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By K. Nuttall, S. Vijayan, A. J. Meinyk, R. D. Singh

For conventional applications, there is limited demand for rare earth elements as well as yttrium and scandium. But the emergence of new high technology applications such as supermagnets, lasers, and superconductors should result in significant demand for some of these elements. This article examines the anticipated applications and demands for rare earth elements over the next decade. It also looks at the implications on the use of available resources. In the context of a growing demand, process methods are reviewed for the recovery of rare earth elements from conventional and unconventional resources. And the article also discusses the challenges facing the mining industry in meeting this opportunity. Reserves and reserve base The rare earths (RE) are a homogeneous group of metallic elements occupying the area from lanthanum to lutetium in group IIIB of the periodic table. Yttrium and scandium are also included with the rare earths because of their chemical similarities and common existence in nature. These 17 elements and their atomic numbers are shown in Table 1. The rare earths are widely distributed in low concentrations throughout the earth's crust (Hedrick, 1985). They occur in many rock formations including basalts, granites, shales, and silicate rocks at concentrations of 10 - 300 ug/g. They also occur in more than 160 discrete minerals. Most of these are rare, but may contain as much as 60% rare earth oxides (REO). More than 95% of the REO occurs in three minerals: monazite and bastnasite for the light rare earths and xenotime for yttrium and the heavy rare earths. Apatite and multiple-oxide minerals, such as euxenite and loparite, are also commercial sources of the lanthanides and yt-trium. Rare earths do not occur in nature in the elemental state. And, except for scandium, they do not occur in minerals as individual compounds. Bastnasite and monazite are the two major minerals used commercially to supply most of the rare earths (Hedrick, 1985). Bastnasite is a key raw material source for the cerium subgroup elements. The largest known bastnasite deposit occurs with iron ore minerals in China. The second largest deposit is situated in California. Typical rock analyses of the fluorocarbonate mineral bastnasite deposit in California show about 15% bastnasite. The REO content of that is about 50%. Monazite is present in beach sands in many parts of the world. This includes India, Brazil, Australia, South Africa, the

Jan 1, 1989

By Michael J. Shulman

During-all phases of exploration limited resources must be allocated among exploration methods and among exploration prospects. This problem,, an exercise in optimization, can be treated mathematically. For three objective functions - maximizing return, return to cost and return minus weighted cost - theoretical results exist which enable the exploration planner not only to gain valuable insight into the problem, but also to estimate the resources necessary and to allocate these resources for' at least-two stages of exploration prior to initial field work. A two-stage exploration strategy for volcanogenic-sedimentary iron in northern Egypt illustrates, how the results can be used. Stage 1 consists of an aeromagnetic survey to map the structure of five areas;" stage 2 consists of field reconnaissance work. For the three objectives, lower bounds are calculated as a function of exploration expenditures for each stage in order to facilitate the choice of an-optimal exploration budget. Nomograms are then presented which, based on the Kuhn-Tucker Conditions', enable the incremental allocation of airborne and reconnaissance effort among the five areas.

Jan 1, 1989

By C. E. Jordan, B. J. Scheiner

The Bureau of Mines has developed a continuous ultrasonic flotation cell for the recovery of Florida phosphate ore. Within a small mixing chamber near the bottom of the flotation cell, an ultrasonic probe agitates an injected mixture of air, water, and phosphate ore and breaks the air into fine bubbles. Phosphate particles are preferentially attached to these fine bubbles and floated in the main chamber of the flotation cell. Over 94 pct of the phosphate was recovered, resulting in a 30 pct P205 concentrate. The ultrasonic energy consumption was less than 7 kW.h/mt of phosphate ore.

Jan 1, 1989

By K. A. Sauer

Blasting can create severe interference for a mine's carbon monoxide based fire detection system. At the present time, without being able to differentiate between blast and non-blast carbon monoxide, a fire detection system must either set fairly high alarm levels for its sensors, or allow frequent "false" alarms to sound during blasting. This paper will introduce current work being done which will attempt to define characteristics of the carbon monoxide concentrations time curve for blasting. The work uses drift blasting for its data base as it is one of the more common forms of blasting. Future work with the data may produce a mathematical model which can be used to monitor and identify the carbon monoxide time curve for drift blasting.

Jan 1, 1989

By G. T. Adel

As a prerequisite to removing mineral matter from coal by any physical separation technique, the mineral and coal particles must be sufficiently liberated. In the case of the production of superclean (< 2% ash), low-sulfur products, the appropriate liberation size may be less than 10 µm. Unfortunately, much of the liberation data obtained at these fine sizes is only qualitative due to the lack of appropriate instrumentation. In the present work, computerized image analysis has been used to characterize several common eastern U.S. coals. In most cases, it has been found that micronizing of the coal is necessary in order to achieve sufficient liberation for deep cleaning. Liberation analyses of the products from the microbubble column flotation process have been used to distinguish problems in liberation from problems in selectivity, especially as they pertain to pyrite rejection.

Jan 1, 1989

By S. R. Maynard

The Ortiz Mountains lie 25 mi (40 km) northeast of Albuquerque, New Mexico in Santa Fe County (Figure 1). Approximately 350,000 ounces (11,000 kgs) of gold have been produced from the Ortiz Mountains since the 1820s. The 100 square mile (260 square km) Ortiz Mine Grant was secured from the Mexican government in 1833 by Jose Francisco Ortiz for the purpose of mining gold. The Grant has remained more or less intact to the present. The mineral rights are currently owned by Ortiz Mines, Inc. of Joplin, Missouri and are leased to LAC Minerals, USA, Inc. (west half) and to Gold Fields Mining Corporation (east half).

Jan 1, 1989

By Fernando H. Muge

The first application of dynamic pro¬gramming to the problem of grade control and scheduling was by Muge et al (1979) and Ribeiro (1982) who applied it to the simple, two-dimensional case of longitudinal open stoping using two sublevels. In this paper the formulation of the problem is extended to cover the general case applied to a cut-and-fill mining method. The criterion for optimization is the total deviation of the average, grades of mining blocks from the overall average panel grade (or the average grade of a set of mining panels or the mine processing working point). This means to schedule the operation by removing a certain number of mining blocks at a time, subject to the geometric (mining) constraints, and such that the total deviation of average block grades from overall average grade is minimum. The method can be applied to complex orebodies with several ore characteristics and the deviation of each one of these characteristics can be further constrained by specifying maximum values. The method can also be generalised in order to take into account any necessary geometric constraints used to define the mining method. In this paper a case study is presented concerning the mine planning of a complex sulphide orebody located in the South of Portugal. As input for the definition of the mining sequence, a geostatistical numerical model of the orebody was built based on a previous ore typology. The short term planning is used to assess specific mining sequences and the production scheduling is performed on the basis of an objective function (e.g. minimization of grade fluctuation).

Jan 1, 1989

By J. Abbott

This paper gives a brief description of the Compania Ninera del Pacifico (CNP) a subsidiary of the Campania Acero del Pacifico (CAP), its participation in the Chilean Iron Ore mining and the gradual development of its activities. mainly in this paper, it is explained the CNP experience in the production of 34 million tons of self-fluxing pellets for Blast Furnace in a period of ten years in its Huasco Pellets Plant.

Jan 1, 1989

By D. M. Range

Exxon is reclaiming an 80-hm2 (200¬acre) Wyoming uranium tailings basin in accordance with US Nuclear Regula¬tory Commission (NRC) requirements. The reclamation plan is designed to control the tailings and their radioactive emissions for at least 1000 years. Rigorous modeling and analyses of potential erosion by wind and water were used in planning. The use of riprap was minimized and the need for long¬term reclamation maintenance was eliminated. The resulting design is simi¬lar to regions stable from erosion cre¬ated by nature. The concepts used in the design and implementation have wider reclamation application. Highland history Exxon operated the Highland uranium operations from 1972 until mid-1984. Open pit and underground operations mined the roll front, sandstone ore body. The 2.5 kt/d (3000 stpd) mill employed conventional crushing, grinding, sulfu¬ric acid leach, CCD, SX, precipitation, and drying circuits. The mill produced 10 Mt (11 million st) of tailings. An¬other operator began commercial scale in situ leach operations in 1988. The tailings basin was constructed by deposition of mill tailings in a natural ravine dammed with a 30-m (100-ft) high by 1050-m (3400-ft) long clay core earthen dam built entirely downstream of tailings. Figure 1 shows the layout of the tail¬ings basin in 1984. Tailings were de¬posited along the dam face on the east side of the basin as well as in the west end and along the south edge until the early 1980s. This left a deep water pond in the middle of the basin. The deep pond was largely filled with tailings during the last four years of mill opera¬tions by the construction of two tailings causeways and the operation of a float¬ing tailings line. The pond water volume was mini¬mized by recycling tailings water to the mill and by operating a 32-L/s (500¬gpm) evaporation enhancement spray system during the last few years of mill operations. Regulatory requirements Several conceptual tailings basin rec¬lamation plans were prepared during the mine life. In September 1984, Exxon began preparation of a detailed plan in response to an NRC request. Water, Waste and Land Inc. (WWL) of Fort Collins, CO was selected to help pre¬pare the plan that was submitted to the NRC in December 1984. The design had to meet the require¬ments found in NRC regulations (NRC, 1985). These were based on regulations prepared by the Environmental Protec¬tion Agency (EPA, 1983) at the man¬date of federal law (UMTRA, 1978). The NRC regulations contain strict primary standards and a somewhat more flexible set of secondary standards. The primary standards include requiring that: • radiation from tailings be reduced to background levels; • radon gas emitted by the tailings be reduced to 20 pCi/m2/s from the surface of the reclaimed tailings pile; • tailings not be dispersed into the environment; and • these conditions endure without routine maintenance for at least 200 years and for 1000 years to the extent reasonably attainable. The lengthy time requirements pre¬sented a large engineering challenge. Radon is a radioactive, chemically inert gas with a 3.8 day half-life. It is released from uranium tailings by the radioactive decay of radium, which, in turn, is a radioactive decay product of uranium. Radon emissions from ura¬nium tailings can be controlled with an earthen cover thick enough that the radon gas decays to its solid, short-lived radio¬active daughters before the radon dif¬fuses through the cover material into the air.

Jan 1, 1989

By Jan M. Mutmansky

The application of computers and operations research to mine planning problems has changed and progressed significantly over the last several decades with a continuing growth and increased breadth of applications being quite evident. A scan of the volume associated with the 1969 APCOM published two decades ago (Weiss, 1969) indicates that the primary applications in mining were often in the areas of short-term and long-term planning and production scheduling. The applications at that time were oriented toward underground and surface mining, but block and other mine sequencing and scheduling problems for large open pit mines were perhaps the most popular target for the operations research approach. A variety of operations research techniques were used at that time with heuristic models, mathematical programming models and simulation programs all being commonplace. The computers used were usually mainframe models which were of ten shared by accounting, engineering, planning and research groups.

Jan 1, 1989

By R. Herrera-Urbina, D. W. Fuerstenau

A large number and a wide variety of chemical reagents are used in flotation processes for wettability and Eh control, particle agglomeration/dispersion and bubble stability. A historical account of the use of flotation reagents through the years since flotation was introduced as a viable and economic process for the concentration of sulfide minerals is given and a review of old and modern postulates of their interaction with minerals is presented. Although the results of surface and colloid chemistry studies with well characterized mineral/flotation reagent systems have advanced our understanding of the role played by these chemicals in the flotation process, many questions remain unanswered. Moreover, new flotation reagents are needed to solve the challenge posed by the treatment of problematic-type ores and fuel deposits that have increasingly become the source of our raw and energy materials. Because of the depletion of high-grade and relatively easy-to-process ores, flotation scientists and engineers are confronted with finding more specific and selective flotation chemicals to effectively and economically concentrate minerals. The development of new flotation reagents is vital for cleaning fine coal and processing polysulfide, polymetallic ores, and mixed oxide/sulfide ores.

Jan 1, 1989

By Harry M. Conger

Good afternoon, fellow members of the international mining community. I appreciate the opportunity to participate in this special three-day, international gathering, and to join with you in honoring one of my very good friends, Doug Fuerstenau. It couldn&apos;t be more fitting to have this kind of event to mark Doug&apos;s 60th birthday. You know, in addition to his faculty position at the University of California in Berkeley, Doug is a member of the Board of Directors of our Homestake Mining Company. So it is a double pleasure for me to help pay tribute to one of the outstanding academicians of the mining industry as well as a man with whom I work closely in running Homestake. I have been asked to talk about "The Future of Precious Metals," but I will concentrate my remarks on gold. Since the theme of this Symposium is "Challenges in Mineral Processing," what I&apos;m going to talk about is a challenge that relates especially to a major problem faced by those of us who process ores to recover gold. I noted that in the Scope of this Symposium, it stated: "the mineral industry is currently facing many challenges to improve the economics, operating efficiencies and environmental concerns of the mineral processing system." I couldn&apos;t agree more with that statement. I think that a need exists for us to address this situation as it involves gold. And who better to consider this than the worldwide leaders of mineral processing research here assembled. I start with the premise that we need a new method for cyanide use or a chemical to replace sodium cyanide entirely. In the case of using cyanide differently, I see a continuing difficulty in getting general public acceptance regardless of how

Jan 1, 1989

By Bo Forsman

The computer program SYGRISIS estimates number of units of equipment and operating costs on the basis of yearly production for different loading (wheel loader, LHD, digging arm loader) and transport (truck, train, conveyor belt, hoist, pump) equipment either individually or in any specified combination. Input data are yearly capacity, working time and technical data for the equipment. For the cost analysis input data are technical quantities and unit costs. SYGRISIS is written in TURBO Pascal and can be used on IBM compatible PCs with MS-DOS operating system.

Jan 1, 1989

By Glenn A. Shirey, Robert D. Stoessner, S. Gopalakrishnan

Under a contract awarded by the U.S. DOE-PETC, the Pennsylvania Electric Company and New York. State Electric and Gas Corporation are conducting a test program to evaluate and optimize the performance of a two-inch air-sparged. hydrocyclone (ASH) for cleaning fine coal. The test program is being conducted at the Homer City EPRI Coal Quality Development Center, utilizing Upper Freeport coal classified to minus 0.15 mm as the process feed material. A matrix of experiments has been conducted to establish the influence of significant design and operating variables (including overflow and underflow orifices, inlet slurry pressure, airflow rate, and reagent dosage) on the production of deep cleaned coal. Performance of the ASH is being compared to conventional froth flotation, utilizing advanced techniques and selected flotation reagents. This paper focuses on work completed to-date to optimize the performance of the air-sparged hydrocyclone for cleaning fine coal. INTRODUCTION The Pennsylvania Electric Company (Penelec) and New York State Electric and Gas Corporation (NYSEG) have been evaluating advanced fine coal cleaning processes for the production of compliance grade coal (1.2 pounds S02/million Btu). Laboratory bench-scale froth flotation results were compared with results of advanced flotation processes as performed by various organizations, utilizing the same coal feed. Among the processes evaluated, the air-sparged hydrocyclone (ASH) - developed by Dr. Jan Miller at the University of Utah - was considered to offer the best potential for retrofitting into an existing coal preparation facility because of the increased capacity per unit volume. The ASH has been shown to process over 100 times the throughput of conventional froth flotation cells. In May of 1988, Penelec/NYSEG was awarded a contract from the Department of Energy&apos;s Pittsburgh Energy and Technology Center (DOE-PETC) to optimize the performance of a five cm (two inch) ASH for producing compliance grade coal from raw classified minus 0.150 mm (1.00 mesh) Upper Freeport coal, and to compare its performance with conventional froth flotation utilizing advanced techniques and selected flotation reagents. The test work is being conducted at EPRI&apos;s Coal Quality Development Center (CQDC) in Homer City, Pennsylvania, utilizing a circuit processing 0.10 to 0.25 tons of coal per hour. Other members of the Penelec/NYSEG contract team include the University of Utah, Advanced Processing Technologies, Inc., Davy Dravo, Kaiser Engineers, Ebasco Services, and Management and Technical Systems. ASH DESCRIPTION AND OPERATION The ASH-2 System is a five cm ID (actually 4.76 cm) air-sparged hydrocyclone manufactured by Advanced Processing Technologies, Inc., under license from the University of Utah, for the purpose of research, evaluation and development. A schematic drawing of the air-sparged hydrocyclone is presented in Figure 1. Basically the air-sparged hydrocyclone consists of two concentric right-vertical tubes, a conventional cyclone header at the top, and a froth pedestal at the bottom. The inner tube is a porous tube through which air is sparged radially. The outer nonporous tube simply serves as an air jacket to provide for even distribution of air through the porous inner tube. The slurry is fed tangentially through the conventional cyclone header to develop a swirl flow in the radial direction. Air is sparged through the jacketed, inner porous tube wall and is sheared into small bubbles by the swirl flow. Hydrophobic particles in the slurry collide with these bubbles and, after attachment, are transported radially into a froth phase which forms on the cyclone axis. The froth phase is stabilized and constrained by the froth pedestal, thus moving towards the vortex finder of the cyclone header and discharged as an overflow product. Hydrophilic particles generally remain centrifuged in the slurry phase and are discharged as an underflow product through the annulus created by the froth pedestal.

Jan 1, 1989

By Pierre Mousset-Jones, Felipe Calizaya, Malcolm J. McPherson

The objective of this study is to provide potential users of booster fans in coal mines with the necessary information on monitoring and control of fans and environmental factors. The guide-lines listed in this paper were formulated based on the current practice of mine monitoring, the U.S. Code of Federal Regulations on environmental monitoring, and the United Kingdom&apos;s National Coal Board recommendations on the use of booster fans. The principles involved in the design of booster fans as well as the provisions needed to guarantee a safe operation of these units, are illustrated by means of an example problem. The example includes a summary of costs for two ventilation systems: a conventional surface fan system and a fully automated booster fan alternative. A comparison of these costs showed that significant gains may be attained by selecting a combined surface-booster fan strategy over a conventional surface fan alternative.

Jan 1, 1989

By A. G. Mayton

Bureau of Mines research has addressed improved operator protection for thin-seam shuttle cars. Because of working height restrictions in thin-seam mines (1.22 m or 48 in), MSHA regulations require that-canopy protection on shuttle cars be provided only in mines 1.07 m (42 in) and greater; however, variances are given to mines 1.22 m (48 in) and below. This paper reviews past Bureau efforts to develop protective structures for thin-seam shuttle car operators. The paper also discusses recent research leading to a novel method of protecting shuttle car operators, in mines as low as 1.02 m (40 in), through the use of a cross-car, end-mounted operator compartment.

Jan 1, 1989

By L. Adler

Existing classifications of mining and construction equipment have had major deficiencies. They often lack organization, balance, and have remained obscure. Particularly when proceeding to great.er resolution these deficiencies have proven crippling. By adopting "Classes", "Groups" f "Types" and "Kinds" at successive degrees of refinement, a "Taxonomy" is developed based on clear visual differentiation or on a "Morphology??. This symbiotic application, adopted from the Biological Sciences, yields clear, simple and unambiguous results. Supporting this effort are guidelines for easily and credibly sketching equipment which are also distinctive. Numerous illustrative examples are provided. Communications are improved and the engineer obtains a confident feel for the equipment at hand.

Jan 1, 1989

By T. Janke

When Homestake Mining Company&apos;s Mclaughlin Gold Project was being evaluated for development, it was apparent that recovery of gold from mined ore would be difficult and relatively expensive. The ore was refractory, averaging less than 50% recovery in conventional direct cyanidation milling tests. Extensive testing narrowed the processing choices to either autoclave or roaster oxidation before cyanidation. Roasting was ruled out due to higher capital and operating costs --the Mclaughlin mill would be the first large-scale application of autoclave oxidation of a refractory gold ore.

Jan 1, 1989

By M. A. Weaver

This paper will investigate the historic and present state of the bituminous coal industry within the Commonwealth of Pennsylvania, with special emphasis on surface mining operations. It will address pertinent parameters such as production, markets, quality, number and size of operations, price, and productivity from a statistical viewpoint. In addition, relevant statistical parameters of select areas of the Appalachian Coal Region will also be presented and discussed.

Jan 1, 1989

By G. M. Wilemon, B. J. Scheiner

The Bureau of Mines conducted investigations on extracting phosphate values from fine-particle wastes generated during the mining and beneficiation of phosphate ore by leaching dried wastes using a H2SO4-methanol mixture. Although phosphatic clay waste contains up to a third of the phosphate originally present in the ore, recovery of these values represents a significant challenge due to the fine grain size of the material, the particles averaging less than one micrometer in diameter. Waste samples obtained from two Florida producers yielded phosphate extractions of 71 and 84 pct, respectively, when leached under ambient conditions and at a stoichiometric acid ratio of 1.4:l. Elevated temperatures did not improve the amount of phosphate extracted. Undesirable A12O3, Fe2O3, and PlgO impurities were largely rejected; higher grade wastes gave acids that meet established industry impurity standards and lower grade samples yielded acids that marginally fell short of the standard. Separation of the crude acids from the insoluble residues was accomplished via vacuum filtration through either filter paper or commercial filter cloths. Both filtration rates and solids retention were improved by the addition of 0.5 lb/ton of poly(viny1 acetate) (PVAc) or poly(ethy1ene oxide) (PEO) to the methanol-acid slurries. These results show potential for substantially increasing the reserves of an important domestic resource.

Jan 1, 1989