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By Joel L. Morrison

The preparation of coal-water slurry fuel (CWSF) has the potential to be a commercially viable technology for the coal industry. The technology base required to prepare stable CWSF using grinding circuits has been developed over the past decade and is now being applied to the preparation of CWSF from wet coal fines which are generated during coal beneficiation. When preparing CWSF, the optimum CWSF formulation must be determined to ensure that the fuel will be stable while having acceptable atomization and combustion properties, and the production run must be monitored closely to ensure that the CWSF quality is maintained. This paper describes the CWSF formulation process, CWSF preparation circuits, and some of typical problems encountered in, and solutions to, the transportation and storage of CWSF.

Jan 1, 1993

By D. W. Fuerstenau

One of the more energy-efficient methods for size reduction, namely particle-bed comminution under high compressive loads, was employed to grind eight minerals and ores, using up to 250 MPa pressure. A new approach based on the self-preserving character of the ground product size distributions and a linear energy-reduction ratio relationship is proposed for analyzing this mode of size reduction. The grind ability of the material when comminuted in a particle bed is about one-half that of the single-particle crushing mode, which is in agreement with previous estimates of the relative efficiencies of energy utilization based on direct measurements of surface area produced. The loss of efficiency may be attributed to energy dissipation by particle interaction phenomena in compressed beds.

Jan 1, 1993

By Rajiv Hadkar, M. D. McKinley, J. B. Hiskey, B. J. Scheiner, G. W. Warren

Flyash from municipal solid waste incinerators containing roughly 13 to 15% Zn, 2% Pb and 0.2% Cd is an attractive material for simultaneous metal recovery and detoxification. Results have shown that Pb in flyash is present as PbSO4 and PbC12 and that about 70% of the Zn is present in the form of soluble amorphous compounds. Leaching results in a number of acid and basic lixiviants show that acid leaching is clearly more effective than basic leaching which is limited by low solubility of Cd and Zn. Cementation in acid solution with pH < 1 promotes redissolution of the precipitated metal. Successful zinc electrowinning from chloride leaching solutions has also been demonstrated, although Pb2+ and Na+ can be potentially detrimental. The presence of Pb2+ can prevent deposition of metallic Zn, forming zinc oxychloride, ZnC12.4Zn(OH)2, instead. High concentrations of Na+ can also result in precipitation of NaCl. This investigation has shown that hydrometallurgical treatment of MSW flyash through leaching, cementation and electrowinning is a potentially feasible method for simultaneous detoxification and recovery of metal values. Several issues have also been identified which would require further investigation for final process development.

Jan 1, 1993

By L. Blain

In practice, geochemical analyses can be grouped in two broad categories according to their aim. Those that seek to determine the exact chemical composition of geological materials fall under the heading of assays, whereas applied geochemistry concerns itself with the detection of anomaly contrasts. Recent trends have blurred the distinction between both approaches for many users, as methods that were traditionally used for assays are being adopted in applied geochemistry and assays make increasing use of instrumental techniques. Nevertheless. it is important to keep a clear distinction between the two types of analyses because it has immediate practical consequences, cost is the most obvious, as well as fundamental implications. In the broadest terms, the goal of geochemistry is to strike an optimal balance between throughput and accuracy, at the lowest reasonable cost, while assays strive for accuracy. Traditionally, complete silicate analysis has been the concern of assayers whereas exploration geochemists have been more interested in base metal analyses where acid extractions of the elements, without dissolution of the silicate matrix, has been the norm. This kind of distinction is less realistic now, especially with the growth in lithogeochemical studies, and some overlap in methodology is unavoidable. However, where such overlaps occur the distinction remains in the emphasis of the work. A commonly used example is that although HF acid preparations are used by both, the emphasis in applied geochemistry is on sample throughput and batch analysis, whereas assayers are more concerned with the range of elements to be determined (Thompson and Walsh, 1983).

Jan 1, 1993

By H. W. Renner

The paper industry is an $80 billion/year business that is the largest consumer of industrial minerals. Paper industry generally refers to paper and paperboard products, including pulp mills. Grades and uses of paper and paperboard are very diverse, including such things as napkins, paper plates, corrugated boxes, magazines, newsprint, currency, and copier paper. Only about 40% of paper utilizes industrial minerals as fillers or coating materials. Minerals are used for both functional and economic reasons. Most often, minerals such as kaolin clay and calcium carbonate are used to improve print quality, brightness and opacity of paper. The minerals can be added as fillers into the paper in the wet end of the papermaking system, or can be applied as part of a coating to the paper. Coated papers are the highest quality paper, being used for magazines, advertising brochures and annual reports. Common uses for filled uncoated paper are books, copier paper, envelopes and many of the Sunday newspaper advertising inserts.

Jan 1, 1993

The heat of immersion of coals in different immersional liquids is measured as a function of particle size and moisture content. Decrease in particle size shows a concomitant increase in the heat of immersion. The heat of immersion is dependent upon the nature of immersional fluids. In addition the nature of moisture present in coal influences the heat of immersion.

Jan 1, 1993

By George Owusu, Ernest Peters, A. J. Monhemius, G. W. Warren, David B. Dreisinger, E. Peters

Lignin sulphonic acid (or its salt) is commercially used as a surfactant in the Zinc Pressure Leach process. The surfactant prevents liquid sulphur from coating unreacted zinc minerals thus allowing the leaching reaction to proceed. Infrared studies have been performed using the Attenuated Total Reflection-Fourier trans- form infrared technique (ATR-FTIR); the application of this technique permitted the "in-situ" study of the adsorption of the surfactant by sphalerite. The spectral records obtained from study indicate that the lignin sulphonate ions are both physically and chemically adsorbed by the sphalerite.

Jan 1, 1993

By Merrill P. Allen

The Vernal phosphate rock concentrator is located in the Uinta Mountains near Vernal, Utah. Ore is sedimentary rock from the Phosphoria Formation. Truck and shovel mining is done at a rate of 11,500 TPD. Run of mine ore is crushed and then milled through a SAG mill and ball mill to minus 16 mesh. Milled ore is deslimed using cyclones and hydrosizers. Sands are conditioned with fatty acid, petroleum sulfonate, diesel fuel and frother prior to primary rougher and cleaner flotation. Primary flotation tailing is milled to 95% minus 48 mesh, deslimed in cyclones, conditioned using reagents previously described, and then processed through rougher and cleaner scavenger flotation. Product of scavenger cleaner concentrate is upgraded by reverse flotation of dolomite. Flotation concentrates are combined and dewatered, pulp being milled to 99.5% minus 65 mesh and then thickened to 65% solids. Product is pumped from storage through a 10 inch, 94 mile pipeline to a conversion plant at Rock Springs, Wyoming. Mill tailing is stored behind an earthen dam, water from the settled tailing being reclaimed for mill use.

Jan 1, 1993

By C. D. Secrest

Visiting Spring Canyon, a historic coal mining district near Helper, Utah, I was impressed by the great accomplishments that had taken place there. A tour book of the region tells of a period that began in the early 1900&apos;s, when the land was still very much the Old West, when settlers lived out their lives in coal company towns and produced a resource that was to build a nation (Cunningham, F., 1990). Between 1912 and the early 1970&apos;s, 11 mines had come and gone in that narrow canyon less than 15 kilometers long. Spring Canyon is a historic district now, but I could not dwell too long on the richness of its history. I was there to look for evidence of PCBs.

Jan 1, 1993

By W. M. Colwell

When it comes to the analysis of gold bearing ore, there are literally dozens of variables that contribute to the final "true value" of a given sample. Initial sample selection, splitting size and method, inherent nugget gold, pulverization method, and analytical method variations are but a few. However, it seems that the inherent nugget gold particle is targeted as the primary reason for intra and inter-laboratory variations in assay. The following study will show that this is not always the case. A series of tests were undertaken for the Aurora Partnership-Aurora Project to solve inter-laboratory variations in the analyses of blasthole cuttings. Initial concern was centered on the probability that free gold occurrence was resulting in erratic results for the mine&apos;s cyanide shake assays and outside laboratory fire assays. Comparison of fire assay and cyanide shake assay was sporadically consistent with previously demonstrated extraction percentage for the cyanide method. The goal was to delineate the factors that ensure consistency in analyses; implement, where needed, Good Laboratory Practices; and reestablish acceptable analytical method correlation.

Jan 1, 1993

By C. R. Stephan, N. B. Greninger, W. A. Slivensky

The U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) are participating jointly in a research program to evaluate strength characteristics and air-leakage resistance of various proposed seal designs for use in underground coal mines. Over 20 full-scale seals were constructed in the Bureau&apos;s experimental mine at the Lake Lynn Laboratory, air-leakage tested, then subjected to pressure pulses of 0.14 MPa or greater. A discussion on the experimental procedure, construction techniques, and the explosion and air-leakage test results is presented. Four types of construction material were used during this seal testing program: solid-concrete-blocks, low-density foam blocks, cementitious foam, and wood blocks. Only one of the solid-concrete block designs using a mortared thick wall survived the explosion and air-leakage tests. Most of the low-density foam block and cementitious foam seal designs were judged to meet the requirements to be considered a coal mine seal. One of the wood block convergence seal designs failed explosion testing. Based, in part, on these research findings, several alternative seal design constructions using low-density foam blocks, cementitious foam, or wood have been approved by MSHA for use in coal mines.

Jan 1, 1993

By Q. Xu, P. Somasundaran

Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied, with •Sodium dodecylsulfate as the anionic surfactant, and •Octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactants was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in wettability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant molecules at the interface.

Jan 1, 1993

By Darryl Amick, Keith A. Prisbrey, Lee E. Plansky

The problem addressed was to develop automated image analysis of metal welds to replace unreliable and costly 100% visual inspection. The objective was to evaluate neural networks combined with features from gray level surfaces. Photomicrographs of the welded seam in Zircaloy-4 channels used in nuclear fuel rod assemblies were examined. The methodology used was to select a set of morphological feature coefficients from Bessel Fourier morphological feature coefficients extracted from digitized photomicrographs. The selected morphological feature coefficients were then used to train a neural network. The approach was verified initially by successfully training a neural network using the known, secondary chemistry of the alloy welds. The results were good. The Bessel Fourier coefficients captured sufficient information from the metallographic images to distinguish weld quality. This approach has the combined advantages of compressing the images through Bessel Fourier coefficients and give the ability to rapidly process large amounts of data using neural networks.

Jan 1, 1993

By X. Cheng

The mechanism of cathodic decomposition of pyrrhotite was studied in deoxygenated solutions at natural, near neutral pH using potential and cyclic voltammetric measurements. Reaction products on pyrrhotite surfaces were examined by AES and XPS, and by analyzing the voltammograms for the electron balance of the reactions. Surface properties of the pyrrhotite/solution interface were characterized using ac impedance technique. The parameters of an equivalent circuit were determined by the nonlinear least squares fit (NLLSF) technique. The effect of cathodic polarization on floatability was investigated by micro-flotation tests. Possible implications to the flotation separation of chalcopyrite-pyrrhotite ores are discussed.

Jan 1, 1993

By Takeshi Tanaka, Yasuhiro Komamura, Yuusaku Tominaga, Takayoshi Iwamoto

In order to assist better countermeasures for ventilation control in normal/abnormal condition of mine ventilation network in real time, branch relation table derived from a macroscopic characteristic of ventilation network is introduced in this study. The main results in this study are as follows; 1) One of macro characteristics of a ventilation network, as a relation between airflow rates in two branches chosen arbitrarily, is specified under the change of aerodynamic resistances in a branch. Airflow rate in a branch can be estimated by airflow rate in other branch changing aerodynamic resistance by using empirical formula. The empirical formula by computer simulation of the Horonai coal mine, Japan is considered to be a one-valued function with monotone or extremums. 2) A branch relation table shows the macro characteristics, mentioned above, of all the set of two-branch combinations in a network. Elements in the table give both information of control possibility range of airflow rate and total number of extremums in an empirical formula. 3) It is important that when aerodynamic resistance change in a branch is estimated by measuring airflow rates in two typical branches, the two branches should be chosen from branch combinations with monotonous relation in the branch relation table. 4) A flexible expert system to assist ventilation control in the specified branch in real time has been developed by using a branch relation table for a ventilation transfer diagram of the specified branch, such a coal face and an advancing face. A fuzzy reasoning is utilized in the recognition of the safety factor, methane concentration, in the system. And when conviction degree in recognition for methane concentration at the specified branch is too low, the system searches for other branch combinations in the branch relation table stored in the system, to use other ventilation transfer diagram of the specified branch. When a needed ventilation transfer diagram is not stored in the system, the expert system asks automatically the ventilation simulation from other computers linked to the main computer automatically. The system repeats consultation until conviction value of safety in the specified branch approached

Jan 1, 1993

By B. K. Mishra

Power draw of the mill has been accepted as an indicator of the performance of the mill, yet the problem of predicting power under a given set of mill operating conditions still remains to be solved. In the literature, this problem of predicting power is attributed to a lack of knowledge with regard to the motion of the charge. Here a DEM based model is used to analyze the motion of the charge. The resulting information is used to predict the power draw of the mill. A 16-ft diameter mill is simulated. A factorial design study of the variables-mill speed, lifter configuration and ball size distribution-as independent variables is taken up. The power draw as a response variable is analyzed to establish the best operating condition of the mill.

Jan 1, 1993

By James I. Mathis

Should an arbitrary reduction factor be applied to laboratory compressive strengths when designing pillars? The answer is, as is the main contention of Peng&apos;s article, probably not. Many factors affect the strength of the material remaining in the pillar. On the other hand, outside influences will influence the strength testing results from the lab. This is not the first article, nor the last, to discuss the discrepancy between the two strengths. As was discussed in the article, actual pillar strength is affected by several factors. The two mentioned were: • The scale effect of discontinuities. How large must the pillar be so that the increase in discontinuity count with size will not decrease the strength. • Non-uniform strengths and lithologic units within the pillar. The scale effect of discontinuities is important. What size block must be tested so that the rock mass strength is actually measured? For a highly fractured rock mass, or coal with a high cleat density, this sample may be quite small. Conversely, if an unaltered, moderately jointed, quartz monzonite was examined, the sample block would likely be very large. This is the subject of ongo¬ing research. More to the point, if the tested sample is sufficiently large to model the rock mass strength, then no reductions should be made in the lab strength based on this factor alone. Non-uniform strengths and variations in lithologic units will also affect the pillar strength. I am not an expert in coal mines, having gained my experience in hard rock metal mining. These problems, though, are commonplace. However, strength sampling for pillar strength determination involves sampling material from within the lithologic unit that will form the pillar, not from pieces of material found on the floor. In addition, this sampling should cover the entire range of strengths of the material in the pillar-hard units (such as the partings described by Peng), as well as soft units. Testing results should then be included in the pillar design. Contrary to statements in Peng&apos;s article, at least one rock mass rating system (Laubscher, 1990) allows for the compositing of strong and weak units into a design rock mass strength that can be used for pillar design.

Jan 1, 1993

By J. C. Yingling, G. T. Lineberry

A control system for reducing peak loads on mine conveyor networks is proposed. The system involves continuous monitoring of flows into the conveyor network and section feeders with variable discharge capability. The control strategy uses differences in material transit times from various production units to the transfer points in the network to forecast load levels that will he intersected by the discharge of the controlled feeders over future time intervals. Feeder setpoint adjustments are made to prevent excessive peaks in the combined flows at the transfer points, while maintaining adequate feeder through flow to avoid production bottlenecks. Simulation studies suggest that the control strategy would be very effective in reducing capacity requirements of gathering belts.

Jan 1, 1993

By L. B. Rothfeld

This paper presents preliminary results of a Bureau of Mines study of potential costs of compliance with the federal Resource Conservation and Recovery Act for copper heap and dump leaching. Specifically, estimates are given for the cost of compliance with possible technology standards that would require the use of liners and closure caps regardless of terrain and underlying geology and hydrology. This cost is compared to the co lit of compliance with present state requirements for terrain a typical of those found at existing copper leach sites in the Southwestern U.S.A. Incremental compliance costs are found to widely exceed screening criteria used by the Environmental Protection Agency to denote significant economic impact.

Jan 1, 1993

By M. A. Chandler, G. T. Adel, J. N. Richardson, E. C. Gutierrez

A rapid, bench-top analyzer has been developed to determine P2O5 content and CaO/P2O5 ratio in phosphate ores. The analyzer utilizes a portable computer equipped with a frame grabber to measure the reflective intensity (gray level) of phosphate samples placed in front of a television camera. P2O5 content is related to the average gray level of the sample, while CaO/P2O5 ratio is determined from the amount of bright material present. The sensor is currently being used to analyze flotation concentrate samples at Texasgulf&apos;s phosphate operation near Aurora, North Carolina. Sensor development along with results from laboratory and in-plant testing are discussed.

Jan 1, 1993