation and reduces the capital costs for the downstream processing plant. There are several reasons why high-pressure grinding rolls have not been used more extensively in the mining industry: - The mining industry adheres to conventional grinding technology and regional preference for certain comminution circuits. - Design, scale-up and flowsheet assessment procedures are viewed as being immature and reduce confidence in the potential application of the technology. - Downstream process benefits are unproven on a plant scale.

Jan 1, 1995

By L. G. Austin

The general manner in which the liberation function must change during size reduction is described. Data from float-sink (washability) analysis of a coal is used as an illustration, and a Locking Index is defined and calculated. Ash is not distributed equally with respect to sieve size but is concentrated more in the finest sizes. On the other hand, the ash is less locked with coal in the finer sizes than in the larger sizes. Further crushing showed decreased locking in intermediate sizes, but the material in the fine sizes (produced from breakage of highly locked larger sizes) was more locked than material of the same size in the feed. Future work is also discussed.

Jan 1, 1995

By Peter K. Weissenborn, Robert J. Pugh

The contrasting behaviour of electrolytes in inhibiting coalescence of bubbles was explained by the positive and negative distribution of anions and cations at the gadwater interface. Further, the efficiency of electrolytes which do inhibit coalescence of gas bubbles can be linked to a counter ion hydration mechanism and the effect of electrolyte concentration on gas solubility. A correlation was found between the transition concentration of electrolyte needed to prevent the coalescence of bubbles and the reduction in gas solubility. Hence, the inhibition of bubble coalescence in electrolyte solutions appears to be linked with the utilization of water molecules in the hydration of cations and a consequent reduction of water available for gas solubility.

Jan 1, 1995

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By Frank E. Kottlowski

Widespread high-calcium (HC) limestones in New Mexico and adjoining areas, are low in magnesium, but some units include shale interbeds that would be deleterious for usage in sulfur removal. In southwest New Mexico, southeast Arizona, and adjoining parts of Mexico, limestones in the thick Mississippian Escabrosa, Pennsylvanian-Permian Horquilla, and Cretaceous U-Bar units are HC as are strata in the Mississippian Lake Valley, Pennsylvanian formations, Permian Hueco, and parts of the Permian Capitan Limestone of south-central and southeast New Mexico and west Texas. In north-central and central New Mexico, many limestones in the Pennsylvanian Madera Formation are HC as are some of the Cenozoic travertines. In northwest New Mexico, where the present-day mine-mouth coal- fired power plants occur, there are no HC limestones, but to the north in southwest Colorado some beds of the Mississippian Leadville Limestone and Pennsylvanian Hermosa Formations are HC. HC limestones considered contain at least 95 percent calcium carbonate and less than 3 to 5 percent magnesium carbonate. Limits for other impurities are alumina, 1 percent; silica, 2 percent; sulfur 0.05 percent; phosphorous, 0.02 percent; and iron oxide, about 1 percent. Chemical and physical requirements differ slightly depending upon the ultimate use.

Jan 1, 1995

By Roger D. Sharpe

The United States Gypsum Company operation at Plaster City, in Imperial County, California, consists of the largest gypsum quarry in the United States, a company-owned, narrow-gauge railroad and wallboard and plaster manufacturing facilities. A variety of gypsum products, including many types of wallboard, construction plasters, portland cement setting agent, and agricultural gypsum are manufactured. Gypsum is quarried from the Miocene age Fish Creek Gypsum. Evaporite minerals were deposited in a clastic-rich sabkha environment along the margin of a small embayment in the Salton Trough. The Salton Trough is a major regional structure that formed by rifting and transform faulting along the Elsinore, San Jacinto, and San Andreas fault zones. Sedimentary basins were formed between tilted fault blocks. The basins were filled by prograding alluvial fans, basin margin sabkha and marine sediments, and deltaic deposits from the Colorado River. Gypsum is exposed in the quarry on rounded hills with 250-300 feet of relief. The evaporites are up to 200 feet thick and average 125 feet in thickness. Anhydrite commonly occurs in the lower part of the evaporites under the crests of hills and beneath thick alluvial cover.

Jan 1, 1995

The use of controlled recirculation can be dated back to the early 1930s. Although this method has been applied in many mines since then, a generalized comprehensive network analysis is still lacking. This paper presents a unique approach in which the ventilation network with a controlled district recirculation is divided into two subsystems: a main subsystem and a recirculation subsystem. The subsystems are analyzed individually and the results and their relationships are then integrated into discussions of the total ventilation system. The analysis of the recirculation subsystem is facilitated by introducing a non-dimensional parameter A, which represents the ratio of the air quantity for the working face to that for the subsystem. As a result, fan and regulator pressures and air power for various recirculation arrangements can be effectively expressed as a function of A and the subsystem air quantity. Numerical examples are included.

Jan 1, 1995

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By V. I. Ryaboy, V. A. Luknitsky, V. V. Zuyev

The action has been studied of three types of reagents used as intensifiers in grinding copper-molybdenum, sulphide-sheelite, polymetallic and other types of ores, namely N-donor, dispersant, and surface-acting agents. It has been proved that, depending on the type of ore treated, the C (N-donor) and C-170 (dispersant) reagents increase the yield of the principal size fraction of 0.074mm by 8-16% (relative). Consequently, the specific mill capacity improves by 13-21 %. The C and C-170 reagents activate the subsequent flotation stage and are thus beneficial to the mineral recovery. The surface-acting reagents affect the mineral grinding process to a lesser extent. The intensifying action of the reagents is attributed to the effective crushing energy decrease (lower crack-resistance factor) or else to the slime-dispersing effect of the reagents. The pilot-plant test results for the C reagents are given. Both C and C170 reagents are commercially produced and recommended for use at a number of concentrators in Russia, Uzbekistan and Kazakhstan.

Jan 1, 1995

By M. Akser

Ilmenite, rutile, and zircon deposits of commercial importance have not been reported to-date from Turkey. However, information from recent reconnaissance activities indicates the possibility of an economically viable heavy-mineral deposit along the Black Sea coast of Turkey in the vicinity of Ormanli, northwest of Istanbul. Consequently beach and sand dune samples were collected from that area for additional analysis. Laboratory methodologies, designed to simulate standard industrial heavy-mineral plant practices, were used to analyze and evaluate the samples. Based on the analyses, and current market needs, none of the deposits in the Ormanli area qualify as a commercial heavy-mineral deposit.

Jan 1, 1995

By Steven W. Hunt, Ronald E. Heuer, Safdar A. Gill

A 3.3 m (11 feet) diameter, 51 m (168 feet) deep temporary steel casing which had been sunk within glacial soils buckled and collapsed on July 29, 1985. The collapse occurred at the CT-8 Dropshaft site in Milwaukee while two workmen were contact grouting outside the casing in an attempt to stop groundwater inflows through a bottom plug. This paper describes the soil and groundwater conditions at the site, the casing design, the method of shaft construction, and probable causes of the buckling failure. Specific aspects of the paper include: slurry method of shaft excavation and casing installation, soil creep, earth pressure due to three dimensional arching, and buckling strength of a casing surrounded by slurry rather than grout and firm soil. The paper should be of interest to designers and constructors of temporary ground support systems for deep shafts.

Jan 1, 1995

By L. J. Nicks

The current U.S. Bureau of Mines research program is addressing the recovery of flake graphite from kish, a steelmaking waste product, and the use of zeolites from abundant domestic natural deposits for efficiently cleaning up mining industry wastewater. The United States is almost totally dependent on imports for its graphite needs, but this may change depending upon the results from a pilot plant being constructed by industry using Bureau technology. Standard mineral processing techniques were applied by the Bureau to recover high-quality flake graphite from kish. It was considered innovative enough to receive an R&D 100 Award in 1992, and its commercialization has the potential to supply the total U.S. demands for graphite many times over. Zeolites have ion exchange properties similar to ion exchange resins, but are less expensive and available in large quantities. Samples of naturally occurring zeolites were tested for their efficiency in removing metal ions from synthetic and industrial waste solutions. The tests focused on defining their selecting, loading, eluting, and regenerating characteristics, and on developing a method for recovering the metal ions as added value products. The results showed that the removal of metal ions with zeolites from acid rock drainage (ARD) solutions is technically feasible and that this technique has the potential for being used in an integrated chemical treatment systems approach either as a primary or secondary cleaning step.

Jan 1, 1995

By J. M. Mutmansky

The objective of this study was to produce coal dusts for laboratory research that are similar to mine airborne dusts in chemical, mineral, and physical characteristics. In this investigation, dusts produced in laboratory comminution equipment were compared with continuous-miner-generated dust for similarity in physical characteristics. Mining-generated dust (MGD) and bulk coal samples were first collected from an underground mining operation. The bulk samples were then processed in the laboratory for size reduction in various comminution devices. These laboratory-generated dust (LGD) samples were subjected to size and microscopic analyses. Physical properties of the dust particles were studied on a scanning electron microscope (SEM). A numerical shape coordinate system (SCS) was also developed and applied to 300 particles from each sample. Statistical analysis was then performed on the collected data and characteristics of the MGD and LGD samples were compared.

Jan 1, 1995

By J. G. Jenkins

Magma Copper Co.'s San Manuel solvent extraction/electrowinning (SX-EW) facility has operated since May 1986. The original facility had a design capacity of 22.6 kt/a (25,000 stpy) of electrowon copper cathode produced by processing pregnant leach solution from an open pit-heap leach operation. In 1988, the plant was expanded to 45.3 kt/ a (50,000 stpy) to incorporate processing in-situ leach solutions. This pager focuses primarily on the heap leaching area with regard to exploration, testing, feasibility, permitting, design and construction, and operating practices. Research using surfactant leaching aids to enhance copper recovery is also discussed.

Jan 1, 1995

By Greg R. Wheeler

Few members of the general public have a clear understanding of mineral resources. Most people do not know how minerals are mined or why they must be extracted from many diverse locations. Many people acquire knowledge of mineral development from mass media sources with incomplete details or obvious anti-mining bias. The California Mineral Education Foundation was formed in 1991 to provide educational opportunities for the public and industry. There have been major changes in earth science teaching requirements for kindergarten through 12th grade (K-12) curricula since the passage of California Senate Bill 813 in 1983. Model graduation standards, curriculum standards and the state science framework mandate substantial coverage of geoscience topics. The California State Commission on Teacher Credentialing has completed changes in multiple subject and single subject science credentials which will require more geoscience preparation for all teachers. The need for pre-service and in-service education in geoscience is at an all time high. Teachers must have continuing education to maintain their credentials and many are now seeking information in geoscience. The California Mineral Education Foundation designed and conducted the California Mineral Education Conferences held in August 1991 and 1992. The conferences involved lectures and field trips on mining geology, environmental problems and political concerns. Master teachers were employed to share how they get across mineral resource concepts in the classroom. Ninety-six percent of the participants stated that they had changed to a more positive perception of mining after taking the three day course.

Jan 1, 1995

By Richard J. Frechette

Final reclamation of mine tailings impoundments typically involves addressing the broad issues of surface stabilization and water management. Surface stabilization includes immobilizing the tailings particles and providing long-term protection of the containment facility. Water management typically includes provisions for handling both the external water (rainfall and runoff) and the internal water (pore fluids). Wet tailings disposal facilities, and sites with limited access and steep topography, present challenges to implementing effective surface stabilization and water management plans. This paper presents a generalized discussion of the approach to tailings impoundment reclamation based on project experience.

Jan 1, 1995

By C. Patrick

Annually, the U.S. coal industry generates and must dispose of over 200 million tons of coal refuse, expanding a major environmental problem. The purpose of this research was to investigate the feasibility of utilizing coal refuse as an aggregate in concrete. This paper reports on findings of the initial phases of a project to determine the viability of replacing traditional concrete blocks, used for under-ground ventilation stoppings, with refuse blocks. Refuse was collected from three active preparation plants in Eastern Kentucky and used as the primary aggregate for concrete cylinders. The refuse fell within ranges normally observed for size consist, moisture, and ash. Stress-strain analyses yielded compressive strengths of the refuse cylinders from 59% to 77% of the control group strengths. Low variability within groups while significant differences between groups were found. On-going determination of effects of weathering on the refuse cylinders is being conducted and will be completed in early 1995. The research results are favorable for the future direction of the overall project objectives.

Jan 1, 1995

By Andrea B. Baldwin

In recent years, federal and state regulatory agencies have tightened air emission standards. Two of the acid gases, hydrochloric acid (HCI) and sulfur dioxide (SO2), are under heavy scrutiny for reduction. . Most traditional scrubbing systems, i.e. wet scrubbers and spray dryers, meet the standards but they typically are high in capital cost, have significant space requirements for equipment, and are difficult to maintain. Dry sodium injection (DSI) is a alternative technology that has been shown to be effective in HCl and SO2 removal while being the inverse to the problems listed with traditional systems. This paper covers the mechanics of dry injection scrubbing using the most effective sorbents, sodium bicarbonate and mechanically-refined trona (natural sodium sesquicarbonate). It presents DSI performance data for Chambers Medical located in Hampton, SC. This facility incinerates local medical and municipal solid waste. Chambers Medical has used mechanically-fined trona for HCl and SO2 removal since late 1991.

Jan 1, 1995

By J. M. Mutmansky, B. Kolonja

A PC-based simulation model using the software packages SIMAN and CINEMA was developed to simulate and animate truck-shovel operations. The model is capable of simulating one mathematical dispatching strategy using linear and dynamic programming and six heuristic dispatching strategies. Data were collected from an actual operating mine through time studies and analysis of historical records. Statistical analyses were performed, and appropriate theoretical distributions were fitted for various time events in the truck-shovel cycle. The model was then applied to study overall impact of these dispatching strategies on constrained and unconstrained mine productivity. The simulation/animation model developed in this study seems to be an efficient planning tool for choosing optimal fleets and finding an optimal dispatching strategy to produce an equilibrium between the quality and quantity of production.

Jan 1, 1995