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By A. E. Torma

The efficiency of Thiobacillus ferrooxidans in the desulfurization of a high-sulfur content New Mexico coal was demonstrated. The optimum condition of process variables were found to be pH = 2.3, particle size = 38 µm, pulp density 14.1% (W/V) and temperature 33.9°C. Larger scale experiments carried out with these optimum conditions resulted in coal desulfurizations above 97%, while in sterile controls this was only about 10%.- The rate of desulfurization was described with an exponential expression with respect to the effects of coal particle size. The effect of pulp density on coal desulfurization was quantified by a Monod type equation. The apparent activation and deactivation energies, the frequency factor and temperature coefficient were derived from the effects of temperature to be ?aE - 11720 cal mol-1 and A = 30.44 mol dm-3s-lin the range of 20 - 35°C; ?Ed = 43930 cal mol-1 and A = 9.82 x 10-39 mol dm-3s-1 in the range of 35 - 45°C; and Q10 = 1.94 in the range of 20 - 30°C. The thermodynamic values [(?G+, ?H+ and ?S+)] of the activated complex were calculated. The generalized second order regression equation relating the degree of biodesulfurization of coal to the leach parameters was shown to adequately predict coal desulfurization within the range of process variables studied.

Jan 1, 1987

By T. S. Mackey

The industrial types, sources, and quantities of US tin residues are identified and the methods of treatment reviewed. The effect of a lower tin price, due to a current major world surplus of tin metal, is mentioned and covered in some detail. The names and locations of over 100 US firms recovering tin residues are listed. Current smelting and refining charges are included to convert the residues into tin metal and alloy. The impact of the complete with-drawal of the LME daily tin price since Oct. 24, 1985, and the collapse of the International Tin Council, which at one time supported the Buffer Stock Manager, are reported with comments.

Jan 1, 1987

By J. A. King, D. R. Weir, P. C. Robinson

The complex mineralogy of the Porgera resource has a pronounced effect on process selection for the recovery of refractory gold and silver. Intimate association of gold with pyrite necessitates a high degree of sulphur preoxidation to achieve acceptable levels of gold recovery. Acid pressure oxidation has been demonstrated to be the only commercially proven process capable of achieving the required level of pyrite oxidation. Gangue mineralization dictates preconcentration of the sulphides to limit the acid consuming capacity and carbon dioxide generation during oxidation. However, the relationship between concentrate sulphur grade and gold recovery to concentrate ultimately governs the optimum degree of sulphide preconcentration. Minipiloting of the preconcentration and oxidation stages of the Porgera flowsheet are described. The influence of these processes on subsequent recovery of precious metals together with the technical and economic necessity of concentrate pretreatment prior to oxidation are discussed.

Jan 1, 1987

By L. R. Stoiser

The mineral resource potential of the Los Bronces deposit was successfully evaluated by an intense, coordinated field program over a 37-month period (April 1978 - May 1981). This project was part of a much larger study to determine the economic feasibility of expanding the open-pit, mine-mill operation 10-fold to 80 kt/d (88,000 stpd). The resource project included more than 120 km (74 miles) of core drilling and 64 km (40 miles) of drill rig access way construction under adverse topographic and climatic conditions, detailed geological mapping, and other related activities. The Los Bronces deposit is composed of an earlier mineralized porphyry-type body intruded in part by a large complex of mineralized hydrothermal breccia pipes. The mineralization is hosted by intrusive and extrusive igneous rocks. Various stages of erosion, oxidation, leaching, and supergene enrichment of copper are present. Drill hole indicated geologic reserves are estimated at 1.3 Gt (1.4 billion st), averaging 0.81% copper and 0.016% molybdenum at a cutoff grade of 0.6% copper equivalence decreasing to 0.25% over the life of the mine. Trace amounts of silver are also present.

Jan 1, 1987

By W. Trask

The state of the art in crawler transporters for loads to 3 kt (3300 st) is sufficiently advanced to allow compilation of job cost figures showing the economics of tracked vehicle use under a wide variety of circumstances. Initial costs, cost per ton of capacity, and operational and maintenance expenses are presented. Data is derived from participation by the Neil F. Lampson Co. in more than 3 Mt - km (2.05 million st - mile) of crawler operation during the past 16 years. The effects of economics on future design trends will be examined with particular reference to versatility, portability, and capacity.

Jan 1, 1987

By T. Ertekin, R. V. Ramani, W. Sung

The emission of methane in the coal mine working faces has two immediate impacts with regard to coal mine planning. Firstly, at the planning stage, the coal mine ventilation system must be designed such that airflows in the faces keep the concentrations of the gas in faces areas to below one percent. If the concentrations were greater than one percent, the production machine has to be shut down resulting in a loss of productive time. In an extreme case, concentration can reach explosibility limits which may lead to ignitions and explosions. Secondly, in excessively gassy coal seams, several alternatives can be applied to the mine layout configuration, and the mining method to be predicted for the extraction of coal, so as to insure a productive and safe operation. In this study a two-phase, two-dimensional finite-difference model was used to predict the methane emission rates into active mine working area under several methane drainage schemes. The numerical model utilizes a recently developed multi-mechanistic flow theory which describes the flow of methane in an heterogeneous and anisotropic coal seam. Transport of methane in the micropore structure of the coal is described by the Fick's law of dif- fusion under the influence of existing concentration gradient, while flow in the more permeable butt and face cleats (macropore spaces) is formulated by Dar- cy's law under the influence of existing pressure gradient. The desorption of the methane is accounted with the aid of a quasi-steady kinetic sorption model. A series of simulation studies were conducted in a systematic manner by sifting through the parameters associated with the coal seam characteristics and the degasification strategies in order to understand those which most significantly affect the methane emission rates in the face areas during mining. Along these lines, the effects of coal seam properties such as thickness, porosity, permeability, sorption characteristics and scheduling of drainage process against the mining operation have been isolated to understand the role of each individual parameter on the methane emission rates.

Jan 1, 1987

By George J. Dvorznak, Robert W. Waytulonis

The Bureau of Mines is conducting a research project in cooperation with the Mine Safety and Health Administration (MSHA). Mining companies, and equipment manufacturers are also participating through the Colorado Mining Association (CMA). The objectives of this cooperative research project are to determine the practicality of coupling a dry exhaust conditioning system (dry system) and diesel particulate filter (DPF) to make an integrated control system, and to determine the effectiveness and durability of the integrated system in an underground coal mine. Diesel-powered mining machines must be equipped with control devices to reduce surface and exhaust temperatures to safe levels and prevent flames and sparks from being emitted to the mine atmosphere. Diesel exhaust-gas water scrubbers have been successfully used for many years but they have several disadvantages; they are large, consume large quantities of water, and require frequent maintenance to remain functional. Additionally, diesel exhaust is a source of noxious gases and particulate matter. Particulate emissions are composed primarily of small carbon particles with absorbed hydrocarbons and they are almost entirely respirable in size. Even an engine in good mechanical condition can emit up to 400 mg/cu m of respirable particulate matter. A dry system for control of diesel fire and explosion hazards, coupled to a DPF, promises to be a complete control system for diesel engines. The dry system cools the exhaust and suppresses sparks and flame with a heat exchanger and flame and spark traps. The conditioner is smaller, consumes no water, and requires less maintenance than a comparable water scrubber. The DPF uses a ceramic substrate as a wall-flow filter and is very efficient at collecting exhaust particles. Average particulate mass collection efficiency is 90%. This report describes a cooperative research project to combine the dry system with the DPF, conduct performance tests on the integrated system at Bureau and MSHA 1aboratory facilities, and conduct field tests of the system on a production machine in an underground coal mine.

Jan 1, 1987

By S. D. Thompson, J. C. Dzurino

This investigation mainly focused on designing a bunker system for a large underground coal mine. The primary purpose of this bunker system was to keep high- and low-sulfur coal segregated on the underground belt system. These bunkers were also required for protecting the mine faces from out by belt delays. Methodologies used in developing this plan are briefly discussed. The final design and the procedures formulated for implementing it are also presented.

Jan 1, 1987

By G. V. Sullivan, B. E. Davis, T. O. Liewellyn

A technique was devised by the US Bureau of Mines to recover coarse [+1.2-mm (14- mesh)] North Carolina phosphate now discarded as waste. Concentration utilizes the difference in particle sphericity between the relatively flat calcite and the rounded phosphate pebbles. Sizing, treatment in a continuous hydraulic classification system, and grinding upgraded a 17% P,O5 reject to 4.5% P,05 with a phosphate recovery of 63%. The CaO: P2O5 ratio was reduced from 2.49 to 1.66.

Jan 1, 1987

By Earl L. Rau

At the present time, whether an electric utility uses high-sulfur coal is largely determined by geographical location, clean air legislation, and the age of the power plant. Acid rain legislation may well be the new force to change the use of high-sulfur coal. A number of coal papers were presented at the SME Fall Meeting in St. Louis, MO, Sept. 1986. These papers discussed high-sulfur coal in relation to its economics, trends and prospects, value of cleaned coal, and coal-cleaning technology. The Clean Air Act of 1970 required the reduction of SO, emissions from most stationary electric-generating plant to 0.5 kg (1.2 lbs) SO2, per million Btu of heat input. It was possible for many plants to utilize lower-sulfur coal or a mixture of high-sulfur and low-sulfur coal to meet this emission requirement. This 1970 act greatly increased the use of low-sulfur western coal. The 1978 amendment to the Clean Air Act required all new plants to use Flue Gas Desulfurization (FGD) to meet a requirement of 70% reduction of potential SO2 emissions to 0.3 kg (0.6 lb) SO2 per million Btu of heat input. With the requirement to use FGD, there was little or no demand for low-sulfur western coal in new eastern power plants. If' new acid rain legislation is enacted, it likely will require sizeable reductions in SO2, emissions by existing coal users. There might then be a shift to greater use of low-sulfur coals. The low-sulfur coals could come from either western or eastern mines or from cleaned eastern coals. Economics will dictate the approach older power plants will take to meet new regulationsuse FGD or low-sulfur coal. Coal use for electric power generation has changed from 1970 to 1985. Table 1, (Land, preprint 86-333) shows the change. The table shows that in 1985, US utilities used about 255 Mt (280 million st) of high-sulfur coal. Some 45 to 54 Mt (50 to 60 million st) of high-sulfur coal is being used in plants equipped with FGD and most of this use is in eastern states. This leaves 200 to 209 Mt/a (220 to 230 million st) of high-sulfur coal being used without FGD treatment. These plants are at risk if acid rain legislation is passed. Most of these plants are in the east and are more difficult to supply with low-sulfur coal. Estimates range from $20 to $30 billion capital investment and from $5 to $9 billion dollars per year operating costs to reduce SO2, emissions from those old medium-to-high-sulfur coal-burning plants. G. W. Land, (preprint 86-333), also presents tables relating to power generating costs and coal types. The author's tables are extracted from Land's tables IV and V. Table 2 here presents costs for a new plant. This includes the impact of different heat rates, fuel costs, fuel qualities, operating and maintenance costs, labor costs, and waste disposal costs. Table 3 compares estimated costs to retrofit an older plant with a limestone scrubber versus switching the same plant to low-sulfur eastern or western coal. Costs of switching include upgrading the electrostatic precipitator and - with western coal - costs of derating. Bhagwat, (preprint 86-325), details the trends in high-sulfur coal markets from 1974 to 1984. He also gives some prospects for high-sulfur coal markets, 1984 to 1994. The prospect depends mostly on whether acid rain legislation is enacted. By 1994, if New Source Performance Standards (NSPS) continue to be applied, high-sulfur coal demand from six mid-west and eastern states is expected to increase by 27 Mt (30 million st). • L. A. Khan and J. W. Baxter, (preprint 86-373), discuss several coal cleaning technologies such as froth flotation of fines, bulk oil separation and oil agglomeration, oil agglomeration/flotation, and air-floc flotation. ? (Space limitations preclude listing references. A complete list is available from the author.)

Jan 1, 1987

The following errors were inadvertently included in "How millisecond delay periods may enhance or reduce blast vibration effects" by R.M. Wheeler in the September issue of Mining Engineering.

Jan 1, 1987

By S. G. Malghan

This paper reviews uses of sodium sulfide in the flotation of oxide minerals of copper, lead, and zinc. The activation and depression effects of sodium sulfide are of particular importance because of their applications with oxidized lead and copper ores. In spite of its industrial importance, the nature of the heterogeneous reactions between sulfide ions in solution and the surface of oxidized minerals has not been fully understood. Hence, proposed mechanisms of the sulfide action in flotation, methods of measuring and monitoring sodium sulfide in flotation pulps, and variables influencing the sulfide addition are analyzed. Recent studies on sodium sulfide addition to flotation pulps, monitoring its concentration, and the optimum dosage control using platinum and/or sulfide specific ion electrodes are discussed.

Jan 1, 1987

By K. A. Brame, L. G. Austin, R. S. C. Rogers

The breakage parameters of phosphate ore were determined by batch first-ordering grinding studies in a laboratory ball mill according to the Austin, Klimpel, and Luckie procedures. The results were scaled to five larger mills of 0.56, 0.82, 8.36, 4.41, and 5 m in diameter assuming equilibrium ball charges for the full-scale mills. The results were used to predict product size distributions and capacities for batch grinding in the smaller mills and open-circuit grinding in the larger mills. The predicted capacities were in approximate agreement with experimental values except for the 5-m diam mill. The Bond method gave capacity predictions that were 4570 to 150% too high.

Jan 1, 1987

By Dirk van Zyl, Clint Strachan

A study was conducted to assess the feaeibility of increasing the heap height above one lift at the Alligator Ridge Mine. This study concentrated on the physical aspects of the heap and liner performance. Two principle aspects were addressed during this investigation: (a) the adequacy of heap permeability under present and future loading conditions; and (b) the adequacy of the liner to limit seepage losses. Field and laboratory test a were performed and their details and results are presented. It was concluded that the permeability of the heap would remain adequate for higher heap. The geometry of the heap will be the major constraint. It was also concluded that the liner would perform satisfactorily beneath higher heap.

Jan 1, 1987

By A. I. Arol, I. Iwasaki

Clay minerals adversely affect the selective flocculation of iron ores. The effect of montmorillonite on a hematite-quartz mixture was studied. Montmorillonite, particularly in the presence of Ca++, caused indiscriminate dispersion of the pulp. Three possible mechanisms were postulated, namely, card-house structure formation, adsorption of dissolved species from montmorillonite, and montmorillonite- hematite interaction. It was determined that hetero- coagulation of montmorillonite on hematite was responsible for the behavior. Flocculation tests, montmorillonite abstraction tests, starch adsorption tests, zeta potential measurements, and surface analysis techniques were used to ascertain the montmorillonite-hematite interaction and to account for the manner in which it affected selective flocculation.

Jan 1, 1987

By Phoebe L. Hauff, Jeffrey P. Kurtz, Paul D. Chamberlin

Clay minerals can be a source of problems in heap leaching operations. The ore for many heap leach operations is commonly acid-sulfate alteration zone rocks which may be found in hot springs deposits as well as the supergene zone of other near- surface gold deposits. Clays can be important constituents of these ores. Swelling clays, such as smectite, can come loose from the agglomerated ore, migrate within the heap, concentrate in pore spaces and often plug up flow channels in the heap Cement is often added to the ore as a binder during the agglomeration process. Lime is added for pH control. Their presence, combined with the sodium cyanide commonly used to leach, can raise the pH of the leach solution to 10 or even 12. This very alkaline solution can cause dissolution of some mineral Some clays, such as kaolinite, are not very stable in high pH solutions. They can be dissolved and reprecipitated as other clay species if sufficient silica and the appropriate cations are available in solution. Silica gels and amorphous materials can also be created from the dissolved kaolinite and other minerals and act as retardants to the flow of leach solutions in the heap. Therefore, before a heap leach operation is built, the operator should evaluate the clays in the ore and test the agglomeration procedure. It is important to know not only the mineralogy and the chemistry of the leach environment but how the minerals and solutions interact and what the products of this interaction are. A hypothesis is presented in this paper that expanding smectite- bearing clays can be generated within the heap. How and why this happens will be explained.

Jan 1, 1987

By I. Ehie, Y. P. Chugh

Physical mine modeling and computer simulation techniques were used to conduct technical feasibility and economic analyses of selected pit configurations for surface mining a single coal seam dipping at about 15% to a maximum depth of 46 m (150 ft). Pit orientations along the true dip (dipline), along the strike (strikeline), and along an apparent dip were studied. Physical models of each pit configuration were prepared first to delineate potential operational problem areas and also to furnish data for the computer simulation models. A dragline microsimulation, a shovel/truck simulation, and a surface mine cost analysis models were used to conduct the study. Sensitivity analyses were conducted on variables such as the pit width, block length, and seam pitch. The productivity (m3/h) of the mining equipment (dragline or stripping shovel) under each set of conditions was used to optimize the pit configuration. Both block length and panel width were found to significantly affect the dragline productivity. Larger size trucks were preferable to smaller size trucks in the pit con¬figuration along an apparent dip. The cost analysis results showed that the pit configuration along the seam dip was more economical than the pit along the strike or along an apparent dip for the mining condition studied.

Jan 1, 1987

By J. Bartrum, A. Bowler, G. Butcher

The purpose of this paper is to outline the design, specification, and operation of the 8.5-m- diam (28-ft-diam) SAG mill commissioned at Kidston Gold Mines during January 1985. Amenability of Kidston ore to SAG milling, coupled with substantial cost advantages, led to the specification of this mill, equipped with variable speed drive to overcome the large variation in ore hardness. Operation of the mill is effected via a number of automatic control loops. Problems experienced with automatic control plus other electrical and mechanical failures have led to design changes and the formulation of future operating strategies.

Jan 1, 1987

By D. S. Holmes

Biological processes for metal solubilization and ore beneficiation are in widespread use today. There are also some promising new applications of biotechnology in the areas of metal concentration and toxic metal cleanup. Recent progress in genetic engineering promises both to revolutionize the existing biological process and to expedite the adoption of the new biological applications. But before it can do so effectively, progress must be made in many areas of fundamental research and in biochemical engineering. These issues are addressed with special reference to the biotechnology of semi-enclosed containers (bioreactors), dumps, heaps, in situ and under- ground leaching, and with respect to the biotechnology of metal concentration. Finally, certain biological considerations for bacterial strain improvement are discussed.

Jan 1, 1987

By B. H. Richard, P. J. Wolfe, T. G. Holdeman

Guided seismic wave propagation was studied in the Lower Freeport (6A) coal seam in the Oak Park No. 7 mine near Cadiz, OH. Three component geophones were implanted in the coal at distances ranging from 72 m to 183 m from the seismic source. Both Love- and Rayleigh-type modes were observed but the Love-type mode produced the best data. Detailed analysis was performed on the best Love data and a Dziewonski map of group velocity vs. frequency was constructed. This map was in excellent agreement with a theoretical dispersion curve calculated for a model of the coal seam. The Love wave group velocity was found to have a minimum value of 510 m/sec at 275 Hz. Only the fundamental mode contributed significantly to the observed signal and it was observed up to the maximum distance available.

Jan 1, 1987